Hydrogen Deficiency Research Articles

Non-thermal emission in M31 and M33

Context. Spiral galaxies M31 and M33 are among the γ-ray sources detected by the Fermi Large Area Telescope (LAT). Aims. We aim to model the broadband non-thermal emission of the central region of M31 (a LAT point source) and of the disk of M33 (a LAT extended source), as part of our continued survey of non-thermal properties of local galaxies that includes the Magellanic Clouds. Methods. We analysed the observed emission from the central region of M31 (R < 5.5 kpc) and the disk-sized emission from M33 (R ∼ 9 kpc). For each galaxy, we self-consistently modelled the broadband spectral energy distribution of the diffuse non-thermal emission based on published radio and γ-ray data. All relevant radiative processes involving relativistic and thermal electrons (synchrotron, Compton scattering, bremsstrahlung, and free–free emission and absorption), along with relativistic protons (π0 decay following interaction with thermal protons), were considered, using exact emissivity formulae. We also used the Fermi-LAT-validated γ-ray emissivities for pulsars. Results. Joint spectral analyses of the emission from the central region of M31 and the extended disk of M33 indicate that the radio emission is composed of both primary and secondary electron synchrotron and thermal bremsstrahlung, whereas the γ-ray emission may be explained as a combination of diffuse pionic, pulsar, and nuclear-BH-related emissions in M31 and plain diffuse pionic emission (with an average proton energy density of 0.5 eV cm−3) in M33. Conclusions. The observed γ-ray emission from M33 appears to be mainly hadronic. This situation is similar to other local galaxies, namely, the Magellanic Clouds. In contrast, we have found suggestions of a more complex situation in the central region of M31, whose emission could be an admixture of pulsar emission and hadronic emission, with the latter possibly originating from both the disk and the vicinity of the nuclear black hole. The alternative modelling of the spectra of M31 and M33 is motivated by the different hydrogen distribution in the two galaxies: The hydrogen deficiency in the central region of M31 partially unveils emissions from the nuclear BH and the pulsar population in the bulge and inner disk. If this were to be the case in M33 as well, these emissions would be outshined by diffuse pionic emission originating within the flat central-peak gas distribution in M33.

Enhancing the Startup Rate of Microbial Methanogenic Systems through the Synergy of β-lactam Antibiotics and Electrolytic Cells.

The slow startup and suboptimal efficiency of microbial carbon sequestration and methane-production systems have not been fully resolved despite their contribution to sustainable energy production and the reduction of greenhouse gas emissions. These systems often grapple with persistent hurdles, including interference from miscellaneous bacteria and the slow enrichment of methanogens. To address these issues, this paper examines the synergistic effect of coupling β-lactam antibiotics with an electrolytic cell on the methanogenic process. The results indicated that β-lactam antibiotics exhibited inhibitory effects on Campylobacteria and Alphaproteobacteria (two types of miscellaneous bacteria), reducing their relative abundance by 53.03% and 87.78%, respectively. Nevertheless, it also resulted in a decrease in hydrogenogens and hindered the CO2 reduction pathway. When coupled with an electrolytic cell, sufficient electrons were supplied for CO2 reduction to compensate for the hydrogen deficiency, effectively mitigating the side effects of antibiotics. Consequently, a substantial improvement in methane production was observed, reaching 0.57 mL·L-1·d-1, exemplifying a remarkable 6.3-fold increase over the control group. This discovery reinforces the efficiency of methanogen enrichment and enhances methane-production levels.

White Dwarf Photospheric Abundances in Cataclysmic Variables. III. Five Dwarf Novae with an Evolved Secondary Donor Star* * Based on observations made with the NASA/ESA Hubble Space Telescope, obtained from the data archive at the Space Telescope Science Institute. STScI is operated by the Association of University for Research in Astronomy, Inc., under NASA contract NAS 5-26555.

In the last two decades infrared spectroscopy has brought mounting evidence, in the form of weak CO features together with enhanced 13C, of the presence of CNO-processed material in the atmosphere of the donor star of some nonmagnetic cataclysmic variables. Some of these donors also exhibit a temperature too high for their binary orbital period, indicating that they evolved off the main sequence before mass transfer began. The ultraviolet spectra of evolved donor systems exhibit strong N v (λ1240) and the almost complete absence of C iv (λ1550) emission lines. We present here an archival Hubble Space Telescope ultraviolet spectral analysis of five systems containing an evolved donor star. We derive their white dwarf masses, effective temperatures, and photospheric chemical abundances. The [N/C] ratio is very large, of the order 102–103 (in solar units) for the short-period systems V485 Cen, GZ Cet, and QZ Ser, and of the order 20 for the longer-period systems HS 0218 and EY Cyg. Silicon ([S/H]) is solar for GZ Cet and QZ Ser, suprasolar for V485 Cen, and subsolar for HS 0218 and EY Cyg. We also derive abundances of O, Mg, Al, Si, P, S, Ca, and Fe, which vary from system to system. The abundances we derived are consistent with the more evolved nature of the donor star (metal enriched, hydrogen depleted). It is impossible to confirm hydrogen deficiency for these systems, since at these wavelengths (1100–2000 Å) white dwarf spectra show little dependency on the [He/H] ratio, unless it is extremely large ([He/H] ≫ 1).

Automated method using direct-immersion solid-phase microextraction and on-fiber derivatization coupled with comprehensive two-dimensional gas chromatography high-resolution mass spectrometry for profiling naphthenic acids in produced water

Naphthenic acids (NAs) are naturally occurring organic acids in petroleum and are found in waste waters generated during oil production (produced water, PW). Profiling this class of compounds is important due to flow assurance during oil exploration. Compositional analysis of PW is also relevant for waste treatment to reduce negative impacts on the environment. Here, comprehensive two-dimensional gas chromatography coupled with high-resolution mass spectrometry (GC×GC–HRMS) was applied as an ideal platform for qualitative analysis of NAs by combining the high peak capacity of the composite system with automated scripts for group-type identification based on accurate mass measurements and fragmentation patterns. To achieve high-throughput profiling of NAs in PW samples, direct-immersion solid phase microextraction (DI-SPME) was selected for extraction, derivatization and preconcentration. A fully automated DI-SPME method was developed to combine extraction, fiber rinsing and drying, and on-fiber derivatization with N-methyl-N‑tert-butyldimethylsilyltrifluoroacetamide (MTBSTFA). Data processing was based on filtering scripts using the Computer Language for Identifying Chemicals (CLIC). The method successfully identified up to 94 NAs comprising carbon numbers between 6 and 18 and hydrogen deficiency values ranging from 0 to -4. The proposed method demonstrated wider extraction coverage compared to traditional liquid-liquid extraction (LLE) – a critical factor for petroleomic investigations. The method developed also enabled quantitative analysis, exhibiting detection limits of 0.5 ng L−1 and relative standard deviation (RSD) at a concentration of NAs of 30 µg L−1 ranging from 4.5 to 25.0%.

Enhancing Voltage Reversal Tolerance of Proton Exchange Membrane Fuel Cells by Tuning the Microstructure of IrOx Catalysts.

Voltage reversal of proton exchange membrane fuel cells caused by hydrogen deficiency seriously deteriorates the anodes and lowers their performance and lifetime. A commonly used method is to add oxygen evolution reaction catalysts (e.g., IrO2) to the anode to extend the water electrolysis plateau against harmful carbon corrosion. Herein, strongly connected IrOx nanoparticles (SC-IrOx) are prepared by removing the low surface area carbon carrier of the as-synthesized Ir/C catalyst. The reversal-tolerant anode with SC-IrOx owns an anti-reversal time of 9.32 h, which is 3.2 and 4.4 times that of the reversal-tolerant anode with commercial IrOx and weakly connected IrOx, respectively. Further transmission electron microscope characterizations reveal that SC-IrOx can construct a stable electron and proton transport pathway in the anode catalyst layer, which can delay the isolation of oxygen evolution reaction catalyst from the electron and proton conducting network, thus extending the water electrolysis plateau. Herein, our findings suggest that tuning the microstructures of IrOx catalysts is indeed an effective and promising approach to extend the water electrolysis plateau and alleviate the performance degradation of proton exchange membrane fuel cells during the voltage reversal process.

Ups!... I did it again: unveiling the hidden companion in Upsilon Sagittarii, a unique binary system at a second mass transfer stage

ABSTRACT Upsilon Sagittarii is a hydrogen-deficient binary that has been suggested to be in its second stage of mass transfer, after the primary has expanded to become a helium supergiant following core helium exhaustion. A tentative identification of the faint companion in the ultraviolet led to mass estimates of both components that made the helium star in Upsilon Sagittarii a prototypical immediate progenitor of a type Ib/c supernova. However, no consistent model for the complex spectrum has been achieved, casting doubt on this interpretation. In this study, we provide for the first time a composite spectral model that fits the ultraviolet data, and clearly identifies the companion as a rapidly rotating, slowly moving $\approx 7\, \mathrm{M}_\odot$ B-type star, unlike previously suggested. The stripped helium supergiant is less luminous than previous estimates, and with an estimated mass of $\lt 1\, \mathrm{M}_\odot$ is ruled out as a core-collapse supernova progenitor. We provide a detailed binary evolution scenario that explains the temperature and luminosity of the two components as well as the very low gravity (log g ≈ 1) and extreme hydrogen deficiency of the primary (atmospheric mass fraction XH, 1 ≈ 0.001). The best-fitting model is an intermediate-mass primary ($M_\mathrm{ZAMS,1} \approx 5\, \mathrm{M}_\odot$) with an initial orbital period of a few days, and a secondary that appears to have gained a significant amount of mass despite its high rotation. We conclude that Upsilon Sagittarii is a key system for testing binary evolution processes, especially envelope stripping and mass accretion.

Vanadium and nickel distributions in selective-separated n-heptane asphaltenes of heavy crude oils

Understanding vanadium and nickel distributions in asphaltene fractions have significant commercial importance throughout the petroleum value chain and the potential use of heavy feedstocks as a precursor of carbon-based materials, such as carbon fibers. This work extends our previous studies and aims to characterize volatile and non-volatile vanadium and nickel distributions by selective separation of n-heptane asphaltenes obtained from two Venezuelan heavy crude oils and the NIST Standard Reference Material (SRM) 8505. Asphaltenes were separated by extrography, i.e., adsorption on SiO2 and subsequent extraction with acetone, heptol (n-heptane/toluene 1:1 vol), and a mixture of toluene, THF, and methanol (TTM). The results suggest that their solubility and aggregation strongly correlate to a higher hydrogen deficiency and increased heteroatom levels. The qualitative analysis of the spent silica gel, containing irreversibly-adsorbed asphaltenes, by Light-Induced Breakdown Spectroscopy, suggests that regardless of the solvent power used during the extraction, strong chemisorbed Ni and V species remain on the SiO2, presumable associated with porphyrin molecules present on such feeds. High-Temperature Gas Chromatography coupled with Inductively Coupled Plasma Mass Spectrometry (HTGC-ICP-MS) showed that vanadium and nickel compounds have boiling points starting at 1050 °F. Quantification of the V-content below 1300 °F for the Venezuelan crude 1 indicated that the acetone fraction contains a large amount of distillable vanadium (∼62 %wt.). Interestingly, whole/unfractionated asphaltenes revealed only 47% of distillable vanadium, which suggests that the extrography method can obtain asphaltene fractions with “improved” properties (weaker aggregation, increased solubility, and lower boiling points). The characterization by atmospheric pressure photoionization Fourier Transform ion cyclotron resonance mass spectrometry (APPI FT-ICR MS) and HTGC-ICP-MS revealed that the acetone asphaltene fractions have a higher relative abundance of vanadyl porphyrins (with and without sulfur) than heptol and TTM.

Pulsating hydrogen-deficient white dwarfs and pre-white dwarfs observed with TESS

Context. The Transiting Exoplanet Survey Satellite (TESS) mission is revolutionizing the blossoming area of asteroseismology, particularly of pulsating white dwarfs and pre-white dwarfs, thus continuing the impulse of its predecessor, the Kepler mission. Aims. In this paper, we present the observations from the extended TESS mission in both 120 s short-cadence and 20 s ultra-short-cadence mode of two pre-white dwarf stars showing hydrogen deficiency. We identify them as two new GW Vir stars, TIC 333432673 and TIC 095332541. We apply the tools of asteroseismology with the aim of deriving their structural parameters and seismological distances. Methods. We carried out a spectroscopic analysis and a spectral fitting of TIC 333432673 and TIC 095332541. We also processed and analyzed the high-precision TESS photometric light curves of the two target stars, and derived their oscillation frequencies. We performed an asteroseismological analysis of these stars on the basis of PG 1159 evolutionary models that take into account the complete evolution of the progenitor stars. We searched for patterns of uniform period spacings in order to constrain the stellar mass of the stars. We employed the individual observed periods to search for a representative seismological model. Results. The analysis of the TESS light curves of TIC 333432673 and TIC 095332541 reveals the presence of several oscillations with periods ranging from 350 to 500 s associated to typical gravity (g)-modes. From follow-up ground-based spectroscopy, we find that both stars have a similar effective temperature (Teff = 120 000 ± 10 000 K) and surface gravity (log g = 7.5 ± 0.5), but a different He/C composition of their atmosphere. On the basis of PG 1159 evolutionary tracks, we derived a spectroscopic mass of M⋆ = 0.58−0.08+0.16 M⊙ for both stars. Our asteroseismological analysis of TIC 333432673 allowed us to find a constant period spacing compatible with a stellar mass M⋆ ∼ 0.60 − 0.61 M⊙, and an asteroseismological model for this star with a stellar mass M⋆ = 0.589 ± 0.020 M⊙, as well as a seismological distance of d = 459−156+188 pc. For this star, we find an excellent agreement between the different methods to infer the stellar mass, and also between the seismological distance and that measured with Gaia (dGaia = 389−5.2+5.6 pc). For TIC 095332541, we have found a possible period spacing that suggests a stellar mass of M⋆ ∼ 0.55 − 0.57 M⊙. Unfortunately, we have not been able to find an asteroseismological model for this star. Conclusions. Using the high-quality data collected by the TESS space mission and follow-up spectroscopy, we have been able to discover and characterize two new GW Vir stars. The TESS mission is having, and will continue to have, an unprecedented impact on the area of white-dwarf asteroseismology.

Theoretical study on the formation of diamond germanium vacancy color center

Germanium-vacancy (GeV) color centers in diamond are superior to other color centers in terms of luminescence intensity. The Ge-doping process is key to the successful preparation of GeV color centers in diamond. In this study, the formation mechanism of GeV color centers is explored via first-principles calculations of the adsorption and migration of Ge on the (001) surface of diamond. The results reveal that Ge atoms on the surface of completely hydrogenated diamond have a negative adsorption energy, indicating that they cannot be adsorbed. In contrast, the adsorption energy of Ge atoms on the surface of non-perhydrogenated diamond is relatively large, which indicates that the surface of non-perhydrogenated diamond can adsorb Ge atoms. When Ge atoms are closer to hydrogen defects, their adsorption energy is greater. As the extent of hydrogen deficiency increases, the overall adsorption energy increases accordingly. The hydrogen deficiency of the diamond surface may determine the extent of the Ge content on the diamond surface. Magnetic moment, differential charge, and Bader analyses reveal that charge is transferred between Ge and carbon atoms on the diamond surface. In addition, the Ge and carbon atoms form covalent bonds at positions where the adsorption energy is maximum. Finally, the migration of Ge atoms on the diamond surface enables them to reach a stable position easily.

Influence of Naphthenic Hydrocarbons and Polar Solvents on the Composition and Structure of Heavy-Oil Aquathermolysis Products

Estimates of the conventional proven hydrocarbon reserves show a tendency toward depletion, and in the near future they will be insufficient to meet the ever-growing global energy demand. The problem of crude oil deficiency can be solved by involving unconventional hydrocarbon resources in both recovery and refinery. However, the hydrogen deficiency of heavy oil and natural bitumen requires technical and technological solutions. Therefore, the hydrogen-donating capacity of water and solvents, particularly in reservoir conditions, is very attractive. In this paper, we study the hydrogen-donating capacity of naphthenic and polar solvents during hydrothermal treatment of heavy oil from Ashal’cha reservoir (Republic of Tatarstan, Russia). It was established that naphthenic solvents significantly influence the viscosity reduction due to the destructive hydrogenation of resins and asphaltenes. Among naphthenic solvents, decalin significantly increases the amount of evolved gases, particularly C4–C10 isomers and aromatics. However, the maximum evolved gases among all of the used solvents correspond to formic acid. The results of elemental analysis revealed that the H/C ratio rises in crude oil samples after hydrothermal treatment in the presence of cyclohexane and decalin. FT-IR spectral indices revealed an increase in crude oil aliphaticity in case of using solvents from the cyclohexane–tetralin–decalin series due to the cleavage of carbon–heteroatom bonds in aliphatic substitutes of resins and asphaltenes. Significant changes in the FT-IR spectra of crude oil are observed in the presence of tetralin.

Combustion kinetics of alternative jet fuels, Part-I: Experimental flow reactor study

A comprehensive collection of technical aviation fuels enabled an experimental and numerical study on detailed combustion chemistry and pollutant formation presented in a series of 3 interlinking parts. Part-I: Experimental Flow Reactor Study focuses on the characterization of 42 technical jet fuels and provides experimental speciation data for model development presented in Part-II: Model and Surrogate Strategy. Model validation based on the presented technical fuels here is presented in Part-III: Model Application on Technical Jet Fuels.The fuels investigated in this study cover a broad range of approved SAFs (Sustainable Aviation Fuels), candidates for approval, and technical products outside the present ASTM-D7566 specification and is completed by reference fuels (ASTM-D1655). This includes SAF components such as HEFA (Hydroprocessed Esters and Fatty Acids), ATJ (Alcohol-To-Jet), SIP (Synthesized Iso-Paraffins), and Fischer-Tropsch-products as well as their blends.A systematic investigation of the soot precursor chemistry by analyzing the influence of the complex chemical fuel composition on the intermediate species pool is presented. The experimental set-up consists of an atmospheric flow reactor with coupled molecular-beam mass spectrometer (MBMS). Quantitative evolution of combustion reaction intermediates is recorded for fuel-rich (Φ = 1.2) and fuel-lean (Φ = 0.8) conditions at intermediate temperatures up to 1200 K including small intermediate species (e.g. ethylene, butene) and soot precursor species (e.g. benzene, naphthalene, phenanthrene).A general systematic dependency of the soot precursor concentration on the degree of unsaturation (Index of Hydrogen Deficiency) or the hydrogen content, respectively, is demonstrated. Furthermore, larger soot precursor concentrations depend on the naphthalene content of the fuel.

Lipid Remodeling in the Mitochondria upon Ageing during the Long-Lasting Cultivation of Endomyces magnusii

In this study, we used Endomyces magnusii yeast with a complete respiratory chain and well-developed mitochondria system. This system is similar to the animal one which makes the yeast species an excellent model for studying ageing mechanisms. Mitochondria membranes play a vital role in the metabolic processes in a yeast cell. Mitochondria participate in the metabolism of several pivotal compounds including fatty acids (FAs) metabolism. The mitochondria respiratory activity, the membrane and storage lipids composition, and morphological changes in the culture during the long-lasting cultivation (for 168 h) were under investigation. High metabolic activity of E. magnusii might be related to the active function of mitochondria increasing in the 96- and 168-h growth phases. Cardiolipin (CL), phosphatidylethanolamine (PE), phosphatidylcholine (PC), and sterols (St) were dominant in the membrane lipids. The St and sphingolipids (SL) shares increased by a lot, whereas the CL and phosphatidylinositol (PI) + PE ones decreased in the membrane lipids. This was the main change in the membrane lipid composition during the cultivation. In contrast, the amount of PE and phosphatidylserine (PS) did not change. Index of Hydrogen Deficiency (IHD) of phospholipids (PL) FAs significantly declined due to a decrease in the linoleic acid share and an increase in the amount of palmitic and oleic acid. There were some storage lipids in the mitochondria where free fatty acids (FFAs) (73–99% of the total) dominated, reaching the highest level in the 96-h phase. Thus, we can conclude that upon long-lasting cultivation, for the yeast assimilating an “oxidative” substrate, the following factors are of great importance in keeping longevity: (1) a decrease in the IHD reduces double bonds and the peroxidation indices of various lipid classes; (2) the amount of long-chain FFAs declines. Moreover, the factor list providing a long lifespan should include some other physiological features in the yeast cell. The alternative oxidase activity induced in the early stationary growth phase and high mitochondria activity maintains intensive oxygen consumption. It determines the ATP production and physiological doses of reactive oxygen species (ROS), which could be regarded as a trend favoring the increased longevity.

Proton exchange membrane fuel cell multi-stack parallel gas supply and load-up experiment

Given the current situation that there is no parallel experiment of multiple stacks in China, this paper uses a fuel cell test platform independently designed and produced by a company to study the performance of three fuel cells. This article describes the construction of the experimental test platform and the multi-stack load-up experiment. The experimental results show that the power generation of the three fuel cells is almost the same, which are 9475W, 9385W, and 9512W. When carrying out multi-stack load-up experiments, it was found that as the number of stacks increased, the voltage efficiency continued to decrease. The Analysis revealed that the parallel gas supply method caused uneven gas distribution, which caused some fuel cells to be in a state of hydrogen deficiency. This article proposes amendments to this problem.

Vanadium and nickel distributions in Pentane, In-between C5-C7 Asphaltenes, and heptane asphaltenes of heavy crude oils

After selective solvent extraction, the volatile and non-volatile vanadium and nickel distributions for two Venezuelan heavy crude oils and the NIST Standard Reference Material SRM 8505 were determined for the Entrained n-pentane (C5) maltenes, In-between C5-C7 asphaltenes, and n-heptane asphaltenes. The fractions were analyzed via the asphaltene solubility profile, size exclusion chromatography (SEC), High-Temperature Gas Chromatography coupled with Inductively Coupled Plasma Mass Spectrometry (HTGC-ICP-MS), and atmospheric pressure photoionization Fourier-transform ion cyclotron resonance mass spectrometry (APPI FT-ICR MS). Results showed that petroleum elution is strongly correlated to high hydrogen deficiency and increased heteroatom levels. The solubility decreased in the following order: Entrained C5 Maltenes, In-between C5-C7 asphaltenes, and C7 asphaltenes. Qualitative HTGC-ICP-MS shows that 51V traces of the first two asphaltene fractions showed a bimodal (Venezuelan crude oil 1 and NIST SRM 8505) or a multimodal distribution (Venezuelan crude oil 2). On the other hand, the 51V signal intensities for C7 asphaltenes were the lowest among all samples studied. FT-ICR MS revealed that the chemistry of vanadyl and nickel porphyrins is multimodal in terms of DBE. N4O1V1 and N4O2V1 classes exhibited abundant homologous series with DBE values of ≤22; when sulfur was incorporated, e.g., N4O1S1V1 class, the DBE increased by 4–6 units. Ni-containing porphyrins showed two major homologous series, pointing toward a bimodal chemical nature. We hypothesized that this compositional feature could be why the bimodal and multimodal distributions of boiling points were found in the studied heavy crude oil fractions.

Investigation of the sooting propensity of aviation fuel mixtures

Aromatic compounds occurring naturally in jet fuels are precursors for the formation of soot in the exhaust gas of jet engines. Directly emitted in cruising altitude, soot particles lead to the formation of contrails and clouds influencing the radiation balance of the atmosphere. Hence, a detailed knowledge on the effect of aromatics on the sooting behavior is of great importance, especially for the development of alternative synthetic jet fuels. Investigations on the sooting propensity influenced by the molecular structure and concentration of diverse aromatic compounds contained in synthetic and fossil aviation fuels as well as blends of synthetic paraffinic kerosene (SPK) with aromatic compounds (SKA) were carried out experimentally. Using a predefined SPK fuel, five different blends—each containing a single aromatic compound—were prepared in addition to one blend with a typical composition consisting of all these aromatic compounds. In subsequent measurements, the concentration of the aromatics was increased from initially 8.0 vol%, to about 16.5, and 25.0 vol%. The aromatics added were toluene, n­-propylbenzene, indane, 1­methylnaphthalene, and biphenyl. The studied jet fuels include fossil-based Jet A-1 as well as different synthetic jet fuels (with and without aromatics). Furthermore, the experimental results of the sooting propensity are compared with the results of the hydrogen deficiency model being a measure for the amount of cyclic and unsaturated molecular structures occurring in a hydrocarbon fuel. This study shows the hydrogen deficiency as a useful tool to make predictions about the sooting behavior of different fuels compared to a reference fuel at a specified condition. Additionally, it is observed from the measured sooting propensities as well as from the model predictions of hydrogen deficiency that the structure of aromatic compounds presents greater influence on the soot formation than the aromatic concentration.

Sooting characteristics of hydrocarbon compounds and their blends relevant to aviation fuel applications

The sooting characteristics of neat hydrocarbon compounds from different molecular classes and their blends that are relevant to aviation fuels were systematically investigated in the present work. Smoke points and maximum soot volume fractions of 10 neat hydrocarbon compounds and 33 binary fuel blends were measured in a standard wick-fed flame burner. The threshold sooting indices of test fuels were derived based on the fuel uptake flow rate with threshold imaging method. At the smoke point conditions, flames of all test fuels were noted to have relatively close maximum soot volume fractions, thereby suggesting that the maximum soot concentration contained by a diffusion flame without escaping smoke is relatively insensitive to the effects of fuel molecular structure. At the constant fuel carbon flow rate conditions, it was found that the soot formation generally follows: naphthalenes > monocyclic aromatics > cycloalkanes >iso-alkanes >n-alkanes. The relationships between soot formation and various sooting tendency indices were further examined. For given constituents, their binary blend result at varying blending ratio showed that the maximum soot volume fraction can be approximately linearly correlated with aromatics content, hydrogen content, hydrogen deficiency, and threshold sooting index; the slope varies with different blends. At a given constant fuel carbon flow rate, the results of all test fuels demonstrated that the reciprocal of smoke point is able to correlate linearly with the maximum soot volume fraction through a single curve. Therefore, the present findings indicated that smoke point is more effective even than threshold sooting index in predicting soot formation in diffusion flames.

Poisoning of Ammonia Synthesis Catalyst Considering Off-Design Feed Compositions

Activity of ammonia synthesis catalyst in the Haber-Bosch process is studied for the case of feeding the process with intermittent and impurity containing hydrogen stream from water electrolysis. Hydrogen deficiency due to low availability of renewable energy is offset by increased flow rate of nitrogen, argon, or ammonia, leading to off-design operation of the Haber-Bosch process. Catalyst poisoning by ppm levels of water and oxygen is considered as the main deactivation mechanism and is evaluated with a microkinetic model. Simulation results show that catalyst activity changes considerably with feed gas composition, even at exceptionally low water contents below 10ppm. A decreased hydrogen content always leads to lower poisoning of the catalyst. It is shown that ammonia offers less flexibility to the operation of Haber-Bosch process under fluctuating hydrogen production compared to nitrogen and argon. Transient and significant changes of catalyst activity are expected in electrolysis coupled Haber-Bosch process.

H i deficiencies and asymmetries in HIPASS galaxies

ABSTRACT We present an analysis of the sky distribution of neutral hydrogen (H i) deficiency and spectral asymmetry for galaxies detected by the H i Parkes All-Sky Survey (HIPASS) as a function of projected environment density. Previous studies of galaxy H i deficiency using HIPASS were sensitive to galaxies that are extremely H i rich or poor. We use an updated binning statistic for measuring the global sky distribution of H i deficiency that is sensitive to the average deficiencies. Our analysis confirms the result from previous studies that galaxies residing in denser environments, such as Virgo, are on average more H i deficient than galaxies at lower densities. However, many other individual groups and clusters are not found to be on average significantly H i poor, in contradiction to previous work. In terms of H i spectral asymmetries, we do not recover any significant trend of increasing asymmetry with environment density as found for other galaxy samples. We also investigate the correlation between H i asymmetry and deficiency, but find no variation in the mean asymmetry of galaxies that are H i rich, normal, or poor. This indicates that there is either no dependence of asymmetry on H i deficiency, or a galaxy’s H i deficiency only has a small influence on the measured H i asymmetry that we are unable to observe using only integrated spectra.

Carbon corrosion: A novel termination mechanism of the water electrolysis plateau during voltage reversal

Although the mechanism of the voltage reversal process due to overall hydrogen deficiency is clear, the termination mechanism of the water electrolysis plateau (WEP) is still very controversial. In this work, for the first time, the termination mechanism of the WEP is analyzed by synchronously detecting the internal resistance (IR) change in the process of the voltage reversal. The results show that in the WEP, the IR of the cell increases slowly, but increases sharply once the plateau is finished. The IR-corrected voltages have directly indicated that the termination of the WEP is mainly due to a significant increase in cell IR resulting from carbon corrosion, rather than commonly believed OER (oxygen evolution reaction) catalyst deactivation and lack of water inside the cell. Remarkably, the IR at the end of the WEP is about 180 mΩ cm2, which is independent of anode gas relative humidity, IrO2 loading, and carbon support type. Besides, the performance of the cell damaged by voltage reversal is partly recoverable, which may be due to the rehydration of the proton exchange membrane and the reestablishment of the charge and gas transport channel during the reactivation process.

Biomass Pyrolysis Technology by Catalytic Fast Pyrolysis, Catalytic Co-Pyrolysis and Microwave-Assisted Pyrolysis: A Review

With the aggravation of the energy crisis and environmental problems, biomass resource, as a renewable carbon resource, has received great attention. Catalytic fast pyrolysis (CFP) is a promising technology, which can convert solid biomass into high value liquid fuel, bio-char and syngas. Catalyst plays a vital role in the rapid pyrolysis, which can increase the yield and selectivity of aromatics and other products in bio-oil. In this paper, the traditional zeolite catalysts and metal modified zeolite catalysts used in CFP are summarized. The influence of the catalysts on the yield and selectivity of the product obtained from pyrolysis was discussed. The deactivation and regeneration of the catalyst were discussed. Catalytic co-pyrolysis (CCP) and microwave-assisted pyrolysis (MAP) are new technologies developed in traditional pyrolysis technology. CCP improves the problem of hydrogen deficiency in the biomass pyrolysis process and raises the yield and character of pyrolysis products, through the co-feeding of biomass and hydrogen-rich substances. The pyrolysis reactions of biomass and polymers (plastics and waste tires) in CCP were reviewed to obtain the influence of co-pyrolysis on composition and selectivity of pyrolysis products. The catalytic mechanism of the catalyst in CCP and the reaction path of the product are described, which is very important to improve the understanding of co-pyrolysis technology. In addition, the effects of biomass pretreatment, microwave adsorbent, catalyst and other reaction conditions on the pyrolysis products of MAP were reviewed, and the application of MAP in the preparation of high value-added biofuels, activated carbon and syngas was introduced.