This study studies the problem of synchronisation control for spacecraft formation via extended state observer approach over directed communication topology. The attitude kinematics and dynamics of spacecraft are described by Lagrangian formulations, and the decentralised controller is designed with time-varying external disturbances and unmeasurable velocity information. In particular, the estimation of disturbances obtained via extended state observer is used for the decentralised controller design. A novel Lyapunov function is proposed to show that both static regulation and dynamic synchronisation are realised. Finally, simulation results are given to demonstrate the effectiveness of the controllers proposed in this study.