Decay Spectra Research Articles

Inducing molecular orientation in solution-processed thin films of fluorene-bithiophene-based copolymer: thermal annealing vs. solvent additive.

A deep understanding of the factors influencing the morphology of thin films based on conjugated polymers is essential to boost their performance in optoelectronic devices. Herein, we investigated the electronic structure and morphology of thin films of the copolymer poly(9,9-dioctyl-fluorenyl-co-bithiophene) (F8T2) in its pristine form as well as samples processed with the solvent additive 1,8-diiodooctane (DIO) or post-processed through thermal annealing treatment. Measurements were carried out using angle-resolved S K-edge NEXAFS (near-edge X-ray absorption fine structure) in total electron yield (TEY) and fluorescence yield (FY) detection modes. Two main transitions were observed at the S 1s NEXAFS spectra: S 1s → π* and S 1s → σ* (S-C). The observed dichroism pointed to a face-on orientation of the conjugated backbone, which was significantly increased for F8T2 films processed with DIO. Resonant Auger decay spectra were obtained and analyzed using the core-hole clock (CHC) method. An enhancement in the charge transfer process was observed for thermally annealed films, especially for samples processed with DIO, corresponding to an increase in film ordering. Furthermore, the investigated films were characterized using X-ray photoelectron spectroscopy, attesting to the presence of the thiophene unit in the samples and demonstrating that some of its sulfur atoms were positively polarized in the F8T2 films. All these experimental findings were compared with molecular dynamics (MD) simulations of film evaporation with and without DIO. The use of MD, together with mathematical modeling, was able to explain the major effects found in the experiments, including the polarization of sulfur atoms. The simultaneous use of powerful spectroscopic techniques and theoretical methods shed light on key aspects linking film morphology with fabrication procedures.

Lipidomic Profile of Human Sperm Membrane Identifies a Clustering of Lipids Associated with Semen Quality and Function.

Reduced sperm motility and/or count are among the major causes of reduced fertility in men, and sperm membranes play an important role in the spermatogenesis and fertilization processes. However, the impact of sperm lipid composition on male fertility remains under-investigated. The aim of the present study was to perform a lipidomic analysis of human sperm membranes: we performed an untargeted analysis of membrane lipid composition in fertile (N = 33) and infertile subjects (N = 29). In parallel, we evaluated their serum lipid levels. Twenty-one lipids were identified by their mass/charge ratio and post-source decay spectra. Sulfogalactosylglycerolipid (SGG, seminolipid) was the most abundant lipid component in the membranes. In addition, we observed a significant proportion of PUFAs. Important differences have emerged between the fertile and infertile groups, leading to the identification of a lipid cluster that was associated with semen parameters. Among these, cholesterol sulfate, SGG, and PUFAs represented the most important predictors of semen quality. No association was found between the serum and sperm lipids. Dietary PUFAs and SGG have acknowledged antioxidant functions and could, therefore, represent sensitive markers of sperm quality and testicular function. Altogether, these results underline the important role of sperm membrane lipids, which act independently of serum lipids levels and may rather represent an independent marker of reproductive function.

Auger-Meitner and X-ray Absorption Spectra of Ethylene Cation: Insight into Conical Intersection Dynamics.

We present a theoretical investigation of the near-edge X-ray absorption fine structure and the Auger-Meitner decay spectra of ethylene and its cation. Herein, we demonstrate that our method, coupled with the nuclear ensemble approach, successfully reproduces the natural bandwidth structure of the experimental resonant Auger-Meitner decay spectra of ethylene, which is not very well reproduced within the Franck-Condon approximation. Furthermore, we analyze the Auger-Meitner decay spectra of the ethylene cation in light of minimum energy conical intersection structures involving the two lowest cationic states (D1 and D0), providing valuable insights into the ultrafast D1/D0 relaxation dynamics. Our results suggest that Auger-Meitner electron spectroscopy can help elucidate the mechanism behind the initial 20 fs of the relaxation dynamics.

S-doped g-C3N4 for fluorescence sensing of Fe3 + and photocatalytic dye degradation under solar light

Sulfur doped graphitic carbon nitride nanosheets were synthesized via polycondensation reaction of urea-thiourea mixture. Structure and morphology were characterized by XRD (X-ray diffraction), SEM (scanning electron microscope), and XPS (X-ray Photoelectron Spectroscopy). DRS (diffuse reflectance spectroscopy), PL (Photoluminescence spectroscopy) and time-resolved fluorescence decay spectra were used to study the optical characteristics. The photocatalytic dye degradation of Rhodamine B (RhB) in the presence of as-synthesized catalysts was investigated with the help of a UV–visible spectrophotometer. The photocatalytic activity of carbon nitride prepared from urea-thiourea mixture is almost three times higher than that of the pure sample. The detection of Fe3+ was also investigated by using the fluorescence sensing method. The as-synthesized samples hold greater selectivity and sensitivity for fluorescence sensing of Fe3+within a range of 0–3 µM. This range is comparable to the performance of other Fe3+ fluorescent probes previously reported.

New energy spectra in neutrino and photon detectors to reveal hidden dark matter signals

Neutral particles capable of travelling cosmic distances from a source to detectors on Earth are limited to photons and neutrinos. Examination of the Dark Matter annihilation/decay spectra for these particles reveals the presence of continuum spectra (e.g. due to fragmentation and W or Z decay) and peaks (due to direct annihilations/decays). However, when one explores extensions of the Standard Model (BSM), unexplored spectra emerge that differ significantly from those of the Standard Model (SM) for both neutrinos and photons. In this paper, we argue for the inclusion of important spectra that include peaks as well as previously largely unexplored entities such as boxes and combinations of box, peak and continuum decay spectra.

Development of Highest Value of the Measured Efficiency of Mesoporous Petal Shaped Europium (III) Doped Cobalt Tetroxide@Cupric Oxide Hybrid Nanomaterials for Enhanced Room Temperature Photoluminescence and Fluorescence Decay Properties.

In our work, a novel series of europium (III) (Eu3+) (5, 10 and 15 wt %) doped cobalt tetroxide@cupric oxide (Co3O4@CuO) nanomaterials (NMs) were synthesized by facile coprecipitation method. The synthesized NMs were characterized by XRD (X-ray diffraction), FT-IR (Fourier transform infrared), UV (ultraviolet)-visible absorption spectra, XPS (X-ray photoelectron), BET (Brunauer-Emmett-Teller) analytical methods. Crystal structure studies revealed the formation of polycrystalline nature with monoclinic and cubic phase. The morphology studies of Eu3+x:Co3O4@CuO (x = 5, 10 and 15 wt %) showed petal shape nanoparticles (NPs) with agglomeration. Redshift in optical absorption spectra appeared with a significant impact on the optical band gap as Eu3+ concentration increases on Co3O4@CuO bimetallic oxide NMs. The chemical composition and valence state of the elements confirmed from XPS studies detected the presence of Eu, Cu, Co, O and C elements. An increase in the pore size and surface area resulted as the Eu3+ concentration increased on Co3O4@CuO NMs. However, room temperature photoluminescence (RTPL) spectra of Co3O4@CuO bimetallic oxide NMs at two different excitations (λ excitation = 280nm, 320nm) showed sharp, strong emission intensities located at near ultraviolet (NUV) region and weak emissions detected at far ultraviolet (FUV) regions of the RTPL spectrum. Further, visible range emission intensities were displayed by Eu3+:Co3O4@CuO (5, 10 and 15 wt %) NMs when exited at 280nm. The characteristic white light emission peaks in the visible range of the RTPL spectra showed intense blue, green and orange colours. Emission intensity increases with an increase in Eu3+ concentration on Co3O4@CuO bimetallic oxide NMs. The fluorescence (FL) decay spectra of Eu3+ 10wt% and 15 wt%: Co3O4@CuO NMs showed a decay lifetime of 2.54 and 2.31ns (ns) attributed to the dynamic, ultrafast excitation energy transfer between Eu3+ (dopant) and Co3O4@CuO (host) NMs. It is proposed that enhanced RTPL emission intensity and FL decay behavior of Eu3+x:Co3O4@CuO NMs closely related to the change in the optical band gap, variation in the crystallite size, formation of more number of oxygen vacancies in the crystal structure of hybrid nanomaterials.

Visible light driven hydrogen peroxide production by oxygen and phosphorus co-doped CoP-C3N4 photocatalyst

Photocatalytic hydrogen peroxide (H2O2) by oxygen and phosphorus co-doped graphitic carbon nitride (C3N4) with cobalt phosphate (CoP) cocatalyst is investigated. The photocatalyst powder of CoP-C3N4 1:n, n = 0–4, n is the weight ratio of cyanuric acid added) was synthesized by melamine cyanurate template method. Characterization of the catalyst was performed by X-ray diffraction analysis, and scanning electron microscopy, X-ray photoemission spectra, and fluorescence decay spectra. Oxygen doping was performed by the melamine and cyanuric acid template method, followed by phosphorus doping of the C3N4 backbone by the introduction of CoP. Co-doping of O and P atom facilitated charge transfer on the C3N4 backbone, while CoP facilitated charge separation at the C3N4 interface. The CoP-C3N4 (1:4) photocatalyst increased H2O2 production rate by 293 % compared to that of the cyanuric acid-free photocatalyst and also achieved the photocatalytic oxygen evolution from water. These results indicate that O,P co-doped CoP-C3N4 can perform sacrificial agent-free hydrogen peroxide under visible light irradiation.

Quasiparticle resonance in decay spectrum of unbound nuclei near neutron drip-line

Quasiparticle resonance in decay spectrum of unbound nuclei near neutron drip-line

Study of the velocity-selection satellites present in the () electric quadrupole transitions in atomic rubidium

This article presents detailed experimental and theoretical studies of the satellite fluorescence lines observed when the , (, ) electric quadrupole transition (E2) is excited in a room temperature vapor of rubidium atoms. The initial state of this E2 transition is prepared by a narrow linewidth (9 MHz) laser locked to one of the dominant D2 hyperfine excitations for zero-velocity atoms. Effects due to the selection of different atomic velocity classes in this preparation step are responsible for the presence of several satellite lines that can be found in the fluorescence decay spectra of both 85Rb and 87Rb. Compared to the main lines, these satellites do not show a strong dependence on the relative linear polarization directions of the lasers used in the preparation and the electric quadrupole steps. The relative intensities of the satellites decrease as the intensity of the preparation laser increases. Results of a rate equation calculation that explicitly includes selection-of-velocity effects indicate that optical pumping plays a central role in determining the relative intensities and the polarization dependence of the satellite lines. When the preparation laser is locked to the low-F cyclic transition in 87Rb, six lines were found in addition to the lone electric quadrupole transition for zero velocity atoms. In this case, the calculated spectrum is necessary for the correct interpretation of the experimental results, clearly indicating that optical pumping and selection of velocities are responsible for these six additional electric quadrupole lines.

Enhanced visible‐light photocatalytic activity of S-scheme Bi3NbO7/Bi2MoO6 heterojunction composite photocatalyst

S-scheme Bi3NbO7/Bi2MoO6 (BNO/BMO) heterojunction composite photocatalysts were successfully synthesized by hydrothermal method, the photocatalytic degradation of TC by the prepared catalysts was evaluated under visible light. The supreme photocatalytic activity of the prepared samples was achieved when BMO loading is 20%, and its degradation rate is 1.8 times higher than pure BNO. BNO and BMO closely contacted each other to achieve efficient separation of photogenerated carriers under the internal electric field. The main active species and carrier lifetimes were investigated by capture experiments and time-resolved transient decay spectra, combined with other characterization techniques, suggesting possible S-scheme photocatalytic mechanism, which also provides a new way for the treatment of antibiotics in environmental remediation.

Search for keV-scale sterile neutrinos with the first KATRIN data

In this work we present a keV-scale sterile-neutrino search with a low-tritium-activity data set of the KATRIN experiment, acquired in a commissioning run in 2018. KATRIN performs a spectroscopic measurement of the tritium upbeta -decay spectrum with the main goal of directly determining the effective electron anti-neutrino mass. During this commissioning phase a lower tritium activity facilitated the measurement of a wider part of the tritium spectrum and thus the search for sterile neutrinos with a mass of up to 1.6, textrm{keV}. We do not find a signal and set an exclusion limit on the sterile-to-active mixing amplitude of sin ^2theta < 5times 10^{-4} (95% C.L.) at a mass of 0.3 keV. This result improves current laboratory-based bounds in the sterile-neutrino mass range between 0.1 and 1.0 keV.

Trinuclear Re(I)-Coordinated Organic Cage as the Supramolecular Photocatalyst for Visible-Light-Driven CO2 Reduction.

Photocatalytic reduction of excess CO2 in the atmosphere to value-added chemicals by visible light can be an effective solution to fuel shortage and global warming. Considering these issues, we designed and successfully synthesized a trinuclear Re(I)-coordinated organic cage (Re-C4R) as the supramolecular photocatalyst. Photophysical, electrochemical properties, and photocatalytic performance comparison of Re-C4R and its mononuclear analogue Re-bpy are discussed in detail. Notably, the covalent linkage of three Re(I) subunits in Re-C4R leads to TONCO = 691 (per Re(I) site in 4 h) more than three times as much as TONCO = 208 of Re-bpy. Compared to Re-bpy, higher current enhancement in the control CV experiments under CO2 was observed for Re-C4R. CO2 adsorption process can be promoted because of the cryptand structure and multiple amine groups of Re-C4R. Moreover, decay lifetimes of Re-C4R are shorter than those of Re-bpy in the ultrafast transient absorption (TA) and photoluminescence (PL) decay spectra, indicating that the trinuclear cryptate structure of Re-C4R could facilitate electron transfer efficiency during CO2 reduction.

Sounds from a Mountain. Acoustics at La Peña de los Enamorados (Antequera, Spain), a Neolithic sanctuary

La Peña de los Enamorados, a limestone massif located in Antequera, Spain, is a famous landmark since (at least) the Middle Ages on account of its marked anthropomorphic silhouette and geographic position right at the crossroads of Andalucía’s two main communication routes (connecting Málaga and Córdoba, in a South-North direction, and Sevilla and Granada in a West-East direction). In the last fifteen years, archaeological research has revealed substantial evidence of intense Late Neolithic, Copper Age and Early Bronze Age activity (spanning from the mid-4th to the early 2nd millennia BC) on its northern sector. This includes various loci of activity: (i) the Matacabras shelter, with schematic-style rock art, which is located at the foot of Tajo Colorado, a 100 m-high rocky wall that forms the mountain’s ‘chin’; (ii) the recently discovered Piedras Blancas megalithic grave; (iii) and several remains of activity, including Locus 4, on the steep glacis at the foot of Tajo Colorado. In this paper, we examine the acoustic behaviour of Tajo Colorado, Matacabras and Locus 4. Signals produced by means of a blank-shot pistol were recorded at each reception point by means of a high-quality audio recorder via a microphone condenser mic while controlling background noise levels. The study included impulse response analysis based on its temporal and frequency behaviour, through Schroeder decay curves, Envelop-Time Curves, spectrograms and spectrum curves. The results show good acoustic conditions, not unlike some ancient theatres, which reinforces the interpretation of the area as a major Neolithic open-air sanctuary.

Investigation of CO2 photoreduction mechanism over the Zn2V2O7/Zn3V2O8/ZnO Z-scheme system

CO2 photoreduction under mild conditions remains challenging, attributing to sluggish kinetics of complex coupling process of multi-electrons-protons and inefficient electron-hole pairs utilization. Herein, with Zn3V2O8 as a phase transformation material, we construct an effective Zn2V2O7/Zn3V2O8/ZnO (OVZn) Z-scheme system by partial decomposition of Zn3V2O8 into Zn2V2O7 and ZnO. Time-resolved fluorescence decay (TRFD) spectra investigation shows that the photogenerated electrons of Zn2V2O7 and ZnO recombine with the holes of Zn3V2O8, retaining more reductive electron of Zn3V2O8 for CO2 reduction. Moreover, in-situ Fourier-transform infrared spectroscopy suggests that the heterostructure can lower the energy barrier of CO desorption by changing bridge-bonded CO to linear-bonded CO and optimizing the energy barrier of CO production. Moreover, Cu, Ag and Au loading on OVZn greatly enhance light harvesting and promote photoelectric conversion, producing much photogenerated electron-hole pairs for CO2 reduction. OVZn and metal loaded OVZn have better photocatalytic performance, showing application superiority on CO2 photoreduction.

Description of the KLL Auger-Meitner decay spectra of argon following primary and satellite core-ionized states.

The K-edge photoelectron and KLL Auger-Meitner decay spectra of Argon have been investigated computationally at the restricted active space perturbation theory to the second order level using biorthonormally transformed orbital sets. Binding energies were computed for the Ar 1s primary ionization, as well as for satellite states originated from shake-up and shake-off processes. Based on our calculations, the contributions of shake-up and shake-off states to the KLL Auger-Meitner spectra of Argon have been completely elucidated. Our results are compared with recent state-of-the-art experimental measurements on Argon.

Relativistic corrections to polarized-tritium β decay

Forthcoming experiments like Project8 and Ptolemy aim at investigating with high precision the end-point of the tritium $\beta$-decay spectrum sensitive to the neutrino mass. In light of this, using the standard parametrization in terms of nuclear polar form factors, we analyze the complete relativistic expression for the spectrum of the $\beta$-electron emitted by a tritium nucleus. Given the small parameters in the problem, we systematically discuss the approximations that can be made, and present the first two corrections to the standard lowest order formula. We particularly discuss the case of an initially polarized target, and the consequences on the spectrum as a function of the neutrino mass. We show that, while it induces an angular anisotropy that can be measured by future experiments, such anisotropy cannot be used as an additional handle to constrain the neutrino mass.

Volume-to-area law entanglement transition in a non-Hermitian free fermionic chain

We consider the dynamics of the non-Hermitian Su-Schrieffer-Heeger model arising as the no-click limit of a continuously monitored free fermion chain where particles and holes are measured on two sublattices. The model has \mathcal{PT}𝒫𝒯-symmetry, which we show to spontaneously break as a function of the strength of measurement backaction, resulting in a spectral transition where quasiparticles acquire a finite lifetime in patches of the Brillouin zone. We compute the entanglement entropy’s dynamics in the thermodynamic limit and demonstrate an entanglement transition between volume-law and area-law scaling, which we characterize analytically. Interestingly we show that the entanglement transition and the \mathcal{PT}𝒫𝒯-symmetry breaking do not coincide, the former occurring when the entire decay spectrum of the quasiparticle becomes gapped.

Methylammonium Cation-Regulated Controllable Preparation of CsPbBr3 Perovskite Quantum Dots in Polystyrene Fiber with Enhanced Water and UV Light Stabilities

In situ fabrication of lead halide perovskite quantum dots (PQDs) is important for narrow-band emitters for LED displays due to the simple work procedure and convenient usability; however, the growth of PQDs is not readily controllable in the preparation, resulting in low quantum efficiency and environmental instability of PQDs. Here, we demonstrate an effective strategy to controllably prepare CsPbBr3 PQDs in polystyrene (PS) under the regulation of methylammonium bromide (MABr) via electrostatic spinning and thermal annealing techniques. MA+ slowed down the growth of CsPbBr3 PQDs and acted as a surface defect passivation reagent, which was proved by Gibbs free energy simulation, static fluorescence spectra, transmission electron microscopy, and time-resolved photoluminescence (PL) decay spectra. Among a series of prepared Cs1-xMAxPbBr3@PS (0 ≤ x ≤ 0.2) nanofibers, Cs0.88MA0.12PbBr3@PS shows the regular particle morphology of CsPbBr3 PQDs and the highest photoluminescence quantum yield of up to 39.54%. The PL intensity of Cs0.88MA0.12PbBr3@PS is 90% of the initial intensity after immersing in water for 45 days and 49% of the initial value after persistent ultraviolet (UV) irradiation for 27 days. A high color gamut containing 127% of the National Television Systems Committee standard with long-time working stability was also obtained on light-emitting diode package measurements. These results demonstrate that MA+ can effectively control the morphology, humidity, and optical stability of CsPbBr3 PQDs in the PS matrix.

Cd113 β -decay spectrum and gA quenching using spectral moments

We present an alternative analysis of the $^{113}\mathrm{Cd}\phantom{\rule{4pt}{0ex}}\ensuremath{\beta}$-decay electron energy spectrum in terms of spectral moments ${\ensuremath{\mu}}_{n}$, corresponding to the averaged values of $n\mathrm{th}$ powers of the $\ensuremath{\beta}$ particle energy. The zeroth moment ${\ensuremath{\mu}}_{0}$ is related to the decay rate, while higher moments ${\ensuremath{\mu}}_{n}$ are related to the spectrum shape. The here advocated spectral-moment method (SMM) allows for a complementary understanding of previous results, obtained using the so-called spectrum-shape method (SSM) and its revised version, in terms of two free parameters: $r={g}_{\mathrm{A}}/{g}_{\mathrm{V}}$ (the ratio of axial-vector to vector couplings) and $s$ (the small vectorlike relativistic nuclear matrix element, $s$-NME). We present numerical results for three different nuclear models with the conserved vector current hypothesis (CVC) assumption of ${g}_{\mathrm{V}}=1$. We show that most of the spectral information can be captured by the first few moments, which are simple quadratic forms (conic sections) in the $(r,\phantom{\rule{0.16em}{0ex}}s)$ plane: An ellipse for $n=0$ and hyperbolas for $n\ensuremath{\ge}1$, all being nearly degenerate as a result of cancellations among nuclear matrix elements. The intersections of these curves, as obtained by equating theoretical and experimental values of ${\ensuremath{\mu}}_{n}$, identify the favored values of $(r,\phantom{\rule{0.16em}{0ex}}s)$ at a glance, without performing detailed fits. In particular, we find that values around $r\ensuremath{\approx}1$ and $s\ensuremath{\approx}1.6$ are consistently favored in each nuclear model, confirming the evidence for ${g}_{\mathrm{A}}$ quenching in $^{113}\mathrm{Cd}$, and shedding light on the role of the $s$-NME. We briefly discuss future applications of the SMM to other forbidden $\ensuremath{\beta}$-decay spectra sensitive to ${g}_{\mathrm{A}}$.

Preparation of Laterally Chloro-Substituted Schiff Base Ester Liquid Crystals: Mesomorphic and Optical Properties

A new class of Schiff base/ester compounds: ICln, 4-((2′-chlorophenylimino)methyl)phenyl-4″-alkoxy benzoates, were synthesized and their mesophase characteristics and thermal behavior were evaluated. Differential scanning calorimetry (DSC) was used to study mesophase transitions, and polarized optical microscopy was carried out to identify the phases (POM). The results show that all compounds are monomorphic, and enantiotropic nematic (N) phases were seen at all side chains. It was found that lateral Cl atoms in the terminal benzene ring influence both conformation and mesomorphic properties. Comparisons between the present investigated lateral Cl derivatives and their laterally neat, as well as their isomeric, compounds have been briefly discussed. Results revealed that the insertion of lateral Cl substituent in the molecular structure impacts the type and stability of the formed mesophases. The exchanges of the ester-connecting moiety improve their thermal nematic stability than their previously prepared structurally isomeric derivatives. These compounds exhibit a broad absorption in the UV-Visible region, including a peak in UV region and a tail around 550 nm, and there were observed to be absorption tail increases and energy band gap decreases with the increase of the alkoxy side chain length. The photoluminescence (PL) intensity was noted to be quenched for the bulky alkoxy group ascribed to non-radiative recombination through the defect states. Moreover, time resolved fluorescence decay spectra reveal that both the radiative and non-radiative recombination lifetime increases with the increase of alkoxy side chain length.