Decay Behavior Research Articles

Long-lived, pulse-induced transient absorption inLiNb1-x Ta x O3 (0≤x≤1) solid solutions: the case of three intrinsic defect sites for electron localization with strong coupling

Abstract Femto-/nanosecond pulse-induced, red and near-infrared absorption is studied in LiNb1-x Ta x O3 (0≤x≤1, LNT) solid solutions with the aim of studying transient optical nonlinearities associated with the formation, transport and recombination of optically generated small bound electron polarons with strong coupling to the lattice. As a result, a pronounced, long-lived transient absorption is uncovered for LNT which exceed lifetimes and starting amplitudes of LiNbO3 (LN) and LiTaO3 (LT) by a factor of up to 100 and 10, respectively. The transients reveal a stretched-exponential decay behavior and a thermally activated process which provide strong evidence for an underlying hopping transport mechanism of small bound polarons. All findings are discussed in comparison to the model systems LN and LT within the framework of appropriate band models and optical generation of polarons via two-photon excitation. To explain the significant differences, the simultaneous presence of Nb5+ Li , Ta5+ Li antisites, and Ta5+ V interstitial defects, i.e. a mixture of the intrinsic defects widely established for LN and LT, is assumed for LNT.

Optical characterizations of densely doped Tm3+:KYW crystals at low temperatures

We investigate the optical lifetime, decay characteristics, spectral linewidth and energy level properties of thulium ions doped in a KY(WO 4 ) 2 crystal at 4 K temperature. High doping concentration of thulium ions with inhomogeneous broadening allow us to study nonradiative behaviors, instantaneous spectral diffusion, and spectral power broadening in this solid-state material. The theoretical consideration of ion–ion interactions is shown to accurately characterize the absorption, decay and other spectral behaviors of Tm 3+ ions. We observe more than ten-fold reduction in the decay time of 3H4 state and about three-fold reduction in the spectral-hole lifetime as we approach the center of the inhomogeneous broadening, corresponding to higher optical densities.

Structure and Screening in Confined Electrolytes: The Role of Ion Association.

The effect of ionic association on the structure and property of confined electrolytes is investigated using the classical density functional theory. We find that ionic association strongly affects the ion distribution, surface force, and screening behavior of confined electrolytes. The decay length ξ, which can describe the screening effect of high-concentration electrolytes, satisfies a scaling relationship ξ/λD ∼ (σ/λD)n, with λD being the Debye length and σ representing the ion diameter. We find that n = 1.5 in the nonassociation model, which is contributed by the charge correlation, but n = 3 in the association model, which is contributed by the density correlation. The ion association changes the concentration-dependent characteristics of the screening length by promoting the shift of the decay behavior from the charge-dominated regime to the density-dominated regime. Our result reveals the importance of ion association for electrolyte structure and screening behaviors.

In-situ synthesis of samarium activated MgO–LaAlO3 nanocomposite for enhanced and prolonged phosphorescence

A series of MgO–La1-xAlO3:xSm (x = 0–5 mol.%) nanocomposite phosphors have been synthesized in-situ using Pechini sol-gel method. The rhombohedral and face-centered crystal structures of LaAlO3 and MgO, respectively, were corroborated utilizing X-Ray Diffractograms and their Rietveld refinement. The optical band gaps of these nanocomposites have been observed in the range of 5.20–5.63 eV. Upon excitation by n-UV 405 nm radiation, the emission characteristics of these phosphors spanning 450–750 nm have been thoroughly investigated. The most notable emission occurred at 599 nm in the orange region, confirmed by CIE-1931 chromaticity coordinates. The MgO–La1-xAlO3:xSm (x = 2 mol.%) is found to be the optimum concentration exhibiting maximum luminescence with a high color purity of 90 %. Insights from Riesfeld's theory pointed towards d-q multipolar interactions as the underlying mechanism behind concentration quenching observed beyond this optimum concentration. Bi-exponential decay behavior was observed via Time-Resolved Photoluminescence (TRPL) technique, with an Internal Quantum Efficiency of 63 % calculated utilizing Auzel's formalism. The study extensively explored the impact of MgO addition on the crystallite size, band-gap, luminescence, and life-time properties, attributing the enhanced and prolonged luminescence behavior to the MgO–La1-xAlO3:xSm (x = 2 mol.%) nanocomposite. Assessment of additional parameters such as CCT (Correlated Color Temperature) and energy transfer efficiencies further reinforced the suitability of these orange emissive phosphors for potential applications in photonics and forensics, underlining their promising prospects in various technological domains.

UV and X-ray induced photochromic material based on defect state exchanges

Inorganic photochromic (PC) materials are gaining increasing recognition as promising candidates for applications in optical storage and information display. However, conventional photochromic materials exhibit sluggish coding rates and a deficiency in intelligent response for writing and erasing under multiple excitation sources. This deficiency contributes to suboptimal readout/decoding efficiency and storage security. Here, we show a Ba2NaNb5O15:Er3+ photochromic material with photoluminescence reversible modulation that can fast respond to both ultraviolet light and 532 nm laser within about 1 s, which accompanied by thermal bleaching. The PC mechanism which is based on defect state exchanges between oxygen vacancy defects and color centers is attributed to the structural flexibility of Nb-O systems and oxygen vacancy increased under irradiation. More importantly, it shows differential PC decay behavior in response to X-ray and UV light due to the difference in the number of trapped carriers. Therefore, a simple strategy based on different self-recovery levels induced by double excitation is constructed to develop an encrypted optical memory model. This fast and differential excitation source response behavior hopefully stimulates the development of new encrypted optical memory.

Effect of wall length on an interacting supersonic rectangular jet

PurposeThis study aims to study the interaction effects between a rectangular supersonic jet with a flat wall computationally using wall length as a parameter. The purpose of this study is to investigate the effect of change in wall length on supersonic core length (SCL) reduction, jet deflection and jet decay behavior.Design/methodology/approachThe design Mach number and aspect ratio at the rectangular exit were 1.8 and 2, respectively. To study the wall length effects on jet-wall interactions, wall length (Lw) was varied as 0.5Dh, 1Dh, 2Dh, 4Dh and 8Dh, where Dh was the hydraulic diameter of the nozzle exit. The flat wall with the matching width of the rectangular exit section of a supersonic nozzle was placed at the nozzle exit such that the supersonic jet grazed past the wall. The studies were carried out at over-expansion [nozzle pressure ratio (NPR) = 4], near optimum expansion (NPR = 6) and under-expansion (NPR = 8) levels.FindingsResults indicated that significant reduction in wall-bounded SCL was noticed in the range of 0.5Dh ≤ Lw ≤ 1Dh for both over-expansion and under-expansion conditions. At Lw ≥ 4Dh, SCL got enhanced at NPR = 4 and 6 but had a negligible effect at NPR = 8.Practical implicationsThrust vector control, noise reduction and easy take-off for high-speed aircraft.Originality/valueThe effect of change in flat wall length on interaction characteristics of a rectangular supersonic jet was not studied before in terms of SCL reduction and jet decay behavior.

Quasi-localization and Wannier obstruction in partially flat bands

The localized nature of a flat band is understood by the existence of a compact localized eigenstate. However, the localization properties of a partially flat band, ubiquitous in surface modes of topological semimetals, have been unknown. We show that the partially flat band is characterized by a non-normalizable quasi-compact localized state (Q-CLS), which is compactly localized along several directions but extended in at least one direction. The partially flat band develops at momenta where normalizable Bloch wave functions can be obtained from a linear combination of the non-normalizable Q-CLSs. Outside this momentum region, a ghost flat band, unseen from the band structure, is introduced based on a counting argument. Then, we demonstrate that the Wannier function corresponding to the partially flat band exhibits an algebraic decay behavior. Namely, one can have the Wannier obstruction in a band with a vanishing Chern number if it is partially flat. Finally, we develop the construction scheme of a tight-binding model for a topological semimetal by designing a Q-CLS.

Evaluation of topological protection in kagome lattice-based thermal diffusion systems

We evaluated topological protection for edge and higher-order corner states in topological diffusion systems based on the breathing kagome lattice. In the kagome lattice, the corner states appear at the corner boundary where all three Wannier centers in nontrivial unit cells are located. The three Wannier centers in a unit cell can be placed on the obtuse- and acute-corner boundaries utilizing the armchair boundary, generating topological acute- and obtuse-corner states. For another representative zigzag boundary, only the acute-corner unit cell has three Wannier centers located at the boundary; hence, only the acute-corner state appears. Our band analysis and numerical studies show that the topologically protected decay behavior for armchair boundaries is as robust as that for zigzag boundaries, unlike wave phenomena with space and time periodicities. Our findings can guide the flexible design of topological diffusion applications such as heat localization and recovery systems.

Study on the decay behavior of a flexible sensor based on silver fiber fabrics

Abstract Flexible sensors are affected by various external factors during their use, such as water, thermal oxidation, and ultraviolet light, which causes a decrease in their sensitivity, but little research has been done in this area. This paper investigates the effects of washing, acid, ultraviolet, and thermal oxidation treatments on flexible sensors made of silver fiber fabrics, and the sensitivity and sensing performance before and after the treatments are compared. The findings show that the flexible sensor in use has a broad response range (0–70%) and strong stability (>1000 cycles). The sensitivity decreased significantly after washing, acid treatment, UV treatment, and thermal oxidation treatment but maintained good stability after 1000 tensile cycle tests.

Strong decays of the Λc(2910) and Λc(2940) in the ND* molecular frame

Stimulated by the observation of a new structure, named Λc(2910), in the Σc(2455)0,++π+,− decay channel from B meson decay process by the Belle Collaboration, and the similarity of the Λc(2910)/Λc(2940) and Pc states, we investigate the decay behavior of the Λc(2910) and Λc(2940) in the ND* molecular frame with the possible JP quantum numbers to be 1/2− and 3/2−. We employ an effective Lagrangian approach to evaluate the partial widths of ND, Σcπ, and Σc*π channels. The estimations in the present work indicate that the JP quantum numbers of Λc(2910) and Λc(2940) are preferred to be 1/2− and 3/2−, respectively. From the present estimations, we also find the branching ratio of Λc(3/2)→Σc*π is much larger than that of Λc(1/2)→Σc*π, thus Σc*π could be a good channel to distinguish the JP quantum numbers of Λc(2910) and Λc(2940). Therefore, we suggest searching for the structure in Σc*π invariant mass distribution in Belle II. Published by the American Physical Society 2024

Judd-Ofelt analysis of Sm3+ doped Ca2LiMg2V3O12 phosphors: Unveiling luminescent and thermometric properties for multifunctional applications

This study investigated the luminescent and thermometric properties of pure and Sm³⁺-doped Ca₂LiMg₂V₃O₁₂ (CLMV) garnet-type vanadates synthesized by the solid-state reaction method. The synthesized materials, with varying Sm³⁺ concentrations (0.01–0.09 mol%), were comprehensively characterized using powder X-ray diffraction (PXRD) analysis to confirm their phase purity. Diffuse reflectance spectroscopy (DRS) measurements were employed to determine the band gap energy of both pure CLMV and CLMV:0.07Sm³⁺ samples. Photoluminescence (PL) excitation and emission spectra were recorded for the pure and Sm³⁺-doped CLMV phosphors using an excitation wavelength of 345 nm and monitoring the emission at 618 nm. These spectra revealed detailed information about the energy levels involved in light emission processes. An efficient energy transfer from the (VO₄)³⁻ groups to the Sm³⁺ ions was observed, exceeding 48%. This energy transfer process is crucial for achieving high-intensity luminescence in Sm³⁺-doped materials. Judd–Ofelt (J-O) theory was applied from the emission spectra and calculate the Judd–Ofelt intensity parameters, which govern the radiative properties of the Sm³⁺ ions. Based on the J-O analysis, the branching ratio (β) was estimated to be greater than 75%. This value, exceeding the threshold of 50% for display devices, signifies the suitability of the phosphor for solid-state lighting applications due to its efficient light emission. The thermal quenching behavior of both the Sm³⁺ ions and the (VO₄)³⁻ groups was further investigated to explore the optical thermometric characteristics of the Sm³⁺-doped CLMV phosphors. Notably, a maximum absolute sensitivity (Sa) of 0.35 K⁻1 and a relative sensitivity (Sr) of 2.55% K⁻1 were achieved, demonstrating the materials potential for non-contact optical temperature sensing applications. Lifetime decay analysis revealed double exponential decay behavior, indicating the presence of multiple luminescence centers within the phosphor. The average lifetime in the millisecond range further supports the suitability of these materials for practical applications. Finally, the CIE color coordinates, correlated color temperature (CCT), and color rendering index (CRI) values were also reported, providing insights into the colorimetric properties of the Sm³⁺-doped CLMV phosphors. These aspects are crucial for optimizing the materials for solid-state lighting applications.

Assessing sampling interval-dependent roughness in fractured steel fiber reinforced concrete using a double-exponential decay model

This study introduces a double-exponential decay (DED) model to investigate the sampling interval (δ)-dependent behavior of crack morphology roughness in steel fiber reinforced concrete (SFRC). The root mean square (Z2-3D) of the directional derivatives in 3D digital morphology is employed to quantify the roughness and its anisotropic behavior. Surface morphologies of 24 fractured specimens are captured by using a laser scanner and the obtained results are re-meshed based on the Point-Kriging algorithm. The roughness is represented by the ratio of surface area to projected area (RS) and Z2-3D values along different directions at various δs (4–3000 μm). The outcomes suggest that the values of RS and Z2-3D both decline, but the anisotropy of surface roughness is enhanced at an increased δ. The DED model is able to properly reflect the decay behavior in which the morphology roughness is classified into three corrugated components based on their distinct attenuation laws. A satisfactory agreement with the literature data is observed, validating the presented methodology. The reported findings in this work are useful for enhancing the understanding of the formation of crack morphology roughness and its relationship to the damage process of SFRC.

Quantitative estimation of ·OH-radical density from fluorescence decay behavior near the plasma-liquid interface by incident microscopic LIF spectroscopy

The formation and transportation of short-lived species on/within the plasma-liquid interfacial layer plays a crucial role in various applications because of their high chemical reactivity. However, the experimental detection and quantification of these short-lived species, such as ˙OH radicals, at the gas–liquid interface still pose formidable challenges. This study confronts this challenge by employing incident microscopic laser-induced fluorescence (mLIF) method to capture the OH-LIF signals on the interfacial layer at different time moments of the post-discharge phase under high spatial resolution. The temporal evolution of ˙OH density is subsequently quantified by fitting the OH-LIF decay behavior to a reaction-dissolution model. Results reveal that increasing the pulse width serves better to enhance ˙OH generation on liquid surface, reaching a density of 1.25 × 1016 cm−3. Furthermore, the cathode-solution interface demonstrates significantly enhanced ˙OH production compared to the anode-solution interface. These results underscore the efficacy of incident mLIF in quantitatively probing short-lived ˙OH-radical production at the interfacial layer in pulsed-driven plasma-solution interactions, with potential applicability to other reactive species.

CO-tolerance behaviors of proton exchange membrane fuel cell stacks with impure hydrogen fuel

Carbon monoxide poisoning poses a significant challenge for proton exchange membrane (PEM) fuel cells operating with CO-containing hydrogen. One established solution involves air bleeding, a process that enhances the oxidation of carbon monoxide at the anode side of the fuel cell by blending a small quantity of air with the impure hydrogen before its introduction into the fuel cell. However, researchers have raised concerns regarding durability issues about catalyst sintering and membrane decomposition induced by air bleeding. The effects and underlying mechanisms of air bleeding on PEM fuel cells have yet to be comprehensively elucidated. To address this, this study conducts a detailed durability test to quantitatively evaluate the effects of air bleeding on the CO-containing hydrogen-fueled PEM fuel cells via the micro-current excitation method. The investigation substantiates that the PtRu/C catalysts significantly enhance both the performance and durability of fuel cells when air bleeding is employed, exhibiting different CO-tolerance and decay behaviors compared to the Pt/C anode catalyst. Furthermore, the evolution of MEA parameters indicates that the advantageous behaviors of PtRu/C catalysts can be attributed to their CO-tolerance capabilities, alleviated anodic catalyst sintering and loss, and decreased chemical carbon support corrosion and membrane decomposition through diminished hydrogen peroxide generation. This study contributes critical insights and empirical evidence for researchers focusing on CO-tolerant catalyst materials, the durability of PEM fuel cells, and the conversion and utilization of impure hydrogen energy derived from fossil fuels.

Effect of local and global screening current on the current decay in closed-loop HTS coils

High-temperature superconducting (HTS) coils are generally operated in a closed-loop persistent current mode, which is crucial for ensuring long-term stability and minimizing heat generation in various applications. However, factors such as joint resistance, flux creep, and losses due to external fields can lead to accelerated decay of the coil’s current, making it challenging to achieve an effective persistent current mode. To gain insight into the current decay characteristics of HTS coils, we built a finite element method based model coupled with a lumped parameter electric circuit model. The model is initially verified against the experiment of an inductive magnetized HTS coil subject to a magnetic field perpendicular to the tape surface. The results indicate that the proposed model is highly effective in predicting the current decay behavior of this magnetized HTS coil and is able to provide high accuracy. With the help of this model, we have experimentally and numerically studied the behavior of a current-carrying closed-loop HTS coil subject to external alternating fields. The HTS coil is charged by a DC power supply and then shorted using a thermally-controlled persistent current switch. The current decay behavior of the HTS coil is examined under various scenarios. The simulation results show excellent agreement with experimental data, further validating the effectiveness and versatility of the modeling strategy. The influence of both local and global screening currents on the current decay performance of the closed-loop HTS coils has been investigated. For every case examined, rapid demagnetization occurred in the initial cycle of the applied alternating field. Furthermore, the current decay rate demonstrated a slight dependence on the frequency of the applied fields. Additionally, the resulting resistance has been thoroughly characterized. These insights contribute to the knowledge of the behavior and performance of closed-loop HTS coils, facilitating their practical application.

Global regularity and decay behavior for Leray equations with critical-dissipation and its application to self-similar solutions

In this paper, we show the global regularity and the optimal decay of weak solutions to the generalized Leray problem with critical dissipation. Our approach hinges on the maximal smoothing effect, L p L^{p} -type elliptic regularity of linearization, and the action of the heat semigroup generated by the fractional powers of Laplace operator on distributions with Fourier transforms supported in an annulus. As a by-product, we construct a self-similar solution to the three-dimensional incompressible Navier-Stokes equations. Most notably, we prove the global regularity and the optimal decay without the need for additional requirements found in existing literatures.

Parametric characterization of arcs in semi-sealed splitter plate DC circuit breakers

Precisely assessing plasma parameters holds paramount importance in investigating the arc extinguishing mechanism of semi-sealed splitter plate DC circuit breakers, refining the configuration of splitter plates, and optimizing the overall structural design of circuit breakers. Based on the principle of the Langmuir probe, a double probe diagnostic method is proposed to investigate the air arc plasma in the opening process of a DC circuit breaker. The diagnostic circuit of the probes is designed, and three sets of double probes are arranged to trace the evolution of the plasma density during the opening process. The research reveals that the plasma center density, measured by the diagnostic system during the opening process of the DC circuit breaker, is about 1022 m−3–1023 m−3. This density is compared with the diagnostic results obtained by other methods, confirming the accuracy of the Langmuir double probe for plasma measurements in the DC circuit breaker. The study also revealed an exponential decay behavior of electron density along the radial direction of the arc. A mathematical model was employed to describe this phenomenon, establishing a relationship between the distribution of electron density and arc current.

Constraints on Lorentz invariance violation from the LHAASO observation of GRB 221009A

In some quantum gravity (QG) theories, Lorentz symmetry may be broken above the Planck scale. The Lorentz invariance violation (LIV) may induce observable effects at low energies and be detected at high energy astrophysical measurements.The Large High Altitude Air Shower Observatory (LHAASO) has detected the onset, rise, and decay phases of the afterglow of GRB 221009A, covering a wide energy range of photons approximately from 0.2 to 13 TeV. This observation provides an excellent opportunity to study the Lorentz invariance violation effect. In this study, we simultaneously utilize the data from the KM2A and WCDA detectors of LHAASO, and apply two event by event methods, namely the pair view method and maximum likelihood method, to investigate LIV. We obtain stringent constraints on the QG energy scale. For instance, through the maximum likelihood method, we determine the 95% confidence level lower limits to be E QG,1 > 14.7 (6.5) × 1019 GeV for the subluminal (superluminal) scenario of n = 1, and E QG,2 > 12.0 (7.2) × 1011 GeV for the subluminal (superluminal) scenario of n = 2. We find that the rapid rise and slow decay behaviors of the afterglow can impose strong constraints on the subluminal scenario, while the constraints are weaker for the superluminal scenario.

Elasticity of Diametrically Compressed Microfabricated Woodpile Lattices

Modulus–porosity relationships are invaluable to rational material design of porous and structured solids. When struts in a lattice are compressed diametrically, the mechanics is rather complex. Herein, the problem of modulus–porosity in the spirit of scaling arguments and analyses based on simple ansatz followed by variational minimization of the elastic potential energy is addressed. Using scaling arguments, a simple power law where the apparent modulus of elasticity scales quadratically with the volume fraction for diametrically compressed elastic lattices is obtained. The modulus–porosity relationship is found to be consistent with computations and laboratory experiments on additively manufactured woodpile lattices with various cross‐sectional shapes and lattice spacing. It is also shown that the persistence length of diametrically pinched elastic rods is small, so that the effect of compressive strain from neighboring sites can be ignored. The decay behavior is surprisingly accurately captured by the variational approach and is consistent with computations. Finally, the range of validity of the quadratic power law presented here, up to relative density ~80%, is identified. On the apparent modulus–porosity plane, the experimental data aligns well with the power law for modulus–porosity predicted from simple analyses and finite element calculations.

Exploration of Photoluminescence, Colorimetric, and Decay Performance of Sm-activated CaWO4 Ceramic.

This paper represents structure, photoluminescence, and colorimetric investigations of Sm-activated CaWO4 ceramic made with the help of a solid-state reaction process. Structures of the ceramics are examined through X-ray diffraction spectroscopy. It indicates that these materials have a tetragonal structure and I41/a space group without having any other secondary phase. Energy band gaps are increased with the higher concentrations of Sm dopants. Photoluminescence analyses show that concentration quenching is found at x = 0.02 Sm incorporated CaWO4. The critical distance of energy transfer is obtained as about 20Å. Q-value is observed approximately equal to 6 which denotes that dipole-dipole interactions occur in the materials that create the critical energy transfer distance in them. Chromaticity values are described in that the ceramics emit orange-red color as well as excellent colorimetric parameters. Quantum efficiency of x = 0.02 Sm composition in CaWO4 is measured under 405nm EX wavelength. Photoluminescence decay behaviors are observed and average lifetime values are evaluated.