Charge neutralization is a key operation in many electrostatic processes. A wide-range of charge neutralizers have already been developed for various applications: eliminate shock and ignition hazards, avoid electrostatic discharges that might affect the operation of electronic equipment, reduce electrostatic adhesion forces that might stick granular materials in pneumatic conveyors, and so on. The aim of the present paper is to evaluate several methods of charge neutralization for charged granular insulating materials spread on an electrode energized from a voltage source of opposite polarity, a situation encountered – for instance – in two-metallic-belt tribo-aero-electrostatic separators, and which is not covered by commercially-available solutions. Three corona-discharge-based charge neutralization systems are studied: (i) DC-biased AC voltage applied to a corona dual-type electrode; (ii) DC-biased AC voltage applied to a triode-type electrode system; (iii) DC voltage applied to a corona dual-type electrode. The charged samples of polycarbonate granules are obtained at the outlet of a tribo-aero-electrostatic separator. The electric charge per mass ratio of each sample is measured before and after neutralization. The third of the above-mentioned charge neutralization solutions seems to be the most effective solution, but it requires an appropriate adjustment of the DC voltage applied to the corona dual-type electrode.