The title compound, C27H37NO7, is a Daphniphyllum alkaloid isolated from a branch of Daphniphyllum macropodum Miq. All of the five-membered rings adopt envelope conformations while the six- and seven-membered ring adopt chair conformations. Classical intermolecular O—H⋯O and weak C—H⋯N hydrogen bonds are present in the crystal structure.