Number Of Cycles Research Articles

Fast and accurate approximation algorithms for computing floating point square root

AbstractThe square root is one of the most used functions in many different engineering and scientific applications. We propose new methods for calculating the square root function that are based on the Newton–Raphson method with Heron iteration. A modification of Heron’s formula combined with an improved selection of the magic constants enables a significant reduction of the maximum relative error (MRE). Simple modifications to the Newton–Raphson formula and the magic number method enable implementation on platforms with limited hardware resources, such as microcontrollers and FPGAs, with variable accuracy. Implementations of new approximation algorithms in the C programming language were carefully tested and evaluated against their software and hardware counterparts on the most popular platforms, e.g., CPUs from Intel, AMD and ARM, GPU from Nvidia and IPU from Graphcore. The proposed numerical algorithms are shown to be superior in terms of computational time, the number of clock cycles, accuracy, MRE, and root mean square deviation.

Therapeutic radiation directly alters bone fatigue strength and microdamage accumulation

Radiotherapy (RTx) is an essential and efficacious oncologic treatment, however, post-RTx bone fragility fractures present a challenging clinical problem. Cancer survivors treated with RTx are at variable risk for these late-onset, complex fragility fractures. Little data exists regarding the effects of RTx on bone fatigue properties despite the likelihood of fatigue loading as a mechanism leading up to atraumatic fracture. In this study, femurs collected from adult male rats were irradiated ex vivo with a therapeutic dose of x-irradiation (20 Gy), and then fatigued using a three-point bend setup. Femurs positioned in an isotonic bath at room temperature were loaded to a range of prescribed initial strain levels (based on beam theory equations, prior to any fatigue damage) at 3 Hz in force control. The goals of this study were to determine the feasibility of assessing RTx-induced alterations in 1) femur fatigue strength, 2) structural microdamage (creep and stiffness), and 3) tissue damage (diffuse damage and/or linear microcracking). Mid-diaphyseal morphology and tissue mineral density were not different between the RTx and Sham groups (p ≥ 0.35). With increasing applied apparent strain, the number of cycles to failure was reduced for the RTx femurs when compared to the Sham femurs (treatment x εapp, p = 0.041). RTx femurs had a greater phase II (steady state) creep rate (p = 0.0462) compared to Sham femurs. For femurs that reached 500k cycles, the RTx group had greater diffuse damage area (p = 0.015) than the Sham. This study provides evidence that radiation at therapeutic doses can directly diminish bone fatigue properties. This loss of fatigue properties is associated with increased structural fatigue damage and diffuse microdamage, without alterations in morphology or tissue mineral density, indicating a reduction in bone quality.

On the number of limit cycles for a perturbed cubic reversible Hamiltonian system.

This paper is concerned with the limit cycle problem of a cubic reversible Hamiltonian system under perturbation of polynomials of degree n with a switching line x=0. The upper and lower bounds of the number of limit cycles are obtained using the first order Melnikov function and its expansion. The method for calculating the Melnikov function relies upon some iterative formulas, which differs from other approaches.

Biomass erosion and its effect on heat carrying performance of alumina heat carrier during multiple cycle sintering in solar photothermal coupled with biomass gasification

Biomass coupled with solar photothermal gasification technology is an efficient technology using solar to provide energy by heat carrier for biomass gasification. However, the heat carrier that transferred heat to the biomass feedstock can be eroded by the effects of biomass ash, with the erosion problem worsening as the number of cycles increased. The erosion and adhesion caused by multiple sintering of corn stalk ash (CSA) to heat carrier particles (Al2O3) were investigated. K and Si elements in CSA are the main elements that erode Al2O3 particles, and their erosion depth increases with the number of sintering cycles. The erosion process of CSA on heat carriers deepens with multi-sintering, but the infiltration behavior of CSA can be fairly prevented due to the generation of high fusion minerals during erosion. The infiltration characteristics of CSA change abruptly upon contact, influencing the erosion behavior during the cyclic sintering process.

Designing tungsten armoured plasma facing components to pulsed heat loads in magnetic fusion machines

A possible design rule for preventing surface damage from thermal transients to solid tungsten armour is proposed and formulated for the plasma facing components (divertor, first wall) of magnetic fusion machines. The rule is based on combined results from laboratory experiments and operating fusion machines, and fundamental engineering principles such as the heat flux factor (FHF) and fatigue usage fraction (FUF). As an example, the rule would allow 2.104 transient heat loads cycles at a FHF of 10MJm-2s-½ before the lifetime is considered exhausted. The formulation of the rule using engineering principles allows combining loads of different magnitudes and various number of cycles. A practical example of the rule usage is provided, illustrating loads combination and how the rule may contribute to the component geometrical design. The proposed rule is only valid for surface loading conditions, hence is not usable for volumetric loading conditions such as runaway electrons. Setting a budget lifetime and a design rule does not preclude actual plasma operation beyond the design lifetime. It is actually normal that experimental devices explore a larger domain than the one defined at the time of the design.

Preparation of composites of lithium-aluminum layered double hydroxides and biochar and their performance in lithium extraction from aqueous media

Layered lithium aluminum double hydroxides (LiAl-LDH) have significant potential for industrial applications, particularly as adsorbents for lithium extraction from salt lakes. However, their development is constrained by a relatively low adsorption capacity. To address this limitation, a composite material comprising biochar (BC) and lithium aluminum layered double hydroxide (LiAl-LDH@BC) was synthesized via a hydrothermal reaction, using Al(NO3)3·9H2O, LiNO3, urea, and varying amounts of BC as raw materials. This composite demonstrates excellent Li+ adsorption capacity (19.6 mg/g). LiAl-LDH@BC2.5 was characterized using SEM, XRD, XPS, and other analytical methods. The effects of various adsorption conditions—including adsorption temperature, initial Li+ concentration, time, pH, ion interference, and the number of cycles—on the Li+ adsorption performance of LiAl-LDH@BC were investigated. The increased specific surface area and the electrostatic adsorption of surface functional groups after composite formation are the primary reasons for the high adsorption capacity. The mechanism of Li+ adsorption follows pseudo-first-order kinetics and the Langmuir model, involving both physical and chemical adsorption. This study offers a promising adsorbent for the extraction of Li+ from aqueous media.

The effect of different separated file retrieval strategies on the biomechanical behavior of a mandibular molar: a finite element analysis study.

This study evaluated the effects of retrieval strategies of separated nickel-titanium (NiTi) files on the biomechanical behavior of endodontically treated teeth by finite element analysis (FEA). Six FE models were created; IT: intact tooth, SF: simulated a scenario where the apical 3 mm of a NiTi file is separated and retained, TD: simulated application of a trephine drill to expose 1 mm of the separated file, US180: simulated troughing of 180⁰ at the inner wall of root canal for an extra 1 mm of the separated file beyond the staging platform, US360: simulated circumferential ultrasonic troughing done for an extra 1 mm after the TD, and PM: simulated iatrogenic perforation sealed using MTA. Occlusal loading followed the occlusal fingerprint of the tooth before maximum von Mises stresses (vMS), maximum principal stresses (MPS), safety factor, and number of cycles (NCF) till failure were determined. Cervical region of the teeth and mid-root sections including the separated file were chosen as the areas of interest for further analysis. IT recorded the highest NCF and safety factor. Other models showed a narrow range of variation in all aspects with the PM recording the lowest NCF. The highest vMS was recorded at the mesiobuccal line angle of the PM near its cervical margin, while the lowest was found at the IT. Under the limitation of this study, various file retrieval strategies removing the surrounding root dentin within the amounts of general guidelines do not affect the biomechanical behavior of the tooth.

Control parameter optimisation using the evidence framework for the ant colony optimisation algorithm

The ant colony optimization (ACO) algorithm is a metaheuristic initially designed to solve the travelling salesman problem (TSP). The design of experiments, finding the suitable ACO algorithm configuration, and calibrating the adaptive control parameters are exhaustive and time-consuming exercises, especially for TSPs where the number of cities can exceed 1000. This paper presents an evidence framework driven control parameter optimisation (EFCPO) algorithm for an ACO algorithm solving TSPs. EFCPO performs auto-tuning of the adaptive control parameters and makes recommendations about the ACO algorithms that are best suited for the TSPs in question using the log evidence. In addition, with this ability, the algorithm can take a solution provided by an ACO algorithm and improve the results. The EFCPO accomplishes this over a number of cycles through auto-tuning of the control parameters and re-running the ACO until the process is completed. The capabilities of EFCPO are compared to another configuration tool, irace, using benchmark ACO algorithms to test the efficiency of the framework. The benchmark algorithms make use of a local search strategy to solve TSPs. The results show that ACO algorithms are able to find new and improved solution tours within reasonable times. The improvements are also significant. In addition, ACO algorithms that are best suited for the TSP in question are preferred, making the EFCPO an effective tool for real-time configuration of ACO algorithms for solving TSPs .

On Microplasticity-induced Fatigue Fracture and its Relation to Entropy

Abstract The study delves into the intricate effects of microplasticity on fracture formation in testing specimens under axial cyclic loading. The primary aim is to pinpoint the juncture at which microplasticity becomes discernible across the stress cycle. Fatigue tests are conducted on varied specimens until failure using a fatigue testing machine, while recording parameters such as frequency, stress amplitude, applied power, and tensile strain. The investigation seeks to ascertain whether cracks must attain a specific size before manifesting these subtle alterations. A conjectured relationship is proposed between the number of cycles and entropy throughout the process. Additionally, a hypothesis is posited suggesting that microplasticity emerges only once the crack surpasses a certain threshold, such as grain size. This research provides insights into material fracture mechanisms and their implications for product durability and safety. Such discernments into the product life cycle under analogous conditions hold promise for delineating operational limits.

Self-acceleration effect of Mn/Ce-modified carbide slag in CO2 absorption for CaO/CaCO3 energy storage

Carbide slag, a solid waste from the chlor-alkali industry, can be used for CO2 capture and energy storage. Herein, the cyclic reaction activity of Mn/Ce-modified carbide slag under energy storage conditions was studied. The Mn/Ce-modified carbide slag shows energy storage density over 2100 kJ/kg and CO2 absorption capacity of 0.52 g CO2/g sorbent after 30 cycles. Notably, both carbonation and calcination rates are accelerated with the number of cycles. This self-acceleration effect is related to the evolution of oxygen vacancy concentration and texture structure of Mn/Ce-modified carbide slag during the cycles. In the cycles, CaMnO3 in the Mn/Ce-modified carbide slag reacts with the formed CaCO3 in the carbonation stage to produce more Ca2MnO4. The formation of Ca2MnO4 increases oxygen vacancies in the Mn/Ce-modified carbide slag, significantly enhancing its CO2 adsorption capacity. Thus, the release of the increased CO2 in the calcination stage generates more pores in the 10–100 nm diameter range in the modified carbide slag, facilitating rapid carbonation. Thus, the Mn/Ce-modified carbide slag exhibits good prospect for CaO/CaCO3 thermochemical energy storage.

Enhancing performance of Si/C composite anode in high energy density lithium-ion batteries with CMC-CPAM-SBR binder

Abstract The utilization of polymeric binders is indispensable in the implementation of silicon/carbon anode materials in high-energy-density lithium-ion batteries (LIBs). This necessity arises from their pivotal function in upholding structural integrity. However, current water-based binders solely focus on binder adhesion, neglecting the crucial interaction with the carbon material. In this work, a composite binder (CMC-CPAM-SBR) was constructed by combining Styrene Butadiene Rubber (SBR) with cationic polyacrylamide (CPAM) network binder with self-healing carboxymethyl cellulose (CMC). This innovative binder formulation was designed to enhance the performance of Si@C/graphite composite anodes. A capacity retention rate of 92.86% was achieved after 100 cycles, which represents the improvement over the performance of electrodes utilizing the CMC-CPAM binder, which only retained a capacity of 84.53% after the same number of cycles. A full battery with a capacity of 1992.8 mAh was designed, and the battery capacity remained at 80.6% of its capacity after completing 500 cycles. This research presents an effective technique for manufacturing high-performance anode materials.

Investigation on the evolution of concrete pore structure under freeze-thaw and fatigue loads

Hydraulic concrete structures in seasonal frozen regions serve under freeze-thaw cycles and cyclic loading conditions which cause notable alterations in the concrete pore structure and a significant reduction in the mechanical properties and durability of concrete. To understand the macroscopic and mesoscopic damage processes and mechanism of concrete subjected to freeze-thaw cycles and cyclic loading lead, the compressive experiment and computed tomography test of concrete after freeze-thaw and fatigue loading tests were conducted. And the influences of freeze-thaw cycle damage and cyclic loading damage on the pore structure of concrete were analyzed. The relationships between concrete pore fractal dimension, compressive strength, and elastic modulus were revealed. The concrete average pore size can be regarded to grows linearly under freeze-thaw and cyclic loading. The porosity, pore volume, and pore surface area increase with the increase in freeze-thaw cycles, and their relationship can be represented by a quadratic function. However, they first decrease and then increase with the increase of loading cycles after a specific freeze-thaw cycles number. Under the combined action of freeze-thaw cycles and cyclic loading, the non-uniformity degree of concrete pore distribution decreases, and the overall structure is more regular. The distribution of single pore morphology tends to be spherical and banded, respectively. The cyclic loading promotes the extension of the internal pores and cracks of freeze-thaw-damaged concrete which aggravates damage of concrete. Under freeze-thaw cyclic loading, the concrete compressive strength and elasticity modulus is linearly and positively correlated with fractal dimension. With the increase of loading cycles number after freezing and thawing, the fractal dimension and compressive strength decrease, and the elasticity modulus has a larger dispersion. The relationship model between concrete compressive strength and fractal dimension can well describe the macroscopic and mesoscopic evolution of concrete under freeze-thaw and cyclic loading. The results can provide a scientific basis for improving the design and maintenance of concrete and benefit extending the long-term service life of hydraulic concrete structures in cold climates.

AC poling of high Qm and low acoustic impedance Pb(Mg1/3Nb2/3)O3-Pb(Zr,Ti)O3 single crystals produced by a solid-state crystal growth

The AC poling cycle dependence of Mn-doped Pb(Mg1/3Nb2/3)O3-0.3Pb(Zr.Ti)O3 (PMN-0.3PZT) single crystals (SC) produced via the solid-state crystal growth (SSCG) method was investigated. The piezoelectric strain and charge constants, d 33 ＝ 1130 pC/N, g 33 = 42.7 × 10−3 Vm/N, and mechanical quality factor Q m = 800 were obtained under conditions of 1 Hz, bipolar sine wave, 7.5 kV cm−1 electric field, and 6000 cycles. In contrast to the conventional Bridgman process SC, the low-density and high Q m SSCG SC necessitates a substantial number of AC cycles due to the presence of pores within the SC. In addition, the ACP SC showed a 13 °C increase in the phase change temperature T rt compared to the DC-poled SC. This information on ACP SSCG SCs with improved thermal stability, low acoustic impedance, and enhanced receiving efficiency attributable to high g 33 offers new insight into high-frequency ultrasonic devices.

Design and realization of multifunctional energy meter calibration station under extreme conditions

Abstract This paper designs a multifunctional calibration station that can be installed inside the temperature box in order to adapt to some of the special test requirements, which can be used for the testing of most types of energy meters on the market. Extreme environments such as high and low temperatures can easily cause cracks in equipment welds, aging of material insulation, and functionally cause sensitive components to drift affecting the accuracy of testing during the life cycle of the calibrator. This multifunctional calibration station designed and implemented in this paper is capable of maintaining its functionality without being destroyed under repeated experiences of extreme conditions. In this paper, a multifunctional calibration station is designed and realised. In order to verify the influence of the calibrator on the calibration error of the energy meter after repeatedly experiencing extreme conditions, a comparison test of 40 cycles was carried out by comparing the calibrator with the one placed at room temperature, and the difference between the two calibrators’ measurement results did not show a regular growth trend with the increase in the number of measurement cycles, which proves that the calibrator is able to keep its function undamaged under the repeated experience of extreme conditions.

Study on the deterioration mechanism of hybrid basalt-polypropylene fiber-reinforced concrete under sulfate freeze-thaw cycles

This paper focuses on the deterioration mechanism of hybrid basalt-polypropylene fiber-reinforced concrete (HBPRC) under the coupling of sulfate freeze-thaw cycles. The changes in the macroscopic properties of HBPRC under the influence of different volume contents of basalt fiber (BF), polypropylene fiber (PF) and hybrid BF-BF were investigated. The microstructure of HBPRC was characterized using the nuclear magnetic resonance (NMR) technique, X-ray diffraction (XRD) and scanning electron microscopy (SEM), and the deterioration models of the BF- matrix interfacial transition zone (BF-ITZ) and the PF- matrix interfacial transition zone (PF-ITZ) in HBPRC were developed. The results showed that the fibers effectively reduced the cracking and macroscopic property damage induced by sulfate freeze-thaw cycles as the number of freeze-thaw cycles increased. When both BF and PF volume contents are mixed at 0.05 %, they can produce complementary effects, and their formation of a uniformly distributed three-dimensional mesh structure is more conducive to reducing the damage to the concrete, and their relative dynamic modulus of elasticity and compressive strength after 300 times of sulfate freeze-thaw cycles were increased by 67.10 % and 46.92 % compared with control concrete. At the same time, the addition of fibers resulted in a more stable evolution of the pore structure of the concrete, and the porosity of the specimens with fibers added at a volume admixture of 0.05 % and 0.1 % was reduced by 13.69–21.35 % after 300 cycles of sulfate freeze-thaw cycling, compared with control concrete. From the BF-ITZ and PF-ITZ deterioration models, it was concluded that the differences in the bonding performance of BF and PF to the concrete matrix affected the degree of frost damage to which they were subjected to coupling and the efficiency of salt solution replenishment, which in turn led to differences in the damage of each group of HBPRC. The reliability of the model was further verified by SEM observation of the morphological changes of different fiber-matrix ITZs before and after sulfate freeze-thaw cycles.

The test of masticating and swallowing solids (ToMaSS): An investigation of applicability and clinical utility in children with orofacial myofunctional disorders.

Orofacial myofunctional disorders (OMD) are often associated with limitations of oral ingestion of solid food. The Test of Masticating and Swallowing Solids (ToMaSS) is a simple diagnostic tool to assess and quantify oropharyngeal efficiency while eating a standardised cracker. The objective of this study was to investigate the applicability and clinical utility of the ToMaSS in children with OMD. In this case-control study, data were collected from 18 children between 4 and 11 years with confirmed OMD. Inter-rater reliability and age effects on the ToMaSS parameters were investigated and the specific performance profile of the OMD children was identified. Inter-rater reliability was excellent for the ToMaSS parameters 'bites' (ICC = .999), 'masticatory cycles' (ICC = .961), 'time'(ICC≧ .999) and good for 'number of swallows' (ICC = .810). 'Masticatory cycles' and 'time' decreased as a function of age with a significant difference in the 'number of masticatory cycles' between the youngest (4-6 years) and oldest (10-14 years) participants (p = .006, Z = -2.739). Deviations from normative data in at least one of the four ToMaSS parameters were found in 90% of the OMD children with 'bites', and 'masticatory cycles' predominantly corresponding to the performances expected in typically-developing children in younger age groups. The ToMaSS is a reliable diagnostic instrument and clinically useful to detect limited efficiency of oral solid bolus intake and specific impairments in chewing function and duration of food intake in children with OMD. Our data suggest that OMD is associated with delayed development of efficient solid bolus preparation.

Technique for guttural pouch bead removal using a novel three-dimensional (3D)-printed instrument.

The aim of the present study was to determine if a three-dimensional (3D)-printed instrument technique would improve lavage removal of plastic beads (guttural pouch [GP] chondroid mimics) through a dorsal pharyngeal recess (DPR) fenestration. We hypothesized that using a 3D-printed instrument placed through the DPR fenestration would remove more beads, reduce lavage time and incur less soft tissue damage than using a lavage tube control or instrument placement through the salpingopharyngeal ostium (SPO). Experimental cadaveric study. A total of 30 cadaveric equine heads. DPR fenestration was performed using transendoscopic laser and 50 plastic 12 mm beads were placed into one GP of horse heads. Four removal procedures using a 3D-printed instrument or lavage tube control placed through the DPR fenestration or the SPO were compared. Number of beads removed and number of 2-min lavage cycles to recover ≥96% of beads or three consecutive no-yield cycles were recorded. Endoscopic soft tissue damage was graded. Data were compared by generalized estimating equations (GEE) model and Fisher's exact test (p < .05). More beads (median 48 beads; range 0-49) were removed faster (median 24 beads/cycle; range 12-50) using the 3D-printed instrument compared to control (median 6 beads; range 0-29, 0.66 beads/cycle, range 0-49). There was no difference between total beads removed or removal speed between placement sites. There was no difference in soft tissue damage between procedures. Our 3D-printed instrument enabled efficient plastic bead removal. DPR fenestration and use of our 3D-printed instrument represents an alternative to current chondroid removal techniques, warranting investigation in clinical cases.

Analysis of the influence of brake pipe pressure gradient on heavy haul combined train and optimisation of operation strategy

In this paper, based on the theory of gas flow, the action logic of the control valve, and the principle of multi-rigid-body dynamics, a simulation model of the 20,000 t heavy haul combined train is established to investigate the influence of brake pipe pressure gradient on the braking performance, longitudinal dynamics, braking and release characteristics of trains. Utilizing real railway line conditions, locomotive and vehicle parameters, and train operation monitoring equipment (LKJ) record data of Shuozhou-Huanghua Railway, the cyclic braking condition of the train on the long and steep downhill is simulated, and the control strategy of reducing the coupler force during the cyclic braking is proposed. The results indicate that a larger brake pipe pressure gradient before braking leads to weaker braking capability, and higher coupler forces during braking, but smaller coupler forces during release. As the brake pipe pressure gradient before braking increases, braking synchronicity decreases, while release synchronicity slightly improves. By adjusting the locomotive’s electric braking force during the cyclic braking, it is possible to appropriately increase the brake pipe pressure gradient before braking, effectively reducing coupler forces during release and reducing the number of braking cycles, thus lowering the operational difficulty of the train.

Potential Advantage of Magnetic Resonance Imaging in Detecting Thoracic Wall Infiltration in Pleural Mesothelioma. A Retrospective Single Center Analysis

Objective(s)Thoracic wall infiltration in Pleural Mesothelioma (PM) determines the extent of resection and can be an important prognostic factor. Currently, standardized imaging for restaging after neoadjuvant systemic therapy comprises contrast enhanced computed tomography (CT) or positron emission tomography (PET). Additional thoracic magnetic resonance imaging (MRI) could better discriminate chest wall infiltration preoperatively and increase staging accuracy. For this reason, the added benefit of MRI was evaluated at our center. MethodsA retrospective analysis of the extended imaging protocol was performed from 07/2018 to 03/2024, including descriptive analysis for patient`s sex, age, tobacco consumption, asbestos exposure, histological subtype, TNM-Stage, mRECIST criteria and number of neoadjuvant therapy cycles. Preoperative restaging included routine imaging and MRI. After histological diagnosis of PM, neoadjuvant therapy was conducted, followed by intended macroscopic complete resection, with intraoperative biopsies of suspicious chest wall lesions. CT and MRI results were compared with intraoperative biopsies. ResultsTwenty-six patients (mean age 65.50, 11.50% female) with operable PM were included. Of the 11 patients with histologically proven chest wall infiltration, 10 (90.91%) had a cT-Stage ≥ 3 and 4 (36.36%) and surgery resulted in a R2-Resection. Thoracic MRI showed a high sensitivity (90.91%) for the detection of chest wall infiltration, especially when compared with the CT scan (9.09%). ConclusionWith the adjunctive use of MRI we demonstrated a much higher sensitivity for detection of chest wall infiltration compared with conventional imaging prior to surgery. This may improve patient selection for surgery. Nevertheless, larger studies are required to confirm these results.

Sol-gel synthesized flexible Na2Ti6O13–aluminium oxide fibres for photocatalytic degradation of Acid red 1

Sodium titanate (Na2Ti6O13; NTO) was loaded onto aluminium oxide fibres (AFs) using the sol–gel method to synthesize NTO/AF fibres. The surface roughness of NTO/AF-n fibres increased with increasing number of dip-coating cycles (n = 1–3). The Fourier transform infrared spectra and X-ray photoelectron spectroscopy spectra of NTO/AF-n demonstrated the loading of NTO onto AF. The bandgap energies of NTO/AF-1, NTO/AF-2, NTO/AF-3 and NTO were determined to be 3.08, 3.12, 3.38 and 3.45 eV, respectively. The production of hydroxyl radicals by fibres under irradiation decreased in the order of NTO, NTO/AF-1, NTO/AF-2 and NTO/AF-3. NTO/AF-n fibres were designed for convenient separation from water, with NTO/AF-1 exhibiting the highest activity among the NTO/AF-n samples. The photocatalytic degradation efficiencies of NTO/AF-1, NTO/AF-2 and NTO/AF-3 after 30 min of reaction were determined to be 61.4 %, 51.7 % and 44.3 %, respectively. Complete removal of Acid Red 1 from the solution was achieved through a photocatalytic reaction using NTO/AF-n. The activity of NTO/AF-n samples remained stable over five reaction cycles, indicating their application potential for large-scale water treatment.