Cyanoethyl Derivatives Research Articles

Chemistry of Bis-2'-Cyanoethyl Derivatives of some Aromatic Primary Amines: Part VI. Preparation and Reactions of NN-Bis-2'-Cyanoethyl-m-Phenetidine

Chemistry of Bis-2'-Cyanoethyl Derivatives of some Aromatic Primary Amines: Part VI. Preparation and Reactions of NN-Bis-2'-Cyanoethyl-m-Phenetidine

Chemistry of bis-2' Cyanoethyl Derivatives of some Aromatic Amines: Part V. Preparation of some new Tertiary Amino Benzaldehydes and a study of some of their Reactions

Chemistry of bis-2' Cyanoethyl Derivatives of some Aromatic Amines: Part V. Preparation of some new Tertiary Amino Benzaldehydes and a study of some of their Reactions

Reactions of nitriles. Part V. Cyanoethylation of hydroxycoumarins

Cyanoethylation of some hydroxycoumarins has been investigated. The cyanoethyl derivatives obtained were hydrolysed to the corresponding acids. Cyclisation of the acids gave benzodipyrans.

Chemistry of Bis-2'-Cyanoethyl Derivatives of some Aromatic Amines: Part. IV*. Some Reactions of 2-Methyl-4-NN-bis- 2' -Cyanoethyl-amino benzaldehyde

Chemistry of Bis-2'-Cyanoethyl Derivatives of some Aromatic Amines: Part. IV*. Some Reactions of 2-Methyl-4-NN-bis- 2' -Cyanoethyl-amino benzaldehyde

Chemistry of Bis-2'-Cyanoethyl Derivatives of some Aromatic Amines. Part III. Some More Reactions of p-NN-Bis-2'-Cyanoethylaminobenzaldehyde

Chemistry of Bis-2'-Cyanoethyl Derivatives of some Aromatic Amines. Part III. Some More Reactions of p-NN-Bis-2'-Cyanoethylaminobenzaldehyde

Reduction of cobalt chelates of bis(acetylacetone)-ethylenediimine and synthesis of organocobalt derivatives

Complexes of CoIII and CoII of the type BrCo(BAE)PPh3 or CoII(BAE) can be reduced to NaCoI(BAE) by Na or 1% Na(Hg).The preparation of stable organocobalt complexes, RCo(BAE) and RCo(BAE)H2O (R = alkyl, vinyl, acyl), by reaction of NaCoI(BAE) with RX, is described.Six-coordinated complexes, RCo(BAE)L (L = pyridine, benzylamine, benzimidazole) were also prepared.The reactions of NaCoI(BAE) with acetylene and acrylonitrile in the presence of water yielding the vinyl and cyanoethyl derivatives are reported.Binuclear complexes (BAE)Co(CH2)4Co(BAE) and [RCo(BAE)NH2CH2]2 are also obtained.The chemical behaviour of the CoI complex shows a strong analogy with that of the Vitamin B12s.

Nucleic acid components and their analogues. CXI. Decyanoethylation of the cyanoethyl derivatives of uracil, 2-thiouracil, and 6-azauracil

Nucleic acid components and their analogues. CXI. Decyanoethylation of the cyanoethyl derivatives of uracil, 2-thiouracil, and 6-azauracil

The Function of Pseudouridylic Acid in Transfer Ribonucleic Acid: I. THE SPECIFIC CYANOETHYLATION OF PSEUDOURIDINE, INOSINE, AND 4-THIOURIDINE BY ACRYLONITRILE

Abstract The ability of acrylonitrile to cyanoethylate 13 nucleosides was examined. Only pseudouridine, inosine, and 4-thiouridine were found to react rapidly, yielding N1-cyanoethyl pseudouridine, N1-cyanoethyl inosine, and S-cyanoethyl 4-thiouridine, respectively. At much slower rates, a reaction with position N3 of uridine, ribothymidine, and N1-cyanoethyl pseudouridine was observed, and at very slow rates a 2'- (or 3'-) cyanoethyl derivative was produced with adenosine, guanosine, cytidine, and N1-cyanoethyl inosine. The variation of rate constant with pH showed that the rapidly reacting nucleosides must be in the anionic form for reaction to occur. The spectral, chromatographic, and electrophoretic properties of the derivatives were determined and used to assign the structures as given. The stability of the cyanoethyl derivatives to alkali and acid was examined and found to be sufficient to allow the application of standard procedures for the detailed nucleotide analysis of cyanoethylated transfer RNA.

Chemistry of Bis-2'-cyanoethyl Derivatives of Some Aromatic Primary Amines. Part I. Preparation of Some New Tertiary Aminobenzaldehydes and a Study of Some of their Reactions

Chemistry of Bis-2'-cyanoethyl Derivatives of Some Aromatic Primary Amines. Part I. Preparation of Some New Tertiary Aminobenzaldehydes and a Study of Some of their Reactions

The Preparation of Some Cyanoethyl Derivatives of Glucose.

The Preparation of Some Cyanoethyl Derivatives of Glucose.

Cyanoethylation of α-Amino Acids. III. Hydrolysis of Cyanoethyl Derivatives

Cyanoethylation of α-Amino Acids. III. Hydrolysis of Cyanoethyl Derivatives