Macro fibers could contribute to absorb energy through fiber sliding, which significantly enhance the energy absorption capacity of concrete beams. In this research, the synergistic effect of macro steel fibers and polypropylene (PP) fibers on the energy absorption capacity of concrete under bending is under investigated. The three-point bending test is adopted to compared the residual flexural strength and energy absorption capacity of fiber reinforced concrete (FRC) beams. Besides traditional Load-deflection curves, the energy absorption-crack mouth opening displacement (CMOD) curves are adopted to reflect the toughness of FRC beams. The synergistic effect of steel fibers and PP fibers on the residual flexural strength and energy absorption capacity is evaluated. A linear function is proposed to describe the relationship between energy absorption and CMOD for FRC beams. In addition, fiber distribution on cracking surface of FRC beams is analyzed through fiber distribution density and fiber spacing to explain the synergistic effect. Experimental results indicate that the behaviors of FRC beams, that is, residual flexural strength and energy absorption, are improved by adding macro fibers, in particular macro steel fibers. Besides, the relationship between energy absorption and CMOD of FRC beams can be fitted very well by the linear function. The slope of the energy absorption and CMOD relationship is adopted to analyze the contribution of macro fibers to energy absorption. The uniformity of fiber distribution is improved by increasing of fiber dosage for SFRC and PFRC beams. The hybrid use of macro steel fibers and PP fibers demonstrates a positive synergistic effect on the energy absorption capacity and flexural strength of concrete. The improved fiber spacing and fiber distribution density of hybrid fiber on cracking surface contribute to the positive synergistic effect observed in hybrid fiber reinforced concrete (HyFRC) beams.