Abstract Limitations on rated voltage and discharge current density pose challenges to battery miniaturisation, affecting their application in missiles and other weapon systems. A modification method of graphene composite manganese dioxide (MnO2) cathode material has been proposed. This method enhances the performance of lithium manganese dioxide thermal batteries (heat activated reserve batteries) by achieving a continuous discharge time from milliseconds to seconds, with a single-cell voltage exceeding 2.6V and a cathode output of 160 mA/cm2. Experimental results indicate that graphene-composite modification improves the output performance of individual lithium manganese dioxide thermal cells and facilitates the reduction of thermal battery design volume. However, further research is necessary to address the relatively low output current density of this thermal battery system.
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