Cumulative CO2 Research Articles

Assessing Transition Pathways of Hydrogen Production in China with a Probabilistic Framework.

The transition of China's hydrogen production system to meeting carbon neutrality is considerably uncertain. This study uses a probabilistic framework to assess the transition pathways of hydrogen production in China to meet the goal of carbon neutrality and reveals the key technology selection mechanism. Three strategies for hydrogen production transition were considered: delayed, orderly, and radical, corresponding to the green hydrogen shares between 70 and 95% in 2060. More ambitious strategies tended to result in greater uncertainty of green hydrogen production and introduce higher system costs and cost uncertainty. The different strategies showed notable differences in carbon dioxide (CO2) reduction pathways. The cumulative CO2 emissions of the delayed strategy may reach 3 times that of the radical strategy, and the CO2 reduction uncertainty of the orderly strategy may be twice that of the other strategies. Alkaline electrolyzers were predicted to dominate green hydrogen production until being surpassed by proton exchange membrane electrolyzers (PEM) after 2060. The synergy of the solar-energy storage-PEM technology combination was notable because expensive electrolyzers tended to increase utilization, thereby diluting fixed costs. Our results underscore the importance of studying the impact of uncertainty and technology selection mechanisms on transition pathways.

Pathways to zero emissions in California’s heavy-duty transportation sector

California contributes 0.75% of global greenhouse gas (GHG) emissions and has a target of reaching economy-wide net zero emissions by 2045, requiring all sectors to rapidly reduce emissions. Nearly 8% of California’s GHG emissions are from the heavy-duty transportation sector. In this work, we simulate decarbonization strategies for the heavy-duty vehicle (HDV) fleet using detailed fleet turnover and air quality models to track evolution of the fleet, GHG and criteria air pollutant emissions, and resulting air quality and health impacts across sociodemographic groups. We assess the effectiveness of two types of policies: zero emission vehicle sales mandates, and accelerated retirement policies. For policies including early retirements, we estimate the cost of early retirements and the cost-effectiveness of each policy. We find even a policy mandating all HDV sales to be zero emission vehicles by 2025 would not achieve fleetwide zero emissions by 2045. For California to achieve its goal of carbon neutrality, early retirement policies are needed. We find that a combination of early retirement policies and zero emission vehicle sales mandates could reduce cumulative CO2 emissions by up to 64%. Furthermore, we find that decarbonization policies will significantly reduce air pollution-related mortality, and that Black, Latino, and low-income communities will benefit most. We find that policies targeting long-haul heavy-heavy duty trucks would have the greatest benefits and be most cost-effective.

A Power System Study on Hydrogen Conversion Pathways for Gas Turbine Power Plants in Vietnam towards Net Zero Target

The potential applications of hydrogen in various fields of the energy sector are attracting attention worldwide, including the use of hydrogen for decarbonizing power systems. In Vietnam, hydrogen is considered to gradually replace natural gas in power generation to achieve the country’s net zero target by 2050 but there is a lack of research about this new subject. This study focuses on the computational simulation of the evolution of Vietnam’s power system in the period 2030–2050 according to non-conversion and slow, moderate, and accelerated scenarios of natural gas-to-hydrogen conversion at gas turbine power plants. Based on a total power system generation capacity of 150.5 GW in 2030, the modeling results show that the system capacity range of the scenarios is between 568.7 GW and 584.6 GW. In terms of economic performance, the slow conversion scenario has the lowest system cost of USD 1269.0 billion, and the accelerated scenario represents the highest system cost of USD 1283.2 billion. As for CO2 emissions of the power system, the accelerated scenario has the lowest cumulative CO2 emissions in the studied period while the non-conversion appears highest, 2933 and 3212 million tons, respectively. Based on the study results, the possible pathway recommendation of natural gas-to-hydrogen conversion for Vietnam’s power system is proposed.

Impact of carbon dioxide removal technologies on deep decarbonization: EMF37 MARKAL–NETL modeling results

This paper examines the MARKAL-NETL modeling results for the Energy Modeling Forum study on Deep Decarbonization and High Electrification Scenarios for North America (EMF 37) with a specific focus on carbon dioxide removal (CDR) technologies and opportunities under different scenario guidelines, policies, and technological advancements.The results demonstrate that CDR, such as bioenergy with carbon capture and storage (BECCS), direct air capture (DAC), and afforestation, are key technologies in deep decarbonization scenarios and account for 40–60 % of avoided carbon dioxide (CO2) emissions annually. From 2025 to 2050, cumulative CO2 abatement by CDR technologies will range from 37 to 47 billion tons (GtCO2), or more than 2 GtCO2 annually by 2050. The potential scale of CDR and its impact depends on the advancement and costs of energy supply and demand technologies, end-use sector electrification, and availability and costs of CDR. Results show that the price of carbon is substantially lower when advanced technologies are available, particularly in the EMF 37 carbon management scenarios [1].While BECCS deployment is likely to be constrained for environmental and/or political reasons, the results display relatively large-scale BECCS deployment. The study found that BECCS could make a substantial contribution to emissions reductions after 2035, and, in the medium term, CO2 sequestration by BECCS will depend on CO2 price; BECCS deployment starts at a carbon price of around $70/tCO2. Long-term CO2 sequestration by BECCS increases in all scenarios, reaching the same annual level of ∼890 MtCO2 by 2050 in net-zero CO2 scenarios. According to the modeling results, DAC acts as a true backstop technology at carbon prices of around $600/tCO2.

Co-composting of dewatered sludge and wheat straw with newly isolated Xenophilus azovorans: Carbon dynamics, humification, and driving pathways

Composting is a biological reaction caused by microorganisms. Composting efficiency can be adequately increased by adding biochar and/or by inoculating with exogenous microorganisms. In this study, we looked at four methods for dewatered sludge waste (DSW) and wheat straw (WS) aerobic co-composting: T1 (no additive), T2 (5% biochar), T3 (5% of a newly isolated strain, Xenophilus azovorans (XPA)), and T4 (5% of biochar-immobilized XPA (BCI-XPA)). Throughout the course of the 42-day composting period, we looked into the carbon dynamics, humification, microbial community succession, and modifications to the driving pathways. Compared to T1 and T2, the addition of XPA (T3) and BCI-XPA (T4) extended the thermophilic phase of composting without negatively affecting compost maturation. Notably, T4 exhibited a higher seed germination index (132.14%). Different from T1 and T2 treatments, T3 and T4 treatments increased CO2 and CH4 emissions in the composting process, in which the cumulative CO2 emissions increased by 18.61–47.16%, and T3 and T4 treatments also promoted the formation of humic acid. Moreover, T4 treatment with BCI-XPA addition showed relatively higher activities of urease, polyphenol oxidase, and laccase, as well as a higher diversity of microorganisms compared to other processes. The Functional Annotation of Prokaryotic Taxa (FAPROTAX) analysis showed that microorganisms involved in the carbon cycle dominated the entire composting process in all treatments, with chemoheterotrophy and aerobic chemoheterotrophy being the main pathways of organic materials degradation. Moreover, the presence of XPA accelerated the breakdown of organic materials by catabolism of aromatic compounds and intracellular parasite pathways. On the other hand, the xylanolysis pathway was aided in the conversion of organic materials to dissolved organics by the addition of BCI-XPA. These findings indicate that XPA and BCI-XPA have potential as additives to improve the efficiency of dewatered sludge and wheat straw co-composting.

Carbon dioxide fluxes over irrigated and rainfed alfalfa in the Southern Great Plains, USA

The annual dynamics of carbon dioxide (CO2) fluxes for irrigated and rainfed alfalfa (Medicago sativa L.) in the Southern Great Plains of the United States of America (USA) under different watering regimes are not yet fully understood. The main objective of this study was to examine the dynamics of eddy covariance (EC) measured CO2 fluxes in relation to various biophysical factors and hay harvests for irrigated and rainfed alfalfa in central Oklahoma, USA. The study also aimed to investigate the relationship between CO2 fluxes and satellite-derived enhanced vegetation index (EVI) at different spatiotemporal scales and to assess the temporal variability in CO2 fluxes and EVI to variable growing conditions and hay harvests. The cumulative hay yields were 7.15 t ha−1 (two harvests in 2019) in the rainfed field and ∼9 t ha−1 (4–5 harvests in 2020 and 2021) in the irrigated field. Having sufficient rainfall during April and May was crucial to achieve economically feasible yields of alfalfa during the first harvest in May. The availability of water strongly regulated the potential for regrowth and carbon uptake of alfalfa following harvesting. The alfalfa fields were near carbon neutral or a small carbon source from January to mid-March and carbon sink after the initiation of vegetative growth in mid-March. The alfalfa fields were strong carbon sinks (cumulative annual net ecosystem CO2 exchange, NEE, up to −578 g C m−2 in irrigated field) on an annual scale. When accounting for the loss of carbon due to the removal of hay from the fields, the carbon balance of the alfalfa fields varied from small carbon sinks to small carbon sources, depending on the amount of hay harvested annually and the growing conditions. In general, the temporal patterns of CO2 fluxes and EVI were similar in relation to growing conditions and hay harvests. However, some discrepancies and time lags were observed due to the coarse spatiotemporal resolution of the EVI products. Thus, it is essential to integrate two or more satellite products with different temporal and spatial resolutions to accurately monitor the frequent and varying sizes of hay harvests and vegetation regrowth after harvesting, and to simulate continuous time-series CO2 fluxes.

Large-Scale Experimental Investigation of Hydrate-Based Carbon Dioxide Sequestration

Hydrate-based CO2 sequestration is a novel approach that can not only realize permanent CO2 sequestration but can also form an artificial cap to prevent its upward migration. In this work, a self-developed large-scale 3D apparatus was employed to investigate hydrate formation characteristics in hydrate-based CO2 sequestration at a constant liquid CO2 injection rate through a vertical well for the first time. Temperature and pressure evolutions in the sediment were analyzed in detail. Key indicators, including cumulative sequestered CO2, CO2 in hydrate and liquid phases, the instantaneous hydrate conversion, and liquid CO2 retention rates, were calculated. The results show that hydrate continuously forms with increased CO2 injection and exhibits strong heterogeneity due to the variation in hydrate formation rate and quantity. Severe liquid CO2 heterogeneous figuring phenomena occur since hydrate deteriorates the effective pore structure and topology, resulting in relatively small cumulative sequestered CO2 when a large amount of CO2 is released from the outlet. Meanwhile, the instantaneous hydrate conversion and liquid CO2 retention rates have large fluctuations owing to water consumption and variation in the effective contact area between liquid CO2 and water. However, hydrate formation does not cause blockage of wellbore and formation nearby under given experimental conditions, which is beneficial for hydrate formation in deeper sediment. This study provides insights into hydrate formation and liquid CO2 immigration regularity during hydrate-based CO2 sequestration and demonstrates its feasibility at a field scale.

Soil respiration response to reductions in maize plant density and increased row spacing (Southeast pampas, Argentina)

Previous studies have recognized the influence of crop cover and agricultural management on variables (soil temperature, soil moisture, and root biomass) that influence soil respiration. However, despite the influence of plant density and row spacing on these variables in the maize crop (Zea mays L.), their impact on soil respiration has received little attention. Thus, the aims of this study were (i) to investigate whether reducing plant density and row spacing influences soil respiration, and (ii) to identify the controlling variables (soil temperature and soil moisture) underlying this response. We conducted field experiments in Balcarce, Argentina, over two seasons. Treatments included (i) maize crops at high plant density (≈8 plants m−2) and narrow rows (0.52 cm, HDN), and (ii) maize crops at low plant density (≈6.5 plants m−2) and wide row spacing (0.70 cm; LDW). Leaf area index (LAI), soil CO2 fluxes, soil superficial temperature, and moisture (characterized by the water-filled pore space, WFPS) were assessed throughout the growing season. Grain yield and cumulative soil CO2 emissions were determined at the final harvest. Major findings relevant to understanding the influence of reducing plant density and wider row spacing on instant CO2 fluxes include: (i) LAI reductions were related to higher superficial soil moisture, which was consistent at LAI ≥ 3; suggesting higher decreases in water uptake than increases in soil evaporation, and in turn (ii) increments in soil moisture were associated with higher CO2 fluxes. While lower plant density and wider row spacing had notable short-term effects on WFPS and soil respiration fluxes, they did not significantly affect cumulative soil respiration throughout the growing season. However, the combination of this practice with low-yield potential genotypes that exhibit low stability to changes in resource availability can increase CO2 emissions per unit of grain yield. These findings contribute to a better understanding of the impacts of management practices on soil respiration and, consequently, on carbon cycling within agricultural ecosystems.

Anaerobic digester liquor replacing chemical fertilizer in reducing greenhouse gas emissions under drip irrigation: Factors, pathways, and strategies

Anaerobic digester liquor (ADL) is a widely used alternative to mineral fertilizers, especially in the context of drip irrigation. However, differences in the manner in which drip irrigation systems are configured could alter the dynamics of the greenhouse gas emissions inherent in the use of ADL by the agricultural sector. Column experiments and structural equation modeling were used to explore the factors and pathways of drip irrigation methods (surface and subsurface drip irrigation) and substitution ratios of ADL (full, partial, and no substitution) on greenhouse gas emissions. The results showed that compared with surface drip irrigation, subsurface drip irrigation reduced daily and cumulative CO2 and N2O emissions but led to an increase in CH4 emissions. Similarly, substituting ADL for chemical fertilizers can also reduce greenhouse gas emissions, and when combined with subsurface drip irrigation, it can reduce the global warming potential (GWP) by up to approximately 50%. Over time, the contribution rates of the three greenhouse gases to the GWP remained essentially unchanged, mainly dominated by CO2 and N2O emissions. Drip irrigation methods and substitution ratios can drive differences in soil physiochemical properties. These differences directly or indirectly affect gas emission quantities and pathways. Soil water, carbon, and pores are important factors and mediators of gas-emission pathways. Overall, adopting the strategy of fully substituting subsurface drip irrigation of ADL for chemical fertilizer can significantly reduce greenhouse gas emissions and enhance the carbon sequestration effect.

Investigation on coal permeability evolution considering the internal differential strain and its effects on CO2 sequestration capacity in deep coal seams

The gas adsorption/desorption-induced coal deformation effect is a significant factor governing the evolution of coalbed permeability. Current theoretical investigations typically coal bulk and fracture deformation induced by gas are equivalent, neglecting the matrix-fracture interactions. Based on internal adsorption stress, this paper proposes Internal Differential Strain Coefficient (IDSC) to quantitatively characterize the relationship between coal bulk and fracture strain under equilibrium conditions. Coupling this coefficient constructs a binary gas permeability evolution model considering matrix-fracture interactions. Through numerical simulations of CO2-ECBM processes under various internal differential strain circumstances using this model, dynamic evolution patterns of diverse parameters are obtained. The research findings indicate that along the direction of CO2 injection, matrix-fracture interactions exhibit a complex trend of initially increasing, then decreasing and then increasing, and the increase in internal differential strain levels results in a downward trend in permeability peak. Additionally, the evolutionary characteristics of CH4 recovery and cumulative CO2 storage rising with increasing internal differential strain levels were obtained on time scales using a fixed-point monitoring methodology. Inspired by the aforementioned laws, this paper discusses the macroscopic influence of burial depth on the effects of internal differential strain, providing new theoretical support for CO2 sequestration injection methods in deep coal seams.

Effects of Straw Addition on N2O and CO2 Emissions from Red Soil Subjected to Different Long-Term Fertilization

Straw return, as an important measure for soil fertility improvement in farmland, significantly affects the emissions of greenhouse gases N2O and CO2. Thus, the collected soil samples from five long-term (30-year) fertilization treatments (no fertilization, CK; recommended chemical fertilizer, F; 200 % of recommended chemical fertilizer, 2F; pig manure, M; and chemical fertilizer combined with pig manure, FM) were amended with and without straw and incubated under constant temperature and humidity conditions (25 ℃ and 65 % maximum field water holding capacity) for 20 days so as to investigate the key factors influencing N2O and CO2 emissions in response to straw addition in long-term fertilization treatments. The results showed that fertilization significantly increased N2O emissions. Compared to those under the unfertilized treatment[(22.05 ±2.09) μg·kg-1, calculated as nitrogen, the same as below], cumulative N2O emissions from the chemical fertilizer treatments significantly increased by 119 %-195 %[(48.38 ±20.81) μg·kg-1 and (65.13 ±12.55) μg·kg-1 from the F and 2F treatments, respectively], and those from the manure treatments increased by 275 %-399 %[(82.72 ±12.73) μg·kg-1 and (1 101.99 ±425.71) μg·kg-1 from the M and FM treatments, respectively]. Soil NO3--N, DOC, and DTN were the main factors influencing N2O emissions from fertilized treatments in the absence of straw addition. Straw addition significantly increased cumulative N2O emissions by 345 % and 247 % in the 2F and M treatments, respectively, compared to those in the corresponding fertilized treatments without straw addition, with no significant effect on N2O emissions in the CK, F, and FM treatments. Straw addition increased DOC content and microbial activity and decreased soil NO3--N and DTN contents, thereby increasing N2O emissions. Fertilization also significantly increased CO2 emissions. Compared to those from the unfertilized treatment, cumulative CO2 emissions from the manure treatments significantly increased by 120 %-130 %[(122.11 ±4.3) mg·kg-1 (calculated as carbon, the same as below) and (116.47 ±4.55) mg·kg-1 from the M and FM treatments, respectively], and those in the 2F treatment increased by 28 %[(65.13 ±12.55) mg·kg-1]. In the absence of straw addition, soil MBC, DOC, and DTN were the main factors influencing CO2 emissions. Compared to those in the treatments without straw addition, straw addition significantly increased cumulative CO2 emissions by 660 %-1132 % among fertilization treatments, due to increased DOC and MBC contents and enhanced microbial activity. In conclusion, straw addition significantly increased N2O and CO2 emissions through increased soil DTN consumption and DOC content among fertilization treatments. In soils treated with manure amendment, straw return should be rationally considered for the purpose of balancing the comprehensive trade-offs between fertility improvement and greenhouse gas emissions.

Investigating the effects of climate change and anthropogenic activities on SOC storage and cumulative CO2 emissions in forest soils across altitudinal gradients using the century model

This study investigated the impact of climate change, grazing, manure application, and liming on soil organic carbon (SOC) stock and cumulative carbon dioxide (CO2) emissions in forest soils across different altitudes. Despite similar soil texture, acidity, and salinity across elevations, SOC stock significantly increased with altitude due to cooler temperatures and higher precipitation. The highest SOC stock (97.46 t ha−1) was observed at 2000–2500 m, compared to the lowest (44.23 t ha−1) at 500–1000 m. The Century C Model accurately predicted SOC stock, with correlation and determination coefficients exceeding 0.98. A climate change scenario projecting decreased precipitation (2.15 mm per decade) and increased temperature (0.4 °C) revealed potential SOC stock losses ranging from 28.36 to 36.35 %, particularly at higher altitudes. Grazing further decreased SOC stock, with a more pronounced effect at higher elevations. However, manure application (40 t ha−1 every four years) and liming (7–10 t ha−1 every three years) had positive effects on SOC stock, again amplified at higher altitudes and with an increase in lime application rate. In scenarios combining climate change with manure application and climate change with liming, manure application and liming mitigated some negative impacts of climate change, but could not fully offset them, resulting in 1.49–5.42 % and 0.39–4.07 % decreases respectively. Simulations of cumulative CO2 emissions mirrored the distribution of SOC stock, with higher emissions observed at higher altitudes and with management practices that increased SOC stock. This study emphasizes the critical role of conserving high-altitude forest soils and implementing optimal forest management strategies to combat climate change by minimizing SOC losses.

Effects of Ratoon Rice Cropping Patterns on Greenhouse Gas Emissions and Yield in Double-Season Rice Regions.

The ratoon rice cropping pattern is an alternative to the double-season rice cropping pattern in central China due to its comparable annual yield and relatively lower cost and labor requirements. However, the impact of the ratoon rice cropping pattern on greenhouse gas (GHG) emissions and yields in the double-season rice region requires further investigation. Here, we compared two cropping patterns, fallow-double season rice (DR) and fallow-ratoon rice (RR), by using two early-season rice varieties (ZJZ17, LY287) and two late-season rice varieties (WY103, TY390) for DR, and two ratoon rice varieties (YLY911, LY6326) for RR. The six varieties constituted four treatments, including DR1 (ZJZ17 + WY103), DR2 (LY287 + TY390), RR1 (YLY911), and RR2 (LY6326). The experimental results showed that conversion from DR to RR cropping pattern significantly altered the GHG emissions, global warming potential (GWP), and GWP per unit yield (yield-scaled GWP). Compared with DR, the RR cropping pattern significantly increased cumulative methane (CH4), nitrous oxide (N2O), and carbon dioxide (CO2) emissions by 65.73%, 30.56%, and 47.13%, respectively, in the first cropping season. Conversely, in the second cropping season, the RR cropping pattern effectively reduced cumulative CH4, N2O, and CO2 emissions by 79.86%, 27.18%, and 30.31%, respectively. RR led to significantly lower annual cumulative CH4 emissions, but no significant difference in cumulative annual N2O and CO2 emissions compared with DR. In total, the RR cropping pattern reduced the annual GWP by 7.38% and the annual yield-scaled GWP by 2.48% when compared to the DR cropping pattern. Rice variety also showed certain effects on the yields and GHG emissions in different RR cropping patterns. Compared with RR1, RR2 significantly increased annual yield while decreasing annual GWP and annual yield-scaled GWP. In conclusion, the LY6326 RR cropping pattern may be a highly promising strategy to simultaneously reduce GWP and maintain high grain yield in double-season rice regions in central China.

Carbon Cycle Response to Stratospheric Aerosol Injection With Multiple Temperature Stabilization Targets and Strategies

AbstractWe analyze the global carbon cycle response to a set of stratospheric aerosol injection (SAI) simulations performed by the CESM2(WACCM6‐MA) model. The simulations are performed under the specified SSP2‐4.5 CO2 concentration pathway. It is found that both the temperature stabilization target and the SO2 injection strategy have important effects on the global carbon sink. Relative to the SSP2‐4.5 scenario, averaged over the last 20 years of our simulations (year 2050–2069), simultaneous multi‐location SO2 injection causes an increase in cumulative land carbon uptake of 45 and 23 PgC, and an increase in cumulative ocean carbon uptake of 6 and 2 PgC for temperature stabilization targets of 0.5°C and 1.5°C respectively. For a temperature stabilization target of 1.0°C, SO2 injections increase land and ocean carbon sinks by 22–42 PgC and 4–7 PgC, respectively, depending on the strategies of SO2 injections (low latitude, mid‐to‐high latitude, and multi‐objective injection). Relative to SSP2‐4.5, by year 2069, SAI increases diagnosed cumulative CO2 emissions by 25–53 PgC (3%–6%), implying a decrease in atmospheric CO2 if SO2 injections were performed under a prescribed CO2 emission pathway. Stratospheric SO2 injections slow permafrost thaw, but do not restore permafrost to the previous extent at the same warming level for all injection strategies. An abrupt termination of SO2 injection weakens both the ocean and land carbon sink, and causes a rapid decline of permafrost extent. A gradual phaseout of SO2 injection slows sharp decline of permafrost and delays the rebound of carbon sink.

Maize straw increases while its biochar decreases native organic carbon mineralization in a subtropical forest soil

Organic soil amendments have been widely adopted to enhance soil organic carbon (SOC) stocks in agroforestry ecosystems. However, the contrasting impacts of pyrogenic and fresh organic matter on native SOC mineralization and the underlying mechanisms mediating those processes remain poorly understood. Here, an 80-day experiment was conducted to compare the effects of maize straw and its derived biochar on native SOC mineralization within a Moso bamboo (Phyllostachys edulis) forest soil. The quantity and quality of SOC, the expression of microbial functional genes concerning soil C cycling, and the activity of associated enzymes were determined. Maize straw enhanced while its biochar decreased the emissions of native SOC-derived CO2. The addition of maize straw (cf. control) enhanced the O-alkyl C proportion, activities of β-glucosidase (BG), cellobiohydrolase (CBH) and dehydrogenase (DH), and abundances of GH48 and cbhI genes, while lowered aromatic C proportion, RubisCO enzyme activity, and cbbL abundance; the application of biochar induced the opposite effects. In all treatments, the cumulative native SOC-derived CO2 efflux increased with enhanced O-alkyl C proportion, activities of BG, CBH, and DH, and abundances of GH48 and cbhI genes, and with decreases in aromatic C, RubisCO enzyme activity and cbbL gene abundance. The enhanced emissions of native SOC-derived CO2 by the maize straw were associated with a higher O-alkyl C proportion, activities of BG and CBH, and abundance of GH48 and cbhI genes, as well as a lower aromatic C proportion and cbbL gene abundance, while biochar induced the opposite effects. We concluded that maize straw induced positive priming, while its biochar induced negative priming within a subtropical forest soil, due to the contrasting microbial responses resulted from changes in SOC speciation and compositions. Our findings highlight that biochar application is an effective approach for enhancing soil C stocks in subtropical forests.

Carbon footprint and carbon balance of three long‐term dryland cropping sequences

AbstractCarbon footprints from plants, soil, and the environment are needed to evaluate C balance of an agroecosystem, which indicates if a system is a C source or sink for mitigating climate change. There is scarce information about C footprint and C balance in dryland agroecosystems. We measured C storage of above‐ and belowground crop biomass, CO2 fluxes, soil C sequestration rates, and C balances of three long‐term (34‐year‐old) dryland cropping sequences from 2016 to 2018 in the US northern Great Plains. Cropping sequences were no‐till continuous spring wheat (NTCW; Triticum aestivum L.), no‐till spring wheat–pea (NTWP; Pisum sativum L.), and conventional till spring wheat–fallow (CTWF). Carbon storage in grain, straw, root, and rhizodeposit were 29%–61% greater for NTCW and NTWP than CTWF. The CO2 flux peaked immediately after tillage, planting, fertilization, and intense precipitation (>10 mm) for 3 months in 2016–2017. Cumulative annual CO2 flux was 8%–37% greater for NTCW than NTWP and CTWF in 2016–2017, but was not different among cropping sequences in 2017–2018. Soil C sequestration rate at 0–10 cm measured from 2012 to 2019 was in the order: NTCW (0.27 Mg C ha−1 year−1) > NTWP > CTWF (−0.23 Mg C ha−1 year−1). Carbon balance remained negative and was not significantly different among cropping sequences but varied by year. Carbon loss increased with increased precipitation, regardless of cropping systems. Although a C source, the legume–nonlegume rotation can reduce C loss due to greater grain C output than other cropping sequences in the semiarid region of the northern Great Plains.

Study on the active regeneration characteristics of DPF in diesel-methanol dual-fuel engine under different exhaust oxygen concentrations

This study proposes a method to control exhaust oxygen (O2) concentration by adjusting the intake throttle valve, achieving intake throttling, and reducing intake airflow. The impact of exhaust O2 concentration at the inlet of the diesel oxidation catalyst (DOC) the diesel particulate filter (DPF) performance during active regeneration in diesel engines is investigated. Experiments are conducted under methanol substitution rates (MSR) of 0% and 20% to investigate how different exhaust O2 concentrations affect the performance of the DOC and DPF during active regeneration. A comparative analysis of fuel consumption and cumulative CO2 emissions during DPF active regeneration under different exhaust O2 concentrations is performed. Research results indicate that decreasing exhaust O2 concentration reduces exhaust flow, raising DOC inlet temperature. This enhancement improves catalytic conversion efficiency, accelerating the rise in DPF inlet temperature. The average conversion efficiency of DOC to unburned methanol exceeds 98.07%. After initiating DPF active regeneration, O2 concentration sharply drops, leading to elevated CO2 emissions. As soot combustion advances, the required O2 diminishes, resulting in a gradual rise and eventual stabilization of O2 emissions. Economically and environmentally, irrespective of MSR (20% or 0%), there exists an optimal exhaust O2 concentration that minimizes effective regeneration time during DPF active regeneration, achieving minimal fuel consumption and the lowest CO2 mass emissions. This study offers theoretical support for optimizing energy-saving and emission-reduction processes during DPF active regeneration.

Global aviation contrail climate effects from 2019 to 2021

Abstract. The current best-estimate of the global annual mean radiative forcing (RF) attributable to contrail cirrus is thought to be 3 times larger than the RF from aviation's cumulative CO2 emissions. Here, we simulate the global contrail RF for 2019–2021 using reanalysis weather data and improved engine emission estimates along actual flight trajectories derived from Automatic Dependent Surveillance–Broadcast telemetry. Our 2019 global annual mean contrail net RF (62.1 mW m−2) is 44 % lower than current best estimates for 2018 (111 [33, 189] mW m−2, 95 % confidence interval). Regionally, the contrail net RF is largest over Europe (876 mW m−2) and the USA (414 mW m−2), while the RF values over East Asia (64 mW m−2) and China (62 mW m−2) are close to the global average, because fewer flights in these regions form persistent contrails resulting from lower cruise altitudes and limited ice supersaturated regions in the subtropics due to the Hadley Circulation. Globally, COVID-19 reduced the flight distance flown and contrail net RF in 2020 (−43 % and −56 %, respectively, relative to 2019) and 2021 (−31 % and −49 %, respectively) with significant regional variations. Around 14 % of all flights in 2019 formed a contrail with a net warming effect, yet only 2 % of all flights caused 80 % of the annual contrail energy forcing. The spatiotemporal patterns of the most strongly warming and cooling contrail segments can be attributed to flight scheduling, engine particle number emissions, tropopause height, and background radiation fields. Our contrail RF estimates are most sensitive to corrections applied to the global humidity fields, followed by assumptions on the engine particle number emissions, and are least sensitive to radiative heating effects on the contrail plume and contrail–contrail overlapping. Using this sensitivity analysis, we estimate that the 2019 global contrail net RF could range between 34.8 and 74.8 mW m−2.

Greenhouse gas emissions and their driving factors among different flowering Chinese cabbage (Brassica campestris L.) varieties.

Crop cultivars have an influence on greenhouse gas (GHG) emissions, and there is variation between varieties. However, there are few reports available on the differences in GHG emissions and their driving factors among vegetable varieties. In this study, we conducted a field experiment to examine the variances in GHG emissions and their contributing factors among eight flowering Chinese cabbage varieties (considering growth period, leaf shape, and colour). The results showed significant differences in GHG emissions within varieties; early-maturing varieties exhibited GHG by 25.6% and 15.3%, respectively, when compared to mid- and late-maturing varieties. Among the different leaf types and color classifications, light-colored and sharp-leafed varieties had the lower global warming potential (GWP) overall. Cumulative CO2 emissions were influenced by leaf SPAD values and biomass, while cumulative N2O emissions were driven mainly by stem thickness, carbon accumulation, leaf SPAD values, and biomass. In summary, the selection of light-colored varieties with pointed leaves and shorter growth periods in actual production contributed positively to the reduction of carbon emissions from flowering Chinese cabbage production. Through efficient variety screening, this study provides a win-win strategy for achieving efficient vegetable production while also addressing the global climate challenge.

The Role of Ocean Mesoscale Variability in Air‐Sea CO2 Exchange: A Global Perspective

AbstractOcean mesoscale flows significantly influence nutrient distribution and biological productivity, yet the scarcity of eddy‐permitting observational data sets and climate modeling hinders understanding their role in carbon sequestration. Using an eddy‐resolving global simulation, this study investigates the significance of ocean mesoscales in air‐sea carbon dioxide (CO2) exchange. Results show over 30% of CO2 flux variance in energetic regions attributed to flows with horizontal scales smaller than 2°. Mesoscale flows can drive a cumulative CO2 flux that is either a net carbon sink or source depending on region, with magnitudes on the order of 105 tonnes of carbon per year. Variations in this mesoscale‐related CO2 flux are correlated with local relative vorticity and the background gradient of ocean partial pressure of CO2. This analysis underscores the importance of considering ocean mesoscales in monitoring carbon flux, highlighting the need to explore the influence of increasing eddy activity on carbon uptake in a changing climate.