Crystal Technology Research Articles

Progress and prospect of ultrafast response liquid crystal technology

Progress and prospect of ultrafast response liquid crystal technology

Creating Tunable Micro-Optical Components via Photopolymerization 3D Printing Combined with Polymer-Dispersed Liquid Crystals

Based on additive manufacturing via photopolymerization, this study combines polymer-dispersed liquid crystal (PDLC) technology with 3D printing technology to produce tunable micro-optical components with switchable diffraction or focusing characteristics. The diffraction grating and Fresnel zone plate are the research targets. Their structures are designed and simulated to achieve expected optical functions. A liquid crystal display (LCD) 3D printer is used to produce structures on transparent conductive substrates. The printed structures are filled with PDLCs and covered with transparent conductive substrates to achieve tunable functions. The proposed configurations are implemented and verified. The experimental results show that the diffraction efficiency of the 0th order increases from 15% to 50% for the diffraction grating and the focusing spot intensity decreases from 74% to 12% after the application of an electric field. These results demonstrate the feasibility of the proposed tunable optical component configurations.

Decontamination and Circular Economy of Dredged Material and Mining Waters Using Adiabatic Sonic Evaporation and Crystallization (ASEC) Technology

Decontamination and Circular Economy of Dredged Material and Mining Waters Using Adiabatic Sonic Evaporation and Crystallization (ASEC) Technology

Engineering of Rotational Dynamics via Polymorph Manipulation.

We used dielectric spectroscopy to uncover the rotational dynamics of the fluorophenyl rotor in different polymorphs of two amphidynamic crystals with identical sizable cores. The rotor solid-state dynamics were investigated in various crystalline environments. We did not change the chemical structure of the crystal itself, but while maintaining the same atomic composition, we changed the arrangement of atoms in space by taking advantage of crystal polymorphism, providing an alternative approach to one based on searching for new, chemically different entities with desirable functionality. We demonstrated that via polymorph variation, we can efficiently improve rotor solid-state performance and reduce the rotational barrier height by 30%. Our findings advance the understanding of polymorph engineering as a prospective trend in amphidynamic crystal technology, which uses the phenomenon of crystal polymorphism to design crystals displaying applicable internal rotational dynamics.

LD-Pumped 228 nm Nd:GdVO4/Cr4+:YAG Passively Q-Switched Solid-State Laser

The 228 nm deep ultraviolet laser, leveraging its advantages of short wavelength, high photon energy, and low thermal effect, can significantly enhance the Raman signal in resonance Raman spectroscopy and demonstrates broad application potential in areas such as precision processing of photonic devices. This paper investigates a solid-state linear-cavity passively Q-switched 228 nm deep ultraviolet laser. Firstly, the laser employs an Nd:GdVO4 crystal as the gain medium, combined with Cr4+:YAG crystal passive Q-switching technology to generate 912 nm pulsed fundamental frequency light. Subsequently, a lithium metaborate (LBO) crystal is used to generate 456 nm second-harmonic light, and finally, a barium metaborate (BBO) crystal is utilized to achieve 228 nm fourth-harmonic laser output. In this paper, we investigate the variation in 456 nm and 228 nm laser output power under the cavity length of 63 mm. Ultimately, at a pump power of 41.75 W, the highest average power of 670 mW was achieved for a 456 nm blue laser output with a repetition rate of 12 kHz and a pulse width of 32 ns. Additionally, a maximum average power of 18 mW was obtained for a 228 nm deep ultraviolet laser output, featuring a repetition rate of 12 kHz and a pulse width of 33 ns.

Tunable Optical Filter Based on Thin Film Lithium Niobate Photonic Crystals

In this paper, we propose a tunable optical filter with a high Q factor based on photonic crystal technology, achieving a Q factor of 442.85 using thin film lithium niobate technology. By proportionally adjusting the dimensions of the unit structure, this filter enables coarse tuning across the 1520–1570 nm range (C band). Furthermore, by utilizing the thermo-optic effect of lithium niobate, we can achieve fine-tuning of the optical filter within a temperature range of 300 K to 600 K, allowing for a center wavelength tuning capability of up to 3.7 nm. This design not only enhances the filter’s performance but also broadens its potential applications in optical communication and optical signal processing.

Influence of silica fume on pore structure, mechanical properties and carbon emission of reactive powder concrete prepared by ice crystal homogenization technology

Under ultra-low water-to-binder ratio conditions, the liquid-bridge effect between powders seriously restricts the development of reactive powder concrete (RPC). Ice crystal homogenization technology fundamentally solves the liquid-bridge problem between powders. However, high carbon emissions still constrain the application of RPC. This paper introduces an innovative RPC material incorporating silica fume (SF) as a supplementary cementitious material to solve environmental concerns and alleviate powder aggregation challenges based on the ice crystal homogenization technology. Experimental results show that there was a significant improvement in compressive and flexural strengths observed, particularly in RPC material containing 15% SF, which exhibited the most notable enhancements: a 19.7% increase in compressive strength to 296.3MPa and a 23.6% increase in flexural strength to 43.8MPa. Moreover, the optimized microstructure was reflected in a substantial reduction in water absorption rate and cumulative pore volume by 44.7% and 54.4%, respectively. Besides, RPC incorporating 15% SF achieved the lowest carbon emissions efficiency, with carbon emissions efficiency could be reduced by 79%~93% compared with conventional UHPC. In conclusion, the use of SF and ice crystal homogenization technology in RPC provides the great potential for developing sustainable construction materials and promoting carbon reduction strategies.

Issue Information: Crystal Research and Technology 12'2024

Issue Information: Crystal Research and Technology 12'2024

Cu2O@Cu-composed hollow spheres capable of Generating Rich reactive oxygen species for efficient photodynamic antibacterial application

Cuprous oxide (Cu2O), which has an appropriate band gap, is widely used as a marine antifouling biocide. This makes it increasingly valuable for photocatalytic antibacterial applications. Using crystal engineering technology to create Cu2O with tailored Cu2O/Cu interfaces and crystal planes can effectively enhance its performance but presents challenges. Herein, we report a simple wet chemical method for the controlled preparation of Cu2O@Cu hollow heterostructure. Experimental results demonstrate that the prepared composites exhibited highly efficient and broad-spectrum photocatalytic antibacterial effects against both Gram-negative and Gram-positive bacteria, achieving 100% antibacterial efficiency under 10 min of irradiation, much more effective than the bulk Cu2O. Characterization results show that a hollow spherical structure consisted of fine Cu2O@Cu nanoparticles in their wall, and the generated interfaces facilitated the migration and separation of photogenerated charge carriers and promoted the formation of hydroxyl radicals with stronger oxidizing abilities. Meanwhile, the Cu outside layer of each Cu2O@Cu particle not only acted as a shield to protect Cu2O from corrosion but also served as an electron acceptor to efficiently transfer photogenerated electrons, thereby demonstrating highly effective and stable antibacterial performance. This study not only offers a valuable reference for developing highly efficient and universal photocatalytic materials but also provides insight into the chemical reaction in the photocatalytic antibacterial process.

A Comprehensive Review on Polymer-Dispersed Liquid Crystals: Mechanisms, Materials, and Applications.

Polymer-dispersed liquid crystals (PDLCs) stand at the intersection of polymer science and liquid crystal technology, offering a unique blend of optical versatility and mechanical durability. These composite materials are composed of droplets of liquid crystals interspersed in a matrix of polymeric materials, harnessing the optical properties of liquid crystals while benefiting from the structural integrity of polymers. The responsiveness of LCs combined with the mechanical rigidity of polymers make polymer/LC composites-where the polymer network or matrix is used to stabilize and modify the LC phase-extremely important for scientists developing novel adaptive optical devices. PDLCs have garnered significant attention due to their ability to modulate light transmission properties, making them ideal candidates for applications ranging from smart windows and displays to light shutters and privacy filters. The incorporation of different ferroelectric, thermoelectric, magnetic, and ferromagnetic nanoparticles, quantum dots, nanorods, and a variety of dyes in the PDLC matrix has gained momentum over a span of few decades, as it lowers the otherwise-required high operating voltage and reduces the electro-optical response time of these devices. Due to better contrast in the transmittance of these materials in the field-off and on states, they find extensively wide application in a variety of photonic applications, viz., optical shutters and smart windows, photorefractives, modern displays, microlens arrays encompassing polymer-gravel lenses, and many other. Since the functional parameters of these devices embrace the thermophysical attributes of PDLC networks, it therefore becomes necessary to perform a detailed analysis of the properties of PDLCs and their ameliorations upon the addition of different dopants. This Review aims to review the recent advances in PDLCs and their enrichment in terms of their performance parameters upon the addition of a variety of dopants, as well as the improvement of different photonic applications owing to superior parametric implementation of these networks.

Structural optimization of pyridine quinoxaline cobalt (II) catalysts for MMA polymerization based on systematical SCSC transformation study

The Schiff base condensation reaction was adopted to synthesize a series of pyridine-based quinoxaline ligands (L1, L2, L3, L4) using 2-acetylpyridine and 1,2-phenylenediamine aromatic amines with different substituents of –OCH3, –F, -Cl, -Br. Then, four symmetrical dinuclear metal complexes (1–4) were obtained by coordination reaction of the synthesized ligands with CoCl2·6H2O, and six unexpectedly systematic and novel solvent-involved asymmetric mononuclear metal complexes (1A-4A, 3B, 4B) were obtained during single crystals cultivating by solvent diffusion method. The microscopic composition of the complexes were proved by a series of characterizations such as elemental analysis, IR and UV–vis. At the same time, by improving the single crystal culture technology, full crystal sample of compounds was obtained and X-ray single crystal diffraction showed a rare single crystal to single crystal structure transition (SCSC) phenomenon in this study. Furthermore, the catalytic properties of the complexes for MMA polymerization was explored, it was found that the catalytic activity of complexes 1–4 containing different types of substituents on pyridyl quinoxaline ligand was in the order of 1 < 2 <3 < 4, indicating that the complex with an electron-withdrawing substituent showed the higher activity than that of electron-donating substituent. Complexes 1A-4A, 3B and 4B showed higher catalytic activity in MMA polymerization than 1–4, which confirmed that the catalytic activity of mononuclear complexes were generally higher than that of binuclear complexes.

Dual-sided transparent display enabled by polymer stabilized liquid crystals for augmented reality

In the past decade, display technology has been reimagined to meet the needs of the virtual world. By mapping information onto a scene through a transparent display, users can simultaneously visualize both the real world and layers of virtual elements. However, advances in augmented reality technology have primarily focused on wearable gear or personal devices. Here we present a single display capable of delivering visual information to observers positioned on either side of the transparent device. This dual-sided display system employs a polymer stabilized liquid crystal waveguide technology to achieve a transparency window of 65% while offering active-matrix control. An early-stage prototype exhibits full-color information via time-sequential processing of a red-green-blue light-emitting diode strip. The dual-sided display provides a perspective on transparent mediums as display devices for human-centric and service-related experiences that can support both enhanced bi-directional user interactions and new media platforms.

Issue Information: Crystal Research and Technology 11'2024

Issue Information: Crystal Research and Technology 11'2024

Polarization Independent Dynamic Beam Steering based on Liquid Crystal Integrated Metasurface

Digital Micromirror Devices, extensively employed in projection displays offer rapid, polarization-independent beam steering. However, they are constrained by microelectromechanical system limitations, resulting in reduced resolution, limited beam steering angle and poor stability, which hinder further performance optimization. Liquid Crystal on Silicon technology, employing liquid crystal (LC) and silicon chip technology, with properties of high resolution, high contrast and good stability. Nevertheless, its polarization-dependent issues lead to complex system and low efficiency in device applications. This paper introduces a hybrid integration of metallic metasurface with nematic LC, facilitating a polarization-independent beam steering device capable of large-angle deflections. Employing principles of geometrical phase and plasmonic resonances, the metallic metasurface, coupled with an electronically controlled LC, allows for dynamic adjustment, achieving a maximum deflection of ± 27.1°. Additionally, the integration of an LC-infused dielectric grating for dynamic phase modulation and the metasurface for polarization conversion ensures uniform modulation effects across all polarizations within the device. We verify the device’s large-angle beam deflection capability and polarization insensitivity effect in simulations and propose an optimization scheme to cope with the low efficiency of individual diffraction stages.

Exploring the feasibility of using fluidized bed homogeneous crystallization technology to recover sulfate ions from briny water as calcium sulfate pellets

The increasing salinity of water sources poses significant operational and environmental challenges, highlighting the importance of developing efficient methods for recovering [SO42−] ions from briny wastewater. In this study, the potential of fluidized bed homogeneous crystallization (FBHC) technology for recovering [SO42−] ions from briny water is explored. FBHC is an innovative technique that enhances scalability and separation efficiency by promoting the growth of crystalline particles in a fluidized state. To achieve maximum [SO42−] recovery and maintain stable fluidized bed conditions, a pH of 8 is recommended. A removal ratio (RR) of 71 % was recorded at a [SO42−] concentration of 0.14 M. Various [SO42−] concentrations exhibited a molar ratio (MR) of [Ca2+]/[SO42−] = 1.5. Smaller particles, which are more soluble and exhibit less nucleation, are typically formed under conditions with lower pH and [Ca2+] levels. Intermediate-sized particles are favored at neutral to slightly alkaline pH levels and near-stoichiometric [Ca2+]/[SO42−] MR. Greater calcium content and higher pH values promote the development and agglomeration of larger particles, with 50 % of the particles exceeding an average size of 0.38 mm. In the XPS study of CaSO4 crystals (gypsum), the Ca 2p1/2 and Ca 2p3/2 peaks are observed at binding energies of 351.5 eV and 347.7 eV, respectively. Gypsum is identifiable due to the presence of clear and distinct peaks in XRD patterns. SEM analysis reveals the coexistence of amorphous patches and tiny crystalline domains on the surface. These gypsum crystals resemble stacked needle-like structures accompanied by small, powdery crystals. In an acidic environment, the primary phase is CaSO4·2H2O, which generates well-formed, elongated, or tabular crystals that are characteristic of gypsum. The FBHC process, characterized by a high crystallization ratio (CR = 68 %) and the recovery of crystal pellets (>0.3 mm), significantly reduces sludge production compared to traditional chemical precipitation methods. Its cost-effectiveness and recoverability make FBHC a promising technology for the recovery of sulfate ions from briny wastewater.

Low-voltage and high-contrast polymer dispersed liquid crystals enabled by ferroelectric fluoro-copolymer doped polyimide film

Smart windows incorporating polymer dispersed liquid crystal (PDLC) technology provide user-friendly operation and play a significant role in intelligent buildings and building energy conservation. Long standing issues of the PDLCs such as high driving voltage, low contrast ratio, and narrow viewing angle hinder their applications. Here PDLCs are sandwiched between the hybrid substrates composed of the ferroelectric polyvinylidene fluoride trifluoroethylene (P(VDF-TrFE)) copolymer and the homogeneous polyimide. The high dielectric constant and ion-trapping ability of ferroelectric copolymers increase the effective voltage drop in the PDLCs. Concurrently, the local electric field created by large dipole moment of ferroelectric copolymers triggers the alignment of liquid crystals (LCs) along the applied field. These synergistic effects contribute to a substantial decrease in the driving voltage of PDLCs. In the opaque state, the random dipole moments in ferroelectric copolymers disrupt the LC orientations near hybrid substrates, thereby increasing the light scattering and reducing the transmission of PDLCs. Consequently, the proposed PDLCs exhibit a contrast ratio ∼2× higher compared to the conventional PDLCs at normal incident. Moreover, the proposed PDLCs demonstrate a wider viewing angle in the transparent state compared to conventional PDLCs. This development promises energy-efficient, eco-friendly, and cost-effective smart windows.

Issue Information: Crystal Research and Technology 10'2024

Issue Information: Crystal Research and Technology 10'2024

Facilitating Oriented Dense Deposition: Utilizing Crystal Plane End-Capping Reagent to Construct Dendrite-Free and Highly Corrosion-Resistant (100) Crystal Plane Zinc Anode.

Dendrite growth and corrosion issues have significantly hindered the usability of Zn anodes, which further restricts the development of aqueous zinc-ion batteries (AZIBs). In this study, a zinc-philic and hydrophobic Zn (100) crystal plane end-capping reagent (ECR) is introduced into the electrolyte to address these challenges in AZIBs. Specifically, under the mediation of 100-ECR, the electroplated Zn configures oriented dense deposition of (100) crystal plane texture, which slows down the formation of dendrites. Furthermore, owing to the high corrosion resistance of the (100) crystal plane and the hydrophobic protective interface formed by the adsorbed ECR on the electrode surface, the Zn anode demonstrates enhanced reversibility and higher Coulombic efficiency in the modified electrolyte. Consequently, superior electrochemical performance is achieved through this novel crystal plane control strategy and interface protection technology. The Zn//VO2 cells based on the modified electrolyte maintained a high-capacity retention of ≈80.6% after 1350 cycles, corresponding to a low-capacity loss rate of only 0.014% per cycle. This study underscores the importance of deposition uniformity and corrosion resistance of crystal planes over their type. And through crystal plane engineering, a high-quality (100) crystal plane is constructed, thereby expanding the range of options for viable Zn anodes.

Фотонные кристаллы: оптимизация характеристик и перспективы оптических приложений

Background: Photonic crystals (PCs) have emerged as a new material for light manipulation, providing unprecedented control over light-matter interaction. This unique capacity is due to their periodic dielectric structure, which may produce photonic band gaps that impact photon transmission. Objective: The article summarizes current advances in photonic crystal design and use, focusing on their significance in creating next-generation optical systems. Methods: The article performed a complete literature analysis, concentrating on the most recent PC production and characterization approaches. Innovative techniques like 3D printing, nanoimprint lithography, self-assembly, and advanced computational modelling were studied in depth to optimize their optical characteristics. Results: Recent studies show that PC manufacturing accuracy has increased significantly, allowing for more effective light manipulation and enhanced optical device functioning. Applications such as ultrasensitive sensors, improved optical fibers, and innovative laser designs demonstrate PCs' rising value. Conclusion: The ongoing advancement of photonic crystal technology is laying a solid basis for the next generation of optical devices. These developments improve existing applications and provide opportunities to investigate new functionality in optical and other electromagnetic systems. Incorporating PCs into numerous technical sectors holds the prospect of significant advances in both commercial and scientific fields.

Dynamic geometric phase holography based on in-plane switching liquid crystal

ABSTRACT Liquid crystal geometric phase modulation technology is expected to achieve thin, small and achromatic spatial light modulation, which in turn has the potential to achieve holographic displays with large field angles and high clarity. This article presents a continuous dynamic geometric phase liquid crystal spatial light modulation method based on in-plane switching (IPS) mode. The relationship between geometric phase modulation and driving voltage is calibrated by using interferometry. Two hundred fifty-six phase orders within the phase modulation range of 0~π/2 is achieved. Subsequently, a phase hologram with a modulation range of 0~π/2 was designed by combining the GS (Gerchberg-Saxton) algorithm and single Fourier transform, demonstrating the holographic display capability. This article provides a low-cost approach for dynamic geometric phase holographic display.