Cryogenic Storage Research Articles

Advanced natural gas liquefaction and regasification processes: Liquefied natural gas supply chain with cryogenic carbon capture and storage

Natural gas combined cycle power plants generate substantial amounts of CO2. Also, since natural gas is produced in limited sites, the liquefied natural gas (LNG) supply chain consumes considerable energy in transporting natural gas overwide. Herein, advanced natural gas liquefaction and regasification processes using an LNG supply chain with cryogenic CO2 capture and storage (CCS) are proposed using Aspen Plus® V11. This solves three significant problems associated with conventional LNG supply chains. First, through the utilization of LNG cold energy, the cryogenic CCS process reduces the efficiency penalty of power generation from 14.34 to 4.45%. Second, solid CO2 from cryogenic CCS is used as an additional cold source in the natural gas liquefaction process by conveying it to the liquefaction site via the returning LNG ship. As a result, the power consumption in the refrigerant cycle is reduced by up to 67.17% than single mixed refrigerant (SMR) process. Finally, the LNG supply chain with cryogenic CCS minimizes the sustained energy waste between the natural gas liquefaction and regasification stages owing to the geographical separation. LNG cold energy from the regasification stage is utilized in the form of solid CO2 in the CCS and liquefaction stages. Consequently, the exergy efficiency in the overall LNG supply chain increases from 18.18 to 46.39%. The findings of this study can potentially provide environmentally friendly design guidelines for various LNG processes that use LNG cold energy in CCS and natural gas liquefaction.

Mechanical properties degradation of Sn 37Pb solder joints caused by interfacial microstructure evolution under cryogenic temperature storage

The interfacial microstructure, shear property and fracture behaviors of Sn37Pb joints after cryogenic temperature storage for different durations were investigated in this study, storage test at room temperature (298 K) and thermal aging test at 423 K were also carried out as comparison. The morphology of interfacial Cu6Sn5 IMCs for the joints stored under 77 K and 173 K transformed from scallop-like to column-like, moreover, the IMC layer thickness slowly increased with prolonged storage time. The growth rate of Cu6Sn5 layer in Sn37Pb joint stored at 77 K was slightly faster as compared with that stored at 173 K. However, the morphology and thickness of Cu6Sn5 IMC layer still remained roughly unchanged after storage at 298 K for up to 40 days. The Cu6Sn5 IMC growth of Sn37Pb joint stored at 77 K and 173 K was expected to be caused by Cu atom diffusion from Cu pad towards Sn37Pb solder, which was induced by the stress gradient. Additionally, the shear force declined and fracture position changed from in Sn37Pb solder to primarily in Sn37Pb solder and partly along the interface with the prolonging of storage time at 77 K and 173 K, which were induced by IMC layer growth.

Optically pumped polarized [formula omitted]He[formula omitted] ion source development for RHIC/EIC

The proposed polarized 3He++ acceleration in RHIC and the future Electron-Ion Collider will require about 2×1011 ions in the source pulse. A new technique had been proposed for production of high intensity polarized 3He++ ion beams. It is based on ionization and accumulation of the 3He gas (polarized by metastability-exchange optical pumping and in the 5T high magnetic field) in the existing Electron Beam Ion Source (EBIS). A novel 3He cryogenic purification and storage technique was developed to provide the required gas purity. An original gas refill and polarized 3He gas injection to the EBIS long drift tubes, (which serves as the storage cell) were developed to ensure polarization preservation. An infrared laser system for optical pumping and polarization measurements in the high 3–5T field has been developed. The 3He polarization 80–85% (and sufficiently long ∼30min relaxation time) was obtained in the “open” cell configuration with refilling valve tube inlet and isolation valve closed. The development of the spin-rotator and 3He4He absolute nuclear polarimeter at 6MeV 3He++ beam energy is also presented.

Experimental and numerical study on low-temperature supersonic ejector

Ejectors have emerged as a viable solution for handling Boil-Off-Gas (BOG) generated by cryogenic storage tanks. The efficiency of ejector-based systems plays is highly dependent on the ejector's performance which is influenced by various factors including the geometry of the ejector and the boundary conditions. In this study, an axisymmetric supersonic ejector was designed, optimized, and evaluated for BOG removal. The baseline geometric dimensions design of the ejector was obtained via theoretical analysis. Subsequently, computational fluid dynamics (CFD) simulations were employed to optimize the boundary conditions and geometrical parameters. Experimental investigations were conducted to validate the design and evaluate the ejector's performance. The results highlighted the significant influence of two key parameters, namely, the mixing chamber diameter (Dm) and the nozzle exit position (NXP), on the ejector's performance. Optimized Dm showed an increase of about 12.5% compared with the baseline geometry. By operating the ejector within its on-design geometric and boundary conditions, the maximum entrainment ratio (ER) was achieved. The CFD models successfully identified and validated various flow phenomena, including double choke, single choke, and backflow, which were consistent with the experimental observations. Both the numerical models and experimental findings demonstrated that the modified ejector achieved an entrainment ratio of 1.06 under its design condition showing a 33.66% increase compared with that obtained using the baseline geometry. These results indicate the potential of the supersonic ejector as an alternative solution for BOG applications, emphasizing its efficacy in handling this industrial challenge.

Experimental Investigation on Pressure-Control Characteristics of Liquid Hydrogen Tank Based on Active and Passive Thermodynamic Venting System Technology

Pressure control while minimizing the mass loss of liquid hydrogen is one of the key technologies required for the long-term storage of cryogenic propellants in microgravity in space, and the use of a thermodynamic venting system (TVS) has been considered as an effective means to solve this problem. In order to investigate the characteristics of pressure control by TVS technology, a cryogenic test platform for liquid hydrogen that integrated active and passive TVS was set up, a spray-bar exchanger and vapor-cooling screen were used to eliminate thermal stratification and realize the reuse of cold energy. Ten pressure-control tests using passive TVS (PTVS), mixing and active TVS (ATVS) strategies with heating powers of 0 W, 40 W and 80 W, were carried out. The single cycle time under different strategies, the effect of heating power on single cycle time, and the comparison of volume of the venting GH2 in different tests were analyzed in detail, the research showed that TVS technology could accurately control the pressure of cryogenic storage tanks within a predetermined range. An additional evaporation test was carried out using a direct venting method to compare with the above PTVS and ATVS tests, and the results showed that the venting volume of GH2 in unit time by the direct-venting method was close to that of the PTVS test with the heating power of 40 W, and the venting volume in unit time by the ATVS strategy was decreased by 87.3% compared to the direct-venting test.

Non-Oberbeck-Boussinesq effects and sub-critical primary bifurcations in porous media convection

Large temperature variations and highly unstable density stratification may exist between the cold and hot boundaries of the porous non-vacuum gas filled insulation layers of cryogenic storage tanks. For example, the density can vary by about a factor 3 in N2 filled liquefied natural gas (LNG) tank insulation layers and factor 15 in H2 filled liquid hydrogen (LH2) tank insulation layers. In such cases, the bifurcation of the convective states from the conduction state could be sub-critical leading to sudden jumps and hysteresis effects in heat transfer and boil-off rates. This work examines the impact of large physical property variation and non-Oberbeck-Boussinesq (non-OB) effects on the nature of bifurcation of convective states in gas filled porous insulation layers. Specifically, we show that the well-known super-critical (pitchfork) bifurcation of convective states that appear under the OB approximation changes to sub-critical bifurcation when the temperature difference exceeds a critical value. Further, under such large temperature variations, the emerging convective solutions could be highly asymmetric with center of circulation much closer to the cold boundary. We present linear stability results, local bifurcation analysis as well as numerical simulations of the full model equations for the two selected LNG and LH2 cases.

Effect of microorganisms isolated by preoperative osseous sampling on surgical site infection after autologous cranioplasty: A single-center experience

PurposeThe most frequent postoperative complication in autologous cranioplasty (AC) is infection. European recommendations include osseous sampling before cryogenic storage of a bone flap. We evaluated the clinical impact of this sampling. MethodsAll patients who underwent decompressive craniectomy (DC) and AC in our center between November 2010 and September 2021 were reviewed. The main outcome was the rate of reoperation for infection of the cranioplasty. We evaluated risk factors for bone flap infection, rate of reoperation for any reason (hematoma, skin erosion, cosmetic request, or bone resorption), and radiological evidence of bone flap resorption. ResultsA total of 195 patients with a median age of 50 (interquartile range: 38.0–57.0) years underwent DC and AC between 2010 and 2021. Of the 195 bone flaps, 54 (27.7%) had a positive culture, including 48 (88.9%) with Cutibacterium acnes. Of the 14 patients who underwent reoperation for bone flap re-removal for infection, 5 and 9 had positive and negative bacteriological cultures, respectively. Of patients who did not have bone flap infection, 49 and 132 had positive and negative bacteriological cultures, respectively. There were no significant differences between patients with and without positive bacteriological culture of bone flaps in the rates of late bone necrosis and reoperation for bone flap infection. ConclusionsA positive culture of intraoperative osseous sampling during DC is not associated with a higher risk of re-intervention after AC.

Estimation of the tip-height of mixing jet issuing from a nozzle by one-dimensional droplet model

This study newly proposes a one-dimensional droplet model to estimate the jet-tip height of a subcooling mixing jet issuing from the bottom to the top of tank. Cryogenic liquids, such as liquid hydrogen and liquid oxygen, are used as propellants and oxidants in spacecraft propulsion systems that require long-term storage in a closed tank. However, thermal stratification forms near the gas–liquid interface during long-term storage of cryogens due to heat flowing into the tank from the surrounding environment. In addition, boil-off gas (BOG) is generated from the interface, which causes increased pressure in the tank. To reduce the BOG, it is effective to destroy the thermal stratification by mixing in the cold jet issuing from the bottom of the tank. In this case, the tip-height of mixing jet issuing from the bottom of the tank is an important factor for mixing performance. Ground experiments using FC-72 and water as test fluids are conducted to investigate the jet behavior which is visualized using the Shadowgraph system. The height of the jet-tip is investigated under various experimental conditions, and the experimental results compared to the proposed one-dimensional spherical droplet model as the tip of the jet. The proposed model is also verified by comparison with experimental data available in the literature. The results show that the proposed model aligns well with the experimental data.

Cryopreservation of tissues and organs: present, bottlenecks, and future.

Tissue and organ transplantation continues to be an effective measure for saving the lives of certain critically ill patients. The organ preservation methods that are commonly utilized in clinical practice are presently only capable of achieving short-term storage, which is insufficient for meeting the demand for organ transplantation. Ultra-low temperature storage techniques have garnered significant attention due to their capacity for achieving long-term, high-quality preservation of tissues and organs. However, the experience of cryopreserving cells cannot be readily extrapolated to the cryopreservation of complex tissues and organs, and the latter still confronts numerous challenges in its clinical application. This article summarizes the current research progress in the cryogenic preservation of tissues and organs, discusses the limitations of existing studies and the main obstacles facing the cryopreservation of complex tissues and organs, and finally introduces potential directions for future research efforts.

PROSPECTS FOR HELIUM STORAGE IN THE REPUBLIC OF SAKHA (YAKUTIA)

The creation of a strategic helium storage facility is one of the stages in the development of the Russian gas industry. More than 20 oil and gas condensate fields have been discovered on the territory of the Republic of Sakha (Yakutia), which contain helium in industrial concentrations. This work discusses the possibility of creating a helium storage facility in Yakutia. We considered the experience of long-term storage of helium (in salt caverns and in depleted oil and gas condensate fields), as well as the prospects for creating cryogenic helium storage facilities, artificial storage facilities based on quarries and the possibility of returning helium concentrate to blocks or sections of the field under development. It was obtained that based on the analysis of the best technologies for creating a strategic reserve of helium in Eastern Siberia, it is possible to use various types of storage that meet all the requirements.

Experimental study on the flow characteristics during liquid nitrogen leakage

ABSTRACT The accidental leakage from tanks and pipelines is one of the main risks in cryogenic superheated liquid storage and transportation. To investigate the effects of superheat degree and jet pressure on the leakage characteristics, the corresponding liquid nitrogen (LN2) leakage experiments were carried out under different conditions. In this study, a rectangular nozzle ( 1 mm × 3 mm ) was applied to imitate the crack in typical release scenarios. The dynamic evolution process of jet pattern was also investigated. Three jet patterns including the mechanical breakup jet, the partially flashing jet, and the fully flashing jet were identified in the stable stage. The results indicate that the jet angle rises with the increase of superheat degree. At high superheat degree, the jet pressure presents a more significant influence on the jet angle. While the superheat degree decreases, its influence on the jet angle reduces. The leakage mass flow rate declines with the increase of superheat degree and rises with the increase of jet pressure. Furthermore, a new discharge coefficient correlation suitable for superheated LN2 leakage is developed, and its prediction error is within±3.8%. The new correlation is a good tool to predict the mass flow rate during LN2 leakage process.

Multi-Objective Optimization of Variable Density Multi-Layer Insulation for Liquid Hydrogen Containers Based on Reduced-Order Surrogate Model

For liquid hydrogen transportation, thermal insulation materials that are lightweight, compact and exhibit high-performance have been pursued for several decades, and variable density multi-layer insulation (VD-MLI) has been regarded as a promising choice. The thermal insulation performance of the insulation materials is important, but is not at the top of the list; many constraints, such as the space and weight of the insulation structures, are imposed on the design of a VD-MLI. Consequently, this makes the optimization of VD-MLIs more complicated. The present authors conducted a multi-objective optimization of a VD-MLI stacked with specific insulation units. The number of repetitions of the basic insulation unit was regarded as the dimensionless design parameter of the VD-MLI. Based on the experimentally validated layer-by-layer (LBL) model for MLI design, the multi-objective optimization of VD-MLI for liquid hydrogen storage was conducted by the combination of proper orthogonal decomposition with a general regression neural network (POD-GRNN) surrogate model optimization framework. The results showed that the optimal solutions for VD-MLI configurations could be achieved under different constraints. The present optimization framework provides a new reference for the optimization of VD-MLI for cryogenic liquid storage.

Cooling dynamics of energized naphthalene and azulene radical cations.

Naphthalene and azulene are isomeric polycyclic aromatic hydrocarbons (PAHs) and are topical in the context of astrochemistry due to the recent discovery of substituted naphthalenes in the Taurus Molecular Cloud-1 (TMC-1). Here, the thermal- and photo-induced isomerization, dissociation, and radiative cooling dynamics of energized (vibrationally hot) naphthalene (Np+) and azulene (Az+) radical cations, occurring over the microsecond to seconds timescale, are investigated using a cryogenic electrostatic ion storage ring, affording "molecular cloud in a box" conditions. Measurement of the cooling dynamics and kinetic energy release distributions for neutrals formed through dissociation, until several seconds after hot ion formation, are consistent with the establishment of a rapid (sub-microsecond) Np+ ⇌ Az+ quasi-equilibrium. Consequently, dissociation by C2H2-elimination proceeds predominantly through common Az+ decomposition pathways. Simulation of the isomerization, dissociation, recurrent fluorescence, and infrared cooling dynamics using a coupled master equation combined with high-level potential energy surface calculations [CCSD(T)/cc-pVTZ], reproduce the trends in the measurements. The data show that radiative cooling via recurrent fluorescence, predominately through the Np+ D0 ← D2 transition, efficiently quenches dissociation for vibrational energies up to ≈1eV above dissociation thresholds. Our measurements support the suggestion that small cations, such as naphthalene, may be more abundant in space than previously thought. The strategy presented in this work could be extended to fingerprint the cooling dynamics of other PAH ions for which isomerization is predicted to precede dissociation.

Experiment on transient thermodynamic behavior of a cryogenic storage tank protected by a composite insulation structure

Experiment on transient thermodynamic behavior of a cryogenic storage tank protected by a composite insulation structure

Improving small unmanned aerial vehicle flight endurance with cryo-compressed hydrogen vessels

Detailed analysis indicates that substantial increases (22–43%) in flight endurance of small unmanned aerial vehicles (UAVs) powered by liquid hydrogen (LH2) are possible by increasing the maximum allowable pressure of the cryogenic storage vessel beyond the critical point to contain evaporated hydrogen (H2) and mitigate vent losses to the environment. Taking an existing UAV (US Naval Research Laboratory's “Ion Tiger”) as a baseline, we consider the effect of increasing Dewar maximum allowable pressure on flight endurance, under two different scenarios. In Case 1, the weight of the H2 storage system (including H2) is kept equal to the baseline design to maintain flight conditions unchanged. In Case 2, the external volume of the Dewar is kept equal to the baseline design, and the weight of the Dewar (and UAV) increases when the maximum allowable pressure increases, with the result that the propulsion power for the heavier UAV increases.The results are favorable. Although the modified Dewars have smaller inner volume (Case 1) or greater weight (Case 2) than the original Ion Tiger, flight endurance increases by 22% (Case 1) and 43% (Case 2), because the large H2 vent losses (39%) of the original design are reduced to only 1.6% (Case 1) and 1% (Case 2). The much higher utilization efficiency of the H2 stored in these modified Dewars compensates for their volume and weight disadvantages, resulting in UAVs with superior endurance.

Cryogenic Storage Memory with High‐Speed, Low‐Power, and Long‐Retention Performance

AbstractCryogenic‐computing draws attention due to its variety of applications such as cloud‐computing, aerospace electronics, and quantum computing. Low temperature (e.g., 77 K) enables higher switching speed, improved reliability, and suppressed noise. Although cryogenic dynamic random‐access memory is studied, the cryogenic NAND flash is not explored intensively. Herein, a cryogenic storage memory based on the charge‐trap mechanism is reported. By removing the tunneling oxide from the conventional silicon/oxide/nitride/oxide/silicon (SONOS)‐type flash memory (therefore becoming silicon/oxide/nitride/silicon (SONS)), high‐speed and low‐power operation is aimed to be achieved while relieved from poor retention issue thanks to the cryogenic environment. The FinFET‐structured SONS memory device is demonstrated experimentally with gate length of 20–30 nm, which can achieve the retention issue (>10 years) with low voltage (≈6.5 V) and high speed (≈5 µs) operation at 77 K. To have a holistic system‐level evaluation, benchmark simulation of an interface between a host microprocessor and solid‐state‐drive is conducted, considering the refrigerator cooling cost and the heat loss via cables across two temperatures (300 and 77 K). The results show that the SONS‐type cryogenic storage system shows over 81% improvement in both latency and power, compared to the SONOS counterpart located at cryogenics.

Near-thermo-neutral electron recombination of titanium oxide ions.

While the dissociative recombination (DR) of ground-state molecular ions with low-energy free electrons is generally known to be exothermic, it has been predicted to be endothermic for a class of transition-metal oxide ions. To understand this unusual case, the electron recombination of titanium oxide ions (TiO+) with electrons has been experimentally investigated using the Cryogenic Storage Ring. In its low radiation field, the TiO+ ions relax internally to low rotational excitation (≲100 K). Under controlled collision energies down to ∼2 meV within the merged electron and ion beam configuration, fragment imaging has been applied to determine the kinetic energy released to Ti and O neutral reaction products. Detailed analysis of the fragment imaging data considering the reactant and product excitation channels reveals an endothermicity for the TiO+ dissociative electron recombination of (+4 ± 10) meV. This result improves the accuracy of the energy balance by a factor of 7 compared to that found indirectly from hitherto known molecular properties. Conversely, the present endothermicity yields improved dissociation energy values for D0(TiO) = (6.824 ± 0.010)eV and D0(TiO+) = (6.832 ± 0.010)eV. All thermochemistry values were compared to new coupled-cluster calculations and found to be in good agreement. Moreover, absolute rate coefficients for the electron recombination of rotationally relaxed ions have been measured, yielding an upper limit of 1 × 10-7 cm3 s-1 for typical conditions of cold astrophysical media. Strong variation of the DR rate with the TiO+ internal excitation is predicted. Furthermore, potential energy curves for TiO+ and TiO have been calculated using a multi-reference configuration interaction method to constrain quantum-dynamical paths driving the observed TiO+ electron recombination.

Influence of Cryogenic Temperatures on the Mechanical Properties and Microstructure of 2195-T8 Alloy

The 2195 aluminum alloy is widely used in cryogenic storage tanks for space vehicles, where it can reach a temperature of 20 K. In order to explore the reasons for the increased strength of 2195 aluminum alloys at cryogenic temperatures, uniaxial tensile tests were conducted in the range of 20 K–298 K. Tensile fracture was observed. In addition, the microstructures under different temperatures were observed using EBSD (electron back-scattered diffraction) and TEM (transmission electron microscopy) techniques, and the dislocation density of the material was quantitatively characterized using the modified Williamsone–Hall method based on XRD (X-ray diffraction) analysis. The results indicated that the ultimate strength increased at an increasing rate with the temperature decrease, while the elongation increase was insignificant. The fracture’s surface exhibited that dimple characteristics seemed to be unapparent while the quantity of tearing ridges was enhanced by the temperature decrease. Meanwhile, the fracture mode changed from ductile to brittle fracture. The microdeformation degree revealed by KAM images showed an aggravating trend, and the deformation tended to be more uniform. The increasingly enhanced dislocation density quantitatively revealed by the modified Williamsone–Hall method also proved this and that the increase in dislocations had a similar trend to that of tensile strength, which was furtherly revealed by TEM images. This indicated that the more regions are involved in deformation, the more dislocations are generated in the material during deformation, resulting in an increase in strength at cryogenic temperatures.

Aerogel Technology for Thermal Insulation of Cryogenic Tanks—Numerical Analysis for Comparison with Traditional Insulating Materials

The traditional choice of insulation material for liquefied natural gas (LNG) transportation with cryogenic tankers is the back-filled perlite-based system. However, aiming to further cut down the insulation cost, spare additional arrangement space, and provide safety in installation and maintenance, the requirement of looking for alternative materials still exists. Fiber-reinforced aerogel blankets (FRABs) could represent good candidates in designing insulation layers for LNG cryogenic storage because of their ability to ensure adequate thermal performance without the need to create deep vacuum conditions in the annular space of the tank. In this work, a finite element method (FEM) model was developed to study the thermal insulation performance of a commercial FRAB (Cryogel ® Z) for application in cryogenic storage/transport LNG tanks, comparing it with the performance of traditional perlite-based systems. Within the reliability limits of the computational model, the analysis proved that FRAB insulation technology gave encouraging results and might be potentially scalable for transporting cryogenic liquid. In addition to demonstrating superior performance in terms of thermal insulating efficiency and boil-off rate over the perlite-based system, as far as a perspective of cost savings and space gain, FRAB technology allows for higher levels of insulation without vacuum and with lower thickness of the outer shell, which is therefore beneficial for storing more material and lightening the weight of the LNG transportation semitrailer.

THESEUS: A techno-economic design, integration and downselection framework for energy storage

Optimal selection of energy storage technologies is critical to ensure reliable integration of intermittent and often uncertain renewable energy in electricity grids. The consideration of a diverse set of energy storage technologies is required for a more sustainable deployment of energy storage. We present THESEUS (TecHno-Economic framework for Systematic Energy storage Utilization and downSelection), which is a comprehensive framework for the optimal selection, design and operation of energy storage systems. THESEUS includes rigorous models of major energy storage technologies at different maturity levels, such as thermal storage using phase-change materials or molten salt, cryogenic storage, mechanical storage in the form of compressed air and pumped hydro storage, chemical storage using hydrogen, and electrochemical storage in the form of lithium-ion, sodium sulfur and vanadium flow batteries. An illustrative case study on state-wide prospective energy storage shows that storage integration with fossil power plants could reduce the cost of meeting the grid energy demand by 20%, with mechanical storage as the best suited technology. Although high-temperature thermal storage has low storage efficiency, it is optimal for integration with renewable energy plants. In addition, Li-ion batteries are optimal for high ramping but low storage duration requirements. Such insights can enable the deployment of both existing and emerging energy storage technologies to facilitate a smooth transition to a clean energy future.