Crustal Zircons Research Articles

Zircon U–Pb ages and Hf and O isotope systematics of crustal zircons from Mesoproterozoic kimberlites of the Dharwar craton, India: Implications for Neoarchean craton assembly

Plate tectonic models for the amalgamation of the dominantly Paleo-Mesoarchean Western Dharwar Craton (WDC) and Neoarchean Eastern Dharwar Craton (EDC) remain inconclusive on the polarity of Neoarchean subduction. Here we present insitu U-Pb age and Hf-O isotopic compositions of xenocrystic zircons in ca. 1.4-1.1 Ga kimberlites and lamproites emplaced within the ca. 2.8-2.5 Ga EDC as deep probes of the crustal architecture across the WDC-EDC boundary. The different zircon populations yield wide range of ages extending back to ca. 3.6 Ga, including distinctly ‘kimberlitic zircons’ with a mean 206Pb/238U age of 1112 ± 42 Ma, consistent with previous age estimates for kimberlite magmatism. The presence of zircons with ages >3.33 Ga is surprising as this age group of zircons is atypical of magmatic rocks in the EDC, but wide-spread in the WDC. Also, the highest concentration of zircons with ages >3.0 Ga is found in the kimberlites closest to the notional boundary shear zone between the WDC and EDC. The Hf isotope systematics of a majority of magmatic zircons with ages between 2.75-2.50 Ga require melting of older (3.6-3.3 Ga) source rocks. O-isotope data for these Neoarchean zircons show a wide scatter, lie both above (δ18O to 13.5 ‰) and well below mantle values (δ18O to <2 ‰). δ18O values outside the mantle range are closely associated with low εHf. The data are interpreted as evidence for transportation of older upper crustal rocks to lower crust and mantle depths consistent with tectonic models invoking collisional under thrusting of WDC beneath EDC.

Nature and evolution of the lower crust under central Spain: Inferences from granulite xenoliths (Calatrava Volcanic Field-Spanish central system)

So far, the nature and evolution of the lower crust under central Spain have been constrained mainly on the basis of a heterogeneous suite of granulite xenoliths from the Spanish Central System (SCS). In recent years, ultramafic volcanics from the Calatrava Volcanic Field (CVF) have also provided deep-seated crustal xenoliths which have not been studied in detail. Our data, combining mineral, whole-rock and isotopic geochemistry with U–Pb–Hf isotope ratios in zircons from the CVF and SCS xenoliths, highlight the felsic composition of the lower crust under central Iberia. A number of the Calatrava xenoliths represents Variscan igneous protoliths, which are a minor population in the SCS, and were likely formed by crystallisation of intermediate and felsic melts in the lower crust during the Variscan orogeny (leucodiorite protolith age of 314 ± 3 Ma and leucogranite protolith age of 308 ± 2.5 Ma). U–Pb data of metamorphic zircons show that granulite-facies metamorphism mainly occurred from 299 to 285 Ma in both areas. These ages are slightly younger than those of granitic intrusions that could be genetically related to the granulitic residue, which points to a main role of U–Pb isotope resetting in lower crustal zircons during HT or UHT conditions. The zircon U–Pb–Hf isotopic ratios support the idea that the lower crust in central Iberia consists mainly of Ordovician–Neoproterozoic metaigneous and metasedimentary rocks associated with the Cadomian continental arc of northern Gondwana. These rocks provide evidence of mixing between juvenile magmas and an enriched crustal component, ultimately extracted from an Eburnean crust. Other more evolved components present in detrital zircons are likely related to recycling of Archean crust derived from North Africa cratonic terranes.

Magma accumulation underneath Laacher See volcano from detrital zircon in modern streams

The detrital zircon grains from two catchments in the East Eifel Volcanic Field consist of crystals sourced from proximal deposits of Quaternary trachytic–phonolitic volcanic centres, Hocheifel Paleogene trachytic rocks and the Paleozoic basement. The outcrop patterns indicate the derivation of a significant detrital zircon population from deposits of the c. 13 ka Lower and Upper Laacher See Tephra. Intercalated Middle Laacher See Tephra, consisting of valley-filling ignimbrites, by contrast, is a minor zircon source despite thick ignimbrite deposits in one of the catchments. This reflects zircon undersaturation in the hotter and less evolved phonolite tapped from deeper parts of the magma reservoir as the eruption unfolded, as well as fewer antecrysts recycled from the plutonic carapace. A previously unrecognized zircon age population of c. 63 ka, mostly derived from Lower Laacher See Tephra, marks the onset of the presence of evolved magma at the top of the reservoir. Correlative Hf and O isotopic analysis reveals significant crustal interactions during phonolite differentiation in a shallow reservoir, with the assimilation of cogenetic, but hydrothermally modified, plutonic margins. Raman spectra indicate that magmatically heated crustal zircon xenocrysts are absent. Detrital zircon can thus provide more integrated insights into the evolution of Quaternary magma systems than the punctuated sampling of volcanic or cogenetic plutonic rocks. Supplementary material: Data tables presenting U–Th, U–Pb, O–Hf and Raman geochronology results are available at https://doi.org/10.6084/m9.figshare.c.6123823

Desilicification Rims of Zircon Xenocrysts Record the Timing of Kimberlite Emplacement

AbstractKimberlites are deep and relatively rare mantle‐derived igneous rocks, which provide key insights into the lithospheric mantle composition beneath continents (i.e., from the entrained mantle materials) at the time of magma emplacement. In addition, the temporal distribution of kimberlites throughout Earth's history may reveal secular changes in global geodynamics. However, alteration and abundant exotic material (i.e., xenoliths and xenocrysts) of different ages, both typical of kimberlites, often hinder reliable dating of these rocks. In this study, we investigated zircon xenocrysts and their replacement by desilicification reaction rims (DSRs), which consist mainly of baddeleyite, in the metamorphosed Kimozero kimberlites from the Karelian Craton, Russia. Similar DSRs have been identified previously on mantle‐derived zircons in numerous kimberlites, but the precise timing and location of formation of these rims remain unclear. U–Pb isotope dating of mantle zircon xenocrysts in the Kimozero kimberlites indicates that these rocks were emplaced at ca. 1.97 Ga. DSRs with similar textures and baddeleyite chemistry occur on both the 1.97 Ga mantle and 2.70–2.38 Ga crustal zircon xenocrysts in these kimberlites. Pb–Pb isotope dating of the DSRs yields the same age (i.e., ca. 1.97 Ga) as the mantle zircons. The data constrain the formation of DSRs to crustal levels and, more importantly, indicate that these rims record the timing of kimberlite emplacement. Therefore, we suggest that such baddeleyite reaction rims are a new and promising material for kimberlite geochronology.

Archean to Paleoproterozoic crustal evolution of the southern Yangtze Block (South China): U–Pb age and Hf-isotope of zircon xenocrysts from the Paleozoic diamondiferous kimberlites

Crustal zircon xenocrysts from mantle-derived magmatic rocks have the potential to probe the deep crust. Here we present integrated U–Pb dating and Hf-isotope analyses of zircons from a Paleozoic diamondiferous kimberlite dike in the Maping area of Zhenyuan County (southeastern Guizhou Province), with implications for the tectonothermal evolution of unexposed continental crust beneath the southern Yangtze Block, South China. All zircons (n = 236) show a wide range of U–Pb ages between Mesoarchean and middle Carboniferous. Among them, 96 zircons with 90–110% concordance yield concordant ages from 2942 ± 8 Ma to 342 ± 2 Ma, and form major age peaks at ∼2.9 Ga, ∼2.6 Ga and ∼2.0 Ga. The overwhelming majority of zircons are dominated by Mesoarchean–Paleoproterozoic U–Pb ages regardless of their concordance degrees. The zircon populations mainly consist of magmatic zircons, with minor metamorphic grains (Th/U < 0.10). The youngest magmatic zircon (Th/U = 0.43) with a well concordant 206Pb/238U age of 342 ± 2 Ma (M1-16) is interpreted as the maximum emplacement age of the Maping diamondiferous kimberlites. Most zircons with pre-eruption ages are considered to be xenocrysts, and they may be derived from the deep-seated continental crust through which kimberlite host magmas have passed. Their U–Pb ages and Hf isotopic compositions suggest the possible existence of a highly evolved Archean basement beneath the southern Yangtze Block, South China, which is much older than its known surface rocks. A lot of magmatic zircon xenocrysts reveal complex Precambrian crustal evolution in the southern Yangtze Block. These processes involved the important growth of continental crust at 2.6–2.5 Ga, and in the meantime, crustal reworking could be intermittently proceeding at 3.0–2.6 Ga. In addition, a group of xenocrystic zircons are identified to be of metamorphic origin, indicating that the proposed Archean basement beneath the southern Yangtze Block likely experienced a metamorphic event around 2.0 Ga. This geologically significant episode is consistent with the well-developed coeval metamorphism in other places of the Yangtze Block (e.g., Kongling Terrane), which has been considered to link to the assembly of the Paleoproterozoic Nuna/Columbia supercontinent. Our zircon data implies that the unexposed Archean basement beneath the southern Yangtze Block was affected by multiple thermal activities.

Precambrian zircons in chromitites of the Cretaceous Aladag ophiolite (Turkey) indicate deep crustal recycling in oceanic mantle

Crustal recycling into Earth’s deep mantle has been inferred from both seismic tomography and geochemical observations. As a further line of evidence, we report on zircons having a wide range of ages that were recovered from the Aladag chromitites, providing direct evidence for crustal recycling. Mesozoic zircons represent the earliest stages of Neotethyan seafloor spreading magmatism, whereas Neoproterozoic and Mesoproterozoic–Archean zircons record recycled old crustal material entrained in the ophiolitic mantle melt sources. The incorporation of such old, crustal zircons into the Neotethyan mantle might have followed from previous subduction events, from lithospheric delamination, and/or from the dismantling of West Gondwana in the Permo-Triassic. Subduction–affiliated ophiolitic melts may have picked up these recycled zircons and integrated them into chromitites, which precipitated from peridotite–melt interactions in a mantle wedge beneath the Inner–Tauride (a Neotethyan seaway) seafloor spreading system. Common in ophiolitic chromitites within the Neotethyan realm, such unusually old zircons present unique archives for tracking crustal recycling and mantle processes during rift–drift, seafloor spreading and subduction zone evolution of the oceanic mantle. We conclude that ophiolitic mantle peridotite and chromitite may be an important archive for preserving the recycling history of crustal material back into Earth’s deep mantle.

North Atlantic Craton architecture revealed by kimberlite-hosted crustal zircons

Archean cratons are composites of terranes formed at different times, juxtaposed during craton assembly. Cratons are underpinned by a deep lithospheric root, and models for the development of this cratonic lithosphere include both vertical and horizontal accretion. How different Archean terranes at the surface are reflected vertically within the lithosphere, which might inform on modes of formation, is poorly constrained. Kimberlites, which originate from significant depths within the upper mantle, sample cratonic interiors. The North Atlantic Craton, West Greenland, comprises Eoarchean and Mesoarchean gneiss terranes – the latter including the Akia Terrane – assembled during the late Archean. We report U–Pb and Hf isotopic, and trace element, data measured in zircon xenocrysts from a Neoproterozoic (557 Ma) kimberlite which intruded the Mesoarchean Akia Terrane. The zircon trace element profiles suggest they crystallized from evolved magmas, and their Eo- to Neoarchean U–Pb ages match the surrounding gneiss terranes, and highlight that magmatism was episodic. Zircon Hf isotope values lie within two crustal evolution trends: a Mesoarchean trend and an Eoarchean trend. The Eoarchean trend is anchored on 3.8 Ga orthogneiss, and includes 3.6–3.5 Ga, 2.7 and 2.5–2.4 Ga aged zircons. The Mesoarchean Akia Terrane may have been built upon mafic crust, in which case all zircons whose Hf isotopes lie within the Eoarchean trend were derived from the surrounding Eoarchean gneiss terranes, emplaced under the Akia Terrane after ca. 2.97 or 2.7 Ga, perhaps during late Archean terrane assembly. Kimberlite-hosted peridotite rhenium depletion model ages suggest a late Archean stabilization for the lithospheric mantle. The zircon data support a model of lithospheric growth via tectonic stacking for the North Atlantic Craton.

Widespread Os-isotopically ultradepleted mantle domains in the Paleo-Asian oceanic upper mantle: evidence from the Paleozoic Tianshan ophiolites (NW China)

The scale and extent of isotopic heterogeneities in the Paleo-Asian oceanic mantle remain poorly constrained. Here, we report Os isotopic data for mantle peridotites from the Paleozoic Gangou and Kumishi ophiolites, which are preserved in the western Chinese Tianshan sutures (Xinjiang, China) and considered to sample the Paleo-Asian oceanic upper mantle. These heavily serpentinized peridotites display positive correlations between Al2O3, Ti, and Yb contents, indicating variable degrees of melt extraction from fertile mantle sources. However, enriched light rare-earth element patterns in the peridotites are inconsistent with simple residues of partial melting, thus reflecting the effect of post-melting melt percolation. Peridotites from both ophiolites show wide variation of Os isotopic compositions, several of which are characterized by highly unradiogenic 187Os/188Os values (0.117–0.118), reflecting Proterozoic melt depletion. Such feature is common in modern oceanic peridotites and most Phanerozoic ophiolites, meaning that Os-isotopically ultradepleted domains should be widespread in the Paleo-Asian oceanic mantle. The overall similarity of Os-isotope distribution between the Paleozoic Tianshan ophiolites and modern oceanic peridotites suggests that they derive from the same heterogeneous upper mantle reservoir. This might support the hypothesis that isotopically ultradepleted domains are inherent components of the convecting upper mantle and have not been sufficiently homogenized by convection. Alternatively, Re-depletion ages (TRD) for these ancient domains are broadly coincident with the major peaks in crustal zircon ages that are thought to reflect episodes of continental crust growth in the adjacent Yili–Central Tianshan microcontinents. This suggests that the ultradepleted mantle domains in some of the Tianshan ophiolites may derive from ancient subcontinental lithospheric mantle, which detached and were exhumed to form the substrate of ocean basins.

A Palaeoproterozoic basement beneath the Rangnim Massif revealed by the in situ U–Pb ages and Hf isotopes of xenocrystic zircons from Triassic kimberlites of North Korea

AbstractIn situ U–Pb and Hf analyses were used for crustal zircon xenocrysts from Triassic kimberlites exposed in the Rangnim Massif of North Korea to identify components of the basement hidden in the deep crust of the Rangnim Massif and to clarify the crustal evolution of the massif. The U–Pb age spectrum of the zircons has a prominent population at 1.9–1.8 Ga and a lack of Archaean ages. The data indicate that the deep crust and basement beneath the Rangnim Massif are predominantly of Palaeoproterozoic age, consistent with the ages of widely exposed Palaeoproterozoic granitic rocks. In situ zircon Hf isotope data show that most of the Palaeoproterozoic zircon xenocrysts have negative ϵHf(t) values (−9.7 to +0.7) with an average Hf model age of 2.86 ± 0.02 Ga (2σ), which suggests that the Palaeoproterozoic basement was not juvenile but derived from the reworking of Archaean rocks. Considering the existence of Archaean remanent material in the Rangnim Massif and their juvenile features, a strong crustal reworking event is indicated at 1.9–1.8 Ga, during which time the pre-existing Archaean basement was exhausted and replaced by a newly formed Palaeoproterozoic basement. These features suggest that the Rangnim Massif constitutes the eastern extension of the Palaeoproterozoic Liao–Ji Belt of the North China Craton instead of the Archaean Liaonan Block as previously thought. A huge Palaeoproterozoic orogen may exist in the eastern margin of the Sino-Korean Craton.

Experimental evidence for the preservation of U-Pb isotope ratios in mantle-recycled crustal zircon grains

Zircon of crustal origin found in mantle-derived rocks is of great interest because of the information it may provide about crust recycling and mantle dynamics. Consideration of this requires understanding of how mantle temperatures, notably higher than zircon crystallization temperatures, affected the recycled zircon grains, particularly their isotopic clocks. Since Pb2+ diffuses faster than U4+ and Th+4, it is generally believed that recycled zircon grains lose all radiogenic Pb after a few million years, thus limiting the time range over which they can be detected. Nonetheless, this might not be the case for zircon included in mantle minerals with low Pb2+ diffusivity and partitioning such as olivine and orthopyroxene because these may act as zircon sealants. Annealing experiments with natural zircon embedded in cristobalite (an effective zircon sealant) show that zircon grains do not lose Pb to their surroundings, although they may lose some Pb to molten inclusions. Diffusion tends to homogenize the Pb concentration in each grain changing the U-Pb and Th-Pb isotope ratios proportionally to the initial 206Pb, 207Pb and 208Pb concentration gradients (no gradient-no change) but in most cases the original age is still recognizable. It seems, therefore, that recycled crustal zircon grains can be detected, and even accurately dated, no matter how long they have dwelled in the mantle.

Age and tectonic significance of the Louth Volcanics: implications for the evolution of the Tasmanides of eastern Australia

Re-evaluation of geochemical and geophysical datasets, and analysis of magmatic and detrital zircons from drill-core samples extracted from the Louth region of the southern Thomson Orogen (STO), augmented by limited field samples, has shown that two temporally and compositionally distinct igneous groups exist. The older Lower Devonian, calc-alkaline group corresponds to complexly folded, high-intensity curvilinear magnetic anomalies in the Louth region (Louth Volcanics) and are probable equivalents to Lower Devonian volcanics in the northern Lachlan Orogen. A younger Permo-Triassic alkaline assemblage forms part of an E–W corridor of diatremes that appears to relate to focussed lithospheric extension associated with the later stages of the Hunter–Bowen Orogeny in the New England Orogen. The alkaline group includes gabbros previously considered as Neoproterozoic, but all magmatic rocks, including alkaline basalts, contain an unusual number of xenocrystic zircons. The age spectra of the xenocrystic zircons mimic detrital zircons from Cobar Basin sedimentary rocks and/or underlying Ordovician turbidites, suggesting incorporation of upper crustal zircons into the alkaline basaltic magmas. A distinct difference of detrital zircon age spectra from central Thomson Orogen metasediments indicates the STO metasediments have greater affinities to the Lachlan Orogen, but both orogens probably began in the Early Ordovician during widespread backarc extension and deposition of turbidites in the Tasmanides. A surprising result is that Ordovician, Devonian and Permo-Triassic basaltic rocks from the STO and elsewhere in the Tasmanides, all yield the same Nd-model ages of ca 960–830 Ma, suggesting that Neoproterozoic subcontinental lithospheric mantle persisted throughout the evolution of the Tasmanide orogenic system.

Early Permian diamond-bearing proximal eskers in the Lichtenburg/Ventersdorp area of the North West Province, South Africa

Research Article| December 01, 2016 Early Permian diamond-bearing proximal eskers in the Lichtenburg/Ventersdorp area of the North West Province, South Africa Mike C.J. de Wit Mike C.J. de Wit University of Pretoria/Tsodilo Resources Ltd, P O Box 466, Kleinmond, 7195, South Africa e-mail: dewit@icon.co.za Search for other works by this author on: GSW Google Scholar Author and Article Information Mike C.J. de Wit University of Pretoria/Tsodilo Resources Ltd, P O Box 466, Kleinmond, 7195, South Africa e-mail: dewit@icon.co.za Publisher: Geological Society of South Africa First Online: 20 Nov 2017 Online Issn: 1996-8590 Print Issn: 1012-0750 © 2016 December Geological Society of South AfricaGeological Society of South Africa South African Journal of Geology (2016) 119 (4): 585–606. https://doi.org/10.2113/gssajg.119.4.585 Article history First Online: 20 Nov 2017 Cite View This Citation Add to Citation Manager Share Icon Share Facebook Twitter LinkedIn MailTo Tools Icon Tools Get Permissions Search Site Citation Mike C.J. de Wit; Early Permian diamond-bearing proximal eskers in the Lichtenburg/Ventersdorp area of the North West Province, South Africa. South African Journal of Geology 2016;; 119 (4): 585–606. doi: https://doi.org/10.2113/gssajg.119.4.585 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietySouth African Journal of Geology Search Advanced Search Abstract Diamond-bearing gravels of the Lichtenburg-Ventersdorp area of the North West Province are associated with north-south orientated sinuous ‘runs’ that occur almost entirely on a flat erosional surface of the Malmani dolomites (Transvaal Supergroup) at some 1,500 m elevation. East to west, this dolomite plain measures 150 km, and north-south it is on average 40 km wide. This unconformity, which first developed before the Pretoria Group sedimentation over a period of at least 80 Myr, is marked by siliceous breccias (palaeo-karst infill) and conglomerates (reworked breccias). It was exhumed in pre-Karoo and post-Gondwana times. Glacial pavements and remnants of thin Lower Karoo sediments are also found on this polyphase surface. The gravels that make up these ‘runs’ and sinkholes directly or indirectly linked to these runs, are coarse-grained, very poorly-sorted, and are best described as diamictites. The ‘runs’ are narrow, elongated, generally positive ridges that meander across the dolomite surface and are up to 30 km long and between 80 to 300 m wide. They have always been regarded as post-Cretaceous drainage features linked to southward-flowing river systems. Diamonds were discovered in these ‘runs’ and they have produced some 12 million carats. However, no Cainozoic fossils or artefacts have ever been found in almost 90 years of mining. From new field evidence, geomorphological studies, age dating from inclusions in diamond and zircon and clay analyses, it is proposed that these coarse-grained runs represent proximal palaeo-eskers of the last deglaciation of the Dwyka continental ice sheet, that are preserved on this ancient ‘palimpsest’ surface. The age of the deposit is constrained by two populations of agate within the diamictites that are linked to two separate volcanic units of the Pretoria Group. In addition, the youngest crustal zircon ages from the gravels are 1 Ba, but mantle zircons from Lichtenburg suggest that these have been derived from Cambrian age kimberlites. Analysis of inclusions in diamond support a Neoproterozoic to Cambrian source for the diamonds, so the absence of diamonds from Mesozoic kimberlites and Cainozoic fossils within the gravels support the conclusion that the runs are of Karoo age. You do not have access to this content, please speak to your institutional administrator if you feel you should have access.

Two types of the crust-mantle interaction in continental subduction zones

Plate subduction is an important mechanism for exchanging the mass and energy between the mantle and the crust, and the igneous rocks in subduction zones are the important carriers for studying the recycling of crustal materials and the crust-mantle interaction. This study presents a review of geochronology and geochemistry for postcollisional mafic igneous rocks from the Hong’an-Dabie-Sulu orogens and the southeastern edge of the North China Block. The available results indicate two types of the crust-mantle interaction in the continental subduction zone, which are represented by two types of mafic igneous rocks with distinct geochemical compositions. The first type of rocks exhibit arc-like trace element distribution patterns (i.e. enrichment of LILE, LREE and Pb, but depletion of HFSE) and enriched radiogenic Sr-Nd isotope compositions, whereas the second type of rocks show OIB-like trace element distribution patterns (i.e. enrichment of LILE and LREE, but no depletion of HFSE) and depleted radiogenic Sr-Nd isotope compositions. Both of them have variable zircon O isotope compositions, which are different from those of the normal mantle zircon, and contain residual crustal zircons. These geochemical features indicate that the two types of mafic igneous rocks were originated from the different natures of mantle sources. The mantle source for the second type of rocks would be generated by reaction of the overlying juvenile lithospheric mantle with felsic melts originated from previously subducted oceanic crust, whereas the mantle source for the first type of rocks would be generated by reaction of the overlying ancient lithospheric mantle of the North China Block with felsic melts from subsequently subducted continental crust of the South China Block. Therefore, there exist two types of the crust-mantle interaction in the continental subduction zone, and the postcollisional mafic igneous rocks provide petrological and geochemical records of the slab-mantle interactions in continental collision orogens.

Ignimbrites to batholiths: Integrating perspectives from geological, geophysical, and geochronological data

Multistage histories of incremental accumulation, fractionation, and solidification during construction of large subvolcanic magma bodies that remained sufficiently liquid to erupt are recorded by Tertiary ignimbrites, source calderas, and granitoid intrusions associated with large gravity lows at the Southern Rocky Mountain volcanic field (SRMVF). Geophysical data combined with geological constraints and comparisons with tilted plutons and magmatic-arc sections elsewhere are consistent with the presence of vertically extensive (>20 km) intermediate to silicic batholiths (with intrusive:extrusive ratios of 10:1 or greater) beneath the major SRMVF volcanic loci (Sawatch, San Juan, Questa-Latir). Isotopic data require involvement of voluminous mantle-derived mafic magmas on a scale equal to or greater than that of the intermediate to silicic volcanic and plutonic rocks. Early waxing-stage intrusions (35–30 Ma) that fed intermediate-composition central volcanoes of the San Juan locus are more widespread than the geophysically defined batholith; these likely heated and processed the crust, preparatory for ignimbrite volcanism (32–27 Ma) and large-scale upper-crustal batholith growth. Age and compositional similarities indicate that SRMVF ignimbrites and granitic intrusions are closely related, but the extent to which the plutons record remnants of former magma reservoirs that lost melt to volcanic eruptions has been controversial. Published Ar/Ar-feldspar and U-Pb-zircon ages for plutons spatially associated with ignimbrite calderas document final crystallization of granitoid intrusions at times indistinguishable from the tuff to ages several million years younger. These ages also show that SRMVF caldera-related intrusions cooled and solidified soon after zircon crystallization, as magma supply waned. Some researchers interpret these results as recording pluton assembly in small increments that crystallized rapidly, leading to temporal disconnects between ignimbrite eruption and intrusion growth. Alternatively, crystallization ages of the granitic rocks are here inferred to record late solidification, after protracted open-system evolution involving voluminous mantle input, lengthy residence (105–106 yr) as near-solidus crystal mush, and intermittent separation of liquid to supply volcanic eruptions. The compositions of the least-evolved ignimbrite magmas tend to merge with those of caldera-related plutons, suggesting that the plutons record nonerupted parts of long-lived cogenetic magmatic systems, variably modified prior to final solidification. Precambrian-source zircons are scarce in caldera plutons, in contrast to their abundance in some peripheral waning-stage intrusions of the SRMVF, implying dissolution of inherited crustal zircon during lengthy magma assembly for the ignimbrite eruptions and construction of a subvolcanic batholith. Broad age spans of zircons (to several million years) from individual samples of some ignimbrites and intrusions, commonly averaged and interpreted as “intrusion-emplacement age,” alternatively provide an incomplete record of intermittent crystallization during protracted incremental magma-body assembly, with final solidification only when the system began to wane. Analyses of whole zircons cannot resolve late stages of crystal growth, and early growth in a long-lived magmatic system may be poorly recorded due to periods of zircon dissolution. Overall, construction of a batholith can take longer than recorded by zircon-crystallization ages, while the time interval for separation and shallow assembly of eruptible magma may be much shorter. Magma-supply estimates (from ages and volcano-plutonic volumes) yield focused intrusion-assembly rates sufficient to generate ignimbrite-scale volumes of eruptible magma, based on published thermal models. Mid-Tertiary processes of batholith assembly associated with the SRMVF caused drastic chemical and physical reconstruction of the entire lithosphere, probably accompanied by asthenospheric input.

The enigma of crustal zircons in upper-mantle rocks: Clues from the Tumut ophiolite, southeast Australia

We suggest a new explanation for the presence of crustally derived zircons in the upper-mantle rocks of ophiolitic complexes, as an alternative to subduction-related models. Integrated isotopic (U-Pb, Hf, and O isotopes) and trace-element data for zircons from the Tumut ophiolitic complex (southeast Australia) indicate that these grains are related to granitic magmatism and were introduced into the mantle rocks after their emplacement into the crust. These observations emphasize that a clear understanding of the origin of individual zircon populations and their relationship to the host rock is essential to interpretations of the tectonic history of upper-mantle rocks and the dynamics of crust-mantle interactions.

Lower crustal zircons reveal Neogene metamorphism beneaththe Pannonian Basin (Hungary)

Abstract Neogene alkaline intraplate volcanic depositsin the Pannonian Basin (Hungary) contain many lowercrustal granulite-facies xenoliths. U-Pb ages have been determinedfor zircons separated from a metasedimentaryxenolith, using LA-ICPMS and SHRIMP techniques. Thezircons show typical metamorphic characteristics and arenot related to the hostmagmatism. The oldest age recordedis late Devonian, probably related to Variscan basementlithologies. Several grains yield Mesozoic dates for theircores, which may correspond to periods of orogenic activity.Most of the zircons show young ages, with some beingPalaeocene-Eocene, but the majority being youngerthan 30Ma. The youngest zircons are Pliocene (5.1-4.2 Ma)and coincide with the age of eruptions of the host alkalibasalts. Such young zircons, so close to the eruption age,are unusual in lower crustal xenoliths, and imply that theheat flow in the base of the Pannonian Basin was sufficiently high to keep many of them close to their blockingtemperature. This suggests that metamorphism is continuingin the lower crust of the region at the present day.

Svecofennian post-collisional shoshonitic lamprophyres at the margin of the Karelia Craton: Implications for mantle metasomatism

Abstract Petrographic, geochemical, and geochronological data from shoshonitic lamprophyres from the North Savo region, eastern Finland, and the NW Ladoga region, northwest Russia are presented. The two areas are found ~ 250 km apart along a roughly 450 km long palaeosuture between the Archaean Karelia Craton and the Proterozoic Svecofennian Domain. Two of the samples from North Savo are kersantites, while the remaining ten samples (from both North Savo and NW Ladoga) are minettes. Two morphologically different populations of zircon were identified from these lamprophyres and analysed by secondary ionisation mass spectrometry. Concordant analyses of inherited crustal zircon xenocrysts gave both Archaean and Proterozoic 207Pb/206Pb ages. In the NW Ladoga region, these are the first reported Archaean ages from south of the Meijeri Thrust zone. Large, homogeneous and relatively U- and Th-depleted zircons are interpreted as xenocrysts from the metasomatised mantle. U–(Th)–Pb analyses of these zircons resulted in ages of 1790 ± 3 Ma, 1784 ± 4 Ma, 1785 ± 5 Ma and 1781 ± 20 Ma, representative of the timing of dyke emplacement. Geochemical characteristics of the dykes indicate that the source mantle experienced at least two types of metasomatic enrichment. The first of these was caused by a hydrous alkaline silicate melt, resulting in enrichment in SiO2, Al2O3, FeO, K2O, LILE and LREE. The second was caused by a carbonatitic melt that further enriched the source area in Ba, Th, U, Sr, P and LREE. Infiltration of melt along fractures in the mantle wedge probably resulted in a vein assemblage of biotite – (potassic) amphibole – apatite ± carbonate within unreacted mantle peridotite. The most likely source of the metasomatising melts was from partial melting of subducted carbonate-rich pelitic sediment.

The Southward Extension of Cathaysia Block: Evidence from Zircon U‐Pb Dates of Borehole Volcanics in the Northern South China Sea

Abstract:Five Paleogene volcanics sampled from the northern South China Sea were analyzed via LA‐ICP‐MS zircon U‐Pb dating, including basalt and andesite from Borehole SCSV1 and volcanic agglomerate from Borehole SCSV2, respectively. A total of 162 zircon U‐Pb dates for them cover an age range from Neoarchean to Eocene, in which the pre‐Paleocene data dominate. The Paleogene dates of 62.5±2.2 Ma and 42.1±2.9 Ma are associated with two igneous episodes prior to opening of South China Sea basin. Those pre‐Paleocene zircons are inherited zircons mostly with magmatogenic oscillatory zones, and have REE features of crustal zircon. Zircon U‐Pb dates of 2518–2481 Ma, 1933–1724 Ma, and 1094–1040 Ma from the SCSV1 volcanics, and 2810–2718 Ma, 2458–2421 Ma, and 1850–993.4 Ma from the SCSV2 volcanics reveal part of Precambrian evolution of the northern South China Sea, well comparable with age records dated from the Cathaysia block. The data of 927.0±6.9 Ma and 781±38 Ma dated from the SCSV2 coincide with amalgamation between Yangtze and Cathaysia blocks and breakup of the Rodinia, respectively. The age records of Caledonian orogeny from the Cathaysia block are widely found from our volcanic samples with concordant mean ages of 432.0±5.8 Ma from the SCSV1 and of 437±15 Ma from the SCSV2. The part of the northern South China Sea resembling the Cathaysia underwent Indosinian and Yanshannian tectonothermal events. Their age signatures from the SCSV1 cover 266.5±3.5 Ma, 241.1±6.0 Ma, 184.0±4.2 Ma, 160.9±4.2 Ma and 102.8±2.6 Ma, and from the SCSV2 are 244±15 Ma, 158.1±3.5 Ma, 141±13 Ma and 96.3±2.1 Ma. Our pre‐Paleogene U‐Pb age spectra of zircons from the borehole volcanics indicate that the northern South China Sea underwent an evolution from formation of Precambrian basement, Caledonian orogeny, and Indosinian orogeny to Yanshannian magmatism. This process can be well comparable with the tectonic evolution of South China, largely supporting the areas of the northern South China Sea as part of southward extension of the Cathaysia.

Geochronological and geochemical constraints on the formation and evolution of the mantle underneath the Kaapvaal craton: Lu–Hf and Sm–Nd systematics of subcalcic garnets from highly depleted peridotites

Subcalcic garnets carry the major inventory of most trace elements of their host harzburgites and are thus proxies of the bulk composition. We used single garnet grains from heavy mineral concentrates from the Kaapvaal craton (Roberts Victor and Lace mine) to determine the major and trace elements and the Sm–Nd and Lu–Hf isotope systematics of these highly depleted members of the peridotitic suite. The combination of the results with previous work from the Finsch mine (Lazarov et al., 2009a) allowed us to reconstruct the formation and evolution of the mantle underneath the Kaapvaal craton.Several lines of evidence from major and trace elements suggest that mantle melting was mainly at shallow pressures followed by subduction into the garnet stability field. A 3.22Ga metasomatic event underneath the East block occurred in a previously depleted mantle (εHf=+16) which was sufficiently stabilized by that time to hold a crust with tonalite–trondhjemite–granodiorite (TTG’s) and greenstone belts. Such high εHf values can be produced within a few hundred million years by 25% non-modal fractional melting in the spinel stability field. This is the first prove of a mantle underneath the East block with an age similar to a 3.65Ga crustal age.Before the amalgamation around 2.88Ga, oceanic lithosphere was created between the W- and E-block around 2.95Ga (group RV1 samples from the Roberts Victor) and subducted underneath the W-block. Another mantle portion (group RV2 garnets) from Roberts Victor yielded a seeming age of 3.27±0.15Ga with εHf=+17.6. It actually results from an enrichment process in a highly depleted mantle about 2.8–2.9Ga ago. This may have been the depleted mantle wedge above the subduction and final collision between the West and the East block. The creation of a cratonic nucleus for the West-block is unknown until 3.2Ga when the oldest mantle TRD and oldest crustal zircon ages are reported. Such ages were not directly obtained from the study of the subcalcic garnets but the high positive εHf value (+25) of the 2.62Ga enrichment age from Finsch and the existence of a highly depleted mantle wedge before 2.8–2.9Ga at Roberts Victor suggests that the depletion occurred several hundred million years earlier. Subsequently, the 2.6–2.8Ga old voluminous Ventersdoorp volcanics poured over a major part of the unified Kaapvaal craton, an event which also may have modified portions of the mantle underneath Finsch. The attachment of the Kheis–Magondi belt to the Kaapvaal craton from the West caused further modification around 1.90Ga. The latest stages of craton-scale metasomatism recorded in the subcalcic garnets lie between 0.9 and 1.3Ga as can be seen in the Sm–Nd isotope systematic. This age range coincides with the Namaqua–Natal belt orogeny. The present study and previous work on subcalcic garnets show that they can be excellent recorders of multiple mantle events which can be correlated with the tectonomagmatic evolution of the craton.

Recycled crustal zircons from podiform chromitites in the Luobusa ophiolite, southern Tibet

AbstractWe have measured the U–Pb age of zircon grains separated from podiform chromitites from the Luobusa ophiolite, Southern Tibet, using laser ablation microprobe – inductively coupled plasma mass spectrometer (LA‐IC‐PMS), to determine the age relationship between the podiform chromitites and the host mantle peridotite. Spot analyses with LA‐IC‐PMS, assisted by cathodoluminescence images gave a wide age range, from the Cretaceous to the Late Archean (ca 100–2700 Ma). The minimum ages of ca 100 Ma, plotted on the concordia curve, were slightly lower than the metasomatic (magmatic) event in the supra‐subduction zone (120 ± 10 Ma), suggesting that the zircons suffered some Pb loss. However, most of the ages found are much older than those of the chromitite and ophiolite formation. Laser Raman spectroscopy analyses revealed that the zircons recovered from the chromitites contain crustal mineral inclusions, such as quartz and K‐feldspar, but lack mantle minerals (e.g., olivine, pyroxene, and chromite), suggesting that they had a crustal origin. The results indicate that crustal zircons in chromitites had a xenocrystic origin and resided in the mantle peridotite for a long period before being entrained into the chromitite during its formation. This indicates that the mantle peridotite under the Neo‐Tethys Ocean was affected by the crustal material contamination. Our results are consistent with previous reports that mid‐oceanic ridge basalts in the Indian Ocean have the isotopic signature of crustal material contamination. From these results, and previous isotopic studies on Gondwana geology, we conclude that ancient zircons from podiform chromitites could provide evidence of crustal material being recycled through the upper mantle.