The thermal performance and sizing of two-phase heat exchangers employed in various industries can be significantly improved by modifying the surface topology of tubes. The advancement in metal 3D printing technology enables the modification of surfaces to generate distinct patterns that enhance the heat transfer coefficient. This study aligns with these advances by investigating the boiling heat transfer performance of 3D printed surfaces using methanol as the working fluid. The enhanced surfaces studied include four bio-inspired 3D printed surfaces (Mushroom, Cactus, Petal, and Torus), each strategically designed to improve the heat transfer coefficient (HTC) and delay the onset of critical heat flux (CHF). The primary objective of this research is to discuss and analyze the heat transfer mechanism in terms of bubble dynamics, particularly focusing on the interaction between surface morphology and bubble behavior. Experimental results reveal significant enhancements in CHF and HTC for 3D printed surfaces compared to plain surfaces. Among the 3D printed surfaces, the Mushroom surface exhibits the highest enhancement in CHF of 88 % compared to the plain surface. Similarly, the maximum HTC enhancements are 138 %, 86 %, 65 %, and 46 % for the Mushroom, Cactus, Petal, and Torus surfaces, respectively, compared to the plain surface. The methodologies and findings of this study are poised to have a lasting impact on the field, potentially opening new avenues for improving the efficiency and effectiveness of various two-phase heat exchangers.