Coupling Mechanism Research Articles

Investigating Enhanced Convection Heat Transfer in 3D Micro-Ribbed Tubes Using Inverse Problem Techniques

The improved heat dissipation observed in 3D micro-ribbed tubes is primarily influenced by the intricate interplay of multiple structural parameters. Nevertheless, research into the coupling mechanisms of these multi-structural parameters remains constrained by the absence of effective methodology in numerical solutions. In the present work, a new 3D micro-rib structure based on discrete adjoint method is established. Firstly, the research examines the interplay of different parameters (such as arrangement, relative roughness height, angle of attack, and circumferential rows) on the thermo-hydraulic performance. It is noted that the heat transfer efficiency is notably impacted by the relative roughness height. And the arrangement methodology dictates the optimal positioning for heat transfer efficiency. An increase in the number of circumferential rows enhances fluid mixing, while the angle of attack plays a crucial role in the formation of longitudinal vortices. Secondly, the coupling optimization technique is employed to obtain the optimal structure featuring non-uniform relative roughness height by the developed numerical solution. Overall, in comparison to the smooth tube, the optimized ribbed tube exhibits a remarkable 64.9% enhancement in performance evaluation criteria. Finally, a notable enhancement of 10.65–22.78% is observed when comparing with the prevailing micro-rib structures.

Excitation of high-quality quasi-BIC toroidal mode in a lattice perturbed terahertz metasurface

The bound state in continuum (BIC) is a phenomenon that describes the existence of nonradiative modes (dark modes) embedded in the continuum frequency range. However, an ideal BIC cannot be detected experimentally. The BIC can be transformed into a quasi-BIC by establishing a leaky channel to the radiation continuum. In this study, instead of the conventional asymmetric split ring resonator structure, a sharp quasi-BIC mode is excited in a symmetric split ring resonator (SRR) metasurface by the perturbation of the lattice constant of the unit cell via changing the interspacing distance between two adjacent SRRs. The quality factor of the quasi-BIC mode can be tuned by varying the interspacing of two SRRs, while the resonance frequency of the quasi-BIC mode remains stable. An eigenmode analysis confirms the presence of the quasi-BIC mode, while the ab initio Fano theory and a coupled oscillator model elucidate the radiative and nonradiative coupling mechanisms. The influence of geometric perturbations on the quasi-BIC mode is quantitatively assessed through the extracted fitting parameters, providing insights into the transition from the dark mode (ideal BIC) to the quasi-BIC mode. The terahertz time domain spectroscopy measurement demonstrates a signature of the quasi-BIC resonance mode as a result of the band folding in the first Brillouin zone induced by the doubling of the lattice constant.

Direct magnetoelectric coupling in Pr doping Bi6Ti3Fe2O18 relaxor ferroics

Single-phase multiferroics are fractional and rarely meet at room temperature. Direct magnetoelectric coupling in relaxor ferroic phase was observed in Bi6−xPrxTi3Fe2O18 (x = 0.0, 0.3, 0.6, 0.9, and 1.2) films, where the chemical disorder doping-induced effective internal pressure played a key role. It is analytically formulated from the phase-structure shift, ferroelectric domain, and origin of the magnetic order. The strip magnetic domains are broken into a dotted domain structure following a quantitatively increase in lattice stress. A Monte Carlo simulation including stress energy items is used to unveil the hitherto unexplored coupling mechanism by tuning the symmetric exchange restriction of Fe3+–O–Fe3+. Moreover, the observation of coefficient 78.8 mV/cm·Oe at room temperature is intriguing for potential application.

The structure and statistics of language jointly shape cross-frequency neural dynamics during spoken language comprehension

Humans excel at extracting structurally-determined meaning from speech despite inherent physical variability. This study explores the brain’s ability to predict and understand spoken language robustly. It investigates the relationship between structural and statistical language knowledge in brain dynamics, focusing on phase and amplitude modulation. Using syntactic features from constituent hierarchies and surface statistics from a transformer model as predictors of forward encoding models, we reconstructed cross-frequency neural dynamics from MEG data during audiobook listening. Our findings challenge a strict separation of linguistic structure and statistics in the brain, with both aiding neural signal reconstruction. Syntactic features have a more temporally spread impact, and both word entropy and the number of closing syntactic constituents are linked to the phase-amplitude coupling of neural dynamics, implying a role in temporal prediction and cortical oscillation alignment during speech processing. Our results indicate that structured and statistical information jointly shape neural dynamics during spoken language comprehension and suggest an integration process via a cross-frequency coupling mechanism.

Research on the mechanism of electromechanical coupling response of pulse power multilayer ceramic capacitors under high impact and high voltage discharge composite environment

Pulse power multilayer ceramic capacitors (pulse power-MLCC) are commonly used in complex composite environments with high overload and high voltage due to their large size and capacitance. In order to study the electromechanical coupling response characteristics of pulse power-MLCC in high-impact and high-voltage composite environments, a split Hopkinson pressure bar (SHPB) testing system was used to simulate high impact. The mechanical and electrical parameters of pulse power-MLCC were collected under high-impact and voltage environments, and the capacitance changes at different impact velocities were obtained. The stress wave transmission characteristics of pulse power-MLCC were studied by combining numerical simulation and theoretical analysis, and the structural deformation of ceramic dielectric under impact stress was analyzed. The relationship between the capacitance and DC bias of the capacitor was analyzed. A capacitance calculation model for pulse power-MLCC in an electromechanical coupling environment was established, revealing the electromechanical coupling mechanism of pulse power-MLCC.

Nanoporous Submicron Gold Particles Enable Nanoparticle-Based Localization Optoacoustic Tomography (nanoLOT).

Localization optoacoustic tomography (LOT) has recently emerged as a transformative super-resolution technique breaking through the acoustic diffraction limit in deep-tissue optoacoustic (OA) imaging via individual localization and tracking of particles in the bloodstream. However, strong light absorption in red blood cells has previously restricted per-particle OA detection to relatively large microparticles, ≈5µm in diameter. Herein, it is demonstrated that submicron-sized porous gold nanoparticles, ≈600nm in diameter, can be individually detected for noninvasive super-resolution imaging with LOT. Ultra-high-speed bright-field microscopy revealed that these nanoparticles generate microscopic plasmonic vapor bubbles, significantly enhancing opto-acoustic energy conversion through a nano-to-micro size transformation. Comprehensive in vitro and in vivo tests further demonstrated the biocompatibility and biosafety of the particles. By reducing the detectable particle size by an order of magnitude, nanoLOT enables microangiographic imaging with a significantly reduced risk of embolisms from particle aggregation and opens new avenues to visualize how nanoparticles reach vascular and potentially extravascular targets. The performance of nanoLOT for non-invasive imaging of microvascular networks in the murine brain anticipates new insights into neurovascular coupling mechanisms and longitudinal microcirculatory changes associated with neurodegenerative diseases.

Coupling mechanism of trace elements and maceral in medium and high sulphur coal in the Jurassic terrestrial environment of Zhongyuan mine in the Hengshan mining area and adjacent areas

ABSTRACT Considering the urgency of resource utilization and environmental protection, the geochemistry of anomalous trace transition metal elements in coal formed in terrestrial environments has been studied using methods such as inductively coupled plasma atomic emission spectrometry analysis, electron probe micro-area analysis, sequential chemical extraction procedures, and correlation analysis. The results indicate that minerals in the coal samples included pyrite, kaolinite, quartz, dolomite, calcite, and celestite. Furthermore, compared with the average values of coals in China and the upper continental crust, the coal samples were rich in transition metal trace elements such as Ni, Cr, and Sr and were deficient in Be, Cd, Cu, Co, Ga, Mo, Sb, Tl, V, Zn, and Ti. We found that Ni preferentially occurred in the organic matter over minerals, while Cr primarily bonded with sulfide minerals and to a lesser extent with the iron-manganese oxide minerals. Sr had a low correlation with organic matter but adhered to clay minerals and celestite. Ni enrichment in coal samples was the result of terrigenous input, while the Cr enrichment was related to intrusion of magmatic hydrothermal fluids. Sr enrichment was caused by the presence of SO4 2- in the terrigenous debris and the influence of Sr-rich water underground.

Coupling relationship and development patterns of agricultural emission reduction, carbon sequestration, and food security

In-depth exploration of the coupling relationship between agricultural emission reduction and carbon sequestration (ERCS) and food security provides an important basis for promoting sustainable low-carbon development in agriculture. This research investigates the coupling mechanisms and the current state of coordinated development of agricultural ERCS and food security using provincial panel data from 2001 to 2022 in China. The agricultural ERCS level shows an upward trend, with higher levels in the north and lower in the south; externalities are positive in the north but negative in the south. Significant dynamic interactions and spatial correlations between the agricultural ERCS and food security exist, with a local spatial agglomeration pattern of “north–south opposition”. Areas of high-high agglomeration are mainly concentrated in the north, while low-low agglomeration areas are primarily in the south. High-high agglomeration areas drive growth in transitional and low-growth areas through diffusion effects. The average coupling coordination degree of provinces increased from 0.432 to 0.473, indicating more coordinated development, and with a decreasing polarization trend. The spatial distributions of the coupling coordination degree and the relative development index are higher in the north and lower in the south, with many areas showing high adjustment, low adjustment, and high antagonism, particularly in the south where the number of high antagonistic areas has decreased. Implementing differentiated development strategies between the north and the south, using spatial agglomeration characteristics to optimize regional policies, focusing on the diffusion effects of high-coupling coordination areas to drive the development of low-growth and transitional areas, and enhancing the lagged terms can promote sustainable coordinated agricultural development.

Synergistic enhancement of chemical and electromagnetic effects in a Ti3C2Tx/AgNPs two-dimensional SERS substrate for ultra-sensitive detection

BackgroundIt is well established that surface-enhanced Raman scattering (SERS) is one of the most commonly used spectral analysis techniques in real-world applications, including chemical and biological sensing, analytical detection, and even forensics. It offers high sensitivity, high resistance to solvents, photobleaching, and limited spectrum bands. In general, SERS is caused by two mechanisms, the electromagnetic enhancement mechanism (EM) and the chemical enhancement mechanism (CM), although the exact mechanism is not yet known. For increased sensitivity, a SERS substrate based on EM coupled with CM is essential. ResultsUsing electrostatic self-assembly, we fabricated many homogeneous hot spots for the substrate by evenly mixing positive charge Ag nanoparticles (AgNPs) with negative charge Ti3C2Tx. In addition, there is a clearly enhanced effect due to the high affinity between the tested molecule and Ti3C2Tx, which facilitates molecule-to-molecule charge transfer. After successfully preparing the Ti3C2Tx/AgNPs substrate, the R6G dye molecule was used to investigate its SERS activity. According to the results, the substrate can reach an enhancement factor of 3.8 × 108. Furthermore, it has been demonstrated that the coupling effect between EM and CM is the main reason for the excellent performance of the Ti3C2Tx/AgNPs composite substrate. Based upon the results of detecting the two biomarkers, adenosine triphosphate and folic acid, the detection limits were determined to be 4.27 × 10−9 M and 7.26 × 10−13 M, respectively. Significance and noveltyTwo-dimensional metal carbide Ti3C2Tx material can be used to obtain CM in surface Raman scattering. It has been demonstrated that the combination of CM and EM with nano-precious metals can produce an extremely sensitive SERS substrate that is dependable and stable. Additionally, the Ti3C2Tx/AgNPs study offers a novel perspective for the advancement of the SERS coupling mechanism in addition to providing direction for realistic detection.

Fluid-structure interaction mechanism in shear thickening fluid/Foam composite for advanced protective structures

Fluid-structure interaction (FSI) between shear thickening fluid (STF) and soft materials is pivotal in designing advanced protective structures. This study delves into the FSI mechanisms within a composite structure known as STF/Foam, which features the infusion of STF into foam. Through comprehensive drop weight tests, the STF/Foam exhibited exceptional cushioning performance. In addition to analyzing FSI from the perspective of structural materials, this study also examines it from the STF standpoint, enabling a multi-faceted understanding of the energy absorption mechanism. To accurately characterize the rheological properties of STF, a novel decoupling method is proposed, accounting for both temporal and spatial inhomogeneities of STF. The research findings indicate that the viscosity variation of STF significantly enhances the energy absorption capabilities of the STF/Foam composite. This study reveals the intricate fluid-solid coupling mechanism between STF and foam. The STF demonstrates a unique combination of shear resistance akin to high-viscosity fluids and the easy flow characteristics of low-viscosity fluids. The modulation of STF viscosity optimizes the structural deformation pattern, thereby rationalizing the energy absorption mechanism of the composite. Consequently, STF/Foam showcases superior cushioning performance. Further investigation into various parameters associated with STF and foam highlights their influence on the structural cushioning performance. These insights lay a theoretical foundation and provide design guidelines for the future development of STF-based controllable protective structures.

A Numerical Simulation Method for Investigating the Fluid–Structure–Ice Coupling Mechanism of a Wedge Breaking through Ice into Water

A Numerical Simulation Method for Investigating the Fluid–Structure–Ice Coupling Mechanism of a Wedge Breaking through Ice into Water

Structural basis of mRNA decay by the human exosome-ribosome supercomplex.

The interplay between translation and mRNA decay is widespread in human cells1-3. In quality-control pathways, exonucleolytic degradation of mRNA associated with translating ribosomes is mediated largelyby the cytoplasmic exosome4-9, which includes the exoribonuclease complex EXO10 and the helicase complex SKI238 (refs. 10-16). The helicase can extract mRNA from the ribosome and is expected to transfer it to the exoribonuclease core through a bridging factor, HBS1L3 (also known as SKI7), but the mechanisms of this molecular handover remain unclear7,17,18. Here we reveal how human EXO10 is recruited by HBS1L3 (SKI7) to an active ribosome-bound SKI238 complex. We show that rather than a sequential handover, a direct physical coupling mechanism takes place, which culminates in the formation of a cytoplasmic exosome-ribosome supercomplex. Capturing the structure during active decay reveals a continuous path in which an RNA substrate threads from the 80S ribosome through the SKI2 helicase into the exoribonuclease active site of the cytoplasmic exosome complex. The SKI3 subunit of the complex directly binds to HBS1L3 (SKI7) and also engages a surface of the 40S subunit, establishing a recognition platform in collided disomes. Exosome and ribosome thus work together as a single structural and functional unit in co-translational mRNA decay, coordinating their activities in a transient supercomplex.

Theoretical investigations of two-dimensional intrinsic magnets derived from transition-metal borides M3B4 (M = Cr, Mn, and Fe)

ABSTRACT Two-dimensional (2D) magnetic materials with high critical temperatures (T C ) and robust magnetic anisotropy energies (MAE) hold significant potential for spintronic applications. However, most of 2D magnetic materials are derived from the van der Waals (vdW) layered bulks, which greatly limits the synthesis of 2D magnetic materials. Here, 2D M3B4 (M = Cr, Mn, and Fe; B = Boron), derived from hexagonal and orthorhombic M3AlB4 phases by selectively etching Al layers, was studied for its structural stability, electronic structure, and magnetic properties. By utilizing ab initio calculations and Monte Carlo simulations, we found that the orthorhombic Cr3B4 shows ferromagnetic (FM) metal and possesses an in-plane magnetic easy axis, while the remaining hexagonal and orthorhombic M3B4 structures exhibit antiferromagnetic (AFM) metals with a magnetic easy axis which is perpendicular to the two-dimensional plane. The critical temperatures of these 2D M3B4 structures are found to be above the 130 K. Notably, the ort-Mn3B4 possesses highest T C (~600 K) and strongest MAE (~220 µeV/atom) among these borides-based 2D magnetic materials. Our findings reveal that the 2D M3B4 compounds exhibit much better resistance to deformation compared to M2B2 MBenes and other 2D magnetic materials. The combination of high critical temperature, robust MAE, and excellent mechanical properties makes 2D Mn3B4 monolayer exhibits a favorable potential for spintronic applications. Our research also sheds light on the magnetic coupling mechanism of 2D M3B4, providing valuable insights into its fundamental characteristics.

Reliability Analysis of Axial Compressive Strength of Concrete-Filled Steel Tube (CFST) under Coupled Corrosion and Load Effects

This paper presents a finite element analysis (FEA) of and reliability study on concrete-filled steel tube (CFST) members under the combined effects of corrosion and compressive loading. First, a stochastic-based FE model is established through the proposed secondary development program based on ABAQUS 2021 software. The model could account for the uncertainties of material, geometric, and corrosion effect on CFST members. The reliability of the built model was validated through experimental data of corroded CFST members under compression loading. Subsequently, the compressive performance of CFST under a combination of corrosion and loading was further investigated by numerical parameter analysis. A total of 1800 models were created to clarify the coupling mechanism among the core concrete strength, the steel tube strength, the steel ratio, and the maximum strength of the CFST member. Three theoretical formulas presented in classical design standards were used to calculate the axial compressive strength of the corroded CFST, and the uncertainty parameters μkp and δkp were also obtained for the discussed design formulas. Finally, the First Order and Second Moment (FOSM) method was employed to estimate the reliability indices β across different standards. The calculations revealed that the reliability indices β according to European standard ranges from 2.93 to 5.52, with some results falling below the target reliability index βT of 3.65. In addition, the multi-parameter coupling effects on reliability index β were investigated, and the main influencing factors were obtained. By leveraging the reliability analysis, reasonable design requirements can be proposed for CFST members under the coupling effects of corrosion and external load, which provides a design basis for the CFST member.

Coupled Analysis of Risk Factor for Tailing Pond Dam Failure Accident Based on N–K Model and SNA

The failure of tailings pond dams represents a complex coupled system involving various risk factors, including human, governance, facilities, and environmental aspects. It is crucial to identify key risk factors at the system level to enhance the safety management of tailings ponds. We analyzed 74 cases of tailings pond dam failure accidents, both domestically and internationally, from the perspectives of human, governance, facility, and environment. We employed the 2–4 Model to identify and extract the causes of dam failures, summarizing these into four primary risk factors and 40 secondary risk factors, while constructing a risk coupling mechanism model. The natural killing (N–K) model was implemented to analyze the risk coupling values of primary risk factors and quantify these couplings. The N–K model facilitated an analysis of the risk coupling values of first-level risk factors, while social network analysis (SNA) was employed to visualize the relationships among second-level risk factors and assess the centrality and accessibility of nodes within the risk factor network. The out-degree of the risk nodes was corrected by integrating the N–K model with the SNA, leading to the identification of key risk factors associated with tailings pond dam failures and the formulation of corresponding safety prevention and control strategies. The findings indicate that managing multi-risk factor coupling is an effective approach to mitigating the occurrence of tailings pond dam failure accidents. Notably, unfavorable environmental risk factors significantly contribute to the coupling of human–governance–facility–environmental risks, necessitating targeted management strategies. Furthermore, inadequate safety supervision, weak safety awareness, inadequate receipt and inspection, and irregular operation represent additional key risk factors requiring focused prevention and control efforts.

Energy-harvesting tile incorporating an origami coupling mechanism.

We present the design and evaluation of a simple, compact and efficient electromagnetic energy harvesting tile that can be used to harness energy from footsteps. The proposed harvester incorporates a translational-rotational origami-inspired coupling mechanism to transform the axial loads exerted by human footsteps into a localized rotation of an electromagnetic generator. The coupling mechanism employs a non-rigid tunable Kresling spring, the restorative behaviour of which is tunable to maximize energy transduction from the applied load to the generator. A computational model is developed to optimize the design parameters of the mechanism, which are then utilized to fabricate a prototype of the energy harvester. The tile is tested under loading conditions that mimic a human step, where it is demonstrated that it is capable of generating 4.18 W of electrical power per step with a surface power density of 2609 μW cm-2.This article is part of the theme issue 'Origami/Kirigami-inspired structures: from fundamentals to applications'.

On-Surface Synthesis of Two-dimensional Carbon-based Networks via Hierarchical Ullmann Coupling Reactions.

The recent developed bottom-up on-surface synthesis offers unprecedent opportunities for the fabrication of two-dimensional (2D) carbon-based networks with atomic precision. Hierarchical coupling approach has been proposed as an efficient strategy for improving the corresponding reaction selectivity and quality of target structures. Herein, we report the synthesis of a nitrogen-doped carbon-based network on Ag(100) utilizing a hierarchical Ullmann coupling strategy. The accurate identification of reaction intermediates and products by scanning tunneling microscopy allows us to unravel the reaction mechanism. The synthetic process of 2D carbon-based networks is kinetics-driven, relying on the competition between dechlorination and C-C coupling. We expect that our discussion on the mechanism of hierarchical coupling may shed light on the rational design and precise synthesis of 2D carbon-based networks on surfaces.

Baroclinic instability in the Eady model for two coupled flows

ABSTRACT The linear instability of baroclinic flows in two superimposed and coupled, immiscible fluids is studied theoretically. These flows are westerlies, and they are thermally or mechanically coupled. The fluids are stably stratified, internally and mutually (the upper fluid is lighter than the lower fluid). In each fluid, two-level surface quasi-geostrophy governs the evolution of the perturbed westerly flow. The perturbations are horizontal normal modes. Firstly, the models are not coupled and the flow instability in each fluid is validated separately against the results of the classical Eady model of baroclinic instability. Secondly, the two fluids are thermally and/or mechanically coupled. With thermal coupling, and for meridionally uniform perturbations, a new mode of instability appears for long waves. This pair of unstable modes converges towards the modes of the uncoupled fluids at medium wavelengths. For perturbations with a non trivial meridional structure, the thermal coupling essentially damps the instability. For an upper flow with a larger deformation radius than in the lower flow, the growth rates of the perturbation are therefore more strongly altered in the former than in the latter. With mechanical coupling, the instability is essentially damped at large to medium scales, while the short-wave cut-off is extended towards smaller waves. When the fluids are both thermally and mechanically coupled, these effects add up. This very idealised study is a first step towards studying more realistic cases.

Quantitative evaluation and optimization of synergistic regulation performance considering wear in short-term response of hybrid pumped storage systems

Amid the extensive integration of renewable energy sources and rapid development of variable-speed pumped storage systems (VPSSs), demanding regulation tasks introduce risks to hydraulic-mechanical systems, revealing a growing trade-off between wear and regulation. From the economic and safe operation perspective, this paper aims to accurately quantify and enhance comprehensive regulation performance of hybrid pumped hydro storage systems (HPHSSs) with VPSS. First, a generic framework is established to quantitatively evaluate synergistic regulation performance (SRP), combining regulation intensity and frequency suppression effect of each unit type. Next, a frequency-division coordinated control method is proposed based on the amplitude-frequency characteristics, designed to leverage the rapid response capabilities of VPSS, and the coupling mechanism between this method and the conventional speed limiter module in affecting system dynamics is elucidated. Finally, comprehensive evaluations of HPHSS under typical disturbance scenarios are conducted, with frequency-division parameter further optimized for different system configurations. The results indicate that HPHSS exhibits excellent global stability with the coordinated control, reducing magnitude of average frequency deviation from 10−3 to 10−4, greatly enhancing the SRP. Additionally, an optimal cut-off frequency is identified within 0.05–0.5 Hz, showing an increasing trend as VPSS proportion decreases. These findings provide a novel sight for the safe and optimized operation of HPHSS.

Principles of designing electrocatalysts to boost C–N coupling reactions for urea synthesis

AbstractThe electrocatalytic C–N coupling reaction can achieve green and sustainable urea synthesis as well as CO2 conversion and nitrogen fixation. However, the electrocatalytic C–N coupling reaction still faces challenges such as difficult adsorption and activation of reactive species, a large number of reactive intermediates, high reaction energy barriers, and inert reactive kinetics, resulting in the low urea yielding rate and Faradic efficiency. The development of efficient catalysts is key to improve the urea yielding rate and Faradic efficiency. This review covers the development history and basic principles of electrocatalytic C–N coupling for urea production, analyzes the nanostructure–catalytic activity relationship as well as the electronic structure–catalytic activity relationship, and discusses the main reaction mechanism of electrocatalytic C–N coupling for urea production. Based on these analyses, the concept of designing efficient C–N coupling catalysts is derived. Finally, the research status of electrocatalytic C–N coupling for urea synthesis is summarized, and the prospect for developing efficient electrocatalysts and C–N coupling mechanism are proposed.