A novel porous corn starch-based antibacterial sustained-release intelligent film was prepared with the porous corn starch as the substrate, purple corn cob anthocyanin (PCA) as the indicator, and tangerine peel essential oil as the antibacterial agent, and its properties were studied. The results showed that the porous corn starch-based antimicrobial sustained-release indicator film had good mechanical strength, surface hydrophobicity and light transmittance. The tensile strength of the sustained-release indicator film (PLSt-12) prepared by porous corn starch with an enzymatic hydrolysis time of 12 h was 14.35 MPa and the elongation at break was 6.55 %. The water contact angle was 89.10°, and the water vapor transmittance was 6.62 × 10−4 g·mm2·s−1·Pa−1. The PLSt-12 was brown at pH 10 and had a sensitive color response. The PLSt-12 reduced the release rate of anthocyanins by 25.01 %, and the sustained-release mechanism was non-Fick diffusion. It showed a significant color change when the pork quality deteriorated, which can be used to monitor the freshness of the pork. This type of antibacterial sustained-release intelligent film had considerable application potential in indicating food freshness.
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