Carbon Copper Research Articles

Discrimination of natural and synthetic forms of azurite: An innovative approach based on high-resolution terahertz continuous wave (THz-CW) spectroscopy for Cultural Heritage

It is not always possible to discriminate natural and synthetic forms of pigments in a non-invasive way. In this work, we demonstrate that THz spectroscopy allows for this selective discrimination of chemically related compounds. In the presented results, we show the spectral characterization of the following copper carbonates: natural azurite and two of its synthetic forms, bice blue and blue verditer. In particular, the physical properties of the two synthetic forms were characterized for the first time in the terahertz spectral range by exploiting a high-resolution coherent terahertz Continuous Wave (THz-CW) spectrometer. The findings reveal distinct absorption spectra for the three chemically related pigments, showing specific fingerprints that can be used to discriminate the natural compound from the synthetic forms.In fact, we show that by THz-CW it was possible to discriminate those pure components in binary mixtures and quantify the single components contribution.This identification is of great interest to assist in dating artworks or evidence restoration and retouching treatments. The results demonstrate that THz-CW spectroscopy can pave the way to an innovative approach to the Cultural Heritage field.

Useful metals recovery from electronic scraps of headphones – A sustainable approach

The utilization of electronic devices has been consistently increasing each year. In the fiscal year 2020–2021, India handled more than 340,000 tonnes of electronic waste, a significant surge from the 69,414 tonnes recorded in 2017–2018. Over the past four years, there has been a remarkable fourfold increase in the collection and processing of e-waste. This project focuses on e-waste generated from headphones, considering their widespread usage globally. Surprisingly, despite their ubiquity, only 15 % of headphones are recycled, with more than 85 % being discarded as waste. To address this issue, hydrometallurgy treatment is employed to extract valuable metals such as copper and iron. Following this treatment, this research successfully obtained copper carbonate and iron oxide as essential elements. The leached solution undergoes analysis using Atomic Absorption Spectroscopy (AAS). Further characterization through X-Ray Diffraction (XRD) of batteries and magnets aids in identifying the crystalline materials. Additionally, a cost-benefit analysis was carried out, revealing a 57 % and a 39 % profit in copper carbonate and iron oxide extraction respectively and this validates the confirmation of circular economy. Finally, a questionnaire survey was conducted with approximately 192 students, revealing that most headset replacements occur roughly once a year, typically within a budget of around Rs. 500–1000. This strongly indicates a high rate of waste disposal.

Copper–Carbon Nanotube Composites Enabled by Brush Coating for Advanced Conductors

Copper–Carbon Nanotube Composites Enabled by Brush Coating for Advanced Conductors

Illuminating the problem of blue verditer synthesis in the early modern English period: chemical characterisation and mechanistic understanding

We present a study into early modern English production of blue verditer, an early synthetic copper-based blue pigment chemically analogous to azurite. Verditers have been identified in numerous wall and easel paintings. While initial documentation occurs in the mid 1500s and production recipes were documented by the 17th c., the synthesis was known to be unreliable. This study replicates historical and recent scientific work on blue verditer and represents a significant advance in our understanding of verditer production and its challenges. Procedures for verditer synthesis are drawn from both 17th c. documentation and 20th c. replication work. The effects of temperature, copper and carbonate sources, solution stirring, copper ion concentration, and atmospheric composition are studied in order to elucidate the mechanism of synthesis and explain its unreliability in early modern refineries. Products are characterised by polarised light microscopy, scanning electron microscopy, Raman spectroscopy, and powder X-Ray diffraction. Rouaite, a green basic copper nitrate, is for the first time confirmed as a product of the refiners’ synthesis and a precursor to blue verditer in laboratory syntheses. This result problematises the blanket identification of green verditer as basic copper carbonate and provides important clues to the mechanism for blue verditer synthesis. Solution chemistry and ion equilibria allow us to explain the route by which rouaite is first formed and then converted to blue verditer. Conditions favouring blue verditer production are also clarified further. Although it is commonly stated that low temperatures are required for blue verditer production, blue verditer is produced here at a range of ambient temperatures. The reaction is found instead to be controlled by solution equilibria and heavily favoured by high partial pressures of carbon dioxide. Alongside archival materials about refining and verditer production, these results are contextualised and explanations for the unreliability of historical synthesis are proposed.

Evaluation of Copper Nanoparticle Synthesis by Fusarium oxysporum Antibacterial Activity Against Staphylococcus aureus

The creation of effective, environmentally friendly antimicrobial alternatives is becoming more and more important in light of the development of antibiotic resistance. The objective of the present study was to illustrate the biosynthetic process of copper (II) carbonate nanoparticles, CuCo3 NPs, by using Fusarium oxysporum culture filtrate as an antibacterial activity against multidrug-resistant (MDR) clinical bacterial isolates, Staphylococcus aureus. Fusarium oxysporum isolate was diagnosed by PCR. One hundred and sixty specimens of pathogenic bacteria were collected from different sources (wounds, urine, sputum) then the bacterial isolates were diagnosed as Staphylococcus aureus by conventional morphological examination, biochemical tests, and the Vitek-2 system. Fusarium oxysporum culture filtrate was prepared by a culture of the fungus on Czapek Dox broth media modified by adding cornmeal and incubated for 14 days with shaking at 27±2°C and filtered in the last stages using a Millipore. The biosynthesis of CuCo3 NPs was done by adding 1g of CuCo3 Cu (OH)2 to 10 ml of Fusarium oxysporum culture filtrate. The NPs were diagnosed using modern methods, including UV-VIS, FT-IR, AFM, FE-SEM, and EDX techniques. Multidrug-resistant Staphylococcus aureus was tested on the produced Cu NPs. The results indicated that the prepared CuCo3 NPs inhibited pathogenic bacterial isolates of Staphylococcus aureus at concentration of 500, 250, 125, and 62.5 mg/ml.

Multifunctional composite material based on piezoelectric nanofibers and Cu-CFRP electrodes for sensing applications

To monitor possible failures of a composite, several Structural Health Monitoring (SHM) systems have been developed. However, these methods typically involve embedding commercial sensors within the laminate, potentially compromising the material's strength.In this study, a self-sensing composite laminate was fabricated by interleaving poly(vinylidenefluoride-trifluoroethylene) (P(VDF-TrFE)) piezoelectric nanofibers between Glass Fiber Reinforced Plastic (GFRP) prepreg plies. Instead of conventional metallic sheets, hybrid Copper-Carbon Fiber Reinforced Plastic (Cu-CFRP) was used as electrodes to collect piezoelectric signals. This innovative approach offers two main advantages: enhanced interlaminar fracture toughness due to nanometric piezoelectric fibers and an intrinsic connection between copper wires and carbon, eliminating the need for additional electrical cables within the laminate. The effect of stacking sequence parameters on the self-sensing laminate's electromechanical response was investigated using a Design of Experiment (DoE) based on the Box-Benken method. Additionally, a lumped electric circuit model was employed to gain analytical insights into the piezoelectric behavior of the laminates.

Formulation of double nanoemulsions based on pH-sensitive carboxymethyl cellulose /Starch copper doped carbon quantum dots for quercetin controlled release

Nanocomposite Hydrogels are versatile and adaptable in drug delivery, suitable for various administrations. They offer prolonged and regulated drug release which makes them valuable in targeting cancer treatments. This study used the water/oil/water approach to construct a drug nanocarrier. It encapsulated hazelnut oil, serving as a protective and organic membrane that enveloped the nanocarrier and regulated drug release. Quercetin (QC), a potent flavonoid with potential therapeutic applications, faces challenges due to its hydrophobic nature and poor solubility. This approach presents a novel approach to enhance QC's solubility and stability by integrating it with copper carbon quantum dots (Cu-CQDs) into a pH-sensitive carboxymethyl cellulose (CMC) and starch-based hydrogel nanocomposite. This system aims to improve QC delivery while minimizing adverse effects. The nanocomposite exhibited exceptional drug loading and encapsulation efficiencies of 47.00 % ± 0.45 and 86.25 % ± 0.75, respectively, ranking among the top-reported values for similar systems. Fourier-transform infrared spectroscopy (FTIR) was used to examine molecular interactions. X-ray diffraction (XRD) assessment demonstrated the presence of components beneficial for drug solubility enhancement at 2Θ = 17–24°, where QC's crystalline peaks are absent from the CMC/Starch/Cu-CQDs@QC XRD pattern. A particle size of 151.57 ± 37 nm is optimized for selectively targeting cancer cells, minimizing interaction with healthy cells, as revealed through DLS assessment. Morphological characteristics analyzed by FE-SEM support this observation as well. Zeta potential measurement (+38.8 mV) highlights nanocarrier stability. CMC/Starch/Cu-CQDs@QC displayed remarkable cytotoxicity against cancerous cells, reducing U87-MG cell viability to 48 % while maintaining high cell viability (92 %) for normal L929 cells. These results emphasize the promise of this nanocomposite as a QC drug delivery system by indicating improved anticancer efficacy with fewer adverse effects.

Computational analysis of hybrid nanoparticles dispersion in Powell-Eyring fluid flow over a stretching surface: A comparative simulation study

This study observes the numerical analysis of Powell-Eyring hybrid nanofluid along a stretching sheet. The movement of sheet in x-direction is taken to be the source of motion in the fluid. Nanoparticles are considered as agents for increasing thermal properties of fluids. This research emphasizes the amalgamation of copper oxide and carbon nanotubes with engine oil as a base fluid. A significant increase is observed by adding these agents. Porous medium is considered using Darcy law. Magnetics field is also taken for studying mass transfer analysis. For heat transfer mechanisms, thermophoresis and Brownian diffusions are taken into account. The whole procedure is shown through nonlinear differential equations. Appropriate transformations are used for simplification purposes. After transformations, partial differential equations are converted into ordinary differential equations and handled through numerical technique. Shooting numerical technique has been used to solve the governing system of equations, and the obtained results are thoroughly examined and discussed graphically. The thermal characteristics of the hybrid nanofluid are analyzed, in the presence of thermal radiation and thermophoresis effects. To validate our results, a comparison analysis is drawn with existing literature in some specific scenarios.

High-frequency characteristics of multilayer graphene nanoribbon interconnects: Exploring the implications OF SKIN effect

A study is undertaken to explore the frequency-dependent traits of crosstalk delay (X-D), crosstalk noise area (X-NA), and the mean time to failure induced by electromigration (EM-MTF) in interconnects constructed from lithium-doped multilayer graphene nanoribbon (Li-MLGNR) and their optimized counterparts, known as optimized Li-MLGNR (O-LiMLGNR) interconnects. The analysis is based on the skin depth and impedance model incorporating scatterers and the finite thickness of the interconnect. The obtained high-frequency impedance and performance characteristics reveals that O-LiMLGNR outperforms Li-MLGNR, rough copper, and mixed carbon nanotube bundle in terms of X-D, X-NA, and EM-MTF. Subsequently, the performance of O-LiMLGNR, limited by process and temperature variations, is analyzed at high frequencies under the influence of skin-effect. As a result of variations in process parameters and temperature, the O-LiMLGNR exhibits an increase in variations of X-D and X-NA, accompanied by a reduction in variation of EM-MTF as the frequency increases.

On the Electrodeposition of Zinc in Low Magnetic Fields

Abstract While aqueous zinc-based batteries have garnered much research on account of their improved safety, lower cost, and easier fabrication over lithium-ion batteries, they remain held back by dendrite growth on the anode. While many different solutions have been proposed, these solutions often greatly complicate the synthesis or materials in the battery. The application of a magnetic field across the battery has been shown to inhibit dendrite formation without the need for any materials or interface engineering. Herein, we provide a study on the effects of low magnetic fields on the electrodeposition and cycling of zinc in various aqueous systems. We demonstrate that although stronger fields have more immediate impacts on the morphology of zinc deposits, low magnetic fields are still suitable for inhibiting dendrite growth over long periods of cycling. Magnetic field strengths as low as 29 mT were shown to decrease charge transfer resistance of zinc ion deposition by up to 54% and to stabilize the cycling of Zn/Zn symmetric cells. Furthermore, the versatility of magnetic field application was demonstrated by affecting the morphology of zinc deposits on both copper and single-walled carbon nanotubes, which are both compatible with anode-free configurations of aqueous zinc-ion batteries.

Ratiometric fluorescence detection of dopamine based on copper nanoclusters and carbon dots

Nanoclusters for fluorescence detection are generally comprised of rare and expensive noble metals, and the nanoclusters based on more affordable transition metal have attracted increasing attention. This study designed a ratiometric fluorescent probe to detect dopamine (DA), an important neurotransmitter. With carbon dots encapsulated within silica (CDs@SiO2) as the reference, the emitted reference signal was almost unchanged due to the protection of inert silicon shell. Meanwhile, copper nanoclusters modified with 3-aminophenyl boronic acid (APBA-GSH-CuNCs) provided the sensing signal, in which the phenylboric acid could specifically recognize the cis-diol structure of DA, and caused the fluorescence quenching by photoinduced electron transfer. This dual emission ratiometric fluorescent probe exhibited high sensitivity and anti-interference, and was able to selectively responded to DA with a linear range of 0–1.4 mM, the detection limit of 5.6 nM, and the sensitivity of 815 mM−1. Furthermore, the probe successfully detected DA in human serum samples, yielding recoveries ranging from 92.5% to 102.7%. Overall, this study highlights the promising potential of this ratiometric probe for detecting DA.

Additive manufacturing of self-sensing parts through material extrusion

ABSTRACT The objective of this study is to develop and evaluate self-sensing capabilities in additively manufactured parts by embedding conductive elements that are copper and continuous carbon fiber. Two sets of test specimen were manufactured using a custom g-code on material extrusion-based Anisoprint A4 machine. Each set contained copper and continuous carbon fiber in an amorphous thermoplastic matrix. A tailor-made test setup was developed by improvising the American Society for Testing and Materials (ASTM D790) three-point loading system. Electrical resistance measurements were conducted under flexural loads to evaluate the self-sensing capability of each test specimen. The results confirmed that material extrusion technology can allow production of self-sensing parts. The electrical resistance increases linearly (Sensing tolerance <±2.6%, R2>93.8% p-value < 0.005), establishing a strong correlation with applied force and strain. The work allows for creating smart parts that can facilitate big data collection, analysis, and evidence-based decision-making for condition monitoring and preventive maintenance needed for Industry 4.0.

Efficient C-N coupling in electrocatalytic urea generation on copper carbonate hydroxide electrocatalysts

Urea generation through electrochemical CO2 and NO3− co-reduction reaction (CO2NO3RR) is still limited by either the low selectivity or yield rate of urea. Herein, we report copper carbonate hydroxide (Cu2(OH)2CO3) as an efficient CO2NO3RR electrocatalyst with an impressive urea Faradaic efficiency of 45.2% ± 2.1% and a high yield rate of 1564.5 ± 145.2 μg h−1 mgcat−1. More importantly, H2 evolution is fully inhibited on this electrocatalyst over a wide potential range between −0.3 and −0.8 V versus reversible hydrogen electrode. Our thermodynamic simulation reveals that the first C-N coupling follows a unique pathway on Cu2(OH)2CO3 by combining the two intermediates, *COOH and *NHO. This work demonstrates that high selectivity and yield rate of urea can be simultaneously achieved on simple Cu-based electrocatalysts in CO2NO3RR, and provide guidance for rational design of more advanced catalysts.

Photothermal/photodynamic antibacterial hydrogel embedded with copper carbon dots and Au nanoparticles

In this paper, we created a hydrogel (named AuNPs-CuCCDs@Gel) with photothermal and photodynamic performance through incorporating copper carbon dots (CuCCDs) and Au nanoparticles (AuNPs) into gelatin and chitosan hydrogels. The thus-obtained hydrogel exhibited a high photothermal and photodynamic antibacterial activity with a superior singlet oxygen yield (0.70), which was better than that of methylene blue (0.52). After laser irradiation at 808 nm for 6 min, the temperature of AuNPs-CuCCDs@Gel rose from room temperature to 50 °C, which manifested good effects for avoiding local heat damage and protecting normal cells. AuNPs-CuCCDs@Gel exhibited the highest antibacterial efficacy of 96.46% and 97.48% against S. aureus and E. coli respectively. The significantly improved bactericidal performance was attributed to the synergistic effects of hyperthermia and reactive oxygen species (ROS). This work suggests that photothermal/photodynamic antibacterial hydrogel is a promising agent for treating wound infection.

Synthesis of Copper Carbonate from Copper Waste Using the Hydrometallurgical Method

&lt;p&gt;Electronic waste in Indonesia continues to increase, electronic waste is categorized as B3 waste which can threaten the environment. Electronic waste contains metals that can berecovery namely 20% copper (Cu), 8% iron (Fe), 4% tin (Sn), 2% nickel (Ni), 2% lead (Pb), 1% zinc (Zn), 0.2% silver (Ag), 0.1% gold (Au) and 0.005% palladium (Pa). Copper can be used as a raw material for making pigments mountain blue. Pigment extraction from copper metal can be done using the hydrometallurgical method which is considered more environmentally friendly and economical. The hydrometallurgical method uses solvents in the liquid phase to dissolve copper metal from waste and convert it into the desired compound. The materials used to make mountain blue pigment are copper waste, sulfuric acid (H&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;), sodium hydroxide (NaOH), sodium carbonate (Na&lt;sub&gt;2&lt;/sub&gt;CO&lt;sub&gt;3&lt;/sub&gt;), hydrogen peroxide (H&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;2&lt;/sub&gt;), and distilled water. Meanwhile, the materials used for pigment application are Carboxymethyl Cellulose (CMC) and titanium dioxide (TiO&lt;sub&gt;2&lt;/sub&gt;). In this process, washing or leaching will be carried out(leaching) namely a chemical concentration process to release ore impurities from a mineral by dissolving it using certain reagents. Factors that influence the metal leaching process are temperature and acid concentration. In this experiment, the hydrometallurgical method succeeded in processing electronic waste into a blue pigment (mountain blue). The average pigment yield mountain blue in this experiment it was 1.25 grams of montain blue/gram of copper. Furthermore, the average conversion of pigment mountain blue was 89.3%.&lt;/p&gt;

G. P. Darnell-Smith and the introduction of copper carbonate ‘dry pickling’ of wheat seed

G. P. Darnell-Smith and the introduction of copper carbonate ‘dry pickling’ of wheat seed

In vitro assessment of antibacterial and antiviral activity of three copper products after 200 rounds of simulated use

Copper has well-documented antibacterial effects but few have evaluated it after prolonged use and against bacteria and viruses. Coupons from three copper formulations (solid, thermal coating, and decal applications) and carbon steel controls were subjected to 200 rounds simulated cleaning using a Wiperator™ and either an accelerated hydrogen peroxide, quaternary ammonium, or artificial sweat products. Antibacterial activity against S. aureus and P. aeruginosa was then evaluated using a modified Environmental Protection Agency protocol. Antiviral activity against coronavirus (229E) and norovirus (MNV-1) surrogates was assessed using the TCID50 method. Results were compared to untreated control coupons. One hour after inoculation, S. aureus exhibited a difference in log kill of 1.16 to 4.87 and P. aeruginosa a log kill difference of 3.39–5.23 (dependent upon copper product and disinfectant) compared to carbon steel. MNV-1 demonstrated an 87–99% reduction on each copper surfaces at 1 h and 99% reduction at 2 h compared to carbon steel. Similarly, coronavirus 229E exhibited a 97–99% reduction after 1 h and 90–99% after 2 h. Simulated use with artificial sweat did not hinder the antiviral nor the antibacterial activity of Cu surfaces. Self-sanitizing copper surfaces maintained antibacterial and antiviral activity after 200 rounds of simulated cleaning. Graphical abstract

Influence of some additives on burning rate of KNO3-based compositions

In this article effect of some additives on combustion behaviour of high energetic compositions based on KNO3 was studied. The KNO3-based samples were made by mixing, rolling, and pressing. Investigated additives were: copper salicylate, nickel salicylate, copper-lead phthalate, nickel-lead phthalate, soot and carbon nanotubes. Burning rate was determined by the pressure increasing by using modification of the corner point method. It is shown that individual additives insignificantly effect on the burning rate of studied samples. The carbon nanotubes brand TMD with specific surface area ~270 m2/g and copper salicylate are the most effective additives on the burning rate. It should be noted that copper salicylate with carbon nanotubes have a significantly greater effect on the burning rate than individual additives or the catalyst with soot.

An insight into recent developments of copper, silver and gold carbon dots: cancer diagnostics and treatment.

Cancer is one of the most fatal diseases globally, however, advancement in the field of nanoscience specifically novel nanomaterials with nano-targeting of cancer cell lines has revolutionized cancer diagnosis and therapy and has thus attracted the attention of researchers of related fields. Carbon Dots (CDs)-C-based nanomaterials-have emerged as highly favorable candidates for simultaneous bioimaging and therapy during cancer nano-theranostics due to their exclusive innate FL and theranostic characteristics exhibited in different preclinical results. Recently, different transition metal-doped CDs have enhanced the effectiveness of CDs manifold in biomedical applications with minimum toxicity. The use of group-11 (Cu, Ag and Au) with CDs in this direction have recently gained the attention of researchers because of their encouraging results. This review summarizes the current developments of group-11 (Cu, Ag and Au) CDs for early diagnosis and therapy of cancer including their nanocomposites, nanohybrids and heterostructures etc. All The manuscript highlights imaging applications (FL, photoacoustic, MRI etc.) and therapeutic applications (phototherapy, photodynamic, multimodal etc.) of Cu-, Ag- and Au-doped CDs reported as nanotheranostic agents for cancer treatment. Sources of CDs and metals alogwith applications to give a comparative analysis have been given in the tabulated form at the end of manuscript. Further, future prospects and challenges have also been discussed.

Multiphase simulation of sustainable nanoenhanced ionic liquid coolants for improved thermal performance in Ti–6Al–4V alloy drilling

Extensive research has been conducted by the manufacturing industry to enhance the efficiency of drilling processes by focusing on the utilization of nanoenhanced cutting fluids that possess excellent heat conductivity. Due to their eco-friendliness and adaptability of physical and chemical properties, ionic fluids offer enormous potential for application as cutting fluids. This study investigates the computational fluid dynamics analysis of the heat transfer performance of various ionanofluid pairs dispersed with nanoparticles as cutting fluids in the drilling process using Ansys Fluent software. For this purpose, 1-Hexyl-3-methyl-imidazolium-tetrafluoroborate is considered the ionic fluid, and its thermal behavior is examined by dispersing it with nanoparticles of copper, silver, and multiwalled carbon nanotubes (MWCNT) at different particle volume fractions and Reynolds numbers. The workpiece is composed of an alloy of titanium Ti–6Al–4V, while the drill bit is made of tungsten carbide-cobalt. It is observed that the ionic nanocoolant mist emanates from the spray tip and moves towards the drill bit-workpiece interface. Initially, the coolant's velocity is greatest close to the orifice, and as time passes, it approaches the drilling space. The data indicates that the spraying velocity of the coolant augments over time and that it disperses heat at the tool-chip interface. The results help us validate the flow and interaction of ionanocoolant with the drilling zone. With a rise in the volume fraction of added nanoparticles and Reynolds number, the results indicated a significant decrease in the drilling temperature. With a higher particle volume fraction, the MWCNT-ionic coolant combination decreases the drilling temperature of pure ionic liquid by 25.64 %. The copper, silver, and MWCNT ionanofluids enhance the average heat transfer coefficient of pure ionic coolant by 35.14 %, 47.42 %, and 62.75 %, respectively. In addition, MWCNT nanocoolants demonstrated improved thermal performance and heat removal rate in comparison to copper and silver ionanocoolants.