The optimal power-water flow (OPWF) is a fundamental tool for operating integrated power and water networks. To address uncertainties in renewable energy and load demands, researchers have used chance-constrained models to investigate OPWF under uncertainty. However, existing work has limitations, such as oversimplified network representations, intractable problem formulations, and high computational burdens. This paper presents a chance-constrained OPWF formulation that incorporates detailed network constraints and stochastic uncertainties from wind speeds and electricity/water demands. By leveraging the concept of quantiles of stochastic variables and convexification techniques, the model is recast into a deterministic mixed-integer second-order cone programming (MISOCP) problem with uncertain margins. To efficiently solve this problem, we propose a novel iterative algorithm assisted by deep neural networks (DNNs). The algorithm integrates two DNNs: one designed to solve power and water flow equations, accelerating the probabilistic evaluation of uncertain margins; and the other to predict pipeline flows and refine variable ranges, facilitating a warm-start approach to the MISOCP model. Case studies conducted on the IEEE 123-node feeder coupled with a 67-node water distribution network validate the two DNNs and the overall iterative algorithm. The findings demonstrate that the proposed DNN-assisted approach effectively balances system security and economy. Compared to existing algorithms, the relative error of the optimization solution is less than 0.03%, with a speedup ratio exceeding 200.
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