A detailed numerical study about the planar incident shock wave impinging on heavy bubbles with different components and nested structures was conducted. Results show that the shock wave convergence occurs when the incident shock wave impinging on the pure SF6 bubble or CO2-SF6 nested bubbles, which triggers the shock wave focusing and obtains a high transient pressure. Changing the nested position and radius of the SF6 bubble in CO2-SF6 nested bubbles will change the interactional time and relative position of waves to affect the shock wave focusing time and peak pressure. Specifically, the shock wave focusing effect is enhanced, and the peak pressure is increased when the inner bubble is drifted downstream, high density, and larger sized. Thus, the later the shock wave focusing occurs, the higher the transient maximum pressure. The shock wave focusing process of double-layer nested bubbles is presented as follows: the new small shock wave (SS) formed by the intersection between the incident transmitted shock wave and the transmitted shock wave and another new shock wave formed by the collision of diffracted transmitted shock waves move in opposite directions to squeeze the undisturbed region and finally produce a high instantaneous pressure, where SS plays a major role in shock wave focusing. Further, the greater the intensity and velocity of focusing shock waves, the stronger the focusing effect and the higher the transient pressure.