The scarcity of highly conductive materials with solution-processable ability and the contradictory relationship between conductivity ( σ ) and Seebeck coefficient ( S ), have greatly limited the development of thermoelectric (TE) materials. To address these challenges, we propose a novel strategy from the following two aspects: 1) Highly conductive materials with solution-processable ability are achieved by simply combining platinum-based complexes with Single-walled carbon nanotubes (SWCNTs). Among them, SWCNT/Pt-4 manifests the highest σ (4166.3 S cm −1 ), which is among the highest for p-type SWCNT-based TE materials; 2) The TE material with high S is applied to the above system to overcome the restrictive relationship between S and σ . The optimized three composites display remarkably higher power factor (PF) than those of either two hybrids at room temperature, and the highest PF is achieved by SWCNT/(Ge 0.87 Pb 0.13 Te) 0.95 (Bi 2 Te 3 ) 0.05 /PtCl 4 (471.8 μW m −1 K −2 ) at 420 K. This strategy simultaneously improves the PF of SWCNTs by innovatively introducing a three-phase system in the composites. Our work opens up new material options for TE applications and provides a robust pathway to the development of high-performance TE materials. • Both the platinum and ligands played a dominate role in enhancing the σ of SWCNTs. • SWCNT/Pt-4 manifested the highest σ with the value of 4166.3 S cm −1 . • The combinations can induce a synergistic effect on the TE performance. • The highest PF (471.8 μW m −1 K −2 ) was achieved by three-phase composites at 420 K.
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