Continuous Gas Research Articles

Stability of Iodine Species Trapped in Titanium-Based MOFs: MIL-125 and MIL-125_NH2.

Two titanium-based MOFs MIL-125 and MIL-125_NH2 are synthesized and characterized using high-temperature powder X-ray diffraction (PXRD), thermogravimetric analysis(TGA), N2 sorption, Fourier transformed infrared spectroscopy (FTIR), Raman spectroscopy, ultraviolet-visible spectroscopy (UV-Vis), and electron paramagnetic resonance (EPR). Stable up to 300°C, both compounds exhibited similar specific surface areas (SSA) values (1207 and 1099m2g-1 for MIL-125 and MIL-125_NH2, respectively). EPR signals of Ti3+ are observed in both, whith MIL-125_NH2 also showing ─NH2 ●+ signatures. Both MOFs efficiently adsorbed iodine in continuous gas flow over five days, with MIL-125 trapping 1.9g.g-1 and MIL-125_NH2 trapping 1.6g.g-1. MIL-125_NH2 exhibited faster adsorption kinetics due to its smaller band gap (2.5 against 3.6eV). In situ Raman spectroscopy conducted during iodine adsorption revealed signal evolution from "free" I2 to "perturbed" I2, and I3 -. TGA and in situ Raman desorption experiments showed that ─NH2 groups improved the stabilization of I3 - due to an electrostatic interaction with NH2 ●+BDC radicals. The Albery model indicated longer lifetimes for iodine desorption in I2@MIL-125_NH2, attributed to a rate-limiting step due to stronger interaction between the anionic iodine species and the ─NH2 ●+ radicals. This study underscores how MOFs with efficient charge separation and hole-stabilizer functional groups enhance iodine stability at higher temperatures.

Monodispersed Bubble Generation Using Hydrophobic Orifices: The Extended Tate's Law.

The use of submerged orifices for bubble generation is ubiquitous in industries with wettability known to influence the bubble departure diameter. In this study, we investigated bubble generation and departure from the orifices (0.3-2 mm) drilled on hydrophobic perfluoroalkoxy (PFA) tubes in water. By varying the gas inflow rate (33 to 200 mL/min), we found that the Sauter mean diameter closely matched those generated by hydrophilic quartz orifices. However, monodispersed bubbles were formed on the PFA tube compared to those on quartz with much wider size distributions. By examining the dynamic bubbling process, we confirmed its agreement with Tate's law, which was originally developed for quasi-steady conditions and emphasizes a balance between capillary and buoyancy forces. However, it should be noted that dynamic conditions lead to an increase in bubble volume compared to the quasi-steady condition despite following the same principle, which is explained by the continuous gas inflow when the bubble departs from the orifice at a necking stage. The above understandings enable generation of monodispersed bubbles under dynamic conditions, benefiting industries requiring precise control on bubble size, such as the bubble assisted wet etching and cleaning processes in semiconductor fabrication.

Phenotypic and genomic characterization of Methanothermobacter wolfeii strain BSEL, a CO2-capturing archaeon with minimal nutrient requirements.

A new variant of Methanothermobacter wolfeii was isolated from an anaerobic digester using enrichment cultivation in anaerobic conditions. The new isolate was taxonomically identified via 16S rRNA gene sequencing and tagged as M. wolfeii BSEL. The whole genome of the new variant was sequenced and de novo assembled. Genomic variations between the BSEL strain and the type strain were discovered, suggesting evolutionary adaptations of the BSEL strain that conferred advantages while growing under a low concentration of nutrients. M. wolfeii BSEL displayed the highest specific growth rate ever reported for the wolfeii species (0.27 ± 0.03 h-1) using carbon dioxide (CO2) as unique carbon source and hydrogen (H2) as electron donor. M. wolfeii BSEL grew at this rate in an environment with ammonium (NH4+) as sole nitrogen source. The minerals content required to cultivate the BSEL strain was relatively low and resembled the ionic background of tap water without mineral supplements. Optimum growth rate for the new isolate was observed at 64°C and pH 8.3. In this work, it was shown that wastewater from a wastewater treatment facility can be used as a low-cost alternative medium to cultivate M. wolfeii BSEL. Continuous gas fermentation fed with a synthetic biogas mimic along with H2 in a bubble column bioreactor using M. wolfeii BSEL as biocatalyst resulted in a CO2 conversion efficiency of 97% and a final methane (CH4) titer of 98.5%v, demonstrating the ability of the new strain for upgrading biogas to renewable natural gas.IMPORTANCEAs a methanogenic archaeon, Methanothermobacter wolfeii uses CO2 as electron acceptor, producing CH4 as final product. The metabolism of M. wolfeii can be harnessed to capture CO2 from industrial emissions, besides producing a drop-in renewable biofuel to substitute fossil natural gas. If used as biocatalyst in new-generation CO2 sequestration processes, M. wolfeii has the potential to accelerate the decarbonization of the energy generation sector, which is the biggest contributor of CO2 emissions worldwide. Nonetheless, the development of CO2 sequestration archaeal-based biotechnology is still limited by an uncertainty in the requirements to cultivate methanogenic archaea and the unknown longevity of archaeal cultures. In this study, we report the adaptation, isolation, and phenotypic characterization of a novel variant of M. wolfeii, which is capable of maximum growth with minimal nutrients input. Our findings demonstrate the potential of this variant for the production of renewable natural gas, paving the way for the development of more efficient and sustainable CO2 sequestration processes.

Carbon accounting methods for the system-wide evaluation of carbon capture, utilisation and storage: A case study in Mexico's Southeast Region

Existing assessments of climate mitigation technologies, like carbon capture utilisation and storage (CCUS), often rely on life cycle assessments (LCA), which are helpful for quantification but may not always be the most complete tools for decision-making. The novel contribution of this study is to provide the first application of a consequential carbon accounting approach, presented as a time-series analysis, to measure the system-wide change in emissions from CCUS linked to CO2-enhanced oil recovery. This method includes emissions from marginal oil production, a variable typically excluded in other LCA methods. The method was applied to a hypothetical CCUS project in Mexico to understand critical factors determining whether such an intervention can effectively contribute to emissions reduction in alignment with net-zero goals. Four intervention scenarios were assessed, comparing two distinct CO2 injection strategies in oil reservoirs (water alternating gas and continuous gas injection) and two energy policy scenarios (current and sustainability). The findings suggest that the energy grid's role in overall emissions is relatively minor, with only a ∼2% difference between the compared scenarios, in contrast, the injection strategy has a significant impact on emissions. Scenarios 1 and 3 report a total change in emissions of −28.39 and −29.87MtCO2e, and scenarios 2 and 4 account for −19.63 and −21.22MtCO2e, respectively. The results highlight the importance of conducting system-wide analysis and comparing different scenarios to identify the critical components that drive changes in emissions and, therefore, support decision-making and project planning.

Maximizing Production Profits: Optimizing Gas Lift Design in the Halfaya Oil Field

Gas lift is one of the most common artificial lift methods which is effectively utilized in the oil industry for enhancing production. However, proper gas allocation into wells can be challenging due to various limitations such as shortage in injected gas and economic considerations. Therefore, the current research is conducted to address the critical requirement to effectively distribute gas to maximize profits in the Halfaya Oil Field- Mishrif formation. Continuous gas lift is one of the most commonly used artificial lift methods. To enhance production rate, a sufficient amount of gas is injected into the production tubing at specific depths to reduce the liquid column pressure as each well has an optimal point for production in an oil reservoir. On the other hand, constraints of gas availability restrict achieving the optimal state of production. Such restrictions combined with economic limitations including high gas prices and compression costs, emphasized the necessity for optimal methodology to enhance oil production. Aside from the importance of the Halfaya oil field, there are limited relevant studies on artificial lifting methods specifically associated with the gas-lifting method used in this paper. Thus, the purpose of the current investigation is to propose a well-tested gas lifting design for oil production improvement. The approach combines the skill of the fmincon function built in MATLAB as an optimizer and the PIPESIM network model to create gas lift performance curves. This resulted in an oil production rate of 18860 STB/d, with a gas lift rate of 9.42 mmscf/d. Establishing such a systematic optimization process can manage the challenges of gas allocation in the Halfaya Oil Field towards maximizing production rates and ultimately increasing net profits.

Optimization of CO2 EOR and geological sequestration in high-water cut oil reservoirs

In terms of the collaborative optimization of CO2 flooding for Enhanced Oil Recovery (EOR) and CO2 sequestration, previous studies have co-optimized both cumulative oil production and CO2 sequestration by various algorithms. However, these solutions fail to optimize the CO2 injection schemes for high-water cut oil reservoirs. This paper presents an optimization methodology for CO2 flooding and sequestration in high-water cut oil reservoirs. The production optimization was carried out by adjusting the injection and production rate. To solve the proposed objective functions, the simultaneous perturbation stochastic approximation (SPSA) algorithm is applied in this paper, and the CMG-GEM module is utilized to simulate the reservoir production performance. A typical high-water cut reservoir in the Shengli oilfield was used to verify the feasibility of the presented methodology. In this paper, the production performance and net present value (NPV) for continuous gas injection under different water cuts were analyzed. The optimal timing of transforming from water flooding to gas displacement for the high-water cut reservoir was optimized. In addition, the optimal water–gas ratios for Water-Alternating-Gas (WAG) flooding were determined. The sensitivity of NPV to gas injection price and carbon subsidy was analyzed. The results show that when the gas price is 0.178 $/m3 and the carbon subsidy is 0.0169 $/m3, the optimal timing of transforming from water flooding to gas injection should be earlier than the time when the water cut is 0.82. Through the combination of NPV, cumulative oil production rate, and CO2 sequestration volume for WAG flooding, the optimal WAG ratio should be 1:2. The presented method in this paper considers various economic indicators and can optimize CO2 flooding and sequestration in high-water cut oil reservoirs efficiently, which can provide some guidance for the design of CO2 flooding schemes in high-water cut oil reservoirs.

Investigation of CO2-EOR and storage mechanism in Injection-Production coupling technology considering reservoir heterogeneity

Heterogeneous reservoirs offer greater potential for increased oil production and carbon storage capacity when using CO2 injection-production coupling technology in a broader range of geological formations. However, the impact of heterogeneity on the mechanisms and effectiveness of CO2 utilization and storage remains unclear. This study comprehensively investigates the mechanisms of enhanced oil recovery and the sequestration potential of CO2 injection-production coupling technology in heterogeneous reservoirs using both microscopic visualization experiments and macroscopic core experiments. The results reveal that during continuous gas flooding, CO2 forms rapid flow channels, leading to the formation of oil films and columnar residual oil in high-permeability zones, while small pores remain unaffected. Meanwhile, under high-speed injection conditions, the overall microscopic recovery rate increases by 13.8%. However, a higher proportion of porous residual oil is retained in low-permeability zones. During asynchronous injection-production cycles, the microscopic recovery rate remains above 86%, indicating a more thorough utilization of porous residual oil, which is predominantly present in membranous and angular corner configurations. The mechanisms of enhanced oil recovery include the increase in energy, dissolution expansion, and displacement-transport mechanisms. In asynchronous injection-production mode, macroscopic recovery rates are all above 80%. Additionally, with an increase in permeability contrast, the CO2 utilization efficiency rises from 5.9% to 8.6%, demonstrating the high potential of injection-production coupling technology for enhanced oil recovery and geological carbon sequestration in heterogeneous reservoirs. This study provides theoretical support for CO2 injection development and geological sequestration in heterogeneous reservoirs.

Overcoming equilibrium constraints in the reverse water gas shift with counter-current gas–solid flow and oxygen transport in La0.75Sr0.25Cr0.5Mn0.5O3-δ

Utilizing carbon dioxide in the reverse water gas shift (RWGS) reaction (CO2+H2→CO+H2O) is a potential pathway for mitigating CO2 emissions, as the resulting CO can be used to produce valuable products, such as chemicals and fuels. Here, we explore the implementation of the RWGS reaction by solid-oxide redox cycling in a two-reactor moving-bed process with counter-current gas–solid flow. We also develop a method for obtaining design diagrams from the thermodynamic data of the solid oxide utilized for redox cycling. Using this tool and screening the previous literature for relevant thermodynamic data, we identify the perovskite La0.75Sr0.25Mn0.5Cr0.5O3-δ as a highly promising candidate material, and we experimentally determine its non-stoichiometry under conditions relevant for the RWGS. The reaction kinetics are also obtained for its reduction in H2 and its reoxidation in CO2. We observe that the inward diffusion of oxygen into the perovskite grains during reoxidation in CO2 is likely to determine the minimum feasible temperature at which this process can be operated, and we estimate an effective diffusion coefficient of D = 7.7−1.4+1.8 *10−14 cm2 s−1 at T = 550 °C, with an activation energy of 122±4.4 kJ mol−1. Implementing the RWGS with this material in counter-current gas–solid flow is expected to significantly improve the RWGS process by decreasing the operating temperature, enabling continuous gas production, and increasing the gas conversion.

Particle removal from solid surfaces via an impinging gas jet pulse: Comparison between experimental and CFD-DEM modeling results

Computational and experimental studies are performed to investigate the influence of a gas jet pulse impinging perpendicularly onto a flat solid surface seeded with a monolayer of spherical particles. A numerical resuspension model is derived to predict particle release into the gas phase during jet impingement. To this end, discrete particles are immersed in a continuous gas phase modeled via Large Eddy Simulation to capture the effect of jet turbulence on the particle detachment process. Two-way coupling between particulate and gas phase is established via a near-wall particle drag model and a lift model. Direct particle–wall interactions are captured with adhesion, rolling friction and sliding friction models. To validate the overall modeling approach, numerical results are compared with resuspension experiments for monodisperse polystyrene particles placed on a glass slide. Simulations show that the particles preferentially mobilize by rolling, followed to a limited extend by lift off from the solid surface driven by aerodynamic forces and particle–particle collisions. Resuspension occurs in the first instants after jet impingement. Computational and experimental results for removal efficiency Γ are in good agreement in terms of the location of their r50 parameter, i.e., the radial position where 50% of the particles have been removed by the jet; both results show a linear dependence between the r50 value and the jet Reynolds number of the impinging jet. However, experimental Γ(r) curves generally have a smooth sigmoidal shape whereas numerical results predict a sharp transition. Some model shortcomings are identified which lead to an underprediction of particle lift-off and which explain the observed differences. Furthermore, the experimental Γ curves nearly collapse onto each other when plotted over the predicted local wall-shear stress.

Effect of Cr on the high-temperature corrosion of dissimilar AISI 904L and Inconel 625 joints employed in the coal-fired thermal power plant tubes

ABSTRACT The hot corrosion behaviours of 5-mm-thick plates of dissimilar AISI 904L and Inconel 625 weldments produced by continuous current gas tungsten arc welding process using Ni-Cr-Mo-enriched filler wires (ERNiCrMo-4 and ERNiCrCoMo-1) were investigated. Optical microscopy was used to examine the microstructure of these weldments. The corrosion performance of the weldments and base metals was determined in the mixture of K2SO4 + 60% NaCl molten salt (MS) and air oxidation conditions at 700°C for 50 cycles. The thermogravimetric plots derived the corrosion kinetics of the weldments. The microstructure and the elemental analysis of the scales formed on the corroded samples were evaluated by scanning electron microscopy and energy-dispersive spectroscopy. The phases developed on the oxide layers during the corrosion were analysed using X-ray diffraction. The fusion zones of ERNiCrCoMo-1 weldment and AISI 904L base metal were vulnerable to degradation in the MS environment, causing severe cracks and spallation compared to ERNiCrCoMo-1 weldment.

Ag@SnO2/CsPbBr3 nanocomposite gas sensor for well-behaved low-concentration ethanolamine sensing at room temperature

It is a novel-effective process for realizing high-efficiency sensing and continuous gas monitoring by introducing precious metals into metal–oxide–semiconductors (MOSs). In this study, Ag is exploited to prepare surface functionalized SnO2 nanoparticles (NPs) and innovative xAg@SnO2/CsPbBr3, activating and catalyzing the gas sensing reactions on semiconductors. The results show that the precious metal Ag NPs promote the directional transport of carriers, thus improving the gas sensing performances. In addition, innovative xAg@SnO2/CsPbBr3 composites originated from Ag@SnO2 NPs and 3-mercaptopropionic acid treated all-inorganic perovskite CsPbBr3 are constructed to further accelerate electron transfer on heterointerfaces, enabling continuous and efficient monitoring of ethanolamine (EA) at room temperature. The sensing properties of Ag@SnO2/CsPbBr3 on various volatile organic compounds are investigated. Compared with pure CsPbBr3, the EA response of as-prepared 2Ag@SnO2/CsPbBr3 is obviously improved by about sevenfold. The response/recovery time is greatly shortened, besides the good stability. Another interesting result for xAg@SnO2/CsPbBr3 is the lower limit of detection of 44.43 ppb. The work demonstrates that Ag modification facilitates the adsorption/desorption rate and the response. Furthermore, the catalytic activation of noble metal Ag NPs and the synergistic interaction of SnO2/CsPbBr3 nano-heterojunctions promote EA sensing performances at room temperature.

Experimental Study of the Dynamic Water–Gas Ratio of Water and Gas Flooding in Low-Permeability Reservoirs

WAG flooding is a dynamic process of continuous reservoir flow field reconstruction. The unique advantages of WAG flooding cannot be utilized, due to the fixed water–gas ratio. Therefore, we must investigate the dynamic adjustment of the water–gas ratio for WAG flooding. Using nine cases of long-core displacement experiments in low-permeability reservoirs, the development effects of three different displacement methods, namely, continuous gas flooding, WAG flooding with a fixed water–gas ratio, and WAG flooding with a dynamic water–gas ratio, were investigated after elastic development, water flooding, and gas flooding. This study shows that for early elastic development in low-permeability reservoirs, WAG flooding can significantly improve oil recovery, but WAG flooding with a dynamic water–gas ratio is not conducive to the control of the water cut rise and gas channeling. As a result, it is more suitable to adopt WAG flooding with a fixed water–gas ratio. For early water flooding in low-permeability reservoirs, WAG flooding more clearly improves oil recovery and suppresses gas channeling, but WAG flooding with a dynamic water–gas ratio exhibits a higher oil recovery and thus is recommended. For early gas flooding in low-permeability reservoirs, whether the development effect of WAG flooding can improve oil recovery and inhibit gas channeling strongly depends on whether the water–gas ratio is adjusted. The development effect of WAG flooding with a dynamic water–gas ratio is significantly better than that with a fixed water–gas ratio. Therefore, WAG flooding with a dynamic water–gas ratio is recommended to achieve the best displacement effect. This research has important practical significance for further improving the development effect of WAG flooding in low-permeability reservoirs.

Bubble Unidirectional Transportation on Multipath Aerophilic Surfaces by Adjusting the Surface Microstructure.

Comprehending and controlling the behavior of bubbles on solid surfaces is of significant importance in various fields including catalysis and drag reduction, both industrially and scientifically. Herein, Inspired by the superaerophilic properties of the lotus leaf surface, a series of asymmetrically patterned aerophilic surfaces were prepared by utilizing a facile mask-spraying method for directional transport of underwater bubbles. The ability of bubbles to undergo self-driven transportation in an asymmetric pattern is attributed to the natural tendency of bubbles to move toward regions with lower surface energy. In this work, the microstructure of the aerophilic surface is demonstrated as a critical element that influences the self-driven transport of bubbles toward regions of lower surface energy. The microstructure characteristic affects the energy barrier of forming a continuous gas film on the final regions. We classify three distinct bubble behaviors on the aerophilic surface, which align with three different underwater gas film evolution states: Model I, Model II, and Model III. Furthermore, utilizing the energy difference between the energy barrier that forms a continuous gas film and the gas-gas merging, gas-liquid microreaction in a specific destination on the multiple paths can be easily realized by preinjecting a bubble in the final region. This work provides a new view of the microevolutionary process for the diffusion, transport, and merging behavior of bubbles upon contact with an aerophilic pattern surface.

Numerical Simulation and Parameter Optimization for Water-to-CO2 Flooding in a Strongly Water-Sensitive Reservoir.

Carbon dioxide flooding can accelerate the development of low-permeability reservoirs of the Kexia group in the K region of the T oil field, thus resolving the issue of inadequate water drive effects. This study was focused on the well group 80513 in the K region, and based on the reservoir and fluid parameters, a simulation model of water-sensitive post-CO2 flooding was constructed to refine the gas injection strategy gradually. The injection rate of the continuous gas injection stage was preferred based on the degree of recovery. Multiindicator and multifactor injection and extraction schemes were established to optimize and analyze the key controlling factors, including the gas injection rate, gas injection period, gas-to-water ratio, and bottom-hole flow pressure, in the carbon dioxide gas-to-water alternation process. Recovery efficiency, oil exchange rate, formation pressure, and carbon dioxide storage rate were used as indicators. After 5 years of continuous CO2 flooding, the results indicated that switching to CO2 gas-water alternating flooding was more appropriate for the target block's environment. The best development plan was achieved when the gas injection rates were 1.0 and 1.25 × 104 m3·d-1 for continuous gas injection and CO2 gas-water alternating flooding, respectively, with a gas-water ratio of 1:1, a gas injection cycle of 90 days, and a bottom-hole flow pressure of 25 MPa in the production wells. A comparison between the results revealed that the formation pressure and oil recovery efficiency of this well group significantly increased upon CO2 flooding, and the parameter optimization results were well suited for controlling the gas flurry, offering a versatile model for future development of the block.

Hydrate-based technique for natural gas processing: Experimental study of pressure-dropping and continuous modes

Gas hydrate crystallization is perspective and energy-efficient technology for gas mixtures processing, including natural gas. There were compared pressure-dropping and continuous gas hydrate crystallization methods for separation of gas mixture closed to natural gas. The studied mixture has been chosen similar to the natural gas composition: CH4 (75.68 mol.%) - С2H6 (7.41 mol.%) - C3H8 (4.53 mol.%) - н-C4H10 (2.47 mol.%) - CO2 (5.40 mol.%) - H2S (1.39 mol.%) - N2 (3.01 mol.%) - Xe (0.11 mol.%). Experiments were provided in the 4 L high pressure reactor, using water solution of SDS (0.20 wt.%). The experiment conditions were 280.15 K and pressure of 4.25 MPa. The components separation factors and recovery for two modes have been researched and compared for choosing more effective options. After comparing these characteristics, it was concluded that continuous process is more productive than pressure-dropping mode. At the stage cut (θ) of 0.9, the gas components total recovery (R) for the continuous mode have exceeded the total recovery for the pressure-dropping mode by 8.15 %, and at θ = 0.8, exceeded by 6.11 %. The recovery and separation factors have the highest values for H2S, C3H8, Xe in the continuous mode: 97.62 %, 94.90 %, 84.98 % and 8.7, 10.53, 6.36, respectively. Thus, the choosing of the more effective stage cut depends on the aim of the process: the highest purity or the largest recovery.

A Comparative on the Effects of Thoracic Squeeze Technique Versus Manual Diaphragm Release Technique on Sputum Clearance among Patient with Chronic Obstructive Pulmonary Disease

Background: The COPD, a prevalent and manageable condition, leads to diminished airflow and tissue damage.It is associated with structural lung problems caused by prolonged inflammation due to continuous exposure toharmful particles or gases, particularly from cigarette smoke.Purpose: To compare the effectiveness of thoracic squeeze technique and manual diaphragm release technique onsputum clearance among patient with COPD.Materials and Methods: A total of 30 participants were selected according to inclusion and exclusion criteriawere deliberately sampled. Group A (n=15) received thoracic squeeze technique and the Group B (n=15) receivedmanual diaphragm release technique. All individuals were assessed for COPD assessment test as a pre-test priorto the intervention and again after 6 weeks of intervention. The entire process was performed from November2022 to April 2023.Result: Statistical analysis was done for all the collected data using paired t- tests. The test shows significant effects (p<0.0001)in both groups. The test shows that the subjects receiving thoracic squeeze technique have improved sputum clearance amongpatients with COPD.Conclusion: The results and the data obtained from this research was statistically significant and concludedthat there was a definite and positive effect of thoracic squeeze technique on sputum clearance. This can berecommended in Pulmonary Physiotherapy Practise.

Continuous Flow System for Highly Efficient and Durable Photocatalytic Oxidative Coupling of Methane.

Photocatalytic oxidative coupling of methane (OCM) into value-added industrial chemicals offers an appealing green technique for achieving sustainable development, whereas it encounters double bottlenecks in relatively low methane conversion rate and severe overoxidation. Herein, we engineer a continuous gas flow system to achieve efficient photocatalytic OCM while suppressing overoxidation by synergizing the moderate active oxygen species, surface plasmon-mediated polarization, and multipoint gas intake flow reactor. Particularly, a remarkable CH4 conversion rate of 218.2 μmol h-1 with an excellent selectivity of ∼90% toward C2+ hydrocarbons and a remarkable stability over 240 h is achieved over a designed Au/TiO2 photocatalyst in our continuous gas flow system with a homemade three-dimensional (3D) printed flow reactor. This work provides an informative concept to engineer a high-performance flow system for photocatalytic OCM by synergizing the design of the reactor and photocatalyst to synchronously regulate the mass transfer, activation of reactants, and inhibition of overoxidation.

A TEMPERATURE PRE-RECTIFIER WITH CONTINUOUS HEAT STORAGE AND RELEASE FOR WASTE HEAT RECOVERY FROM PERIODIC FLUE GAS

Flue gas from periodic furnaces with large temperature fluctuation is difficult to be recovered by regular heat exchangers. To recover that unstable waste heat, a temperature pre-rectifier (TPR) with honeycombed structure is developed to smooth down the temperature fluctuation by continuous heat storing and heat releasing. A three-dimensional model of TPR is constructed to analyze the heat transfer process. Temperature rectification rate η is defined to quantify the smoothing-down effect of TPR on temperature fluctuation. The relative size <i>s</i>* as the ratio of hole size to inner wall thickness (i.e., <i>s</i>* = <i>s/δ</i>), can be used to measure the capacity of heat release compared to that of heat storage. The quantity η reaches the highest value when the relative size <i>s</i>* is 1.0, and is increased with dimensionless length <i>l</i>*. When <i>s</i>* = 1.0, η firstly rises and then drops with the increment of <i>s</i>. The peak value of η can be achieved by an optimized hole size <i>s</i><sub>opt</sub>. The <i>s</i><sub>opt</sub> value increases exponentially with the inlet temperature fluctuation intensity. The TPR with segmented structure can enhance n with relatively short length. The three-segment structure with a proportion of 0.18:0.33:0.49 makes η > 0.947, which is recommended for application. Industrial experiments showed that the temperature fluctuation of flue gas can be rectified from 568-1709 K to 1089-1174 K (η = 0.926) by TPR, which verified that the TPR is an effective method for waste heat recovery from periodic flue gas.

A simulation study of CO<sub>2</sub> gas adsorption with bottom ash adsorbent from palm oil mill waste using computational fluid dynamic (CFD)

<abstract> <p>Biogas is a cost-effective, efficient, environmentally friendly, and renewable alternative energy source. While biogas contains CH<sub>4</sub>, it also contains impurities in the form of 27–45% CO<sub>2</sub> gas. Therefore, it is necessary to purify biogas by removing CO<sub>2</sub> gas as it can reduce the calorific value of CH<sub>4</sub>, the main component of biogas. The process of methane purification can be achieved through adsorption. Bottom ash, derived from palm oil mill waste, shows great potential for methane purification by effectively adsorbing CO<sub>2</sub>. This research simulated the methane purification process using the computational fluid dynamics (CFD) method with the student version of the ANSYS R20 software. The study utilized an adsorbent made from bottom ash obtained from palm oil mill waste. The main objective was to investigate the performance of bottom ash as an adsorbent for removing CO<sub>2</sub> gas in a continuous gas flow within an adsorption column. The study involved varying the column bed height (4 cm, 8 cm, 12 cm) and gas flow rate (10 L/min, 15 L/min, 20 L/min). The results showed that the highest efficiency in removing CO<sub>2</sub> gas was 84.53% with a bed height of 12 cm and a flow rate of 10 L/min, while the lowest efficiency was 47.87% with a bed height of 4 cm and a flow rate of 20 L/min. Furthermore, the highest adsorption capacity for CO<sub>2</sub> gas was 1.64 mg/g with a bed height of 12 cm and a flow rate of 10 L/min, while the lowest capacity was 0.93 mg/g with a bed height of 4 cm and a flow rate of 20 L/min. The linearization of adsorption isotherm data indicated that the CO<sub>2</sub> gas adsorption process using bottom ash adsorbent followed the Langmuir model.</p> </abstract>

Electrical Power Management by Flexible Operation of a Continuous Gas Export Plant

Electrical Power Management by Flexible Operation of a Continuous Gas Export Plant