Carbon Content Research Articles

Core-shell structured LiFePO4/C nanocomposite battery material for lithium production from brines

The development of affordable and environmentally friendly methods to produce lithium is urgently required to cope with the accelerating growth of the lithium battery market. Battery materials such as LiFePO4 can be used to selectively sequestrate lithium from brine natural resources, thus producing a high-purity lithium salt for battery manufacture, but the long-term stability of the material is currently not sufficient for practical applications. Here, we report, for the first time, the development of a nanosized core-shell structured LiFePO4/C material for applications in lithium production from brines. This LiFePO4/C with a LiFePO4-core (∼123 nm size) covered by a pinhole-free carbon shell (∼5 nm thickness) was prepared via solvothermal synthesis, and the carbon content was optimised to 5 wt%. The optimal core-shell structured LiFePO4/C material exhibits a lithium extraction capacity of ca. 160 mA h g-1 at C/10 and ca. 130 mA h g-1 at 1C, and >87% capacity retention after 50 cycles of lithium sequestration and release at C/10 in synthetic brines. This excellent electrochemical performance is attributed to the homogenous nanosizing of the LiFePO4 particles as well as the full coverage of the carbon coating, which provides effective protection by preventing the direct contact of LiFePO4 with the brines, thus stopping the surface degradation reactions that compromise the long-term stability. A direct comparison with three commercial LiFePO4 materials demonstrates that, while similar performance is obtained in non-aqueous lithium-ion batteries, for lithium production applications, core-shell nanostructuring is crucial to achieve high capacity and preserve the material's longevity.

Core-shell structured LiFePO4/C nanocomposite battery material for lithium production from brines

The development of affordable and environmentally friendly methods to produce lithium is urgently required to cope with the accelerating growth of the lithium battery market. Battery materials such as LiFePO4 can be used to selectively sequestrate lithium from brine natural resources, thus producing a high-purity lithium salt for battery manufacture, but the long-term stability of the material is currently not sufficient for practical applications. Here, we report, for the first time, the development of a nanosized core-shell structured LiFePO4/C material for applications in lithium production from brines. This LiFePO4/C with a LiFePO4-core (∼123 nm size) covered by a pinhole-free carbon shell (∼5 nm thickness) was prepared via solvothermal synthesis, and the carbon content was optimised to 5 wt%. The optimal core-shell structured LiFePO4/C material exhibits a lithium extraction capacity of ca. 160 mA h g-1 at C/10 and ca. 130 mA h g-1 at 1C, and >87% capacity retention after 50 cycles of lithium sequestration and release at C/10 in synthetic brines. This excellent electrochemical performance is attributed to the homogenous nanosizing of the LiFePO4 particles as well as the full coverage of the carbon coating, which provides effective protection by preventing the direct contact of LiFePO4 with the brines, thus stopping the surface degradation reactions that compromise the long-term stability. A direct comparison with three commercial LiFePO4 materials demonstrates that, while similar performance is obtained in non-aqueous lithium-ion batteries, for lithium production applications, core-shell nanostructuring is crucial to achieve high capacity and preserve the material's longevity.

Unlocking the geochemical features of the Paleocene southern Pacific Ocean using carbon isotopes and biolipids

Little is known about the Paleocene in the southern Pacific Ocean due to scarce marine records. Here, we present a systematic geochemical investigation using biomarkers, carbonate content, and carbon isotopes of a set of early Paleocene deep-sea cores from International Ocean Discovery Program Expedition 378 Site U1553. The results provide a new Paleocene biomarker profile for the Campbell Plateau, New Zealand. The occurrence and distribution of a series of hopenes, ββ hopanes, sterenes and biomarker-based maturity parameters indicate that these organically-lean sediments are in an early diagenetic stage, with an equivalent vitrinite reflectance of approximately 0.4%. Biomarker data (e.g., gammacerane index and homohopane index), carbonate carbon isotopes (−27.9 ‰ to +2.0 ‰) combined with onboard data (sulphur and methane contents) indicate that the redox properties of the Paleocene southern Pacific Ocean changed from an oxidising-anoxic transition zone to a more reducing marine environment (water depth > 1000 m). The sources of the organic matter are diverse, including algae, bacteria, diatoms, dinoflagellates, and higher plants, but are dominated by aquatic organisms. Our new biomarker record bridges a Paleocene biosphere knowledge gap in the high latitude South Pacific.

LAMININ 332 FUNCTIONALIZED SURFACE IMPROVE IMPLANT ROUGHNESS AND ORAL KERATINOCYTE BIOACTIVITY

ObjectiveThe biological seal (BS) at the implant-tissue interface is essential for the success of dental implants (DIs), and the absence of a proper BS can lead to peri-implantitis. The basement membrane (BM) and junctional epithelium are critical for sealing the peri-implant mucosa, and laminin 332 is an important protein in binding the epithelium to the implant surface. The aim of this study was to evaluate the response of oral keratinocytes to titanium dental implant surfaces biofunctionalized with laminin 332. DesignThe dental implant surface was treated with a piranha solution to create hydroxyl (OH) groups, facilitating biofunctionalization with laminin 332. The modified surface underwent scanning electron microscopy, surface roughness evaluation, and chemical composition analysis. Human keratinocytes from the Cal-27 line were then cultured on the modified implants for 24 and 48 hours to assess viability, morphology, cytokine secretion, and mRNA expression of tissue repair-associated genes. ResultsThe results showed that laminin 332 biofunctionalisation of the implant surface resulted in lower values of Ra, Rq and positive surface roughness parameters Rsk, Rku and Rv. The elemental composition showed an increase in nitrogen and carbon content corresponding to protein binding. The biofunctionalized surfaces did not affect cell viability and promoted cytokine secretion (IL-1a and IL-8) and a significant increase (p <0.05) in MCP-1, EGF, FGF, TGF and VEGF gene expression compared to the control. ConclusionIn conclusion, laminin 332 coating Ti implants was shown to be effective in promoting keratinocyte adhesion, spreading, and viability. This approach could be an alternative way to improve biocompatibility.

Spatial heterogeneity, sediment-water exchange, and diffusion mechanisms of organophosphate esters from river to coastal aquatic system in a typical economic circle of northern China

Organophosphate esters (OPEs) have proven to be pervasive in aquatic environments globally. However, understanding their partitioning behavior and mechanisms at the sediment-water interface remains limited. This study elucidated the spatial heterogeneity, interfacial exchange, and diffusion mechanisms of 14 OPEs (∑14OPEs) from river to coastal aquatic system. The transport tendencies of OPEs at the sediment-water interface were quantitatively assessed using fugacity methods. The total ∑14OPEs concentrations in water and sediments ranged from 154 ng/L to 528 ng/L and 2.41 ng/g dry weight (dw) to 230 ng/g dw, respectively. This result indicated a descending spatial tendency with moderate variability. OPE distribution was primarily influenced by temperature, pH, and dissolved oxygen levels. As the carbon atom number increased, alkyl and chlorinated OPEs transitioned from diffusion towards the aqueous phase to equilibrium. In contrast, aryl OPEs and triphenylphosphine oxide, which had equivalent carbon atom counts, maintained equilibrium throughout. Diffusion trends of individual OPE congener at the sediment-water interface varied at the same total organic carbon contents (foc). As the foc increased, the fugacity fraction values for all OPE homologs showed a declining trend. The distinct molecular structure of each OPE monomer might lead to unique diffusive behaviors at the sediment-water interface. Higher soot carbon content had a more pronounced effect on the distribution patterns of OPEs. The sediment-water distribution of OPEs was primarily influenced by total organic carbon, sediment particle size, dry density, and moisture content. OPEs displayed the highest sensitivity to fluctuations in ammonium and dissolved organic carbon. This study holds significant scientific and theoretical implications for elucidating the interfacial transport and driving forces of OPEs and comprehending their fate and endogenous release in aquatic ecosystems.

Air pollution exposure and mortality from neurodegenerative diseases in the Netherlands: A population-based cohort study

BackgroundLong-term exposure to ambient air pollution has been linked with all-cause mortality and cardiovascular and respiratory diseases. Suggestive associations between ambient air pollutants and neurodegeneration have also been reported, but due to the small effect and relatively rare outcomes evidence is yet inconclusive. Our aim was to investigate the associations between long-term air pollution exposure and mortality from neurodegenerative diseases. MethodsA Dutch national cohort of 10.8 million adults aged ≥30 years was followed from 2013 until 2019. Annual average concentrations of air pollutants (ultra-fine particles (UFP), nitrogen dioxide (NO2), fine particles (PM2.5 and PM10) and elemental carbon (EC)) were estimated at the home address at baseline, using land-use regression models. The outcome variables were mortality due to amyotrophic lateral sclerosis (ALS), Parkinson's disease, non-vascular dementia, Alzheimer's disease, and multiple sclerosis (MS). Hazard ratios (HR) were estimated using Cox models, adjusting for individual and area-level socio-economic status covariates. ResultsWe had a follow-up of 71 million person-years. The adjusted HRs for non-vascular dementia were significantly increased for NO2 (1.03; 95% confidence interval (CI) 1.02–1.05) and PM2.5 (1.02; 95%CI 1.01–1.03) per interquartile range (IQR; 6.52 and 1.47 μg/m3, respectively). The association with PM2.5 was also positive for ALS (1.02; 95%CI 0.97–1.07). These associations remained positive in sensitivity analyses and two-pollutant models. UFP was not associated with any outcome. No association with air pollution was found for Parkinson's disease and MS. Inverse associations were found for Alzheimer's disease. ConclusionOur findings, using a cohort of more than 10 million people, provide further support for associations between long-term exposure to air pollutants (PM2.5 and particularly NO2) and mortality of non-vascular dementia. No associations were found for Parkinson and MS and an inverse association was observed for Alzheimer's disease.

PBAT microplastics exacerbates N2O emissions from tropical latosols mainly via stimulating denitrification

Biodegradable plastic mulching films are regarded as promising substitutes for their non-degradable counterparts to ameliorate serious plastic pollution in agriculture. Inevitably, biodegradable microplastics (BMs) can be formed and profoundly affect the function of soil ecosystems. However, little is known about the effects of BMs loading on soil nitrogen (N) dynamics and loss in tropical agricultural soils. Hereby, a 120-day soil incubation trial was performed to evaluate the effects of polybutylene adipate co-terephthalate (PBAT) microplastics on nitrous oxide (N2O) emissions, N transformation, and bacterial community structure in latosols. The results showed that PBAT addition raised soil ammonium nitrogen (NH4+–N) and dissolved organic carbon (DOC) contents, but lowered nitrate nitrogen (NO3––N) contents, accompanied with a smaller potential nitrification rate and a greater potential denitrification rate. The microbial biomass nitrogen and nrfA gene abundance were increased by PBAT, suggesting the processes of microbial N immobilization and dissimilatory nitrate reduction to ammonia were largely promoted. Positive correlations existed between N2O emissions and denitrification-related enzymatic activities and functional gene abundances (narG, nirK/S and Fungal nirK). PBAT amendment stimulated N2O emissions by 54.8 − 317.3 %, accompanied with increased values of those denitrification-related parameters, suggesting that stimulated denitrification was responsible for the exacerbated N2O emissions. Moreover, PBAT addition changed bacterial alpha diversity and bacterial community composition, where the relative abundances of Proteobacteria increased while those of Nitrospirae and Acidobacteria decreased. These findings are beneficial to understanding the fate of N in microplastics-polluted soil, which will provide a new insight into the impact of BMs on soil functions and environmental risks.

Lipid biomarkers and stable isotopes uncover paleovegetation changes in extremely species-rich forest-steppe ecosystems, Central Europe

The historical development of the vegetation of semi-dry grasslands in Central Europe is not satisfactorily understood. Long-term continuity of open vegetation or, conversely, deep-past forest phases are considered possible sources of the current extreme species diversity of these ecosystems. We aimed to reveal the trajectory of paleovegetation development in these ecosystems through detailed analysis of terrestrial in-situ soil geoarchives. We measured the bulk soil carbon and nitrogen contents, lipid molecular distribution, and compound-specific stable carbon and hydrogen isotopic signatures of mid- and long-chain n-alkanes extracted from soil and modern plant material tissues (i.e., deciduous and Pinus leaves and grass/herbaceous species).The C23-C33 n-alkane homologues were identified in soils with different abundances. Normally, C27 and C29 n-alkanes were the most abundant homologues in tree-leaf samples, while grass-derived n-alkanes were mostly C31 and C33 homologues. Soils were largely dominated by C29 and C31 n-alkanes. Odd-numbered C27-C33 soil n-alkane δ13C values ranged from -36.2‰ to -23.2‰, whereas their δ2H values showed a wider range of variability that fluctuated from -224‰ to -172‰. Molecular distribution in combination with radiocarbon analysis of soil organic matter (SOM) and δ13C and δ2H values of n-alkanes revealed a large contribution of C3 trees (both deciduous and coniferous trees/pine trees) as the main source of n-alkanes between the late Pleistocene and early Holocene (ca 15,000–8,200 calibrated year before present/cal year BP). A clear shift toward more grassy/herbaceous vegetation was observed from the early Holocene (ca 11,700–8,200 cal year BP) onwards. Distribution patterns of lipids and soil geochemical parameters showed that plants are the main source of SOM and that biodegradation and kinetic isotope fractionation are not the main reasons for 13C enrichment in soil profiles. Past C3 vegetation shifts as well as paleoclimate changes (i.e., aridity) can have played a role in the observed 13C depth profiles.

Sedimentological and geochemical characteristics of Lower Cambrian Qiongzhusi shale in the Sichuan Basin and its periphery, SW China: Implications for differences in organic matter enrichment

Few studies have systematically investigated the factors controlling organic matter enrichment in shales from the Qiongzhusi Formation, within and surrounding the Sichuan Basin, under different depositional environments. This has resulted in different academic understandings and limited clarity on the mechanisms of organic matter enrichment. On this premise, in this study, the basic geological characteristics and depositional paleoenvironments of shales along the passive continental margin, the western Hubei Trough, and the western Sichuan Trough were compared and analyzed using core, outcrop, and mineral testing. Furthermore, data from organic geochemical and elemental analyses were utilized to investigate the different enrichment mechanisms and formation modes of the organic matter in different periods. The results reveal that the organic matter enrichment in this region should be mainly influenced by the preservation conditions, paleo-productivity, and terrigenous input. However, there were clear differences in the main controlling factors in the different periods. In the Q1 phase, the region had a high sea level, had the strongest rifting, had the largest accommodation space, and exhibited characteristics of low terrestrial input and bottom water hypoxia. The changes in the paleo-productivity caused by upwelling currents were the main factors controlling the variations in the organic matter enrichment. In the Q2 phase, the weakened decreasing sea level co-occurred with a reduction in the accommodation space across the region. The organic matter enrichment was significantly controlled by the paleo-productivity, preservation conditions, and terrigenous inputs, and the organic matter enrichment conditions deteriorated from the passive continental margin to the western Hubei Trough and western Sichuan Trough. The total organic carbon (TOC) content of the shale decreased significantly. In the Q3 phase, the entire region entered an infilling stage, which was dominated by an oxygen-rich environment, and the preservation conditions were the decisive factor controlling the organic matter enrichment. The TOC content was low overall, and there were no evident differences across the different zones.

Litterfall Carbon and Nitrogen Content of Beech Forests in Serbia

This study aimed to analyze the N storage capacity of litterfall and its impact on C mineralization in beech forests. The research was conducted at 15 sample plots under European beech stands located in different ecological conditions on the territory of Serbia. More than half (53%) of the sample plots are characterized by low and very low litterfall N content (&lt;8 g·kg−1; 9–12 g·kg−1), and a wide C/N ratio, which indicates a slow decomposition of the organic soil layer. These results could be useful indicators of the capacity and dynamics of litterfall N storage and its impact on C mineralization in the context of preserving biodiversity, stability, and longevity of beech forests in Serbia.

Impact of fire exclusion and aspect on soil carbon fractions in Afromontane grasslands, Cathedral Peak, South Africa

AbstractDespite the importance of South Africa's Afromontane grasslands for ecosystem services (water supply and biodiversity), soil organic carbon (SOC) research remains limited. These grasslands evolved with fire, and fire exclusion leads to native plant afforestation. This study investigated SOC fractions and origin to understand the impact of fire‐exclusion‐driven afforestation and aspect on SOC storage in Afromontane grasslands. This study in Cathedral Peak Research Catchments, initiated in the 1940s, compared an afforested fire‐excluded site (AF) to a periodically burnt (accidental fires, 2–5 years interval) grassland (PB) within the same catchment (Catchment‐IX). Additionally, it compared a south‐facing periodically burnt grassland (Catchment‐IX) to a north‐facing biennially burnt grassland (Catchment‐VI). Soil samples collected at soil‐depth increments (0–5, 5–10, 10–15, 15–20, 20–30, 30–60 and 60–100 cm) revealed that, within Catchment IX, PB had more topsoil SOC stocks and microbial activity than AF but similar active carbon (C) concentrations. As expected, δ13C values revealed that SOC in PB originates from C4 grasses, whilst it mostly originates from C3 plants in AF. The south‐facing slope (Catchment‐IX) had more SOC stocks, microbial activity and active C compared to the north‐facing slope (Catchment‐VI). Fire‐exclusion‐driven afforestation changed SOC input from roots to litter, thus reducing SOC storage. Cooler south‐facing slopes are better C reservoirs. Afromontane grasslands show greater potential for C sequestration than afforested systems.

Impact of varying dissolved organic carbon load on sediment phosphorus release and its periodic mechanisms

Phosphorus (P) release from sediment poses a severe challenge for eutrophication management in the aquatic environment. The dissolved organic carbon (DOC) concentrations in riverine ecosystems have shown an increasing trend due to intensified climate change and anthropogenic activities, while their impact on sediment P cycling remains unclear. To investigate the effects of different DOC loads on sediment P release and the underlying mechanisms, we conducted a two-month experiment in 15 plexiglass tanks, with five gradient-increasing target DOC concentrations set according to reality: control (S0), 5 mg/L (S5), 10 mg/L (S10), 15 mg/L (S15), and 20 mg/L (S20). The results demonstrated that: i) DOC enrichment promoted the sediment P mobilization and release, with the underlying mechanisms exhibited periodic characteristics. ii) reduced dissolved oxygen (DO) concentration and stimulated alkaline phosphatase activity (APA) were likely the primary and sustained facilitating mechanisms. While after the termination of DOC load, elevated pH level was also considered a contributing factor when chlorophyll a (Chl a) ranged between 5.9 μg/L and 7.7 μg/L iii) ultimate concentration of total P (TP) in the overlying water depended on DOC load. After DOC addition was terminated, decreased TP concentrations were observed when DOC concentration was in the range of 5–15 mg/L, which may be attributed to the direct uptake of P by phytoplankton counteracting the minor promotion of P release induced by anoxic conditions. However, when DOC concentrations exceeded 15–20 mg/L, there were notable increments in TP concentrations. Our findings provide further insight into the response mechanisms of sediment P release to the increasing organic C load in natural ecosystems. The impact of broader C forms or C loads on sediment P cycling needs to be fully elucidated and even quantified in future studies, especially through large-scale field investigations to further clarify the coupled roles between C and P.

Characteristics and source apportionment of black carbon the urban and desert underlying surfaces

The spatial distribution of black carbon (BC) concentrations was highly variable across different underlying surfaces. Differences in meteorological conditions and emission sources led to great temporal and spatial variations in BC characteristics. As the most important absorbing aerosol, BC can affect radiation, clouds, and surface snow. BC mass concentrations were measured using a seven channel aethalometer (AE-33) in the Urumqi and Taklimakan Deserts from January to December 2022.The aethalometer data, potential source contribution function (PSCF), and concentration-weighted trajectory (CWT) models were used to analyse the variation characteristics, potential sources, and affected areas. Results showed that the BC concentrations in the Taklamakan Desert and Urumqi were in the range of 0–500 ng·m−3, accounting for 66.20 % and 59.50 % of the total, respectively. The backward trajectory simulation of BC mass concentration in the tower and Urumqi using the HYSPLIT model found that the airflow trajectories in the tower in summer corresponded to the BC concentration in the following order: trajectory 4 > trajectory 3 > trajectory 2 > trajectory 1, and trajectory 4 originated from the Turpan airflow accounting for 46.19 % of the total, which corresponded to the highest BC concentration of 621.73 ng·m−3. The trajectories of the airflow in Urumqi in summer corresponded to the BC concentration in the order of high to low, and the BC concentration in summer corresponded to the highest concentration in the Turpan airflow. BC concentrations arranged from high to low were trajectory 1 > trajectory 5 > trajectory 3 > trajectory 4 > trajectory 2. Trajectories 3, 4, and 5 airflow directions were the same, and the airflow trajectory accounted for 47.48 %, corresponding to BC concentrations of 599.82 ng·m−3, 579.99 ng·m−3, and 555.85 ng·m−3, respectively. Tower in the spring compared with other seasons of the CWT value of >400 ng·m−3 had the widest coverage, and Urumqi had more source areas contributing to moderate pollution concentration weights in winter (400 ng·m−3 < CWT < 800 ng·m−3). The conclusions of this study provide a scientific basis for regional environmental management and the formulation of air pollution measures in Xinjiang.

Hybrid nanocomposites of Fe3O4/SiO2-EDTA: Holistic comparison of one-step and two-step modification methods

Fe3O4/SiO2-EDTA materials have been used for diverse applications and they have been modification by different methods, but a comparison is lacking between their physicochemical characteristics. This work aimed to compare the physicochemical characteristics of the Fe3O4/SiO2-EDTA nanocomposite obtained by four methods, whose modification of the Fe3O4 surface with SiO2-EDTA occurs in one or two steps, with not hazardous chemicals. In the one-step methods (M1 and M2), Fe3O4 particles were coated and functionalized in consecutive steps (by sonication in M1 and mechanical stirring in M2). In the two-step methods (M3 and M4), the Fe3O4 particles were primarily coated with silica and then functionalized with TMS-EDTA (by sonication in M3 and mechanical stirring in M4). The Fe3O4/SiO2-EDTA nanocomposites were characterized by XRD, TEM, EDX, BET, SQUID magnetometry, FTIR, XPS, and zeta potential. The TEM highlighted that the nanocomposites from methods M1 and M2 there is the simultaneous presence of magnetite particles coated and uncoated with silica, while those from M3 and M4 were totally coated, besides the nanocomposites from M2 and M3 showed to be more aggregated than those from the other methods. The presence of EDTA on the surface of the nanocomposites was evidenced by the carboxyl groups in the FTIR spectra and by the nitrogen in the XPS spectra. The nanocomposites from M3 and M4 presented a higher content of nitrogen than those from M1 and M2, and those from M4 also presented a higher content of carbon than those from M3. Overall, the Fe3O4/SiO2-EDTA nanocomposites from two-step methods showed better SiO2 coating and EDTA functionalization than those from one-step methods, and those from M4 presented the best physicochemical characteristics, being this method recommended for their modification for future applications.

Vegetation composition and organic carbon content along right-of-ways on Interstate Highway 35 in Bexar County, Texas

Roadside habitat through major urban areas may offer remnant examples of natural grasslands. These habitats may be subjected to frequent as mowing and exposure to automobile emissions and runoff. This study was conducted on interstate highway right-of-ways in San Antonio, Texas, U.S.A. We compared the vegetation species and diversity, and the organic carbon of leaf litter, plants, and soils. Two non-native grasses accounted for 50.9% cover, while all native forbs and grasses accounted for only 9.8% cover. The mean biomass of non-native grasses was 4.5 times greater than that of all native species. Organic carbon content of leaf litter, plants, and soils was variable among the study sites, possibly due to management practices and a drought that occurred during the study. The mean organic carbon content in the upper 20 cm soil was 5.0 kg·C/m2 and organic carbon content was greater in the upper 10 cm than organic carbon in the 10.1 to 20 cm portion. Cynodon dactylon and Bouteloua curtipendula exhibited the greatest photosynthesis efficiency indicating these grasses are more adaptable to hot summer temperatures found in Central Texas. The organic carbon content along a major interstate was 13793 kg·C/ha for leaf litter, vegetation, and the upper 20 cm of the soil. We conclude that interstate highways provide habitat for some native species, but the vegetation along right-of-ways is dominated by two non-native grasses. It appears unlikely that roadside habitat can be restored to resemble native grasslands without large scale and costly restoration efforts.

Dissolve organic matter of mature chicken compost contributes to the protection of microorganisms from the stress of heavy metals

Dissolved organic matter (DOM), as the most active component of manure and compost, can influence heavy metal forms and microbial community structure by changing the physicochemical properties of soils. This study employed DOM extracted from fresh chicken manure (FDOM) and mature compost (MDOM) and evaluated their impacts on the physicochemical properties, heavy metal forms, and microbial communities of chernozem and dark brown soil through UV-Vis, EEM-PARAFAC, and high-throughput sequencing. The results showed that all DOM treatments decreased soil pH except for the MDOM at 150mgC/kg applied to chernozem (CLM). MDOM treatments were more favorable in increasing soil available phosphorus content and the degree of humification of soil DOM, and FDOM treatments were more favorable in increasing soil dissolved organic carbon content and decreasing the degree of humification of soil DOM. Except for CLM treatment, the other DOM treatments decreased the content of stable state Pb, increased the risk of Pb migration and biotoxicity, and FDOM treatments were more pronounced. In addition, DOM treatments decreased the Shannon diversity of two soils and the Chao1 index in chernozem. However, DOM at 300mgC/kg could increase the abundance of soil eutrophic and heavy metals tolerant dominant phyla (Proteobacteria and Bacteroidota) as well as dominant genera (Sphingomonas, Lysobacter, and Arthrobacter). This study provides a comprehensive understanding of the risk of manure and compost application in heavy metals-polluted soils and its interaction with microorganisms.

Microwave pyrolysis-prepared engineering carbons from corn cobs and red mombin seeds towards xylene adsorption

High-quality biochars/activated carbons were prepared, optimizing individual parameters of energetically-save microwave pyrolysis (raw material loading - 20 vs. 60g, nitrogen atmosphere - flow vs. batch, ZnCl2 activation) from two agricultural wastes - corn cobs, red mombin seeds. Most promising carbons were examined for gaseous xylene adsorption and showed higher sorption capacity (∼250-475 mgxylene· g-1) than commercial carbon (∼214 mgxylene· g-1). ZnCl2 activation of both raw materials reduces the fixed carbon content and increases volatiles in activated carbon, suggesting microwave pyrolysis of activated feedstock should take 25min. While biochars are microporous materials with inhomogeneous low-surface mesopore/macropore network, activated carbons are highly microporous-mesoporous. ZnCl2 activation of both raw materials contributes to formation of extensive high-surface mesopore network (with pore-size < 20nm) and enlargement of micropore-size, but does not affect the micropore volume. ZnCl2 activation increases H2 and decreases CH4 production. Microwave pyrolysis of larger raw material loading with ZnCl2 leads to CO2 increase. Best xylene adsorption capacity (475 mgxylene· g-1) was determined for activated carbon produced from 60g loading of corn cobs in batch nitrogen atmosphere, showing the largest micropore volume, lowest surface polarity and medium rate of graphitization. Large micropore volume, low surface polarity and high rate of graphitization of carbon are xylene sorption capacity-determining factors.

Soil organic carbon fractions and storage potential in Finnish arable soils

AbstractUnderstanding the factors affecting the total amount and distribution of soil organic carbon (OC) across different functional carbon pools is important to better define the future management of soil OC stocks. The interactions between soil management practices, local physicochemical soil properties and climate are essential for determining the OC content of the soil. Nevertheless, how these factors affect the total amount of OC and its distribution across carbon pools, i.e., more labile particulate (POC) and more stable mineral‐associated (MAOC) organic carbon, is only partly known. In this study, we assessed topsoil (0–20 cm) samples from 93 arable farms in the southern half of Finland to determine the total amount of OC, and its distribution in MAOC and POC, along with relevant soil properties (amount of clay and silt, aluminium and iron oxides and pH), climate (precipitation and temperature) and fertilization (mineral versus organic). The fertilization did not affect the total soil carbon content (12–58 g OC kg−1 soil). The share of OC in the MAOC fraction (on average 86% of total OC) was relatively stable across the large range of OC contents and clay contents (2%–68%). We assessed the highest feasible MAOC of the soils with boundary line analyses and their OC saturation state with Hassink's equation (Hassink, 1997). Only soils with the lowest clay content (&lt;10% clay) were assumed to be carbon‐saturated, suggesting that most of the studied soils have a capacity to accrue more MAOC. Simple linear regression showed that clay, aluminium and iron oxides explained 9%, 21% and 22% of the variation in MAOC, respectively. Multiple regression analyses including the amount of clay, clay+silt, aluminium and iron oxides, pH, type of fertilization, precipitation and temperature as explanatory variables explained 33%–53% of the variation in OC and MAOC. In all soils, aluminium oxides were important explanatory variable for MAOC, whereas Fe oxides were significant only in soils with higher clay content (&gt;30%). In soils with a low clay content (&lt;30%), pH had added value in explaining MAOC. Altogether, it seems that various climatic, edaphic and soil management‐related factors are context‐dependently controlling OC and that soil textural information alone is not necessarily an adequate predictor to assess the MAOC saturation state of the soil.

A study of the efficacy and structural performance of modified coal tar and dimethylpolysiloxane as binders for coal-carbon composites

Amidst global resource depletion and population growth, repurposing carbon-containing waste as raw materials into products offers promise for a more resource-efficient, circular economy. This research examines the efficacy of using coal tar modified through air-blowing as a binder for producing coal composite, alongside exploring dimethylpolysiloxane as an alternative binder. The effects of the binder type, mixing ratios, and coal fine composition on the properties of the composites were systematically studied. Microscopic analysis revealed anisotropic spherules in pitch formed at 400 °C/9 h and 450 °C/6 h possess favorable chemical properties like low H/C ratios (0.24–0.25) and high carbon content (96–97 %). Pyrolyzed coal fines and modified pitch-based composites exhibited moderate weight loss (11–17 %), notable compressive strength (106.58–344.71 MPa), and flexural strength (49–160 MPa). However, composites produced from coal tar pitch (400 °C/9 h) blended with 50 % GG1 and further pyrolyzed at 600 °C for 5 h exhibited a high water absorption (19 %). Also, composites with inferior flexural strength were produced using dimethylpolysiloxane as a binder, rendering them unsuitable for structural applications. This straightforward approach offers a viable means to repurpose significant quantities of coal fines and coal tar destined for landfills. This research is intended as a reference for researchers seeking to tranform coal waste into structural composites, thereby promoting circularity, and mitigating associated environmental risks.

Artificial neural networks in soil quality prediction: Significance for sustainable tea cultivation

In today's era artificial intelligence is quite popular, one of the most effective algorithms used is Artificial Neural Networks (ANN). In this study, the determination of soil quality using the Soil Management Assessment Framework (SMAF) model in areas where tea cultivation is carried out at the micro-watershed scale and the predictability of soil quality using ANN were evaluated. According to the results, the soil quality indices of tea-growing areas were generally classified as “medium” between 55 and 70 %. Among the evaluated features for determining soil quality, the highest relative importance value was for soil organic carbon content (13 %) and potential mineralizable nitrogen (13 %), whereas the lowest values were for exchangeable potassium (4 %) and sodium adsorption ratio (SAR) (4 %). In addition, when comparing the actual and predicted values for soil quality prediction using ANN, the Lin's concordance correlation coefficient (LCCC), ratio of performance to deviation (RPD), and R2 values were found to be 0.93, 2.95, and 0.89, respectively. Significant properties for the determined values within a 90 % predicted interval were found to be organic matter, microbial biomass carbon, bulk density, and aggregate stability of the soils. Moreover, the uncertainty values (standard deviation) in the model predictions were determined to be within the range of 1.01–4.56 %. Consequently, the Soil Quality Index (SQI) obtained from the SMAF model using 12 soil properties in tea-growing areas could be accurately predicted using ANN. As a result of this study, digital maps showing the spatial distribution of SQI and the predicted uncertainties can help monitor SQI levels in this area.