Contamination In China Research Articles

Evolution of polycyclic aromatic hydrocarbons in the surface sediment of southern Jiaozhou Bay in northern China after an accident of oil pipeline explosion.

The 2013 "Qingdao oil pipeline explosion" contaminated about 2.5km of shoreline in the Jiaozhou Bay area and aroused widespread concern because of the serious casualties even though it was not the most severe oil-spill contamination in China. To evaluate the long-term impact, we collected thirty-three surface sediment samples after 3years of the accident, with sixteen polycyclic aromatic hydrocarbons (PAHs) detected. Spatial-temporal variation in PAHs revealed that a minimal impact might still be present after 3years. Source analysis combined with a one-way ANOVA showed that pyrolytic sources were consistently predominant. The environmental impact was already minimal 3years later and negligible thereafter. Although the cancer risk has decreased over the years, there has always been a potential hazard to human for specific occupation, with all of the risk values exceeded 10-6. This study offers a reference for assessing the long-term impact of oil spills in similar bay areas.

Application of Non-Aflatoxigenic Aspergillus flavus for the Biological Control of Aflatoxin Contamination in China.

Biological control through the application of competitive non-aflatoxigenic Aspergillus flavus (A. flavus) to the soil during peanut growth is a practical method for controlling aflatoxin contamination. However, appropriate materials need to be found to reduce the cost of biocontrol products. In this study, a two-year experiment was conducted under field conditions in China, using a native non-aflatoxigenic strain to explore its effect. After three months of storage under high humidity, aflatoxin levels remained low in peanuts from fields treated with the biocontrol agent. Three types of substrates were tested with the biocontrol agent: rice grains, peanut meal (peanut meal fertilizer) and peanut coating. Compared to untreated fields, these formulations resulted in reductions of 78.23%, 67.54% and 38.48%, respectively. Furthermore, the ratios of non-aflatoxigenic A. flavus recovered in the soils at harvest in the treated fields were between 41.11% and 96.67% higher than that in untreated fields (25.00%), indicating that the rice inoculum was the most effective, followed by the peanut meal fertilizer and peanut coating. In 2019, the mean aflatoxin content of freshly harvested peanuts in untreated fields was 19.35 µg/kg higher than that in the fields treated with 7.5 kg/ha rice inoculum, which was 1.37 µg/kg. Moreover, no aflatoxin was detected in the two other plots treated with 10 and 15 kg/ha rice inoculum. This study showed that the native Chinese non-aflatoxigenic strain of A. flavus (18PAsp-zy1) had the potential to reduce aflatoxin contamination in peanuts. In addition, peanut meal can be used as an alternative substrate to replace traditional grains, reducing the cost of biocontrol products.

Efficient electro-catalyzed PMS activation on a Fe-ZIF-8 based BTNAs/Ti anode: An in-depth investigation on anodic catalytic behavior

Phenanthrene (PHE), mainly released from coal tar and petroleum distillation, is an important kind of prevalent polycyclic aromatic hydrocarbons (PAHs) contamination in China (up to 2.38 ± 0.02 mg/kg in soil and 8668 ng/L in surface water) and other countries in the world. Metal–organic frameworks (MOFs) show promising application prospects in the decontamination field, however, suffering from the intrinsic fragility and fine powder forms. Therefore, macroscopic MOFs architecture-sandwich-like Fe-ZIF-8/blue TiO2 nanotube arrays (BTNAs)/Ti substrate (FBTT) anode with strong interfacial bonding (Fe-O-Ti and Fe-2-MIM-Ti coordination) was constructed using innovative in situ growth, condensation-crystallization-deposition, and pyrolysis methods, aiming at exploring the feasibility of MOFs-based anode/peroxymonosulfate (PMS) mediated PHE elimination, revealing the in-depth mechanisms, simultaneously overcoming the intrinsic drawbacks of MOFs. The FBTT-4 (doping content of 30 %) efficiently degraded PHE by 90.01 % and 74.5 % within 10 min at 350 μg/L and 3 mg/L, respectively, mediated by the ·OH compared to the SO4·-, 1O2, and O2·-. Post-optimized range of anodic potential enabled (i) anodic oxidation, (ii) activation of water and PMS molecules to produce active species, (iii) capture of electrons in reactants to reduce Fe3+/Ti4+ to Fe2+/Ti3+, maintaining the proportion of Fe/Ti with low valence and thus stable PMS activation capacity, and (iv) regulation of the Fe/Ti d-band center to modulate the anode adsorption capacity. The further increment in anodic potential could promote “dark photocatalysis” with a Z-scheme-like mechanism. Thus, it is proposed that the development of macroscopic MOFs-based anode, especially those with small band gaps, represents vast potentials in electrocatalytic contamination elimination. Simultaneously, the MOFs-based anode is expected to fully exploit their catalytic capacities and solve their intrinsic defects as well.

Research Progress on Heavy Metals Pollution in the Soil of Smelting Sites in China.

Contamination by heavy metals is a significant issue worldwide. In recent decades, soil heavy metals pollutants in China had adverse impacts on soil quality and threatened food security and human health. Anthropogenic inputs mainly generate heavy metal contamination in China. In this review, the approaches were used in these investigations, focusing on geochemical strategies and metal isotope methods, particularly useful for determining the pathway of mining and smelting derived pollution in the soil. Our findings indicate that heavy metal distribution substantially impacts topsoils around mining and smelting sites, which release massive amounts of heavy metals into the environment. Furthermore, heavy metal contamination and related hazards posed by Pb, Cd, As, and Hg are more severe to plants, soil organisms, and humans. It’s worth observing that kids are particularly vulnerable to Pb toxicity. And this review also provides novel approaches to control and reduce the impacts of heavy metal pollution. Hydrometallurgy offers a potential method for extracting metals and removing potentially harmful heavy metals from waste to reduce pollution. However, environmentally friendly remediation of contaminated sites is a significant challenge. This paper also evaluates current technological advancements in the remediation of polluted soil, such as stabilization/solidification, natural attenuation, electrokinetic remediation, soil washing, and phytoremediation. The ability of biological approaches, especially phytoremediation, is cost-effective and favorable to the environment.

Worldwide cases of water pollution by emerging contaminants: a review

Water contamination by emerging contaminants is increasing in the context of rising urbanization, industrialization, and agriculture production. Emerging contaminants refers to contaminants for which there is currently no regulation requiring monitoring or public reporting of their presence in our water supply or wastewaters. There are many emerging contaminants such as pesticides, pharmaceuticals, drugs, cosmetics, personal care products, surfactants, cleaning products, industrial formulations and chemicals, food additives, food packaging, metalloids, rare earth elements, nanomaterials, microplastics, and pathogens. The main sources of emerging contaminants are domestic discharges, hospital effluents, industrial wastewaters, runoff from agriculture, livestock and aquaculture, and landfill leachates. In particular, effluents from municipal wastewater treatment plants are major contributors to the presence of emerging contaminants in waters. Although many chemicals have been recently regulated as priority hazardous substances, conventional plants for wastewater and drinking water treatment were not designed to remove most emerging contaminants. Here, we review key examples of contamination in China, Portugal, Mexico, Colombia, and Brazil. Examples include persistent organic pollutants such as polychlorinated biphenyls, dibenzofurans, and polybrominated diphenyl ethers, in lake and ocean ecosystems in China; emerging contaminants such as alkylphenols, natural and synthetic estrogens, antibiotics, and antidepressants in Portuguese rivers; and pharmaceuticals, hormones, cosmetics, personal care products, and pesticides in Mexican, Brazilian, and Colombian waters. All continents are affected by these contaminants. Wastewater treatment plants should therefore be upgraded, e.g., by addition of tertiary treatment systems, to limit environmental pollution.

Computational Simulation of Basic Reproductive Strength on Covid 19

The basic reproduction number (R0), is presented to be an indicator of the contagiousness or transmissibility of infectious and parasitic agents. On the inception of a covid-19 epidemic, there’s a period admitted as the the susceptible, exposed or infected duration, earlier than an affected person can spread the virus to every other person. We enhance mathematical fashions to file for this period and observe version to the covid-19 contamination in china. We take a look at the epidemiological constants within the version, such as the transmigration charge and the simple reproductive variety, the usage of statistics of launched cases. We therefore estimate the act of the inclined, exposed or latency length inside the symptoms of a covid-19 infection. Through this critical version giant range R0, has been used to count on the sphere of persons right now infected with the contagious human and categorized the intensity of prone, exposed, and infected populations as quickly because the infectious is over, it can be immediately used to degree the contaminated regions. Primarily based at the power of R0, inclined, uncovered, and infected human being’s price has been calculated through Runge Kutta Felhberg method, maple 18. By using this investigation, the susceptible human’s infectious rates from covid-19 are strongly multiplied because the infected human being’s price moves up and down and the uncovered humans price decelerates with the boom of the basic reproductive wide variety. The transmissibility of covid-19 infection is related to the respiration lack of information of conventional humans and global warming.

Agricultural Plastic Pollution in China: Generation of Plastic Debris and Emission of Phthalic Acid Esters from Agricultural Films.

Agricultural plastic films have been proven highly advantageous, but they also cause pollution of plastic debris and associated chemicals. Phthalates (phthalic acid esters, PAEs), an important additive of agricultural films, can be released and contaminate the environment. Here, we analyzed the agricultural plastic usage and assessed plastic debris in China and developed a method to estimate PAE emissions from agricultural films. Additionally, the environmental fate of PAEs was evaluated using a fugacity-based multimedia model. The agricultural plastic film usage in China in 2017 was 2,528,600 tons. After agricultural film recycling and water erosion, the plastic debris amount was estimated as 465,016 tons. The water erosion process carried 4329 tons of plastic debris into the aquatic environment. During its lifetime, the agricultural film released a total of 91.5 tons of two typical types of PAEs. PAEs from the mulching film would mostly be removed through degradation, while those from the greenhouse film accumulate in vegetables. Populated regions exhibited more serious PAE pollution in vegetables but with no immediate health risks. The model was well evaluated using comparable measured concentrations and uncertainty analysis based on the Monte Carlo method. The findings from this study demonstrate the serious agricultural plastic pollution problem and associated PAE contamination in China.

Is public service transportation increase environmental contamination in China? The role of nuclear energy consumption and technological change

Can China's nuclear energy reduce CO2 emissions? As global climate change is dramatically increasing, countries move to friendly energy substitutions, contributing to carbon emission mitigation. In this circumstance, both academics and policy analysts have paid attention to nuclear energy. Moreover, this study aims to decrease public service contamination, so nuclear energy is the most cost-effective, large-scale, reliable, and low-carbon alternative for electricity production. To this end, the study examines the dynamic linkage among nuclear energy, public service transportation, real income, innovative technology with CO2 emissions for China. Our work employs a novel dynamic autoregressive distributive lag simulation for the years 1985–2018. Results analysis shows that negative and positive simulation graphs for nuclear energy consumption and innovative technology mitigate environmental pollution. On the other, hand public service transportation and income per capita increase the environmental cost. Therefore, decision-makers should boost nuclear power and benefit from the significant influence of a clean environment through innovative technology potentials.

Quantitative determination of pyriproxyfen and its metabolite residues in bee products of China using a modified QuEChERS approach with UPLC-MS/MS

Given the key role of bees as indicators for environmental assessment, residues in bees and bee products have attracted great interest. In this regard, an improved, highly sensitive method for quantifying the insecticide pyriproxyfen and its four metabolites (4′-OH-Pyr, DPH-Pyr, 2-OH-PY, 4′-OH-POP) in honeybees, larvae, and bee products (honey, pollen, royal jelly and wax) should be established. For this purpose, we used ultra-performance liquid chromatography coupled with triple-quadrupole mass spectrometry for rapid quantification (≤5 min). Recoveries for various matrices ranged from 73.77% to 114.97%, with satisfactory intra-day and inter-day precision (relative standard deviations of 0.03–8.61% and 0.10–7.25%, respectively). The results demonstrated excellent linearity (R2 > 0.9903) with a limit of quantification of 1 μg/kg for six different matrices. We collected and analyzed 597 samples (honey, bees and wax) from four major beekeeping areas in China. Only 47 of these samples contained residues of pyriproxyfen and two of its metabolites (2-OH-PY, 4′-OH-Pyr), and high levels of contamination were found in bee samples (2–739 μg/kg), with substantive accumulation in wax (levels were 9.49% higher than in other samples). The result demonstrate that the method provides a reliable and convenient means of monitoring pyriproxyfen and its metabolites in bee products for better product quality, human health, and international commercial competition and also lays a foundation for risk assessment of potential pyriproxyfen contamination in China.

Influence of Mining Activities on Arsenic Concentration in Rice in Asia: A Review

Crop and livestock farming on contaminated soil has been found to induce the accumulation of trace elements in edible parts of plants, with subsequent risk to human and animal health. Since rice crop is a major source of energy in worldwide diets and is consumed by more than 3 billion people, the soil–rice pathway is regarded as a prominent route of human exposure to potentially toxic elements. This study provides an overview of arsenic contamination in paddy rice from mining-impacted areas in several Asian countries that are primary rice consumers. From this review, it may be concluded that mining activities, along with the associated residual waste, significantly contribute to arsenic contamination of this food crop as rice samples from these regions were highly contaminated, with the highest total arsenic concentrations recorded being 3–4 times higher than the maximum levels proposed by the Codex Alimentarius Commission. While the contamination in China, Korea, Indonesia, and Thailand appeared to be slightly affected by mining activities, the elevated levels of arsenic in rice from mining areas in India, Bangladesh, and Vietnam could be derived from arsenic-contaminated groundwater.

Integrating Metagenomic and Bayesian Analyses to Evaluate the Performance and Confidence of CrAssphage as an Indicator for Tracking Human Sewage Contamination in China.

Recently, crAssphage has been proposed as a human-specific marker for tracking fecal contamination. However, its performance has always been validated in a limited number of host samples, which may obscure our understanding of its utility. Furthermore, few studies have quantified confidence of fecal contamination when using crAssphage. Here, we evaluate the performance and confidence of crAssphage by analyzing a large panel of metagenomic data sets combined with Bayesian analyses. Results demonstrate that crAssphage exhibits superior performance with high host sensitivity and specificity, indicating its suitability for tracking human fecal sources. With the marker, a high confidence (>90%) can be obtained and particularly, multiple samples with positive results provide a near certainty of confidence. The application of crAssphage in the sediments of three Chinese urban rivers shows a high confidence of >97% of human fecal contamination, suggesting the serious challenge of sewage pollution in these environments. Additionally, significant correlation is observed between crAssphage and antibiotic resistance genes (ARGs), expanding the utilization of crAssphage for pollution management of ARGs. This study highlights the benefit of using metagenomic-based analysis for evaluating the performance and confidence of microbial source tracking markers in the coming era of big data with increasing resources in available metagenomic data.

Single-cell transcriptomics uncovers phenotypic alterations in the monocytes in a Chinese population with chronic cadmium exposure

BackgroundCadmium is the most prevalent form of heavy metal contaminant globally and its exposure rises serious health concern. Chronic exposure to cadmium causes immune disturbances. However, few studies have addressed how it affects circulating immune cells, one of the most essential elements for the host defense system, at both population and molecular level. Therefore, this is the first single-cell transcriptomic analysis of the response of the human circulating immune system to plasma cadmium level. MethodsWe conducted a cross-sectional study in Hunan province, which has the highest level of cadmium land contamination in China. A total of 3283 individuals were eligible for analyzing the association between plasma cadmium levels and the monocyte counts and its subgroups. Another 780 individuals were assigned for validation. Thirty propensity-matched individuals without chronic disease from the lowest- and highest-quartile groups according to serum cadmium levels were selected for single-cell RNA sequencing (scRNA-seq) and flow cytometry analyses. Moreover, the monocyte phenotypic alterations in the heavy metal-exposed population were validated with a cecal ligation and puncture sepsis mouse model. ResultsFrom August 2016 to July 2017, we conducted a cross-sectional study to identify phenotypic alterations in peripheral immune cells in cadmium polluted areas in China. Monocyte percentages were negatively associated with plasma cadmium levels in multivariable linear regression analysis. Peripheral blood mononuclear cell scRNA-seq revealed that the CD14+ monocyte subset was dramatically reduced in the highest-quartile cadmium-exposed group. Moreover, we assessed different hallmarks of immune cell dysfunction—such as host defense capability, apoptotic signaling, cellular diversity and malignant gene expression in monocytes. Importantly, cadmium induced phenotypic alterations in the immune system were validated in the cecal ligation and puncture sepsis mouse model, in which chronic exposure to cadmium not only increased the death rate but also decreased monocyte numbers and the ability to clear bacterial infections. ConclusionThis transcriptomic analysis provides molecular information about how the most important hallmarks of immune cell dysfunction are affected by plasma cadmium level. The significant phenotypic alterations in monocytes serving as early indicators of increased susceptibility to infectious and malignant diseases.

Status and associated human health risk of zinc accumulation in agricultural soils across China

Zinc (Zn) is not only an essential element for organisms, but it might also be an environmental pollutant. However, to date, there have not been any studies on Zn accumulation in Chinese agricultural soils at the national scale. In this study, soil Zn concentrations were obtained for soils from 277 sites with potential pollution (the “PP group”) and 1186 normal agricultural sites in China through a comprehensive literature search. Compared with the reported Zn contents of soils of other countries and regions in the world, the average concentration of Zn in soils in China (86.14 mg·kg−1) is relatively high. The total inventory of Zn in China’s agricultural soils was calculated to be 3.08 × 1010 tonnes. Zn contamination was serious in the PP group (e.g. 7076 mg·kg−1 in Yunnan province), and was primarily derived from anthropogenic activities including mining, smelting, and sewage irrigation. The accumulation of Zn in soils was influenced by different factors in different regions of China and varied with land-use pattern, with Zn concentrations in soils of different agriculture types decreasing in the following order: orchard > paddy field > vegetable land > wheat land. Zn pollution and associated risks in soils of regions in the PP group were more severe than those in normal agricultural soils. The hazard index (HI) values (for the PP group) for different human population groups varied as follows: children (2.40) > adult females (1.39) > adult males (1.23). The highest HI value obtained of 26.77 pertained to children. Overall, this study provides a comprehensive assessment of Zn accumulation in agricultural soils, and the results provide valuable information for the management and risk prevention of Zn contamination in China’s soils.

Combined remediation of polychlorinated naphthalene-contaminated soil under multiple scenarios: An integrated method of genetic engineering and environmental remediation technology

This study explored the types of polychlorinated naphthalene (PCN)-contaminated soil and determined the practicable scheme of combined remediation using an integrated method of genetic engineering and environmental remediation technology. A multi-scenario comprehensive evaluation system of a plant-microbial combined bioremediation of PCN-contaminated soil was established using the intelligent integration of analytic hierarchy process and formula evaluation methods based on the current situation of PCN contamination in China, which showed the bioremediation of PCN-contaminated soil by the plant-microbial system could be divided into four scenarios. QSAR models were constructed to quantify the remediation mechanism that electronic parameter ∆E was the key factor changing the efficiency of combined bioremediation. Moreover, the macro-control scheme of PCN-contaminated soil was established, which indicated that four new multifunctional proteins promoted the absorption, degradation, and mineralization of PCNs in specific soil pollution types significantly, were obtained through cross gene recombination. The molecular dynamics (MD) simulation results showed the efficiency of the plant-microbial combined bioremediation were increased by 15.45% (Scenario 1, 2, 3) and 20.02% (Scenario 4) under the optimal regulation scheme. The findings will be helpful to realize the regional control of PCN-contaminated soil.

Interactions of arsenic metabolism with arsenic exposure and individual factors on diabetes occurrence: Baseline findings from Arsenic and Non-Communicable disease cohort (AsNCD) in China

The interaction between arsenic metabolism and potential modifiers on the risk of diabetes is unclear. This research aimed to investigate arsenic metabolism and diabetes prevalence and to identify the interactive effects of arsenic metabolism with some risk factors on diabetes in a Chinese population. A baseline cross-sectional survey was performed in two areas with groundwater arsenic contamination in China. Arsenic levels in water and arsenic metabolites in urine were analyzed. The proportions of each arsenic metabolite (inorganic arsenic [iAs%], monomethylarsonic acid [MMA%], and dimethylarsinic acid [DMA%]) were computed to evaluate arsenic metabolism. Odds ratios (ORs) and 95% confidence intervals (CIs) were used to assess the association between arsenic and diabetes. Interaction on the additive scale between arsenic methylation index and effect modifier was evaluated by calculating the relative excess risk due to interaction (RERI). Compared with participants in the lower tertile of MMA%, participants in the middle and upper tertiles of MMA% were less prone to diabetes (OR: 0.47 and 0.31, respectively). However, participants in the upper tertiles of urinary DMA% (OR: 3.18) were more likely to have diabetes than those participants in the lower tertiles. The stratified analyses revealed that a one-unit increase in DMA% was associated with higher odds of diabetes in females (OR: 1.06, 95% CI: 1.01, 1.11), older people (OR: 1.05, 95% CI: 1.00, 1.10), and subjects with body mass index (BMI) under 25 kg/m2 (OR: 1.07, 95% CI: 1.01, 1.14). The additive interactions between DMA% and female gender (RERI: 0.40, 95% CI: 0.01, 11.88), DMA% and age (RERI: 0.02, 95% CI: 0.01, 8.85), as well as DMA% and BMI (RERI: 0.49, 95% CI: 0.01, 9.62), were statistically significant. In conclusion, efficient arsenic metabolism is associated with higher odds of diabetes. Urinary DMA% and individual factors interact to synergistically influence diabetes occurrence in the Chinese population.

Ecological risk evaluation and source apportionment of heavy metals in park playgrounds: a case study in Xi'an, Shaanxi Province, a northwest city of China.

Park playgrounds recently are suffering serious heavy metals contamination in China. It is urgent to assess the ecological risk and identify the sources for heavy metals. A total of 111 topsoil samples were collected from four park playgrounds in Xi'an, and the X-ray fluorescence (XRF) instrument was used to measure the concentrations of heavy metals including chromium(Cr), nickel (Ni), copper (Cu), zinc (Zn), arsenic (As), lead (Pb), manganese (Mn), and cobalt (Co), respectively. Ecological risk ([Formula: see text]) and potential ecological risk index (RI) were introduced to determine the pollution level and ecological risk, and the absolute principal component score-multiple linear regression (APCS-MLR) model was implemented to identify the sources for heavy metals. The main results were as follows. (1) ExceptAs, the mean concentrations of measured heavy metals of four park playgroundssurpassed the soil background values of Shaanxi Province. (2) In each park playground, the [Formula: see text] was below a "low" risk level ([Formula: see text]=10) for Cr, Ni, Zn, As, and Mn; Cu was between a "moderate" and "considerable" risk level; Pb was between a "low" and "moderate" risk level; and [Formula: see text] was between a "considerable" and "high" risk level for Co. Besides, the RI index was on a "high" risk level (120 < RI < 240) with an obvious spatial distinction. (3) The anthropogenic factors were the main sources for heavy metals, and mixed sources and natural sources were considered as the minor sources for metals. (4) The sources contributions for Co had obvious spatial heterogeneity in each park situated in four different urban planning districts.

An assessment of how bio-E10 will impact the vehicle-related ozone contamination in China

Bio-E10 is short for the biofuel made up of 90% gasoline in volume and 10% bio-ethanol, which is the ethanol made from commercially-grown crops such as corn and wheat by the sugar fermentation process. In China, bio-E10 will be supplied nationwide from 2020 as an alternative to conventional gasoline, aiming at ensuring greater energy security and lowering the greenhouse gas emissions. In order to assess the impacts of the upcoming bio-E10 application on the ozone forming potential (OFP) of the emissions from in-use vehicles, this paper examined the carbonyls and volatile organic compounds (VOCs) in the evaporative and tailpipe emissions of three China-4 certified in-use vehicles fueled with a market-available gasoline and two match-blend bio-E10s, and calculated their OFPs using the Maximum Incremental Reactivity (MIR) method. The results revealed that for the evaporative emissions, the use of bio-E10s increased the carbonyl and VOC emissions released within the diurnal-loss stage by 8.5–17.6% and 11.1–78.6% respectively, but decreased the carbonyl and VOC emissions in the hot-soak stage by 47.4%–61.5% and 4.8%–20.6% respectively. Regarding the tailpipe emissions, in comparison to the gasoline baseline, burning bio-E10s increased the carbonyls by 15%–46% while reducing the VOCs by 37%–56% over the New European Driving Cycle (NEDC). Reductions in the tailpipe OFPs up to 47.3% were seen with the application of the bio-E10s, however, there were no clear conclusions with respect to the evaporative OFPs, which varied from −15% to ＋25% compared to the gasoline baseline. Based on the test results and census data, the application of bio-E10 in China is shown to help remove part of ozone contamination from the in-use vehicle sector.

Occurrence of Neonicotinoids in Chinese Apiculture and a Corresponding Risk Exposure Assessment.

Neonicotinoids are the most widely used insecticides worldwide, but there is mounting evidence demonstrating that they have adverse effects on nontarget organisms. However, little is known about the extent of environmental neonicotinoids contamination in China. In this study, a total of 693 honey samples from across China, from both Apis melifera and Apis cerana, were analyzed to examine neonicotinoid concentrations and their geographical distribution, and correlation with the primary plant species from which the honey was obtained. Furthermore, chronic and acute exposure risk and risk ranking for humans eating honey were investigated, and risks to bees were also considered. The results revealed that 40.8% of the samples contained at least one of the five neonicotinoids tested. Honeys from commercial crops were found to be more frequently contaminated with neonicotinoids than those from noncommercial crops. Honey samples from Apis mellifera were more frequently contaminated than those from Apis cerana. The concentrations of neonicotinoids found in honey overlapped with those that have been found to have significant adverse effects on honeybee health. The dietary risk assessments indicated that the levels of neonicotinoids detected in honey were likely to be safe for human consumption.

Assessing the Spatial Distribution of Soil PAHs and their Relationship with Anthropogenic Activities at a National Scale.

Soil polycyclic aromatic hydrocarbon (PAH) pollution is a major concern due to its negative impact on soil quality around the world. In China, accurate data on soil PAHs and information on the relationship with anthropogenic activities are limited. In this study, about 30,800 samples from 1833 soil sample sites were reviewed from 306 published reports to build a soil PAHs database. Based on the data obtained, the results demonstrated that 24.11% of surface soils in China are heavily contaminated. Meanwhile, the concentration of soil PAHs varied, in the order of independent mining and industrial areas (IMIA) > urban areas > suburban areas > rural areas, and the spatial distribution in China demonstrated a descending trend from north to south. Moreover, the characteristic ratio and PCA-MLR (principal component analysis-multiple linear regression) analysis demonstrated that coal combustion and vehicular exhaust emissions were the main sources of soil PAH pollution in China. On the other hand, provincial total Σ16PAHs in surface soil were significantly correlated with the per square kilometer GDP (gross domestic product) of industrial land, the per capita GDP, as well as the production and consumption of energy. These results indicate that anthropogenic factors have greatly affected the levels of soil PAHs in China. This study improves our understanding on the status and sources of soil PAH contamination in China, thereby facilitating the implementation of strategies of prevention, control, and remediation of soils.

Soil contamination in China: Current priorities, defining background levels and standards for heavy metals

The Chinese Government is working to establish an effective framework in managing soil contamination. Heavy metal contamination is key to the discussion about soil quality, health and remediation in China. Soil heavy metal contamination in China is briefly reviewed and the concepts of background values and standards discussed. The importance of contaminated land and its management for China food security and urbanization are discussed. Priorities for China's next steps in developing an effective research and management regime are presented. We propose that critically important to the science-based risk assessment of contaminants in soils is the incorporation of speciation and bioavailability into the measurement and evaluation criteria. Consideration of soil biology/ecological endpoints will be necessary to protect ecosystem health. National and regional/local scenarios of land use type/usage will address residential/urban re-use of industrial land as well as varying agricultural scenarios.