Rock Contact Research Articles

Mechanism of Water Control and Gas Augmentation by Fracturing Interface Modifier in Water-bearing Gas Reservoir

Abstract With the development of oil and gas reservoirs, water containing gas reservoirs have gradually received attention. However, problems such as water production during the production process have reduced gas permeability, leading to a decrease in gas well productivity underground. Phase permeability regulators improve productivity by changing the wettability of rocks and enhancing gas permeability. This article tests the interface performance of a phase permeability regulator and evaluates its temperature resistance, formation water salt resistance, and erosion resistance. The pore bound water saturation of the core before and after modification with the phase permeability regulator, as well as the relative permeability of gas and water phases, are tested. The experimental results show that the phase permeation regulator can reduce the surface tension of water to 22.2 mN/m, and the rock contact angle before and after soaking increases from 26.63 ° to 97.69 °, achieving the transition of rock from hydrophilic to hydrophobic. The surface tension of the phase permeation regulator changes significantly before and after aging at 80-120 °C, and its high-temperature resistance is poor. After mixing with formation water with a salinity of 60000 to 100000, the surface tension increases, and at a salinity of 60000, it increases by 5.1 mN/m. The use of phase permeability regulators for matrix core displacement resulted in a slight increase in displacement pressure, while the formation water remained unchanged after approximately 140 hours of erosion. After modification with phase permeability regulators, the irreducible water saturation of the core decreases by about 25%, and the relative permeability of the gas phase increases, resulting in a significant hydrophobic and gas conducting effect. Phase permeability regulators achieve hydrophobic gas conductivity by changing the wettability of rocks, which can alleviate the problem of water production in shallow and low salinity reservoirs.

Earth surface exchanges (ESEX) discussion of ‘Swelling and flow of expanding clays as a cause for nontectonic deformations in a glacial–interglacial environment: Holy Cross Mountains, Poland’ by E.Jurewicz, P.Karnkowski, A.Czarnecka‐Skwarek, E.Wójcik, I.Gawriuczenkow. Earth Surface Processes and Landforms2023: 1–16. https://doi.org/10.1002/esp.5609

AbstractIn a recently published report focused on the role of swelling of Triassic clays as the dominant process that led to the local steepening of competent Jurassic strata, its authors presented an opinion on the lack of evidence for the existence of the Gnieździska–Brzeziny strike‐slip fault along the contact between the Triassic and Jurassic rocks. This discussion presents the structural, geophysical, cartographic and geomechanical data indicating that the contact of Triassic and Jurassic rocks is defined by the vertical dextral strike‐slip Gnieździska–Brzeziny fault, which was formed after tilting of the beds in the Late Cretaceous. The presented evidence validates the tectonic deformation of Mesozoic rocks related to strike‐slip faulting. The dominant horizontal contraction across the fault planes within the restraining stepovers resulted in tilting of the beds, which is a well‐recognized phenomenon within the strike‐slip fault networks worldwide.

GEOLOGY OF ALAKNANDA BHGIRATHI AND YAMUNA VALLEY, GARHWAL HIMALAYA, PARTS OF CHAMOLI TEHRI UTTAKASHI & PAURI DISTRICTS, UTTRAKHAND STATE, INDIA

The Alaknanda is the trunk stream of Ganga system it drains the eastern part of the area of study .The rocks of Alaknanda valley and adjoining area consist of three units viz Central Cryastalline , Garhwal Group and Dudatoli Groups which from north to south are separated by thrust or fault. The Central Crystalline Group in this area consist of /comprises of northerly dipping sequence of Kyanite schist,Garnet mica schist quartzites and para amphibolites of Tugnath formation and it is intruded by granite at Ragsi,the main Central Thrust seprates it from Garhwal Group.The Dudatoli Groupis represented Pauri Phyllite and Kirsu Quartzite which forms the northern limb of Dudatoil syncline .The north Almora Thrust makes it boundary with Garhwal group. The later is divisiable in to Rudraprayga ,Lamri , Chamoli and Gawangarh and Patrali Formation which occurs in normal stratigraphic order. It is intruded by biotite granite by biotite graninte at Nainidevi and Mohankal , with tourmaline granite around Chirpatikhal and also by basic intrusive . The Rudraprayg , Lameri and Chamoli formations are equivalent to Uttarkashi Shyalnan and Nagnithhank Formation respectively in Bhagirathi valley. The Garhwal Group of has been subjected to three phases of tectonic deformation. The south east to southerly plunging folds such as Marithanasa and Pingapani synclines .Karanprayg anticline were developed during the second phase of movements. The Alaknada fault which cuts off set of the formation and earlier structures between Sunala is the strike slip fault in western part, appears to be the youngest elements. Geologically , the Bhagirathi valley and adjoining areas comprises of four distinct units namely from north to south the Central Crystalline Group , the Deoban Group the Simla Group,and Krol belt rock separating from one another by thrust or faults. The main Central Thrust passing through Sainj in northern part brings the northerly dipping crystalline rocks in sharp contact with under lying Deoban Group (Garhwal Group) sedimentries which comprises a lower Deoban Formation of Phyllite, slate meta basics, minor quartzite and lime stone, the middle Deoban formation of lime stone and upper Deoban formation of Quartzite and basics. The southern contact of Deoban Group is faulted one with comprising mainly siltstone, greywacks and slates dipping south .This fault called Sringar Nalupani fault of fundamental nature. In the southern and eastern part of the area this fault marks the contact between Deoban and Chandpur formation. In the western part south heading Ton Thrust separates the underlying Chanpur formation from the underlying Simla slates which shows abundant development of slump balls rod etc. indicating syndepositional disturbances in the basin of sedimentation while in Chanpur formation, is manly argillaceous, becoming arenaceous towards the top The Tons thrust passes through Laluli in Nagun Gad and is probably truncated by Tehri Nalupani fault at Chandpur in Bhagirathi valley. The full sequence of Krol rocks is exposed beautifully in Mussoorie syncline. The tectonic succession in Yamuna valley is Naogaon sheet comprising more metamorphosed rocks overly the Deoban group rocks separated from the latter by what is called the Naugaon thrust sheet which is folded in a North to Northwest plunging synform. The western limb of the folded thrust crosses Yamuna near the confluence with Kamola Gad and runs along the Kamola Gad. The rocks of the Naugaon sheet can be seen overlying the Deoban formation limestone along this section. The thrust hade towards east in this section. It follows a southerly trend till Tiyan when it takes an easterly swing, heading northward. It closes around Gair. The eastern limb of the synformal thrust sheet, heading westward crosses the Yamuna River at Kisna, Basic intrusive are seen along the thrust sheet near Kisna and around. The complexity of structural and tectonic set up in the area and lack of fossils make the task of correlation extremely difficult. However, on the basis of lithological similarities as well as structural disposition an attempt has been made to correlate the various litho units in the present area.

Simulation of cracking processes of the rectangular cavern surrounding rock based on a continuum–discontinuum method

In a self-developed continuum–discontinuum method that considers the internal cracking of quadrilateral elements, the computational domain is divided into quadrilateral elements with high accuracy. After cracking, the cracks propagate along the boundaries of the elements and the diagonal lines of the quadrilateral elements. Deformation, cracking, and contact of rocks can be simulated using this method. For Brazilian disc rock specimens, the rapid increase of tensile crack segments corresponds to a rapid decrease of the load. Compared with the original method, crack propagation is smoother in the improved method. This is because the propagation paths of cracks are fewer in the original method, and the propagation of cracks is hindered. For uniaxial compressive rock specimens, when two shear cracks intersect, one crack may dominate, forming a main crack, and its direction is consistent with the theoretical direction obtained using the Mohr − Coulomb criterion. For the cavern surrounding rock models, some long and narrow shear cracks appear in the surrounding rock, and their shapes are like logarithmic spirals. An interval exists between the shear cracks, and the more to the interior of the surrounding rock, the larger the interval between cracks. The higher the hydrostatic pressure, the faster the shear crack propagates and the easier it is to form a shear slip line. With an increase of cavern size, the depth and range of the shear cracks increase. With a decrease of the internal friction angle, the interval between the cracks increases, and the propagation direction of the cracks become more internal.

Water thin films on kaolinite gibbsite and edge surfaces and their effects on surface wettability in relation to geological carbon sequestration

Geological carbon sequestration (GCS) is a promising method to alleviate CO2 emission, while CO2 structural trapping is one of main GCS mechanisms, in which the storage capacity is strongly dependent on CO2-water–rock contact angle. Although CO2-water-kaolite contact angle on basal surfaces has been studied, the knowledge about kaolinite edge surface wettability remains unknown. In this work, we use molecular dynamics (MD) simulations to study CO2-water-kaolinite contact angle on kaolinite gibbsite and edge surfaces under a typical GCS condition (330 K and 200 bar). The common belief is that surface wettability in presence of water is determined by surface hydroxyl (–OH) group density. While the surface –OH group density of kaolinite edge surface is much lower than that of gibbsite surface, both gibbsite and edge surfaces are strongly water-wet. Edge surface is better hydrated than gibbsite surface as both silanol and aluminol groups can form hydrogen bonding with water molecules thanks to large effective water accessible volume around them, while pocket water can further anchor water film. Therefore, the atomic-level surface characteristics dictate interfacial water structures which determine CO2-water-kaolinite contact angle. Our study provides important insights into the effect of surface heterogeneity on interfacial water structures, and kaolinite gibbsite and edge surface wettability which is crucial to the optimization of GCS processes.

Sanidinite facies metamorphism at Nagarahal Village of Bilgi taluk, Bagalkot district, Karnataka, India


 
 
 Nagarahal village in the Bilgi taluk of Bagalkot district in Karnataka state shows the contact between the younger Bilgi granites and the Deccan basalts. The thermal impact that has happened on the pre-existing granites by the basalts has been studied by identifying the field occurrence of the contact zone of granites and basalts. The unaffected portion of the granites and the basalts that are far away from the contact are studied as well. The petrographic studies of the contact rocks between the granites and basalts show the polygonal recrystallized quartz with the triple point contact with other grains indicating the decussate texture indicating the high-temperature conditions, crushed quartz grains having contact with each grain appear as sugary crystals from the granoblastic texture, the irregular oriented mafic and felsic crystals show the hornfelsic texture and micrographic, and intergrowth textures showing the effect of thermal metamorphism near to the contact between the granite and basalt. The post-hydrothermal solution activity is at the peripheral region of the contact between granite and basalt which is seen by the formation of tourmaline. The mineral assemblages that are identified by the petrographic studies are muscovite, quartz, orthoclase, sanidine, sillimanite, chlorite, and Fe-Ti oxide minerals. The mineral chemistry data shows the high potash K-feldspar that consists of Or from 84% to 97.97%, Ab2%- 4.26%, and An0.09%-1.34% was identified as sanidine variety of K-feldspar, the plagioclase feldspar shows the dominant composition of Ab ranging from 84.92% to 97.10%, An content in plagioclase was found to be ranging from 0.87% to 14.02%, and the Or content is ranging from 1.06%-7.41%. indicating the presence of the albite variety of plagioclase, the Fe2+ dominating chlorite, and the presence of tourmaline indicates the hydrothermal effects at the periphery of the contact. The two feldspar thermometry indicates the formation temperature was 750°C at the contact and the chlorite formation temperature calculated is found to be 313°C which shows a decrease in the temperature away from the contact of the basalt and the granitic rocks. Whereas the granite and the basalts that are far away from the contact do not show any changes. The mineral assemblages, mineral chemistry data, and thermometric results indicate the high temperature and low-pressure sanidine facies of contact metamorphism in the studied area.
 
 

The Influence of Explosive and Rock Mass Properties on Blast Damage in a Single-Hole Blasting

In rock blasting for mining production, stress waves play a major role in rock fracturing, along with explosive gases. Better energy distribution improves fragmentation and safety, lowers production costs, increases productivity, and controls ore losses and dilution. Blast outcomes vary significantly depending on the choice of the explosive and the properties of the rock mass encountered. This study analyzes the effects of rock mass and explosive properties on blast outcomes via numerical simulation using data from the case study, and later validates the simulation results from the field blast fragmentation. The findings suggest that, for a given set of rock properties, the choice of explosive has a major influence on the resulting fragmentation. Strong explosives (high VOD and detonation pressure) favor large fracture extents in hard rocks, while weaker explosives offer a better distribution of explosive energy and fractures. The presence of rock structures such as rock contacts and joints influences the propagation of stress waves and fractures depending on the structures’ material properties, the intensity and orientations, and the direction and strength of the stress wave. When the stress wave encounters a contact depending on its direction, it is enhanced when traveling from soft to hard and attenuates in the opposite direction. The ability of the stress wave to cause fracturing on the opposite side of the contact depends on the intensity of the transmitted wave and the strength of the rock. Transmitted wave intensity is a function of the strength of the incident wave and the impedance difference between the interface materials. The presence of joints in the rock mass affects the propagation of the stress wave, mainly depending on the infill material properties and the angle at which the stress wave approaches the joint. Less compressible, higher stiffness joints transmit more energy. More energy is also transmitted in the areas where the stress wave hits the joint perpendicularly. Joints parallel to the free face offer additional fracturing on the opposite side of the joint. Other parameters, such as the joint width, continuity, fracture frequency, and the distance from the charge, enhance the effects. To achieve effective fragmentation, the blast design should mitigate the effect of variability in the rock mass via explosive selection and pattern design to ensure adequate energy distribution within the limits of geometric design.

Multi‐geophysical methods for characterizing fractures in an open pit mine, western Bushveld Complex, South Africa

AbstractIn the Bushveld Complex, South Africa, open pit mines are faced with a challenge of rock slope stability due to geological structures (fractures, faults and dykes) that compartmentalize the rock mass. Geophysical surveys (seismics, magnetics and electrical methods) were conducted in a 0.2 km2 area at Tharisa mine, with the goal to delineate fractures that may be potential conduits for water migration into the pit. Special processing techniques were applied to the dataset to obtain good quality seismic, magnetic and resistivity models. The P‐wave velocity models show distinct low velocities in the centre of the seismic profile, indicating the presence of weak zones associated with faulting or fracturing. Seismic reflection method was used to image the deeper discontinuities and mineralization contacts. Near surface reflections are observed throughout the profiles and are correlated with the contact between the chromitite and host rock. Ground magnetic surveys were conducted to delineate dykes and fractures. De‐trending and de‐culturing techniques were applied on the magnetic data for correcting regional and temporal variations. The low magnetic regions indicate the presence of fracture systems in the subsurface, whereas the high magnetic region is correlated with the dolerite dyke that crosscuts the pit. The electrical resistivity tomography exhibits linear low resistivity contrast zones that differentiate between the fractured and undisturbed hard rock at an estimated depth of 4–10 m. Resistivity shows discontinuities that suggests the presence of fracturing and dyke‐host rock contacts. Correlation among magnetics, P‐wave velocity models, resistivity section and seismic data is evident when overlaying the different datasets, implying that the low magnetic regions are highly weathered and prone to fracturing. The integration of geophysical data is encouraging, because it was able to image the depth to the bedrock, fractures within the host rock and dyke in a complex mining environment.

Improvement of the methods for determining ore losses when designing cement raw material deposit mining by surface miner combines

Relevance. The need to optimize production of cement raw materials and reduce the cost of processing raw materials. A surface miner combine allow high selective mining of a deposit, which helps to reduce moisture content of cement raw materials and reduce energy costs in a cement plant. In open-cast mining of cement raw materials deposits with the use of the surface miner combines, the increase in economic efficiency of mining operations can be achieved by determining the rational values of ore losses and dilution. Aim. To determine rational level of cement raw material losses during field development by surface miners. Objects. Cement industry quarries excavated with of the surface miner combines. Methods. Technical and economic analysis of the cement plant Beočin (Serbia), summation and synthesis of materials, sources and data available in the public domain, as well as calculations to determine the amount of loss and dilution of mineral resources at ore–rock contact for mining conditions of the quarry for extracting cement raw materials. Results. The main problems that arise during mining quarries for extracting cement raw materials have been identified. It concerns the determination of the volume of losses and dilution of mineral resources at the ore–rock contact for mining conditions of the quarry for extraction of cement raw materials. The authors present and substantiate conclusions about further effective application of optimal mining technology, with the use of the surface miner combines, which allows reducing the cost of production of minerals and specific operating costs of transporting carbonate rocks compared to the traditional technology of mining works at 50–60%.

Comparing the Tribological Performance of Water-Based and Oil-Based Drilling Fluids in Diamond–Rock Contacts

Oil-based drilling fluids are usually assumed to provide lower friction compared to their water-based alternatives. However, clear evidence for this has only been presented for steel–rock and steel–steel contacts, which are representative of the interface between the drillstring and the borehole or casing. Another crucial interface that needs to be lubricated during drilling is that between the cutter (usually diamond) and the rock. Here, we present pin-on-disc tribometer experiments that show higher boundary friction for n-hexadecane-lubricated diamond–granite contacts than air- and water-lubricated contacts. Using nonequilibrium molecular dynamics simulations of a single-crystal diamond tip sliding on α-quartz, we show the same trend as in the experiments of increasing friction in the order: water < air < n-hexadecane. Analysis of the simulation results suggests that the friction differences between these systems are due to two factors: (i) the indentation depth of the diamond tip into the α-quartz substrate and (ii) the amount of interfacial bonding. The n-hexadecane system had the highest indentation depth, followed by air, and finally water. This suggests that n-hexadecane molecules reduce the hardness of α-quartz surfaces compared to water. The amount of interfacial bonding between the tip and the substrate is greatest for the n-hexadecane system, followed by air and water. This is because water molecules passivate terminate potential reactive sites for interfacial bonds on α-quartz by forming surface hydroxyl groups. The rate of interfacial bond formation increases exponentially with normal stress for all the systems. For each system, the mean friction force increases linearly with the mean number of interfacial bonds formed. Our results suggest that the expected tribological benefits of oil-based drilling fluids are not necessarily realised for cutter–rock interfaces. Further experimental studies should be conducted with fully formulated drilling fluids to assess their tribological performance on a range of rock types.Graphical

A New Experimental Method for Acid Pretreatment in Perforated Horizontal Wells: A Case Study of Mahu Conglomerate Reservoir

The Mahu Oilfield in Xinjiang, China, is the world’s largest conglomerate oilfield, with a daily output of more than 8000 tons. In the fracturing of perforated horizontal wells, the breakdown pressure is high, resulting in difficulties in their treatment. Acid pretreatment has been applied to reduce the breakdown pressure in the field, but with poor performance. Few studies have been conducted on how acid pretreatment affects the breakdown pressure under perforation conditions in the Mahu conglomerate reservoir. Also, existing fracturing or acid pretreatment experiments cannot simulate perforation well. Therefore, a new method was developed to make perforations by hydro jetting the fracturing specimens (300 mm × 300 mm × 300 mm) first. It can achieve specified perforation parameters, including the perforation angle, position, and length. Subsequently, true triaxial hydraulic fracturing experiments were conducted on the conglomerate specimens obtained from the Mahu area. The effects of the acid pretreatment on the fracture initiation and breakdown pressure were investigated by injecting the perforation section of the conglomerate using various acid systems. The study results showed that the perforation made by the new apparatus was extremely close to the perforation on-site. The acid pretreatment effectively dissolved minerals and could decrease the breakdown pressure down to 7.7 MPa. A combination of 6%HF + 10%HCl was recommended for the acid pretreatment in the Mahu conglomerate reservoir. A total of 60 min acid–rock contact time is necessary for sufficient rock dissolution. The mechanism of the acid pretreatment to decrease the breakdown pressure is that the rock dissolution by the acid reduces the rock tensile strength and increases the permeability. The raised permeability increases the fluid pressure of the reservoir near the wellbore so as to reduce the breakdown pressure of the formation. The research results provide technical support for reducing construction difficulty and optimizing parameters in the Mahu Oilfield.

Numerical simulation of ore formation within skarn-type Pb-Zn deposits: Implications for mineral exploration and the duration of ore-forming processes

Skarn-type deposits are typical hydrothermal mineral deposits distributed throughout the world with multiple metal resources and huge economic value. However, their extremely complex forming processes hinder us from further understanding their forming mechanism and exploring their economic potential. This study builds an integrated and simplified model of skarn-type Pb-Zn deposits and applies numerical simulation approach to quantitatively describe the formation of mineralization, analyzing the continuous dynamic changes of the concentrations of generated garnet, diopside and galena/sphalerite within the system. This numerical model includes chemical reactions, heat conduction, fluid-flow, materials migration and diffusion and their complex coupled relationships. The results show that the alterations at the contact of wall rocks and intrusions have clear zoning of garnet and diopside, and the amount of diopside exceeds that of garnet at the distal end of the generated alteration zone; the generation processes of garnet, diopside and galena/sphalerite follows a strict chronological order, controlling the variation of rock porosity; the cooling process of P3 (Fig. 4b) from 700 °C to 170 °C costs 55,000 years, within which the formation of galena/sphalerite merely lasts 30,000 years, meaning that the effective lifespan of Pb/Zn mineralization takes up only 54.54 % of the whole 55,000 years. All these results provide useful information for metallogenic research of skarn-type Pb-Zn deposits as well as magmatic-hydrothermal system. However, the method applied in this research still has limitations, such as the restriction from the single-period magmatic activity, the law of mass action, and the simplified chemical equations. Future development into both mathematical geosciences and geological analytical tests will definitely provide more appropriate calculation models and testing data with higher precision, improving the accuracy and practical significance of numerical simulation of ore formation, and providing more detailed quantitative answers for remaining hot issues related to economic geology research.

Determination of the Rock Contact Lithology of the Nanggulan Formation with the Magnetic Method in the Hargorejo Area of Kulon Progo

The Nanggulan Formation is a formation unit consisting of sandstone, clay, and other sedimentary rocks. Lithological contact between clay and geologically old andesite could indicate an avalanche. The magnetic method in collecting data uses a natural magnetic source with a proton magnetometer. Acquisition data was determined according to the survey design, namely a grid with a distance of 250 meters per point. Data processing to remove noise data, namely noise from magnetic storms, position and altitude, and other natural disturbances. Later, Processing will produce a magnetic anomaly map, which must be separated between local and regional anomalies. This local anomaly will later form the basis for 2.5-dimensional modeling. This 2.5-dimensional modeling can get an overview of lithology, relationships between lithologies, and rock contacts according to the geological model in the field. The modeling results can describe the relationship between the claystone of the Nanggulan Formation and the igneous rocks of the Old Andesite Formation. Its relationship claystone is overlapping Andesite rocks in the Horgorejo Kulon Progo area. This can cause soil movement and landslides if the Andesite rocks experience massive weathering and erosion and if rainfall is high.

Development of Hydrophobic-Modified Nanosilica for Pressure Reduction and Injection Increase in an Ultra-Low-Permeability Reservoir

A low-permeability reservoir contains many fine pore throat structures, which result in excessive injection pressure of the water injection well and difficult water injection in the production process of a low-permeability reservoir. In this study, a new silane coupling agent was synthesized via the ring-opening reaction between dodecyl amine and KH-560 (γ-propyl trimethoxysilane). The modified KH-560 was reacted with nano-SiO2 to synthesize the modified nano-SiO2 as an antihypertensive additive. Fourier infrared spectroscopy, thermogravimetric analysis and laser scattering were used to characterize this modified nano-SiO2. The results show that the particle size of the modified nano-SiO2 is less than 60 nm. The test results of the water contact angle show that the dispersion system can increase the rock contact angle from 37.34° to 136.36°, which makes the rock surface transform from hydrophilicity to hydrophobicity and reduce the binding effect of rock with water. The dispersion test shows that the modified nano-SiO2 has good dispersion stability under alkaline conditions with TX-100 (Polyethylene glycol octylphenyl ether) as the dispersant. The antiswelling test results show that the antiswelling rate of this modified nano-SiO2 is 42.9%, which can efficiently prevent the clay expansion in the formation to reduce the injection pressure. The core displacement test results show that its depressurization rate reaches 49%. The depressurization rate still maintains 46% at a 20 PV water flow rate, indicating that its depressurization effect is remarkable and it has excellent erosion resistance.

Metasomatism at a metapelite–ultramafic rock contact at the subduction interface: Insights into mass transfer and fluid flow at the mantle wedge corner

Metasomatism at a metapelite–ultramafic rock contact at the subduction interface: Insights into mass transfer and fluid flow at the mantle wedge corner

Palaeomagnetism of the Vendian traps of Volyn, southwestern margin of the East European Platform, P. 2: magnetostratigraphy

We present new results of palaeomagnetic studies of the Vendian (Ediacaran) rocks of the Volyn Basalt Province revealed by six boreholes on the NW Ukraine. This is a continuation of previous studies of upper part of the Volyn series described by Bakhmutov et al. [2021]. In the recent works [Shcherbakova et al., 2020; Thallner et al., 2022], the results of palaeointensity determinations of the Volyn series basalts showed the ultra-low dipole moment of Earth’s magnetic field which coincident with other palaeomagnetic data for Ediacaran indicating an extremely weak geomagnetic field. Clear stratification and correlation of the basalt and tuff layers by magnetic parameters allow us to determine the magnetic field reversals throughout the stratigraphic succession of the Volyn series of about 400 m thick. In basalts, tuffs and baked contact rocks, a high-temperature characteristic component of remanent magnetization (ChRM) with all signs of primary magnetization have been isolated. For the directions of inclination of ChRM-components at least six magnetic polarity reversals were revealed. The geochronological ages of rocks is in the range of 580—545 Ma, but the errors in the age estimation are too large for separation of individual formations within the pulses of activity or differentiation of individual eruptions. Therefore the formation time of the entire stratum remains uncertain, and the key issue for interpretation of the magnetic polarity reversal frequency is the duration of accumulation of traps. Two possible interpretations of palaeomagnetic results are considered. In the first, which takes into account different stages of magmatic activity, the time interval of accumulation can be about 10 million years. Then the average frequency of geomagnetic inversions is close to mean for the Phanerozoic. We prefer the other interpretation when the formations of the Large Igneous Provinces have been occurred over a short time interval (e.g. 0.5 Myr). Taking into account the results of palaeointensity estimations for the same samples, which shown the extremely weak geomagnetic field, the hypothesis of the «hyperactivity» of the field with a frequency of at least 12 reversals per one million years on the end of the Ediacaran gain the additional confirmation.

Fluid evolution and metallogenic mechanism of the Xianghualing skarn-type Sn deposit, South China: Evidence from petrography, fluid inclusions and trace-element composition of cassiterite

The Xianghualing Sn-polymetallic deposit is a large skarn-type Sn deposit located in the Nanling polymetallic metallogenic belt, South China. The ore bodies are controlled by NE-trending faults and mainly hosted in the contact of Middle Devonian carbonate rock and granite. The Xianghualing deposit is divided into four mineralization stages, and two stages of Sn mineralization are identified. The mineralization stages from early to late include stage I (prograde stage), stage II (retrograde stage), stage III (cassiterite-magnetite-arsenopyrite-topaz-quartz stage), stage IV (sphalerite-galena-pyrite-chalcopyrite-quartz-calcite stage). Stage II is the initial stage of Sn mineralization where only minor cassiterite precipitates, and stage III is the main Sn mineralization stage where abundant cassiterite precipitates. On this basis, fluid inclusion microthermometry and Raman spectroscopy analyses were carried out for ore and/or gangue minerals at different stages. In addition, trace element composition analysis was also conducted on cassiterite. These data can contribute to reveal the fluid properties, evolution and formation mechanism of Xianghualing deposit. Three types of fluid inclusions were identified in different mineralization stages, including halite-bearing multi-phase inclusions (Type B), liquid-rich two-phase inclusions (Type L) and vapor-rich two-phase inclusions (Type V). Garnet (stage I) contains Type B inclusions and Type V inclusions, with homogenization temperatures and salinities of 511–549 °C, 37.6–48.9 wt% NaCl equiv. and 551–559 °C, 4.0–5.1 wt% NaCl equiv., respectively. Topaz (stage II) contains Type L inclusions with homogenization temperatures of 408–445 °C and salinities of 9.5–12.4 wt% NaCl equiv. Cassiterite (stage III) contains Type L inclusions with homogenization temperatures of 368–417 °C and salinities of 8.7–11.5 wt% NaCl equiv. Quartz (stage IV) contains Type L inclusions with homogenization temperatures of 162–227 °C and salinities of 2.6–5.0 wt% NaCl equiv. The temperature and salinity of the fluid from stage I to stage II decreased significantly, recording intense meteoric water mixing. The temperature of the fluid decreased from stage II to stage III, while the salinity changed little, indicating that, except for minor meteoric water mixing, cooling of fluid is predominant. The temperature and salinity of the fluid from stage III to stage IV continued to decrease, recording the further mixing of meteoric water. From stage II to stage III, the evolution temperature of the fluid is basically consistent with the temperature indicated by trace elements (Nb, Ta, Ti) of cassiterite in the two stages. Fluid mixing may be the predominant mechanism for the minor Sn mineralization occurred in stage II. Fluid cooling may be the predominant mechanism for the abundant cassiterite precipitation in stage III, which is accompanied by redox reactions of Sn (II)-Cl complexes with As (III) and/or CO2 as potential oxidants, and acid neutralization of carbonate rocks. Combined with the cassiterite composition, it is indicated that the ore forming fluid of the Xianghualing deposit mainly derived from the highly evolved granitic magma in the region, and the genesis of cassiterite is consistent with that of typical skarn-type Sn deposits.

РАЦІОНАЛЬНІ ПАРАМЕТРИ КРІПЛЕННЯ ПОЛЬОВИХ ПІДГОТОВЧИХ ВИРОБОК У ЗОНАХ ВПЛИВУ ОЧИСНИХ КАМЕР

Purpose. To develop a methodology for calculating the rational parameters for walling development waies, taking into account changes in the stress state of the massif in the unloading zones of the drawn stopes of the first and second stages of mining. Methodology. To determine the patterns of stress distribution around the fringedrifts of the lying and hanging walls, located at different distances from the contact of the host rocks with the ore deposit, an integrated approach was used, including the analysis and generalization of previous studies, analytical studies of the stress-strain state of the rock mass around development waies, using the energy method and statistical data processing. Results. Studies of changes in the stability of walling development waies in the zones of influence of drawn stopes of the first and second stages of mining made it possible to establish that the stability of fringedrifts is influenced by radial stresses that arise around the drawn stopes. This necessitates taking into account the nature and degree of tension of the rock mass in the zone of unloading drawn stopes, in the process of choosing the type of support for preparatory fringedrifts, the service life of which is equal to the time of mining ore reserves in the level. At the same time, empirical formulas for calculating the magnitude of destruction of a rock mass in the roof of fringedrifts of the lying and hanging walls were obtained. On the basis of which a method for calculating the parameters of the roof bolting of walling development waies has been developed. Scientific novelty. The dependences of the magnitude of the destruction of the rock mass in the roof of the fringedrifts of the hanging and lying walls, depending on the distance to the contour of the ore deposit, the depth of the fringedrifts, and the uniaxial compression strength of the rocks, have been established. Practical implication. A method has been developed for calculating the parameters of the roof bolting of development waies, taking into account the change in the stress state of the array of drawn stopes of the first and second stages of mining. Keywords: iron ore, development way, rock pressure, roof bolting, stress-strain state, drawn stope.

ГЕОМЕХАНІЧНЕ ОБҐРУНТУВАННЯ РОЗРОБКИ ПОТУЖНИХ ТА ВЕЛЬМИ ПОТУЖНИХ ПОКЛАДІВ БАГАТИХ ЗАЛІЗНИХ РУД В УМОВАХ ЗНАЧНИХ ГЛИБИН

Purpose. Improving the quality of the mined ore mass and reducing the operating costs for the extraction of minerals by taking into account the geomechanical state of the ore-rock massif. Methods. A complex method that includes analysis and generalization of previous studies, mine instrumental observations, numerical modeling by the finite element method, analytical studies and statistical data processing. Results. It has been established that the key factors influencing the choice of stable parameters of the structural elements of the stope panels of the stope blocks are: the parameters of the stress-strain state of the stope horizon, determined by the depth of mining, the thickness and dip of the ore deposit, the shape and size of the shear zone of host rocks; the procedure for working out stope panels according to the thickness and strike of the stope block; intensity of development of stocks of compensation spaces. At the same time, the stability of transport drifts and junctions with orts-arrivals depends on the length of their location before the contact of the host rocks of the lying side with the ore deposit, the thickness of the ore deposit and the geological macrostructure of the rocks of the sides, as well as the number of contacts of the stope panel with collapsed host rocks. The maximum possible stable parameters of exposures of compensation chambers, which are formed by explosive breaking of borehole charges, depending on the thickness of the ore deposit and the location of their center from the rocks of the hanging side, have been established. Scientific novelty. For the depth range of 1200–1500 m, the dependences of the stress distribution across the pull of the ore deposit on the horizon of mining have been obtained. Power-law dependences of the equivalent span width of the bottom of the stope panel, equivalent spans of stable horizontal and vertical outcrops on the location of the center of the stope panel along the thickness of the ore deposit on the host rocks of the hanging side have been established. Practical significance. The obtained dependencies allow choosing the most rational technological schemes for the mining of rich iron ore deposits, taking into account the stress-strain state of the ore-rock mass and the location of the stope panel according to the thickness of the deposit.

Alteration at the Base of the Siccar Point Unconformity and Further Evidence for an Alkaline Provenance at Gale Crater: Exploration of the Mount Sharp Group, Greenheugh Pediment Cap Rock Contact With APXS

AbstractChemical data acquired by Curiosity's Alpha Particle X‐ray Spectrometer during examination of the contact between the upper Mount Sharp group and overlying Stimson formation sandstones at the Greenheugh pediment reveal compositional similarities to rocks encountered earlier in the mission. Mount Sharp group strata encountered below the Basal Siccar Point group unconformity at the base and top of the section, separated by &gt;300 m in elevation, have distinct and related compositions. This indicates enhanced post‐depositional fluid flow and alteration focused along this contact. Sandstone targets exposed immediately above the unconformity have basaltic compositions consistent with previously encountered eolian Stimson formation sandstones, except at the contact, where they show the addition of S. Resistant sandstone outcrops above the contact have higher K, Mn, and Na and lower Ni concentrations that primarily reflect changes in provenance. They are compositionally related to cap rock float blocks encountered as Curiosity climbed through the Mount Sharp group, and Bradbury group sandstone outcrops. The higher K, pediment sandstones are interpreted to have a similar provenance to some Bradbury group sandstones, further evidence for widespread, alkaline source rock within and/or in the vicinity of Gale crater. The Bradbury and Siccar Point groups may both be younger than the Mount Sharp group. Alternatively, an alkaline source area in and around Gale crater has been eroded by both water and wind at different times (both before and after deposition of the Mount Sharp group), during the evolution of the crater and its infill.