Consumption Of Fossil Fuels Research Articles

Operando Reconstruction of CuO/SnO2 Nanosheets Promotes the Syngas Production from the Electrochemical CO2 Reduction Reaction.

Electrochemically reducing CO2 (CO2RR) to high-value chemical products is recognized as a promising route to simultaneously reduce the consumption of fossil fuels and carbon emission. The fabrication of syngas with an appropriate H2/CO ratio by CO2RR has been widely studied, but the dynamic evolution of the catalyst is still ambiguous. Herein, the reconstruction of CuO/SnO2 nanosheets (NSs) with a heterojunction structure in the CO2RR process was reported by an in situ X-ray diffractometer technique. The products of the CO2RR on the optimized CuO/SnO2 NSs are CO and H2, achieving a nearly 100% total Faraday efficiency. Moreover, the resulting syngas is maintained at a constant 2:1 ratio of H2/CO over a wide potential of -0.8 to -1.2 V versus the reversible hydrogen electrode. Importantly, the detailed characterizations show that Cu2+ is reduced to Cu during the CO2RR process, while the valence state of Sn remains stable. This study presents strong experimental support for the dynamic evolution process of electrocatalysts in other energy conversion fields.

Towards cleaner desalination systems utilizing waste heat: a bibliometric analysis

Water scarcity is a global issue facing the coming generations. Desalination is a dependable, nonconventional freshwater method. However, desalination is an energy-intensive water treatment method. The primary energy source used to power various desalination processes for thermal and electrical energy consumption is fossil fuels, such as coal, oil, and gas. The widespread use of fossil fuels has been linked to climate change and global warming, leading to numerous demands to reduce their usage and energy utilization. Waste heat has an excellent potential for energy recovery that can reduce the consumption of fossil fuels. This research study has been conducted to evaluate related waste heat desalination literature with data analysis, bibliometric, and clustering methods. Based on articles published between 2013 and 2023, the current study analyzed existing trends, distribution of publication subjects, journals' performances, countries' collaborations, affiliations' performances, most cited publications, authors' contributions, keyword analysis, and future perspectives on waste heat desalination systems. The findings showed that the most active journal in this field is Desalination, with 133 publications and 6332 citations. China led in publications with 242, while the United States topped the list of citations with 3598. Also, King Abdullah University of Science and Technology in Saudi Arabia published 50 documents. The top 10 institutions in this field of research are in the Middle East and North Africa (MENA) region and Asia, particularly in Saudi Arabia, China, Iran, Egypt, and Singapore. Moreover, the most frequently used terms are analyzed and clustered into three main topics. The top 3 clusters are solar-powered desalination technologies, membrane-powered desalination technologies, and power cycles driving desalination technologies.

Fossil Fuel Consumption, Meat Production, Forest Cover, and Greenhouse Gas Emissions in Indonesia

Fossil Fuel Consumption, Meat Production, Forest Cover, and Greenhouse Gas Emissions in Indonesia

Thermogravimetric Analysis of Combustion of Semi-Coke Obtained from Coniferous Wood and Mixtures on Their Basis

Coal remains one of the most used solid fuels for heat and electricity generation but burning coal releases large amounts of CO2 into the urban atmosphere in addition to harmful substances. In order to reduce the consumption of solid fossil fuels, it is necessary to search for fuels capable of replacing coal in terms of its thermal and environmental characteristics. One of the best alternative fuels is biomass, which is considered carbon neutral, but its thermal characteristics are worse than those of solid fossil fuels. In this work, an alternative to coal was studied for the first time, which was semi-coke, obtained by gasification at a temperature of 700–900 °C, the heat of combustion of which turned out to be higher than that of biomass before thermal treatment by 75%. We also studied fuel mixtures based on the resulting semi-coke. The aim of the work is to determine the main characteristics of combustion of semi-coke obtained from coniferous wood and mixtures based on them. The method of thermogravimetric analysis in oxidising medium at a heating rate of 20 °C/min was applied for the research. According to the results of this analysis, the ignition and burnout temperatures were determined, the combustion index was determined, the duration of coke residue combustion was determined, and synergetic interactions between the mixture components influencing the combustion characteristics were established. It was found that the ignition temperature of semi-coke is more than 50% higher than that of biomass and the burnout temperature is 10% higher. Adding 50% of biomass to semi-coke increases the combustion index by more than 30% and decreases the ignition temperature and burnout temperature. The mixture components synergistically interact with each other during combustion to reduce the value of maximum mass loss rate. It was found that the atomic ratios of O/C and H/C in semi-coke are lower than in biomass before gasification.

A Review of the Sustainability of Helium: An Assessment of Its Past, Present and a Zero-Carbon Future

Helium, as a by-product of the natural gas industry, will be impacted by the decline in consumption of fossil fuels as the world moves towards net-zero carbon emissions. In September 2022, all assets relating to the US government’s previous helium industry were sold. In the US, helium is now only available from private suppliers. In June 2022, Russia banned the export of helium to “unfriendly” countries, highlighting the geopolitical issues surrounding the industry. In the past, helium was popularized, and the industry was supported by its military applications (filling dirigible aircraft, welding fighter jets and purging rocket engines). It also plays an important role in supporting present-day technologies (e.g., MRI machines and spectroscopy) and will also be important for a high-tech future (e.g., in quantum computing, fusion power, and space exploration). Shortages of helium will inevitably cause skyrocketing prices and consequently lead to significant challenges for research and development (as has happened in the past) and technological progress, as well as a slowdown in world economic growth and prosperity. Anticipated declines in natural gas production, associated with moves towards net-zero carbon emissions targets, make helium less accessible. While this is problematic for industry in the short term, it perhaps preserves some low entropy helium within the ground, making it more accessible to future generations. Given anticipated limitations to the future supply of helium, technological developments are currently focused on a few areas: the replacement of helium by other gases in industrial applications, changing technological approaches to not require helium, and reducing the cost of obtaining helium from the atmosphere. This paper explores the past, present and future of helium, focusing on the sustainability of the helium industry.

Furfural production from xylan using a Pueraria Residues carbon-based solid-acid catalyst.

The conversion of biomass into high value-added platform compounds is an important method of biomass utilization. The conversion of hemicellulose represented by xylan into furfural can not only reduce the consumption of fossil fuels, but also promotes the development and utilization of non-edible biomass resources. In this study, a bifunctional solid-acid catalyst prepared from agricultural and forestry waste Pueraria (P. eduli) Residues was used to convert xylan into furfural in a biphasic system. In this study, P. eduli Residues was used as raw material to prepare a P. eduli Residues-based carbon solid-acid catalyst (PR/C-SO3H-Fe) by one-step sulfonation carbonization and impregnation. The catalyst catalyzes the conversion of xylan to furfural in a biphasic system (2-methyltetrahydrofuran/water). The physicochemical properties of the catalysts were characterized by X-ray powder diffraction, scanning electron microscopy, differential thermogravimetric analysis, Brunauer-Emmett-Teller surface area, Fourier transform infrared spectroscopy and ammonia temperature-programmed desorption. Subsequently, the experimental conditions were studied and optimized, such as metal species, iron ion concentration, reaction time and temperature, volume ratio of organic phase to water phase and ratio of substrate to catalyst. The results showed that under conditions of 160 °C, 50 mg catalyst, 100 mg xylan and 7 mL reaction solvent, the yield of furfural could reach 78.94% after 3 h of reaction. This study provides an effective research method for the conversion of xylan into furfural, and provides a reference for the catalytic conversion and utilization of hemicellulose in agricultural and forestry biomass. It also provides a feasible method for the resource utilization of agricultural and forestry waste. © 2024 Society of Chemical Industry.

The Function of OPEC in International Climate Change Law: the Route Taken to COP 28 and the Route Ahead

Abstract Since the consumption of fossil fuels is the main source of GHGs emissions and consequently climate change, the approach of OPEC to climate change is very important. The recent position of OPEC regarding the proposal to phasing out fossil fuels at COP 28 in 2023 showed how significant its approach can be in the evolution process of this regime. The question is what function OPEC has had and should have in the evolution of the climate change law. The results of this research show that in the first encounter of OPEC with the issue, due to the inherent conflict of the economic interests of member states with the goals of the climate change regime, it adopted an obstructive approach. But gradually, due to the global acceptance of the regime and comprehensive consensus regarding the scientific certainty of the threats of climate change, OPEC, reluctantly and inevitably, adjusted its former opposite position to some extent through its active participation in climate negotiations. However, in light of the increasing trend of GHGs emissions by the member states, which indicates the inability of OPEC to align the practice of its members with the goals of climate change, and the recent strong position of OPEC regarding the elimination of fossil fuels in COP 28, concerns have been raised about the future function of OPEC in the climate change legal regime. To play a constructive role in the future and use the available opportunities to reduce the climate change damage to the interests of the member countries over the long term, it should adopt initiatives such as functional changes and integration of climate issues into its strategies and projects in member states to be a supportive partner in the fight against climate change.

Dominant factors for solar energy choice by Manufacturing Micro, Small and Medium Enterprises (MSMEs’) in Tanzania

Energy demand by manufacturing industries has increased significantly whereby fossil fuels consumption is dominant. Increased concern over resource depletion, and environmental impacts, suggests future dependence on renewable energies. Tanzania is blessed with abundant solar energy and its exploitation may contribute to increased energy access. Despite the paybacks of renewable energy, studies on the exploration of the dominant factors for energy choice by manufacturing MSME’s are scarce. This study explored the dominant factors for solar energy choice by manufacturing MSME’s. Questionnaires were used to collect data (n = 236) from employees in manufacturing MSMEs’ whereby descriptive and multinomial probit (MNP) model were employed to establish the dominant factors. The findings of MNP revealed that not expensive energy, and other factors (e.g., availability of solar appliances) have significant influence on solar PV use, while the adoption of hydro-electricity was significantly influenced by not expensive and advised to use energy. Easy access, and not expensive have significant influence on fossil fuels. The Confirmatory Factor Analysis (CFA) results revealed that all factors (i.e., environmental, social, and economic) have significant influence on workers perception of sustainable manufacturing. These findings provide critical information for policy making instruments in Tanzania for informed decisions in the formulation of policies in the utilization of renewable energy technologies.

The future of clean energy: Agricultural residues as a bioethanol source and its ecological impacts in Africa

This study presents a comprehensive analysis of Africa's potential to produce bioethanol from agricultural residues and its environmental impact. The relentless consumption of fossil fuels and associated environmental challenges necessitate a shift toward sustainable energy sources, with bioethanol emerging as a promising alternative. This study evaluates the capacity for bioethanol generation from agricultural residues in Africa, considering its land, water, and carbon footprints. Based on data from 85 primary agricultural residues across Africa, approximately 102.256 Gt of fresh agricultural residue is estimated to be available in Africa, translating to approximately 62.117 Gt of dry-weight material. This significant capacity indicates a substantial potential for bioethanol production in Africa, corresponding to a net output of 207.127 EJ. The coproduction potential of bioethanol and electricity are also highlighted, with electricity accounting for 8.016 % of the total net bioethanol energy production. However, the environmental impact of bioethanol production varies across African nations, suggesting the need for optimization and sustainable practices. Additionally, the study discusses the challenges encountered in the bioethanol sector, including the sustainability of production, emission reduction, technological and financial constraints, and the broader context of biomass usage. In conclusion, although bioethanol production from agricultural residues is a promising alternative for Africa's energy sector, it should be realized only after a multifaceted assessment involving technological, economic, policy, and environmental considerations.

The contribution of clean energy consumption and production to sustainable economic development: New insights from the PSTR model

Massive consumption of fossil fuels has posed significant threat to sustainable development. Therefore, clean energy is an urgent requirement for sustainable economic development (SED). There is no comprehensive assessment of the relationship between clean energy and the SED, signifying a research gap in understanding the non-linear effects between them. This study fills this gap by calculating the SED index for China and using a panel smoothed transformation regression model. The findings reveal that the impact of clean energy development and utilisation on SED is characterised by non-linearity, which manifests in two key aspects: (1) Clean energy consumption (CEC) positively influences SED, with its impact strengthening alongside improvements in industrial structure optimisation and economic growth. Notably, the threshold values for the industrial optimisation level, industrial structure level, and economic development are 1.0390, 0.4667, and 43730, respectively. (2) The relationship between clean energy production (CEP) and SED follows a U-shaped curve; once economic development surpasses 38,588 units, CEP transitions from a negative to a positive influence on SED. This study provides valuable insights into comprehensive measurement of SED, offering guidance for countries worldwide to formulate context-specific energy policies aligned with their respective industrial structures and stages of economic development to foster SED growth.

Demise of fossil fuels part I: Supply and demand

According to United Nations , the world needs to reduce the emission of CO2 and other global warming gases by 45 % by 2030 and to negligible amount by 2050. According to UN, this is necessary to keep the goal of keeping earth temperature not exceeding 1.5 °C compared to pre-industrial level temperatures.To achieve this objective means reducing the fossil fuel consumption. Fossil fuels are largely responsible for emitting CO2; therefore, without significant reduction in fossil fuels consumption by 2050, the net zero emission by 2050 is not possible.One argument advanced in support of reducing fossil fuels consumption is limited supply. Using the principle of “Peak Oil Theory,” proponents state that fossil fuels is a limited resource and the world will simply run out of it. Based on the available data, we demonstrate that supply of fossil fuels is relatively abundant, and we will not run out of fossil fuels in near term. Using shale formations as an example, we demonstrate how the success of drilling horizontal wells with hydraulic fractures have significantly increased the oil and gas resource available for exploitation. To reduce fossil fuels demand, the available solutions include improving energy efficiency, reducing subsidies on fossil fuels, imposing carbon tax and life choice changes. We discuss some of those alternatives. Fossil fuel supply is relatively abundant and only possible solution to reduce the consumption is to reduce the demand. By comparing developed countries' consumption with developing countries’ consumption, we see a pathway where growth in GDP can be achieved without significant increase in fossil fuels consumption. Because of efficiency gains in energy usage, GDP in developed countries continues to grow without increase in fossil fuels consumption. Faster we reach the efficiency stage in developing countries, easier it would be reduce the fossil fuel consumption in the world.

Thermal management of sodium-oxygen-hydrogen (Na-O-H) thermochemical water splitting for sustainable hydrogen production

Owing to environmental problems caused by the consumption of fossil fuels and the growing global demand for energy, interests in usage of hydrogen as a green energy carrier has grown. In particular, water is considered a prospect source for green hydrogen production. In this paper, a three-step sodium-oxygen-hydrogen (Na–O–H) thermochemical cycle, which is a newly developed cycle that can operate between 400 and 500 °C is implemented. Also, low number of steps, which results in less system complexity and easier system design is another advantage of the Na–O–H thermochemical cycle. In the first step of this study, a basic model of the three-step pure Na–O–H cycle is modeled in order to produce 1 kg/s of hydrogen. Moreover, output data from basic modeling is used for cycle energy management. Then, heat recovery is performed within the cycle streams to reduce the external energy demand and make the Na–O–H cycle more feasible. To achieve this objective, pinch method, which is an effective method for designing and optimizing plants is used. Several heat exchanger network designs have been developed and compared from different aspects. Finally, a design with the least heat requirement among others is selected and optimized based on total annualized cost objective function to introduce the optimum final design exchanger network. As a result of this work, it is found that using the final optimized design, external heating loads accounted for just 5.8% of the total load, while external cooling loads accounted for 19.3% of the total load. This implies that the Na–O–H thermochemical cycle recovered 74.7% of the energy required for heating and cooling of the streams. The implementation of the proposed heat exchanger network design boosts the overall energy efficiency of the Na–O–H thermochemical cycle. Using final heat recover scheme the overall efficiency of the cycle increased from 45.36% to 52.86%, representing an impressive 7.50% improvement. This significant achievement underscores the pivotal role of this study in developing an effective and optimized model for the Na–O–H thermochemical cycle, which holds great promise for future applications.

“Effect of improving sustainable transportation indicators on quality of life in Tehran”

Although transportation has a fundamental role in economic development and the urban life cycle, its negative consequences, such as air pollution, global warming, traffic, accidents, destruction of natural habitats, significant consumption of fossil fuels, and noise pollution, are non-negligible. These adverse effects have reduced citizens' quality of life (QOL). To decrease the complications caused by urban transportation, sustainable transportation (ST) has been recommended, which simultaneously considers three dimensions (environmental, social, and economic). Like other big cities, the metropolis of Tehran, with a population of over nine million people, is experiencing many challenges due to the lack of integration in the transportation network despite the presence of private transportation (PRT) and public transportation (PT). Air pollution, traffic, accidents, and travel time have affected the reduction of (QOL) in Tehran city. This research goal is to design an integrated model (SD) using indicators (ST) for Tehran transportation to evaluate the impact of these indicators on the (QOL) of residents of Tehran. This model using widely used (ST) indicators are designed and simulated in vansim software with four distinct scenarios. The simulation showed that with the continuation of the current conditions, the performance of ninety percent of indicators will worsen, and the (QOL) in Tehran will decrease (-60%). The best performance of the indicators is related to the simulation of the fourth scenario (doubling the price of gasoline and the capacity of (PT) and reducing the cost of access to (PT) by 50%, which improves the 93% performance of indicators and the (QOL) in Tehran by +206% (up from -60 % to +146%) compared to the current conditions.

Design and analysis of zero-energy and carbon buildings with renewable energy supply and recycled materials

Given the notable consumption of fossil fuels, buildings prioritize their energy utilization. This paper’s aim is to explore the primary strategies in attaining zero-energy and zero-carbon buildings. The investigation employs two specialized software programs: Design Builder, which analyzes energy usage, and PV Syst, which evaluates renewable energy requirements. The study is conducted in Fort Myers, USA, and Dubai, UAE, leveraging diverse regional and climate discrepancies, and real-world data on zero-energy and carbon constructions for comparison and validation. Within the Design Builder software, the research examines four strategies, with the first serving as the realistic baseline. By implementing the second strategy, utilizing internal shading devices such as Shade Roll, a reduction of 376 kWh in Fort Myers and 591 kWh in Dubai is achieved. The third strategy encompasses the deployment of blind-type internal shading systems, resulting in reductions of 212 kWh in Fort Myers and 348 kWh in Dubai. The fourth strategy involves integrating renewable energy via photovoltaic panels, injecting 323.5 kWh in Fort Myers and 2237 kWh in Dubai into the power grid for lighting purposes. Furthermore, 3200.5 kWh and 4722 kWh of energy are respectively injected into the grid for heating in Fort Myers and Dubai. Cooling, however, necessitates additional energy from the grid, amounting to 2243.94 kWh in Fort Myers and 9211.64 kWh in Dubai. In the pursuit of zero-carbon goals, the implementation of suitable low-carbon recycled materials, in place of primary building materials, reduces carbon dioxide emissions from 79 tons to 7.315 tons in Fort Myers and 7.038 tons in Dubai. By employing appropriate materials, the zero-carbon objective is attained.

Analyzing the Impact of Internet Use on Peer Effects in Farmers’ Adoption of Clean Energy: Strengthening or Weakening?

Enhancing farmers’ adoption of clean energy is crucial for promoting sustainable rural development and ecological environmental protection. It not only reduces the consumption of traditional fossil fuels, greenhouse gas emissions, and environmental pollution but also optimizes the structure of rural energy consumption, improves farmers’ quality of life, and supports the goal of building a green countryside. This paper investigates the impact of internet use on farmers’ adoption of clean energy and the associated peer effects, further exploring how internet use influences these peer effects. The analysis is based on data from the 2018 and 2020 waves of the China Family Panel Studies (CFPS). The study’s findings reveal that (1) farmers’ adoption of clean energy exhibits a significant peer effect, and internet use also has a significant positive impact on this adoption. Both the peer effect and internet use effectively enhance farmers’ clean energy utilization, a conclusion that holds even after robustness checks. (2) Internet use significantly strengthens the peer effect, particularly when it is used for social and entertainment purposes, where this reinforcing effect is most pronounced. (3) The peer effect, the impact of internet use on clean energy adoption, and the strengthening of the peer effect by internet use vary according to farmers’ geographical location and household income. These findings provide valuable insights and recommendations for improving policies aimed at promoting clean energy adoption among farmers, ultimately fostering its broader diffusion and application in rural areas.

Optimizing solar collector through constructal design of Y-shaped networks with power-law nanofluid flow

Solar energy is a plentiful and renewable resource; therefore, its use through clean energy technologies is necessary to reduce the consumption of fossil fuels and their consequent impact on the environment. Solar thermal energy can be harnessed to collect thermal energy through solar collectors for domestic or industrial use. In this work, a Y-shaped duct network was developed for a solar collector with a disc-shaped body. The shape and size of the network were defined using the constructal design method to harvest greater thermal energy from exposure to irradiance. For this purpose, the working fluid was a nanofluid composed of nanoparticles and a base fluid with non-Newtonian behavior, as described by the power-law model. The properties of the nanofluid were described using theoretical models that depend on the volume fraction of the nanoparticles in the base fluid. The aspect ratio of each element in the network was defined under the condition of minimum thermal resistance. For the shear-thinning nanofluid with a volume fraction of 0.04, the thermal resistance was reduced by 5.5% with an aspect ratio 5.8% lower than that of the pure base fluid. The minimum thermal resistance of the Y-shaped network arrangement occurs for shear-thinning fluids, whereas thermal resistance increases for shear-thickening fluids. This effect can be observed at different levels of branching and in pumping power. Results show that increasing the volume fraction of the nanofluid and base fluid with shear-thinning behavior aids in achieving minimal thermal resistance more easily with a smaller network. The above offers new design options for devices optimized to improve solar harvesting and thermal management, through shape, structure and rheological characteristics.

Thermal Energy Resource Potentials of the Kara-Bogaz-Gol Gulf as a “Solar Pond”

Introduction. The use of environmentally-friendly engineering systems including solar energy technologies makes it possible to reduce energy costs and therefore to lower production costs and anthropogenic stress on the environment.Aim of the Study. The authors used innovative techniques to assess the thermal resource potential of solar radiation, to analyze the salt deposits of the Kara-Bogaz-Gol Gulf as thermal accumulators for the development, introduction and use of solar thermal technologies and to justify the technical and economic feasibility of their use in engineering systems in the Kara-Bogaz-Gol Gulf (Caspian region).Meterials and Methods. The study design is based on systematic theoretical calculations of the gross, technical, economic and ecological potentials of solar radiation taking into account environmental conditions. For calculating there were used the methods of mathematical modeling of heat and mass transfer processes in active solar energy systems when converting solar energy into thermal energy in the salty reservoir of the Kara-Bogaz-Gol Gulf as a “solar pond”.Results. There have been assessed the solar energy characteristics for the introduction of various engineering storage systems and technologies. There have been determined the results of energy storage on the reservoir salt surface during the day: in winter – 1 009.0 W/m2 per day, in summer – 1 574.7 W/m2 per day. It has been proven that the potential of solar energy conversion into thermal energy varies from 40 to 70% depending on the season. Aaccording to theoretical calculations, the solar pond efficiency in winter is 11.4% and in summer – 14.6%. In summer, there was measured the average temperature on the salt surface of the reservoir bottom, it ranges from 55.04 to 79.8 ºC, in winter from 20.0 to 25.6 ºC.Discussion and Conclusion. The results obtained can be used for strengthening energy security, developing energy systems and producing autonomous thermal power devices based on solar energy that will reduce the energy consumption of fossil fuels and improve the environmental situation in the region. The materials of the article can be used in preparing design estimates and feasibility study for developing various solar energy systems and technologies in the Caspian region.

Assessing the carbon footprint of soybean transportation in Brazil: a network equilibrium model approach.

Brazil has historically invested few resources in its transport infrastructure, leaving gaps and reducing its efficiency. The country presents a high dependence on road transport, which results in increased operational costs and higher greenhouse gas (GHG) emissions. Consequently, the performance of cargo transportation in Brazil has been deteriorating, accompanied by a rise in the consumption of fossil fuels and noteworthy levels of GHG emissions. This article assesses the carbon intensity of soybean transport operations within Brazil. Utilizing a network equilibrium model, this study estimated the soybean transportation flows that minimize the total cost of transporting this product across the origins and destinations within the grain handling system. The modeling also calculated the GHG emissions in transportation. The results show that the transportation of soybeans produced 2.74 million tonnes of CO2 equivalent annually, with road transport accounting for 81.7% of these emissions. The state of Mato Grosso, responsible for 44.08kg CO2 equivalent per tonne of soybeans transported, contributed almost 49% of the total emissions due to the extensive distances involved. In contrast, states like Paraná and Rio Grande do Sul, located closer to southern ports, exhibited the lowest emissions, with rates of 11.55kg CO2 eq/t and 12.52kg CO2 eq/t, respectively. The analysis highlights the significant potential for reducing GHG emissions by increasing the use of rail and barge transport, particularly in high-emission regions such as Mato Grosso.

Nanosized hyperbranched cobalt and metal-free phthalocyanine intercalated with Pd–C matrix using PVA-TEOS as binder for admirable supercapacitor properties

The expanding global economy resulted mainly from consuming fossil fuels, which are scarce and cause prodigious environmental harm. Mankind is shifting towards sustainable, efficient and clean energy sources known as green energy. The storage of green energy is an urge of time, to fulfil the energy requirements. Supercapacitors are gaining popularity in the field of energy storage due to their excellent safety, cost-effectiveness, and environmental friendliness. The forthright strategy of using a nitrogen-rich phthalocyanine macrocycle as a nanosized particle is to increase surface area resulting in a high specific capacitance. Herein, an innovative approach has been made by synthesising nanosized hyperbranched metal-free/Co-Phthalocyanine characterized by various analytical and spectroscopic techniques. The morphology of the composite was confirmed through physicochemical characterization like BET, SEM, XRD and electrochemical features were studied through cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The electrode modification was carried out using the binder Poly (vinyl alcohol)-Tetraethyl orthosilicate (PVA-TEOS) crosslinked hybrid solution. The intercalated nanosized palladium on carbon matrix with HBCoPc and HBPc at different ratios enhanced the performance of capacitance. Amongst all the ratios, HBCoPc: Pd–C with 30:70 ratio has demonstrated superior specific capacitance of 824.25 F g−1 at 0.5 A g−1. Additionally, the fabricated electrode of HBCoPc: Pd–C and HBPc: Pd–C has exhibited good capacitance retention of 84.03 % and 81.01 % over 5000 cycles, respectively. This work delivers a promising approach towards the development of high-performance supercapacitors using metal phthalocyanine/metal-carbon composites as a new way to manufacture devices for conversion and energy storage.

Investigating the Relationship between Urbanization and Air Pollution Using Google Earth Engine Platform: A Case Study of Istanbul

Rapid population growth in megacities such as Istanbul has led to various effects, such as industrialization, urbanization, loss of green areas, increasing vehicle traffic, and higher consumption of fossil fuels. These reasons, along with many other environmental factors, contribute to the rise of air pollution in urban life. This study aimed to examine the relationship between urbanization and air pollution in Istanbul. For this purpose, land cover maps covering Istanbul province were produced using Landsat-5 (TM), Landsat-8 (OLI), and Sentinel-2 (MSI) images for the years 1996 to 2021 at three-year intervals on the Google Earth Engine platform. Land cover for classification purposes was divided into five different classes: forest, water surface, urban area, and bare land, and classified using a random forest machine learning algorithm. To examine the impact of this urban area growth on air pollution, in the second step of the study, the column number density values of Sentinel 5P (TROPOMI) data for SO2, NO2, CO, and O3 gases for 2019, 2020, and 2021 were analyzed. The averages of the data from 39 air pollution monitoring stations across Istanbul were also examined. According to this classification, the urban area expanded from 491 km2 in 1996 to 1222 km2 by 2021. Considering the total surface area of Istanbul province, the urban area, which was 9% in 1996, reached 23% by 2021. The TROPOMI values were calculated as follows: the average column number density values for SO2, NO2, CO, and O3 were 0.0003538 mol/m², 0.0339514 mol/m², 0.0000984 mol/m², and 0.1453515 mol/m², respectively. Similarly, the gas concentrations of SO2, NO2, CO, and O3 measured from the ground stations were calculated as 6.603 µ/m3, 786,815 µ/m3, 43.763 µ/m3 and 45.773 µ/m3, respectively. Correlations between urbanization and TROPOMI values revealed a positive correlation of 0.39, 0.02, and 0.80 for SO2, NO2, and CO gases, while a negative correlation of 0.25 was found for O3 gas. The study also examined correlations between TROPOMI and ground station measurements, resulting in positive correlations of 0.55, 0.66, and 0.16 for SO2, NO2, and CO gases, respectively, while a negative correlation of 0.05 was found for O3 gas. Based on these findings, among the air pollutants studied both through TROPOMI and ground station data, the highest correlation was observed for CO gas.