ABSTRACT The continuous quest for renewable, efficient, and clean energy sources has led to significant advances in the field of biodiesel production. Hydrogenated catalytic biodiesel (HCB) seems to be a promising option among various renewable biodiesel fuels which can be obtained from waste cooking oil. However, its extreme ignitability limits its application in existing engines. Therefore, a blend of n-butanol and HCB has been proposed in the present study, aiming to explore the spray combustion and soot formation behavior of these blends as a step toward the best possible utilization of this blend in engine. The objective was to examine the impact of adding n-butanol to HCB fuel on spray combustion and soot particles. A new skeletal chemical kinetic model of HCB/n-butanol blend was introduced and validated through measured data reported in the literature. Numerical studies have been performed in a constant volume combustion chamber under reactive spray environments. The simulation results concluded that, blending 20%, 40%, and 60% n-butanol with HCB fuel increased the heat release rates by 31.6%, 47.8%, and 87%, respectively. Furthermore, introducing a 20% of n-butanol into HCB fuel resulted in a 35.7% increase in ignition delay time and a 35.3% increase in flame liftoff length. These results demonstrated the reactivity of n-butanol/HCB mixture experienced a decrease when increasing the n-butanol fraction in the blend, while the fuel atomization was improved. The simulation results also demonstrated a notable reduction in the equivalence ratio when the n-butanol addition ratio was increased, which was a result of the entrainment effect that enhanced the mixing of fuel spray and surrounding fresh air. The simulation results also demonstrated that, adding 20%, 40%, and 60% n-butanol to HCB fuel resulted in a 25%, 43%, and 50% reduction in soot mass of HCB, respectively. This was mainly attributed to the less amount of C2H2, A1, and A4 species with n-butanol addition. Consequently, this sequential reduction leads to suppression of PAHs growth, nucleation, surface growth, and soot coagulation. Besides, a longer flame length resulting from the increased blending ratio of n-butanol could also have an additional soot suppression effect by improving air-fuel mixing and thus suppressing the overall soot mass.
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