Scaling Considerations Research Articles

Preliminary thermal-hydraulic deterministic safety analysis of an in-vessel LOCA for the DTT facility

The DTT (Divertor Tokamak Test) facility is a new experimental tokamak under development by an Italian consortium in cooperation with several high-standard European laboratories. The ENEA division FSN-SICNUC is involved in the project for carrying out deterministic safety analysis of postulated accidents. In the first year of activity, it has been analyzed an In-Vessel LOCA (IVLOCA) scenario. The IVLOCA scenario selected is caused by a break in the divertor’s cassette cooling tubes with the consequent release of coolant inside the Vacuum Vessel (VV). The best estimate thermal-hydraulic system code TRACE, developed by USNRC, was selected to conduct the preliminary thermal-hydraulic analysis of this accident. DTT is currently under design, so not all the data are frozen. Therefore, based on some engineering assumptions and scaling considerations from similar facilities, the nodalization of DTT VV was developed using the three-dimensional TRACE component “VESSEL”. Then, a sensitivity analysis was carried out to simulate the break and the consequent water injection in the VV. This was done to compare the system behavior and test different nodalization approaches. Subsequently, the data of the DTT divertor cooling system were used to run additional simulations. The results allow to compare different nodalization approaches and to have a preliminary estimate of the pressure peak and temperature behavior in the VV for an IVLOCA. Finally, a first uncertainty analysis was carried out using the DAKOTA toolkit, coupled with TRACE code in SNAP. Two uncertain input parameters were selected: the rupture area of a cooling divertor tube and the temperature of the divertor coolant. The uncertainty analysis allows having a wider spectrum of system behavior and a preliminary insight on the dispersion of the VV pressure, selected as figure of merit. This paper aims to show the results of this preliminary analysis, characterizing the phenomena that occurred during the selected transient.

Multi-scale effects of habitat loss and the role of trait evolution.

Habitat loss (HL) is a major cause of species extinctions. Although the effects of HL beyond the directly impacted area have been previously observed, they have not been modelled explicitly, especially in an eco-evolutionary context. To start filling this gap, we study a two-patch deterministic consumer-resource model, with one of the patches experiencing loss of resources as a special case of HL. Our model allows foraging and mating within a patch as well as between patches. We then introduce heritable variation in consumer traits related to resource utilization and patch use to investigate eco-evolutionary dynamics and compare results with constant and no trait variation scenarios. Our results show that HL in one patch can indeed reduce consumer densities in the neighbouring patch but can also increase consumer densities in the neighbouring patch when the resources are overexploited. Yet at the landscape scale, the effect of HL on consumer densities is consistently negative. Patch isolation increases consumer density in the patch experiencing HL but has generally negative effects on the neighbouring patch, with context-dependent results at the landscape scale. With high cross-patch dependence and coupled foraging and mating preferences, local HL can sometimes even lead to landscape-level consumer extinction. Eco-evolutionary dynamics can rescue consumers from such extinction in some cases if their death rates are sufficiently small. More generally, trait evolution had positive or negative effects on equilibrium consumer densities after HL, depending on the evolving trait and the spatial scale considered. In summary, our findings show that HL at a local scale can affect the neighbouring patch and the landscape as a whole, where heritable trait variation can, in some cases, alleviate the impact of HL. We thus suggest joint consideration of multiple spatial scales and trait variation when assessing and predicting the impacts of HL.

Recent advances in CO2 reduction with renewable reductants under hydrothermal conditions: towards efficient and net carbon benefit CO2 conversion.

The ever-growing atmospheric CO2 concentration threatening the environmental sustainability of humankind makes the reduction of CO2 to chemicals or fuels an ideal solution. Two priorities are anticipated for the conversion technology, high efficiency and net carbon benefit, to ensure the mitigation of the CO2 problem both promptly and sustainably. Until now, catalytic hydrogenation or solar/electro-chemical CO2 conversion have achieved CO2 reduction promisingly while, to some extent, compromising to fulfill the two rules, and thus alternative approaches for CO2 reduction are necessary. Natural geochemical processes as abiotic CO2 reductions give hints for efficient CO2 reduction by building hydrothermal reaction systems, and this type of reaction atmosphere provides room for introducing renewable substances as reductants, which offers the possibility to achieve CO2 reduction with net carbon benefit. While the progress in CO2 reduction has been abundantly summarized, reviews on hydrothermal CO2 reduction are relatively scarce and, more importantly, few have focused on CO2 reduction with renewable reductants with the consideration of both scale of efficiency and sustainability. This review provides a fundamental and critical review of metal, biomass and polymer waste as reducing agents for hydrothermal CO2 reduction. Various products including formic acid, methanol, methane and multi-carbon chemicals can be formed, and effects of operational parameters such as temperature, batch holding time, pH value and water filing as well as detailed reaction mechanisms are illustrated. Particularly, the critical roles of high temperature and pressure water as reaction promotor and catalyst in hydrothermal CO2 conversion are discussed at the mechanistic level. More importantly, this review compares hydrothermal CO2 reduction with other methods such as catalytic hydrogenation and photo/electrocatalysis, evaluating their efficiency and potential for net carbon benefit. The aim of this review is to promote the understanding of CO2 activation under a hydrothermal environment and provide insights into the efficient and sustainable strategy of hydrothermal CO2 conversion for future fundamental research and industrial applications.

Penerapan Metode Simple Additive Weighting dalam Penentuan Prioritas Program Pembangunan Daerah

Regional governments and institutions related to preparing regional development programs experience several obstacles in determining regional development work plans, one of which is difficulty in determining development priorities that are in line with regional regulations. The effectiveness and efficiency of implementing regional development programs depends on the accuracy of the data collected. One of the challenges faced by the Medan City Regional Development Planning Agency is the lack of consideration of the priority scale and fairness in the regional development stages, as well as the absence of a system that can help determine the priority scale. Therefore, this research requires a decision support system (DSS). In the SPK, there are many solution methods that can be used according to the needs of each problem. In this research, to determine regional development program priorities, the SAW method will be used. Of the 10 proposed regional programs, only one will be a priority development program. After applying the SAW method in making decisions, the development program that has the highest priority level is the highway construction program with the final result obtained, namely 0.77705.

Partnering with People with Lived/Living Experience of Mental Health and substance Use in Participatory Evaluation of an integrated virtual navigation support service for people experiencing substance use challenges.

Introduction/Background: This presentation shares how the Mid-West Toronto-Ontario Health Team (MWT-OHT) in Toronto, Canada involved patients and partners in the design, implementation, and evaluation of the “In Your Corner Program” to support people with substance use challenges. The experience of embedding the voices of people with living/lived experience in co-designing and evaluating the program will be shared.
 Who is it for? The “In Your Corner” program represents the actualization of key recommendations from people with lived/living experience with substance use challenges in MWT-OHT that identified a need for service navigation supports that helps to close transition gaps. The ‘In Your Corner’ program necessitated the MWT-OHT to take a collaborative, team, and consensus-based approach to coordinating services across the region, re-designing care pathways that better meet the needs of a dynamic and diverse population within the constraints of existing resources and structures.
 Who did you involve & engage with? The MWT-OHT brings together partners across health and social sectors in the mid-west downtown region of Toronto Canada to work together for better, more integrated care. In 2019, MWT-OHT completed co-design work with people with living/lived experiences of substance use and mental health focused on improving the care experience and outcomes for people with challenges related to substance use. The In Your Corner program was implemented in 2021 through a 5-month implementation funding and extended for an additional 4 months through in-kind support from implementation partners. During this time, a participatory evaluation approach was employed with partners as well as clients and providers of the program to inform next steps, scale, and sustainability.
 What results did you get? What impact did you have? Initial implementation findings of the program demonstrated that the model of care capitalizes on existing programs and was able to create a more robust scaffolding for integrated care for the clients served by the program. The opportunity to embed Peer support workers into the model was highlighted along with the need for follow-up supports over a longer period. The program was a first step toward working together with people with living and lived experiences from design to evaluation from a partnered approach that is hoped to be embedded in how the MWT-OHT approaches all initiatives.
 What is the learning for the international audience? The learnings from this program demonstrates the processes and supports needed to meaningfully embed the voices of patients and providers from design phase through implementation, evaluation, and scale at various points in the journey from a systems perspective. Considerations for scale are important, as well as minimizing and preventing tokenism and supporting true partnering.
 What are the next steps? Next steps identified from the co-design evaluation sessions with clients and providers of the In Your Corner Program have informed how to leverage, change, and scale the program to reach more people in the region with substance use challenges. More importantly, this process has become a blueprint for the MWT-OHT in how to embed the voices of patients, families, and caregivers in the designing and evaluating initiatives.

(Invited) Mixed Conduction in Ceramic Electrolytes For Intermediate-Temperature Fuel Cells and Electrolyzers

High-temperature fuel cells and electrolyzers (e.g., T > 700 ˚C) rely on oxide electrolytes such as stabilized cubic zirconia that conduct a single defect, oxygen vacancies. Intermediate-temperature electrochemical cells (e.g., T < 650 ˚C) utilize mixed conducting ceramic electrolytes, that conduct multiple defects. Operating at T < 600 ˚C facilitates lower-cost interconnect materials and balance-of-plant components, but the mixed conductor behavior can reduce fuel cell voltages and lower electrolyzer faradaic efficiencies. Predicting behavior of these mixed conductors, even at open-circuit voltage, requires modeling the coupled transport of the multiple conducting defects in the electrolyte. Detailed models of mixed conductors coupled to porous electrode models can simulate cell performance over a broad range of operating conditions. This presentation highlights models of two types of cells with mixed conducting oxide electrolytes. Firstly, gadolinium-doped ceria (GDC) primarily conducts oxygen vacancies but also some electrons via a reduced-ceria small polaron, but it performs well in intermediate temperature solid-oxide fuel cells [1]. Secondly, yttrium-doped barium zirconates (BZY) primarily conducts protons but also oxygen vacancies and small polarons, which contribute to electronic leakage. Variants of BZY electrolytes perform well in fuel cells and electrolyzers [2-4]. This paper focuses on cell-level models of these mixed-conductors and how to identify favorable regions for high performance in fuel cells and electrolyzers. Zhu, A. Ashar, R.J. Kee, R.J. Braun, G.S. Jackson, “Physics-based model to represent the membrane-electrode assemblies of solid-oxide fuel cells based on gadolinium-doped ceria,” J. Electrochem. Soc., Under revision, 2023.J. Kee, S. Ricote, H. Zhu, R.J. Braun, G. Carins, J.E. Persky, “Perspectives on technical challenges and scaling considerations for tubular protonic-ceramic electrolysis cells and stacks ,” J. Electrochem. Soc. 169:054525 (2022).Zhu, Y. Shin, S. Ricote, R.J. Kee, “Defect incorporation and transport in dense BaZr0.8Y0.2O3-d membranes and their impact on hydrogen separation and compression,” J. Electrochem. Soc., Under revision, 2023.Zhu, S. Ricote, R.J. Kee, “Thermodynamics, transport, and electrochemistry in proton-conducting ceramic electrolysis cells,” in High Temperature Electrolysis, W. Sitte and R. Merkle, Editors, IOP Publishing, 2023.

OLDER ADULT PERCEPTIONS OF HEALTHY AGING MEASURES

Abstract Little is known about how lay older adults view measures commonly employed to assess healthy aging. This study examined older adults’ perceptions of scales capturing psychological wellbeing, psychosocial factors, and physical health. Participants (n = 60 US adults; MAge = 65.49, 41.18% Female, 94.12% White) were asked to rate how easy each measure was to understand and interpret on a scale of 1 (Not easy at all) to 7 (Very easy). In addition, they were asked to identify any items with which they had difficulty responding. Finally, participants provided opinions of whether these scales fully addressed their perspective on healthy aging, or if additional components were needed. Results showed that, on average, participants rated the aging-related outcomes measures as easy to understand and interpret (M = 6.14). Older adults rated measures related to physical health and health behaviors as the easiest to use (the PROMIS Health Measure (M = 6.47) and the Good Health Practices Scale (M = 6.49)), while measures that capture future planning were the most difficult to comprehend and interpret (the Consideration of Future Consequences Scale (CFC; M = 5.19) and the Goals Related to Healthy Aging Scale (M = 5.73)). While participants generally reported satisfaction with the comprehensiveness of the measures, some (22%) felt that these measures did not fully capture the social aspects of aging. Future measurement development may benefit from older adults’ input to increase their utility and better capture the experiences of older adults.

Implementing a Non-Specialist Delivered Psychological Intervention for Young Adolescents in a Protracted Refugee Setting: a Qualitative Process Evaluation in Lebanon

There has been an increase in the evaluation and implementation of non-specialist delivered psychological interventions to address unmet mental health needs in humanitarian emergencies. While randomized controlled trials (RCTs) provide important evidence about intervention impact, complementary qualitative process evaluations are essential to understand key implementation processes and inform future scaling up of the intervention. This study was conducted as part of an RCT of the Early Adolescents Skills for Emotions (EASE) psychological intervention for young adolescents with elevated psychological distress (predominantly with a Syrian refugee background) in Lebanon. Our aims were firstly to conduct a qualitative process evaluation to understand stakeholder experiences and perceived impact of the intervention and identify barriers and facilitators for implementation, and secondly to explore considerations for scaling up. Eleven key informant interviews and seven focus groups were conducted with 39 respondents including adolescent and caregiver participants, trainers, providers, outreach workers, and local stakeholders. Data were analyzed using inductive and deductive thematic analysis. Respondents perceived the intervention to be highly needed and reported improvements in adolescent mental health and wellbeing. Key implementation factors that have potential to influence engagement, adherence, and perceived impact included the socio-economic situation of families, mental health stigma, coordination within and between sectors (particularly for scaling up), embedding the intervention within existing service pathways, having clear quality and accountability processes including training and supervision for non-specialists, and sustainable funding. Our findings provide important context for understanding effectiveness outcomes of the RCT and highlights factors that need to be considered when implementing a mental health intervention on a larger scale in a complex crisis.

Preliminary examination of the perceptions of sustainable horse feeding practices in the Netherlands

The purpose of this study was to determine the perception of sustainability among horse owners in the Netherlands and their willingness to switch to more sustainable feeding practices. A survey was distributed to a target group of horse owners in the Netherlands via social media channels. Data (n = 338 valid responses) were stratified based on yard type and size (small (<20), medium (20-50), and large (>50 horses). Most of the yards were livery yards (68 %) and they were small in size (66 %). The term most commonly associated with sustainability was low environmental impact (61.8 %). All participants (338/338) indicated that they were willing to switch to more sustainable feeding practices. Of the six options offered, the most popular was the use of plastic-free packaging products (60.5 %). This study identified that numerically the greatest change in behavior for the Dutch equestrian community would be achieved by small livery yards (P < 0.001). The potential to modify certain practices might be limited by the size of the equestrian operation, such as the available land for altering pasture management, and the financial aspects of the enterprise. Future research should investigate how the scale and economic considerations of the equestrian business influence its capacity and willingness to adopt more sustainable feeding practices.

Unsupervised and supervised AI on molecular dynamics simulations reveals complex characteristics of HLA-A2-peptide immunogenicity.

Immunologic recognition of peptide antigens bound to class I major histocompatibility complex (MHC) molecules is essential to both novel immunotherapeutic development and human health at large. Current methods for predicting antigen peptide immunogenicity rely primarily on simple sequence representations, which allow for some understanding of immunogenic features but provide inadequate consideration of the full scale of molecular mechanisms tied to peptide recognition. We here characterize contributions that unsupervised and supervised artificial intelligence (AI) methods can make toward understanding and predicting MHC(HLA-A2)-peptide complex immunogenicity when applied to large ensembles of molecular dynamics simulations. We first show that an unsupervised AI method allows us to identify subtle features that drive immunogenicity differences between a cancer neoantigen and its wild-type peptide counterpart. Next, we demonstrate that a supervised AI method for class I MHC(HLA-A2)-peptide complex classification significantly outperforms a sequence model on small datasets corrected for trivial sequence correlations. Furthermore, we show that both unsupervised and supervised approaches reveal determinants of immunogenicity based on time-dependent molecular fluctuations and anchor position dynamics outside the MHC binding groove. We discuss implications of these structural and dynamic immunogenicity correlates for the induction of T cell responses and therapeutic T cell receptor design.

Weakly-Supervised Video Anomaly Detection with MTDA-Net

Weakly supervised anomalous behavior detection is a popular area at present. Compared to semi-supervised anomalous behavior detection, weakly-supervised learning both eliminates the need to crop videos and solves the problem of semi-supervised learning’s difficulty in handling long videos. Previous work has used graph convolution or self-attention mechanisms to model temporal relationships. However, these methods tend to model temporal relationships at a single scale and lack consideration of the aggregation problem for different temporal relationships. In this paper, we propose a weakly supervised anomaly detection framework, MTDA-Net, with emphasis on modeling different temporal relationships and enhanced semantic discrimination. To this end, we construct a new plug-and-play module, MTDA, which uses three branches, Multi-headed Attention (MHA), Temporal Shift (TS), and Dilated Aggregation (DA), to extract different temporal sequences. Specifically, the MHA branch can globally model the video information and project the features into different semantic spaces to enhance the expressiveness and discrimination of the features. The DA branch extracts temporal information of different scales via dilated convolution and captures the temporal features of local regions in the video. The TS branch can fuse the features of adjacent frames on a local scale and enhance the information flow. MTDA-Net can learn the temporal relationships between video segments on different branches and learn powerful video representations based on these relationships. The experimental results on the XD-Violence dataset show that MTDA-Net can significantly improve the detection accuracy of abnormal behaviors.

Ecologies of Scale in the Age of Satellites and Television

This essay presents a theory of scale as a nonrepresentational interface, or crossing-point, to reappraise distance in approaches to remote viewing. To do so, it turns to the idea of “action at a distance,” particularly as described by Maurice Merleau-Ponty, as well as to the year 1968, when the photograph Earthrise, the Whole Earth Catalog, and shouts of “the whole world is watching” put a fine point on matters of scale for media such as satellites and television. Variously revered or reviled in this historical moment, these devices implied totalities for some and total fields for others, though in either case, it was distance that assured hierarchy and homogeny, according to critics and scholars. In the years since 1968, this distrust has typically held sway, shaping calls for immediacy as opposed to abstract distance in most accounts of scale. By contrast, this essay argues that distance preserves difference and, emphatically, dependence across vast and variegated milieus, making scale a site for mutual responsibility in addition to variance or invariance. Bearing this out, the essay concludes with considerations of scale in the films Medium Cool and 2001: A Space Odyssey, wherein distance ensures the entangled conditions by which just and unjust circumstances are made and unmade.

Pharmcokinetic and pharmacodynamic considerations for the anticholinergic burden scale of drugs.

Older adults frequently have many systemic diseases that require treatment with multiple drugs, and thus anticholinergic adverse effect by polypharmacy is a significant concern in the management of older adults. The accuracy of the anticholinergic burden rating may be increased by considering pharmacokinetic and pharmacodynamic factors such as biophase drug concentrations, the pharmacologically active metabolites formed after drug administration, and muscarinic receptor-mediated effects. Therefore, a pharmacological evidence-based burden scale that considers pharmacokinetic and pharmacodynamic factors is expected to be a more optimal tool for precisely assessing the anticholinergic burden, specifically risk reductions in anticholinergic adverse events in the poly-medicated elderly. Geriatr Gerontol Int 2024; 24: 81-87.

Validation of the Future Self Continuity Questionnaire (FSCQ)

This oral presentation aims to illustrates a local validation of a recently developed measure of future-self-continuity, the Future Self Continuity Questionnaire (FSCQ). Self-continuity is the sense of psychological connection between the past self, the present self and the future self, in the dimension of time (Chandler, 1994). Rutchick et al. (2018) propose that when people feel a greater sense of continuity between their present and future selves, their decision making may be more influenced by thoughts of their future self. The study will recruit at least 200 participants to fill out a series of questionnaires related to future self-continuity, including the Future Self-Continuity Scale (FSCS), Consideration of Future Consequences-14 Scale (CFC-14), Multidimensional Temporal Self-Continuity Scale (MTSCS), and Beck Hopelessness Scale (BHS). The higher degree people's future self-continuity (according to the FSCQ), the more likely they are to associate their future self with their past/present self (as measured by FSCS and MTSCS). This inclination also tends to result in a greater consideration for the future consequences of their actions (as measured by the CFC), and potentially corresponds with a lower degree of hopelessness (as measured by BHS). Analyses will include item analyses, exploratory and confirmatory factor analyses to examine the factorial structure of the questionnaire, alongside assessments of internal consistency and test-retest reliability.

Chemical Cleaning of Crude Oil Fouling Deposits; Applying the Coke Spectrum

Fouling of heat exchangers and refining equipment by crude oil deposits is a chronic operating problem. In general, many such deposits are narrowly defined as coke fouling, for which the prescribed cleaning has traditionally been high-pressure water blasting. The results for this type of cleaning are mixed at best. Heat exchangers are often returned to service at conditions less than 85% clean performance, driving the need for more efficient cleaning regimens. A detailed characterization of 62 field-based crude oil fouling deposits from hydrocarbon process units was presented by the authors in 2019. This paper demonstrated that such deposits are exceptionally complex, resulting in the introduction of the Coke Spectrum. Here, these deposits are revisited, and chemical cleaning methods are applied. Chemical cleaning encompasses a variety of applications. Circulation, ultrasonic immersion, and clean-in-place techniques were reviewed on laboratory-scale samples to determine what chemical cleaning agents are most effective toward the various categories of foulant making up the Coke Spectrum. Combination techniques which employ both chemical and mechanical applications simultaneously or in sequence are considered in depth. The correlation between chemical composition and the effectiveness of the cleaning method is explored with considerations for scaling from laboratory to industrial application.

Feasibility of wave energy harvesting in the Ligurian Sea

A series of short and mid-term guidelines have been established due to the pursuit to offer clean energy and reduce the environmental impact in the Mediterranean and European environment. Currently, the scientific community and the industrial sector promote to find new technologies and means to achieve these regulations. Efforts to provide sustainable ways to supply electricity in Italy have led to the exploration of marine renewable energies (MRE) in the Mediterranean Sea. In particular, in the Ligurian Sea, where the wave climate can provide one of the higher energy sources, represents an optimal opportunity for supplying this energy resource to coastal cities. However, the wave conditions are not as significant as those in other marine regions around the world. There are several devices currently developed which can be applicable to the region. Hence, an evaluation from a technical and economic perspective is advised. Additionally we also investigate the scaling and survival considerations for Wave Energy Converters (WECs) when facing extreme storm events. The proposed study offers the evaluation of a sustainable alternative for powering the electricity mix in the Liguria region, through the exploitation of the wave energy resource. Attractive findings emerge after the assessment of eight floating-body wave energy converters.

Fabrication and Scale-up of Highly Durable Heavy Duty Fuel Cell MEAs

Medium and heavy-duty PEM fuel cells operate under much harsher conditions than light duty fuel cells and are expected to last 25,000-30,000 hours in the field. These systems must operate successfully in the presence of impurities, starting and stopping, freezing and thawing, humidity and load cycling. Therefore, materials, components, and interfaces used in such systems must be highly resistant to severe mechanical and chemical stress.Novel, highly active stable Pt and ordered PtCo intermetallic nanoparticles with well-controlled particle size and composition have been synthesized on a highly efficient PGM-free single metal active site rich carbon, to maximize their synergistic effects for enhanced performance and durability. Integrating these catalysts integrated with high O2 permeability ionomer (HOPI) in membrane electrode assemblies (MEAs) improved their fuel cell performance and durability, allowing the MEAs to achieve >600 mA/mgPt at 0.9 VIR-free with a mass activity loss < 30% after 150k square wave accelerated stress test (AST) cycles; and > 600 mA/cm2 (~65% efficiency) at 0.8 V, with a performance loss < 40 mV after 150K AST cycles.In a PEM fuel cell, the catalyst ink formulation and mixing processes control catalyst layer coating quality, electrode morphology, and the resulting fuel cell performance and durability. Catalyst ink properties are a result of complex solvent-catalyst-ionomer interactions that depend on the mixing method employed. Here, we compare the performance and durability of electrodes made from bath sonicated inks for ultrasonic spray coating before and after the catalyst scale up. Ink rheology and catalyst particle size are used to correlate ink properties to electrode morphology and structure and ensure consistency from batch to batch, and from small lab scale to subsequent scale-up. We evaluate and discuss the challenges that arise when transitioning from spray coating catalyst ink on a small scale, directly on a membrane, to coating more viscous inks on gas diffusion layers (GDLs), made via Mayer rod coating of ball milled inks, in anticipation of developing a roll-to-roll (R2R) fabrication process. The MEA performance and durability of the novel catalyst was also evaluated under heavy duty operating conditions using M2FCT’s AST, i.e., in H2/Air, 90 ⁰C, and 50% RH.This work provides a comprehensive understanding of interactions between Pt, PtCo, carbon, ionomer, membrane, and GDLs and their impact on electrode structure, fuel cell performance and durability, as well as considerations for scale up to a R2R fabrication process. The attained information will be used to improve fuel cell electrode design, fabrication and scale-up.Acknowledgement: The project is financially supported by the Department of Energy’s Fuel Cell Technology Office under the Grant DE-SC0021671. Figure 1. (a) Comparison of H2-air fuel cell performance of HOPI-based CCMs prepared with different volume ratios of H2O to n-propanol (nPA). (b) Dependence of fuel cell performance at 0.8 and 0.7 V of the CCMs prepared with different volume ratios of H2O to nPA. (c) MEA performance of the best performing Pt (40 wt. %)/Mn-N-C MEA under various relative humidity. (d) The high-frequency resistance (HFR) of HOPI-based CCMs prepared with a volume ratio of 2:1. All of the tests were performed with a 5 cm2 differential cell with 14 parallel channels. The cell temperature was 80 ⁰C, the flow rates for H2 and air are 500 and 2000 sccm, and the backpressure is 250 kPaabs. The Pt loading in the anode and cathode are 0.1 and 0.2 mgPt/cm2, respectively. Figure 1

Single-Cell Protein Production from Industrial Off-Gas through Acetate: Techno-Economic Analysis for a Coupled Fermentation Approach

Third-generation (3G) biorefineries harnessing industrial off-gases have received significant attention in the transition towards a sustainable circular economy. However, uncertainties surrounding their techno-economic feasibility are hampering widespread commercialization to date. This study investigates the production of single-cell protein (SCP), a sustainable alternative food and feed protein, from steel mill off-gas through an efficient coupled fermentation approach utilizing acetate as an intermediate. A comprehensive model that comprises both the gas-to-acetate and the acetate-to-SCP fermentation processes, as well as gas pretreatment and downstream processing (DSP) operations, was developed and used to perform a techno-economic analysis (TEA). Sensitivity analyses demonstrated that significant cost reductions can be achieved by the process intensification of the gas-to-acetate fermentation. As such, an increase in the acetate concentration to 45 g/L and productivity to 4 g/L/h could lead to a potential cost reduction from 4.15 to 2.78 USD/kg. In addition, the influence of the production scale and other economic considerations towards the commercialization of off-gas-based SCPs are discussed. Conclusively, this research sheds light on the practical viability of a coupled fermentation process for SCP production by identifying key cost-influencing factors and providing targets for further optimization of the acetate platform, fostering sustainable and economically feasible bio-based innovations.

Water-Content-Dependent Switching of the Bending Behavior of Photoresponsive Hydrogels Composed of Hydrophilic Acrylamide-Based Main Chains and Hydrophobic Azobenzene.

Photoresponsiveness is a promising characteristic of stimulus-responsive materials. Photoresponsiveness can be achieved by incorporating photoresponsive molecules into polymeric materials. In addition, multiple-stimuli-responsive materials have attracted scientists' interest. Among the numerous multiple-stimuli-responsive materials, moisture- and photoresponsive materials are the focus of this report. These stimuli-responsive materials responded to the stimuli synergistically or orthogonally. Unlike most stimulus-responsive materials utilizing moisture and light as stimuli, the materials studied herein switch their photoresponsiveness in the presence of moisture. Appropriate copolymers consisting of hydrophilic acrylamide-based monomers for the main chain and hydrophobic azobenzene moieties switched their bending behaviors at 6-9 wt% water contents. At water contents lower than 6 wt%, the polymeric materials bent away from the light source, while they bent toward the light source at water contents higher than 10 wt%. At a low water content, the bending behaviors can be described on the molecular scale. At a high water content, the bending behavior requires consideration of the phase scale, not only the molecular scale. By controlling the balance between hydrophilicity and hydrophobicity, the switching behavior was achieved. This switching behavior may inspire additional strategies for the application of polymeric material as actuators.

The association between future self-continuity and problematic mobile video gaming among Chinese college students: the serial mediation of consideration of future consequences and state self-control capacity

BackgroundTo explore the relationship between future self-continuity and problematic mobile video gaming among Chinese college students and to examine the serial mediation of consideration of future consequences and state self-control capacity on the association between future self-continuity and problematic mobile video gaming, based on Identity-Based Motivation Theory.MethodsThe Problematic Mobile Video Gaming Scale, Future Self-continuity Scale, Consideration of Future Consequences Scale, and Short Version of State Self-control Capacity Scale were administered to a sample comprising 800 college students (338 males accounting for 42.3%). Multivariate analysis and latent variables analysis were utilized to explore the separate mediating role consideration of future consequences and state self-control capacity played in the association between future self-continuity and problematic mobile video gaming, and their serial mediation also was investigated. The Bootstrap method was employed to test the significance of these mediation effects.ResultsThe negative association between future self-continuity and problematic mobile video gaming was moderately found. Students with increased consideration of future consequences from higher levels of future self-continuity have decreased their problematic mobile video gaming. Future self-continuity significantly positively predicted state self-control capacity, which in turn significantly negatively predicted problematic mobile video gaming. The serial mediation was also found.ConclusionThe findings revealed why differences in identification with the current and future selves become influencing factors in problematic mobile video gaming. This study observed the mediating role that consideration of future consequences and state self-control capacity play in the association between future self-continuity and problematic mobile video gaming.