Conference Of Governmental Industrial Hygienists Research Articles

Biomonitoring of volatile organic compounds and organophosphorus flame retardands in commercial aircrews after „fume and smell events“

Health risks to humans after „fume and smell events“, short-term incidents on aircrafts that are accompanied by unpleasant odour or visible smoke, remain a subject of controversy. We assessed exposure to volatile organic compounds (VOC) and organophosphorus compounds (OPC) by biomonitoring in 375 aircrew members after self-reported “fume and smell events” and in 88 persons of the general population. A total of 20 parameters were analysed in blood and urine by gas chromatography and mass spectrometry. Median levels of acetone in blood and urine and 2-propanol in blood were elevated in aircrews compared to controls (p < 0.0001). Additionally, elevated peak exposures, best estimated by the 95th percentiles, were observed in aircrews for n-heptane and n-octane in blood, and acetone, 2,5-hexanedione and o-cresol in urine. Only the maximum observed levels of 2,5-hexandione in urine (768 μg/L) and toluene in blood (77 μg/L) in aircrew members were higher than the current biological exposure indices (BEI® levels) (500 and 20 μg/L, respectively) of the American Conference of Governmental Industrial Hygienists (US-ACGIH) for workers occupationally exposed to n-hexane and toluene, two well-accepted human neurotoxicants. Low-level exposures to n-hexane and toluene could be also observed in controls. The majority of OPC parameters in urine, including those of neurotoxic ortho-isomers of tricresylphosphate, were below the limit of quantitation in both aircrews and controls. Our comparative VOC and OPC analyses in biological samples of a large number of aircrew members and controls suggest that exposures are similar in both groups and generally low.

Biomonitoring for workplace exposure to copper and its compounds is currently not interpretable

This paper sets out to explore the requirements needed to recommend a useable and reliable biomonitoring system for occupational exposure to copper and its inorganic compounds. Whilst workplace environmental monitoring of copper is used to measure ambient air concentrations for comparison against occupational exposure limits, biological monitoring could provide complementary information about the internal dose of workers, taking into account intra-individual variability and exposure from all routes. For biomonitoring to be of reliable use for copper, a biomarker and the analytical ability to measure it with sufficient sensitivity must be identified and this is discussed in a range of matrices. In addition, there needs to be a clear understanding of the dose-response relationship of the biomarker with any health-effect (clinical or sub-clinical) or, between the level of external exposure (by any route) and the level of the copper biomarker in the biological matrix being sampled, together with a knowledge of the half-life in the body to determine accurate sampling times. For many biologically non-essential metals the requirements for reliable biomarkers can be met, however, for ‘essential’ metals such as copper that are under homeostatic control, the relationship between exposure (short- or long-term) and the level of any copper biomarker in the blood or urine is complex, which may limit the use and interpretation of measured levels. There are a number of types of biomarker guidance values currently in use which are discussed in this paper, but no values have yet been determined for copper (or its inorganic compounds) due to the complexity of its essential nature; the US The American Conference of Governmental Industrial Hygienists (ACGIH) has however indicated that it is considering the development of a biological exposure index for copper and its compounds. In light of this, we present a review of the reliability of current copper biomarkers and their potential use in the occupational context to evaluate whether there is value in carrying out human biomonitoring for copper exposure. Based on the available evidence we have concluded that the reliable use of biomonitoring of occupational exposure to copper and its application in risk assessment is not possible at the present time.

The ACGIH TLV for lifting: Estimated TLVs for torso asymmetry beyond 30 degrees.

The American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values (TLVs) for Lifting is a manual material handling (MMH) assessment method to identify weight limits that nearly all workers may be exposed to without developing work-related low back disorders (LBD). However, this assessment method only applies to lifting with the torso within 30° asymmetry of the sagittal plane. Estimate TLV weight limits while lifting with torso asymmetry greater than 30° beyond the sagittal plane. Lifting tasks were performed from various horizontal and vertical locations, at torso asymmetry angles of 0°, 15°, 30°, 45°, 60°, 75° and 90°, using ACGIH identified TLVs. Validated MMH assessment methods (NIOSH Lifting Equation, Ohio State University LBD Risk Model) were utilized to estimate TLVs at torso asymmetries greater than 30°. The current ACGIH TLVs resulted in low- to moderate-risk risk levels for torso asymmetries from 0° to 30°, and the risk incrementally increased as torso asymmetry increased to 90°. With the intention to keep the risk levels to that found at 30° torso asymmetry, lower TLV weight limits in the vertical and horizontal zones investigated were estimated for torso asymmetries from 45° to 90°. The resulting adjusted TLVs were consistent with weight limits identified for similar lifting conditions from other assessment methods that account for torso asymmetry. This research found current ACGIH-defined TLVs possess less than high-risk for LBD, and provided guidance to practitioners for reduced TLVs when torso asymmetry is greater than 30° from the sagittal plane.

Establishing short-term occupational exposure limits (STELs) for sensory irritants using predictive and in silico respiratory rate depression (RD50) models

Sensory irritation is a health endpoint that serves as the critical effect basis for many occupational exposure limits (OELs). Schaper 1993 described a significant relationship with high correlation between the measured exposure concentration producing a 50% respiratory rate decrease (RD50) in a standard rodent assay and the American Conference of Governmental Industrial Hygienists (ACGIH®) Threshold Limit Values (TLVs®) as time-weighted averages (TWAs) for airborne chemical irritants. The results demonstrated the potential use of the RD50 values for deriving full-shift TWA OELs protective of irritant responses. However, there remains a need to develop a similar predictive model for deriving workplace short-term exposure limits (STELs) for sensory irritants. The aim of our study was to establish a model capable of correlating the relationship between RD50 values and published STELs to prospectively derive short-term exposure OELs for sensory irritants. A National Toxicology Program (NTP) database that included chemicals with both an RD50 and established STELs was used to fit several linear regression models. A strong correlation between RD50s and STELs was identified, with a predictive equation of ln (STEL) (ppm) = 0.86 * ln (RD50) (ppm) − 2.42 and an R2 value of 0.75. This model supports the use of RD50s to derive STELs for chemicals without existing exposure recommendations. Further, for data-poor sensory irritants, predicted RD50 values from in silico quantitative structure activity relationship (QSAR) models can be used to derive STELs. Hence, in silico methods and statistical modeling can present a path forward for establishing reliable OELs and improving worker safety and health.

Hazards associated with blue light emitted during gas metal arc welding of mild steel using various shielding gases and currents.

Blue light emitted during arc welding is known to potentially cause photoretinopathy. To help prevent retinal injury, it is important to identify the hazards associated with various welding conditions. The present work conducted experiments involving gas metal arc welding of mild steel under various conditions, and measured the spectral radiance of the arcs. The effective radiance values, as used by the American Conference of Governmental Industrial Hygienists (ACGIH) to quantify exposure level of blue light, were subsequently calculated from the data. The resulting values were in the range of 5.0-118 W/cm2/sr, corresponding to hazardous levels according to ACGIH guidelines. The effective radiance was increased at higher welding currents and when pulsed currents were used rather than steady currents. The blue light hazard was also affected by the type of shielding gas employed. These data confirm that it is very hazardous to stare at arcs during gas metal arc welding of mild steel. As such, appropriate eye protection is necessary during arc welding, and directly staring at the arc should be avoided.

Gasoline Generators and their Effects on Air Quality of Some Selected Business Centers in Tertiary Institutions in Rivers State

This study considered gasoline generators and their effects on air quality of some selected business centers in tertiary institutions in Rivers State. Air quality monitor was positioned 1.5m above the floor to determine the concentration levels of CO, CO2 and O2. The measurements were done on a daily for a period of three weeks. At FCE (T), Omoku, the mean concentration values of CO for Business and Institution’s generators were 109.2ppm and 62.3ppm; CO2 283.6ppm and 27.4ppm and O2 185.8% and 192.1% respectively. At IAUE, Port-Harcourt, CO for Business and Institution’s generators had mean concentration values of 144.7ppm and 89.6ppm; CO2 210.9 ppm and 188.8ppm, and for O2, 225.4% and 239.2% respectively. Similarly, for RSU, Port-Harcourt, the mean concentration of CO for Business and Institution’s generators were 144.8ppm and 84.5ppm; CO2 171.1ppm and 124.ppm; and for O2, 196.8% and 164.3%. respectively. CEAP, Port-Harcourt, CO had mean concentration values of 215.3ppm and light 92.2ppm, CO2 226.2ppm and 109.2ppm, whileO2 mean concentration values of 120.1% and 198.2% respectively. The concentration levels of CO, CO2 for business generators were much higher compared to when Institutions’ generators were used. The mean values of CO concentrations for the selected institutions for the period under study were higher than OSHA permissible exposure limit (PEL) of 50ppm (55mg/m3), NIOSH recommended exposure limit (REL) of 35ppm (40 mg/m3) and ACGIH threshold limit value (TLV) of 25ppm (28.6mg/m3), while that of CO2 concentration levels were less than OSHA’s established permissible limit of 5000ppm, and American Conference of Governmental Industrial Hygienists(ACGIH) threshold limit value (TLV) of 25ppm. It was also observed that as the concentrations of CO and CO2 increase, the O2 levels also decrease. It is therefore, very important to state that tertiary institutions’ managements in Nigeria should consider the provision of regular power supply on

Carcinogenic and non-carcinogenic risk of exposure to metal fume in different types of welding processes.

The international agency for cancer research (IARC) has classified welding fumes as definitive carcinogens. The aim of the present study was to assess health risk due to exposure to welding fumes in different welding types. In this study, exposure to fumes of iron (Fe), chromium (Cr), and nickel (Ni) in the breathing zone air of 31 welder engaged in arc, argon and CO2 welding was assessed. Carcinogenic and non-carcinogenic risk assessments due to exposure to fumes were performed using the method proposed by the Environmental Protection Agency (EPA) by Monte Carlo simulation. The results showed that in the CO2 welding, concentration of Ni, Cr, and Fe was lower than the 8-h Time-Weighted Average Threshold Limit Value (TWA-TLV), recommended by the American Conference of Governmental Industrial Hygienists (ACGIH). In argon welding, Cr and Fe concentrations were higher than the TWA-TLV. In arc welding, concentrations of Ni and Fe were more than the TWA-TLV. In addition, the risk of non-carcinogenicity due to exposure to Ni and Fe in all three types of welding was more than standard level (HQ>1). The results indicated that the welders are at health risk due to exposure to metal fumes. Preventive exposure control measures such as local ventilation need to be implemented in welding workplaces.

Metal-organic frameworks derived inverse/normal bimetallic spinel oxides toward the selective VOCs and H2S sensing

As the typical toxic and hazardous gases, volatile organic compounds (VOCs) and hydrogen sulfide (H2S) pose a threat to the environment and human health. The demand for real-time detection of VOCs and H2S gases is growing in many application to protect human health and air quality. Therefore, it is essential to develop advance sensing materials for the construction of effective and reliable gas sensors. Herein, bimetallic spinel ferrites with different metal ions (MFe2O4, M = Co, Ni, Cu and Zn) were designed by using metal-organic frameworks as templates. The evaluation of cation substitution on crystal structures (inverse/normal spinel structure) and electrical properties (n/p type and band gap) is systematically discussed. The results indicate that p-type NiFe2O4 and n-type CuFe2O4 nanocubes with inverse spinel structure exhibit high response and great selectivity towards acetone (C3H6O) and H2S, respectively. Moreover, the two sensors also display the detection limits as low as 1 ppm (C3H6O) and 0.5 ppm (H2S), which are far below the threshold values of 750 ppm to acetone and 10 ppm to H2S for 8 h exposure set by American Conference of Governmental Industrial Hygienists (ACGIH). The finding provides new possibilities for the design of high-performance chemical sensors, which display tremendous potential for practical applications.

A Twenty-Year Retrospective Analysis of Risk Assessment of Biomechanical Overload of the Upper Limbs in Multiple Occupational Settings: Comparison of Different Ergonomic Methods.

Several methods with which to assess the risk of biomechanical overload of the upper limb are described in the literature. We retrospectively analysed the results of the risk assessment of the biomechanical overload of the upper limb in multiple settings by comparing the application of the Washington State Standard, the threshold limit values (TLV) proposed by the American Conference of Governmental Industrial Hygienists (ACGIH), based on hand-activity levels (HAL) and normalised peak force (PF), the Occupational Repetitive Actions (OCRA) checklist, the Rapid Upper-Limb Assessment (RULA), and the Strain Index and Outil de Repérage et d'Evaluation des Gestes of INRS (Institut National de Recherche et de Sécurité). Overall, 771 workstations were analysed for a total of 2509 risk assessments. The absence of risk demonstrated for the Washington CZCL, used as the screening method, was in good agreement with the other methods, with the sole exception of the OCRA CL, which showed at-risk conditions in a higher percentage of workstations. Differences in the assessment of the frequency of actions were observed among the methods, while their assessments of strength appeared to be more uniform. However, the greatest discrepancies were observed in the assessment of posture. The use of multiple assessment methods ensures a more adequate analysis of biomechanical risk, allowing researchers to investigate the factors and segments in which different methods show different specificities.

Alterations to biomarkers related to long-term exposure to diesel exhaust at concentrations below occupational exposure limits in the European Union and the USA

BackgroundWe previously found that occupational exposure to diesel engine exhaust (DEE) was associated with alterations to 19 biomarkers that potentially reflect the mechanisms of carcinogenesis. Whether DEE is associated with...

Evaluation of Seasonal Variation on the Health Risks Using the Quantitative Microbial Risk Assessment Approach in a Wastewater Treatment Plant in Hamadan, Iran.

Wastewater treatment plants (WWTPs) are a source of airborne bacterial contamination that can pose health risks to staff. The aim of this study was to evaluate seasonal variations in the health risks of exposure to Staphylococcus aureus bioaerosols using the quantitative microbial risk assessment (QMRA) approach in a WWTP in Hamadan, Iran. This was a descriptive cross-sectional study. This study determined the emission concentrations of S. aureus bioaerosols in summer and winter. Then, the health risks of three exposure scenarios (the worker, field engineer, and laboratory technician) were evaluated using the QMRA approach. The bioaerosol samples were collected every 12 days in both summer and winter of 2021 with a nutrient agar using a single-stage cascade impactor (Quick Take 30, SKC Inc.) in both outdoor and indoor environments. The results demonstrated that in both seasons, S. aureus bioaerosol concentrations in outdoor and indoor environments were below the standard established by the American Conference of Governmental Industrial Hygienists (500 CFU/m3 ). While in summer, the annual infection risks and the disease burden for the three exposure scenarios in both outdoor and indoor environments were higher than the United States Environmental Protection Agency (≤10-4 pppy) and the World Health Organization (WHO) (≤10-6 DALYs pppy-1) benchmarks, respectively. The findings provided high health risks for staff in the three exposure scenarios of an indoor environment, which should not be ignored, as well as emphasizing the use of the QMRA approach to estimate health risks caused by occupational exposure to bioaerosols and taking executive measures to protect staff working in the WWTPs.

Chromium toxicity among leather industry workers in Kolkata-A pilot Study

Introduction: Chromium (Cr) exposure is known to cause various health issues such as cancer, dermatitis, respiratory problems, etc. The recent exposure of Cr can be determined by analysis of Cr either in blood/urine/plasma, Cr (III) ions cannot permeate through cell membranes of red blood cells (RBC) because their ionic radii are bigger as compared to Cr (VI), and hence Cr in RBC is an indicator for exposure to Cr (VI) ions. The purpose of this study was to investigate chromium exposure, hygienic habits and the occurrence of dermatological problems with leather industry workers in Kolkata. Methods: A total of 68 leather industry workers with minimum work exposure of five years and aged between 18-60 years were recruited for this study. The study protocol included a questionnaire and analysis of Cr in blood and urine samples by GF-AAS. Results: All values were under the Biological Exposure Index (BEI) of 25µg /L at the end of the shift of a five-day work week recommended by the American Conference of Governmental Industrial Hygienists (AcGIH). 15.2% of subjects suffered from dermatological problems at least once in the last year during work in the leather industry. Conclusion: It was found that leather industry workers were not using personal protective equipment and it must be promoted to them for occupational health and safety.

Assessment of safety control measures for centralized Chlorine gas system

As a glove manufacturing plant, the chemical is one of the most highly used materials. Some chemicals impact human health, environmental aspects, and physical hazards such as highly flammable gas. Chlorine gas is one of them. Besides the accidental release of chlorine gas incidents, ill-health issues are another aspect that should be taken care of. This study aims to determine the current chlorine concentration at a centralized chlorine gas manifold system in a rubber glove manufacturing plant and evaluate the existing safety control measures. A concept of safety by design, inherently safety, and the fail-safe system was considered during the study. The results show that the chlorine concentration level during drum replacement by the crew is at an average of 1.154 ppm and the standard deviation at 0.3478. The highest concentration was at 1.8 ppm. The wet scrubber assessment was done using the Industrial Ventilation and visual assessments and measurements within the system, including capture velocity, face velocity, and duct velocity or transport velocity. Other assessed parameters are total pressure, static pressure, and velocity pressure. The assessment found that the duct performance for all parameters complies with a minimum requirement of the American Conference of Governmental Industrial Hygienists (ACGIH) guidelines.

Research on the relationship between the centerline velocity, aspect ratio and exhaust airflow rate for a slot and a rectangular capture hood in an local exhaust ventilation system.

When using a local exhaust hood to remove harmful substances from the production process, the exhaust airflow rate must be calculated according to the capturing velocity specified by the relevant regulations. The Numano and American Conference of Governmental Industrial Hygienists (ACGIH) equations are used in Japan and the US, respectively, for estimating the exhaust airflow rate of slot hoods. However, these equations differ from each other, and when using these equations to calculate the exhaust airflow rate of the capture hood, whether using Japan's equation or ACGIH, the hood type (slot or rectangular hood) should be distinguished at first. Therefore, this study performs experiments and a computational fluid dynamics (CFD) simulation to investigate the relationship between the centerline velocity and the aspect ratio for five types of capture hoods. The results showed good agreement between simulated and experimental centerline velocities when the distance from the hood face. A dimensionless velocity was introduced and a significant difference in the relationship between the centerline velocity and the distance from the hood face with different aspect ratios was found. A unified equation was obtained that can express the relationship between exhaust airflow rate and centerline velocity regardless of the aspect ratio of the hood face of the free-standing capture hood.

Potential harm to the skin from unfiltered krypton chloride ‘far-ultraviolet-C’ lamps, even below an occupational exposure limit

Ultraviolet-C (UVC) radiation can effectively inactivate pathogens on surfaces and in the air. Due to the potential for harm to skin and eyes, human exposure to UVC should be limited within the guideline exposure limits produced by the International Commission on Non-Ionising Radiation Protection (ICNIRP) or the American Conference of Governmental Industrial Hygienists (ACGIHs). Both organisations state an effective spectrally weighted limit of 3 mJ cm−2, although the spectral weighting factors of the two organisations diverged following a revision of the ACGIH guidelines in 2022. Using existing published human exposure data, the effective spectrally weighted radiant exposure was calculated for both unfiltered and filtered (to reduce UV emissions above 230 nm) krypton chloride (KrCl*) excimer lamps. The effective radiant exposure of the filtered KrCl* lamp was greater than 3 mJ cm−2 when applying ICNIRP or either of the revised ACGIH spectral weightings. This indicates that both guidelines are appropriately conservative for this specific lamp. However, the effective radiant exposure of the unfiltered KrCl* lamp was as low as 1 mJ cm−2 with the revised ACGIH weighting function that can be applied to the skin if the eyes are protected. Erythema has therefore been directly observed in a clinical study at an exposure within the revised ACGIH guideline limits. Extrapolating this information means that a mild sunburn could be induced in Fitzpatrick skin types I and II if that particular ACGIH weighting function were applied and an individual received an effective exposure of 3 mJ cm−2. Whilst it is improbable that such an effect would be seen in current deployment of KrCl* lamp technology, it does highlight the need for further research into skin sensitivity and irradiance–time reciprocity for UVC wavelengths.

Engineered Stone Fabrication Work Releases Volatile Organic Compounds Classified as Lung Irritants.

Engineered stones are often characterized for their crystalline silica content. Their organic composition, particularly that of the emissions generated during fabrication work using hand-held power tools, is relatively unexplored. We forensically screened the emissions from dry-cutting 12 engineered stone products in a test chamber for their organic composition by pyrolysis-gas chromatography-mass spectrometry (GC-MS) plus selected traditional capture and analysis techniques. Phthalic anhydride, which has a Respiratory Sensitization (RSEN) Notation by the American Conference of Governmental Industrial Hygienists (ACGIH), was the most common and abundant compound, at 26-85% of the total organic composition of engineered stone emissions. Benzaldehyde and styrene were also present in all twelve samples. During active cutting, the predominant volatile organic compound (VOC) emitted was styrene, with phthalic anhydride, benzene, ethylbenzene, and toluene also detected. These results have important health implications as styrene and phthalic anhydride are irritants to the respiratory tract. This study suggests a risk of concurrent exposure to high levels of respirable crystalline silica and organic lung irritants during engineered stone fabrication work.

"Blood lead level among battery factory workers in low and middle-income countries: Systematic review and meta-analysis".

IntroductionLead is one of the most health-hazardous causes of acute and chronic poisoning at workplaces. A limited study was conducted on the blood lead concentration among battery factory workers in low and middle-income countries. Therefore, this study will improve workplace health and safety conditions of workers in this sector and serve as baseline data for further studies in this segment of the working setup.ObjectiveThis review aims to identify the pooled mean blood lead level among battery factory workers in low and middle-income countries.MethodsThe search methods considered the following electronic bibliographic databases: google scholar, PubMed, and other gray literature. A funnel plot and Begg test were used to see the publication bias. The heterogeneity of studies was checked using I-square statistics with a cut of point 75% and the Joanna Briggs Institute (JBI) quality assessment tool was applied to ensure the quality of the included articles. A random-effect model was applied to pool the blood lead level intoxication. The sub-group analysis and Meta-regression analysis were conducted by country and year of publication to control heterogeneity and to show variation. We included the articles published from 2000 to 2021 year in the English language.ResultsThrough the search strategies, 135 articles were identified and 43 full-text articles were selected for evaluation, and finally, eighteen (18) articles fit the inclusion criteria. From the 18 studies included in the meta-analysis, the mean pooled blood lead level of workers was 37.996 μg/dl (95% CI: 30.680–45.312) which is higher than the threshold limit value set by American conference of governmental industrial hygienists (20 μg/dl). In subgroup analysis by year in the random effect model, the pooled mean of blood lead level from 2006 to 2011= 43.20 μg/dL (35.91–50.50), 2012–2015 = 37.78 μg/dl (25.23–50.29), and 2016–2020 = 36.53 μg/dl (19.44–53.62).ConclusionsThis review showed that the pooled mean blood lead level of workers exposed to lead battery factories was (37.996 μg/dl) which is above the threshold limit value (20 μg/dl). Therefore, attention should be given by employers, government, and researchers to improve the health of working populations exposed to lead exposure in low and middle-income countries through the provision of occupational health and safety services like periodical medical checkups, treatments, and provision of training and adequate and appropriate personal protective equipment.Systematic review registration: Identifier: CRD42022322827.

Oxygen vacancy-enriched ALD NiO sub-50 nm thin films for enhanced triethylamine detection

p-type metal oxide semiconductors have received significant interest in the field of gas sensors; however, it is quite challenging to achieve high sensor response because of inferior surface and electronic properties. Herein, we report a high-performance gas sensor fabricated by plasma-etching an NiO thin film deposited by atomic layer deposition. Ar plasma treatment is found to introduce a large number of oxygen vacancies, which effectively adjusts the electronic and chemical characteristics of the p-type NiO films to afford improved response to toxic triethylamine. The effects of the thickness of the sensing layer on sensor properties are also studied, which reveals that the NiO film with a thickness of 40 nm has the greatest gas sensing performance. After Ar plasma treatment, the response of the NiO thin films is significantly enhanced to enable an excellent limit of detection of 27.4 ppb, which is much lower than the threshold limit of 1 ppm proposed by American Conference of Governmental Industrial Hygienists. The demonstrated strategy and excellent sensor properties suggest a pathway to high performance gas sensors.

Derivation of maximum permissive switching time for automatic welding filter based on retinal thermal and blue light exposure limits

Automatic welding filters are intended to protect the eyes of the welder from optical radiation generated by the welding process. Safety standards for automatic welding filters (AWFs) have been developed worldwide. However, switching time requirements have not been studied considering the exposure limits established by the International Commission on Non-Ionizing Radiation Protection (ICNIRP) or the American Conference of Governmental Industrial Hygienists (ACGIH). The aim of this study is to derive the maximum permissive switching time based on ICNIRP guidelines for exposure to intense optical radiation. The single and cumulative exposures associated with retinal thermal and blue light hazards were assessed in the welding environment. The results show that the maximum switching time is inversely proportional to the exponential function of the shade number difference. The proposed maximum switching time, 1/2 to 1/10 smaller than the current ISO, is derived from the effective blue light radiance limits. In addition, an evaluation of the periodic short circuit welding indicates that AWFs do not transmit hazardous levels of radiation in the dark state.

Field Study of Early Implementation of UV Sources and their Relative Effectiveness for Public Health and Safety

ABSTRACT The emergence of COVID-19 and corresponding public health burden has prompted industries to rapidly implement traditional and novel control strategies to mitigate the likelihood of SARS-CoV-2 transmission, generating a surge of interest and application of ultraviolet germicidal irradiation (UVGI) sources as disinfection systems. With this increased attention the need to evaluate efficacy and safety of these types of devices is paramount. A field study of the early implementation of UVGI devices was conducted at the Space Needle located in Seattle, Washington. Six devices were evaluated, including four low pressure (LP) mercury-vapor lamp devices for air and surface sanitation not designed for human exposure and two krypton chloride (KrCl*) excimer lamp devices to be operated on and around humans. Emission spectra and ultraviolet (UV) irradiance at different locations from the UV devices were measured and germicidal effectiveness against SARS-CoV-2 were estimated. Human safety of KrCl* excimer devices was also evaluated based on measured irradiance and estimated exposure durations. Our results show all LP devices emitted UV radiation primarily at 254 nm as expected. Both KrCl* excimers emitted far UVC irradiation at 222 nm as advertised but also emitted at longer, more hazardous wavelengths (228 to 262 nm). All LP devices emitted strong UVC irradiance, which were estimated to achieve three log reduction of SARS-CoV-2 within 10 seconds of exposure at reasonable working distances. KrCl* excimers, however, emitted much lower irradiance than needed for effective disinfection of SARS-CoV-2 (>90% inactivation) within the typical exposure times. UV fluence from KrCl* excimer devices for employees were below the American Conference of Governmental Industrial Hygienists (ACGIH®) Threshold Limit Values (TLVs®) under the reported device usage and work shifts. However photosensitive individuals, human susceptibility, or exposure to multiple UV sources throughout the course of a worker’s day were not accounted for in this study. Caution should be used when determining acceptability of UV exposure to workers in this occupational setting and future work should focus on UVGI sources in public settings.