Conductive Carbon Black Research Articles

Mesoscale models for effective elastic properties of carbon-black/ultra-high-molecular-weight-polyethylene nanocomposites

In this paper, we apply mesoscale numerical modeling to predict the effective elastic properties of conductive carbon-black/ultra-high-molecular-weight-polyethylene nanocomposites. The models are based on X-ray microcomputed tomography images. The images show that for the considered range of carbon additive weight fractions, the conductive carbon black (CB) particles are distributed around the ultra-high-molecular-weight-polyethylene (UHMWPE) granules forming a carbon-containing layer of a thickness on the order of 1–2 μm.Finite element models of representative volume elements (RVE), incorporating the CB-containing layer, are developed. The RVEs are generated based on the size and shape statistics extracted from processed microcomputed tomography images with further incorporation of the CB-containing layer by a custom image processing code. The layer is modeled analytically as a 2-phase composite consisting of spherical CB inclusions distributed in the UHMWPE matrix. Elastic moduli predicted in the models are compared to experimental data. Results show that the numerical simulations predict effective elastic moduli within the confidence intervals of the experimental measurements up to 7.5 wt % of CB inclusions.

Nanoscale precision welding-enabled quasi-3D conductive carbon blacks for fast-charging and long-lasting secondary batteries

Robust three-dimensional (3D) conductive networks are vital for enhancing the utilization, rate capability, and lifespan of battery electrode materials, which largely relies on the selection and synergy of various conductive additives. As the spatial dimension expands from granular to tubular or lamellar, the conductivity of conductive additives continues to increase, but the cost and dispersion difficulty will sharply rise. This determines that zero-dimensional carbon black (CB) spherical nanoparticles remain the dominant component of current composite conductive additives. Herein, we disclosed a transient high-temperature welding technique that can precisely regulate the “rearrangement-fusion” behavior of carbon atoms at specific temperatures, accurately splicing the CB nanospheres into quasi-3D dendritic aggregates with appropriate spatial extension. This not only enhances the powder conductivity of CBs by 205.1 %, but also improves the processability through reducing the specific surface area. The quasi-3D CBs upgrade their contact mode with active materials from point-to-point to line-to-point, while significantly enhancing the inter-particle connection of active materials. More encouragingly, the modified CBs greatly boost the reaction kinetics, rate and cycling performance of LiFePO4 cathode and SiO@C anode, and derives fast-charging and long-lasting SiO@C//LiFePO4 full battery. Our work provides innovative solutions for upgrading the spatial conductive network within future secondary batteries.

Effect of Carbon Nanotubes Functionalization on the Chemical Composition and Electrochemical Characteristics of Composites with Layered Potassium Manganese Oxide

The influence of pretreatment of multiwalled carbon nanotubes (MWCNTs) in oxidizers (solutions of H2O2 and HNO3) on the structure and electrochemical properties of composites with layered potassium-manganese oxide (KxMnO2) was studied. Composites were obtained by soaking carbon nanotubes in an aqueous solution of KMnO4 at 60 °C. The electrochemical performance of the composites was evaluated by cyclic voltammetry and galvanostatic charge‒discharge methods. It has been established that stronger oxidation of the MWCNTs surface at the functionalization stage leads to a noticeable increase in the reaction rate as well as the optimal potassium content in the KxMnO2 composition, which provides higher capacitive characteristics of the composite (a maximum specific capacitance of 150 F g−1 and a rate capability of 43% with increasing density current from 0.1 to 2.0 A g−1). The resulting composites are promising active components for increasing the capacitive characteristics of conductive carbon black (CB). Compared with an electrode based only on CB, electrodes based on a combination of the composite and CB at a mass ratio of 1:1 showed specific capacitance values approximately 1.5 to 3 times greater, as well as a twofold increase in rate capability (from 35 to 70%) in the range of discharge current density 0.1 to 2.0 A g−1.

Turning coal hydrogenation liquefaction residue into high conductivity carbon black with magnesium citrate-assisted steam activation followed by high temperature treatment

The high conductivity carbon black was prepared using coal hydrogenation liquefaction residue as raw material, through a combination methods of solvent extraction purification, magnesium citrate-assisted carbonization, steam activation, and high-temperature treatment. The effects of carbonization and activation process parameters, heat treatment temperatures, and other factors on the microstructure, specific surface area, degree of graphitization, and conductivity of the carbon black were studied. The coal direct liquefaction residue was firstly purified using a xylene and tetrahydrofuran solution with a volume ratio of 1:1 by centrifugal separation method to obtain coal liquefaction asphalt. Then, the coal liquefaction asphalt was mixed with magnesium citrate in a mass ratio of 3:7 and ball-milled for 90 min. After carbonizing at 950 °C for 120 min, magnesium ions were leached out with hydrochloric acid. The obtained sample was activated with steam at 900 °C for 100 min and then underwent high-temperature treatment at 1500 °C under a N2 atmosphere for 120 min. The microstructure of the conductive carbon black exhibited an irregular blocky structure with an average particle size of 2–10 μm. The specific surface area of carbon material was 579.69 m2/g, with the pore distribution predominantly microporous, accounting for 69.81 % of the total pore volume. It featured a higher degree of graphitization (ID/IG=1.06) and fewer surface oxygen-containing functional groups compared with coal direct liquefaction residue. Electrochemical testing showed that the electrical resistance of the carbon material was only 1.55 Ω, and the reversible capacity under a current density of 1 A/g was 96 mAh/g, which are superior to those of the existing commercial conductive carbon black. The microporous structure and higher degree of graphitization facilitate efficient electron transmission, while the lower content of surface oxygen functional groups effectively reduces electron transfer resistance. This work offers new insights into the structural design and performance enhancement of coal liquefaction residue-derived conductive carbon black functional materials. Furthermore, it has significant implications for the future development of conductive carbon black in energy saving and energy storage.

Quantifying electron transport in aggregated colloidal suspensions in the strong flow regime

Electron transport in complex fluids, biology, and soft matter is a valuable characteristic in processes ranging from redox reactions to electrochemical energy storage. These processes often employ conductor-insulator composites in which electron transport properties are fundamentally linked to the microstructure and dynamics of the conductive phase. While microstructure and dynamics are well recognized as key determinants of the electrical properties, a unified description of their effect has yet to be determined, especially under flowing conditions. In this work, the conductivity and shear viscosity are measured for conductive colloidal suspensions to build a unified description by exploiting both recent quantification of the effect of flow-induced dynamics on electron transport and well-established relationships between electrical properties, microstructure, and flow. These model suspensions consist of conductive carbon black (CB) particles dispersed in fluids of varying viscosities and dielectric constants. In a stable, well-characterized shear rate regime where all suspensions undergo self-similar agglomerate breakup, competing relationships between conductivity and shear rate were observed. To account for the role of variable agglomerate size, equivalent microstructural states were identified using a dimensionless fluid Mason number, [Formula: see text], which allowed for isolation of the role of dynamics on the flow-induced electron transport rate. At equivalent microstructural states, shear-enhanced particle-particle collisions are found to dominate the electron transport rate. This work rationalizes seemingly contradictory experimental observations in literature concerning the shear-dependent electrical properties of CB suspensions and can be extended to other flowing composite systems.

Biomass-derived dynamic polyurethanes: Enhanced self-healing and recyclability through reversible cross-linking

Chemically cross-linked polyurethanes (CCPUs), renowned for their superior solvent resistance, high strength, and exceptional thermostability, have emerged as extensively used polymeric materials. Despite their advantages, CCPUs face a significant limitation that their stable cross-linked structures can preclude healing and recycling once damaged. This limitation underscores the urgent need for a new CCPUs variant that offers self-healing and recyclability to extend service life. In this work, a new type of cross-linked polyurethanes (CPUs) was designed and synthesized by incorporating the biomass-derived castor oil (CO) as a cross-linking agent and dynamic disulfide bond into a traditional polyurethane without using any catalysts. These newly developed CPUs exhibit superior mechanical performance with an impressive tensile strength of 29.37 MPa and a remarkable maximum elongation at break of 769.9 %. Notably, our recycled CPU-2 can retain a tensile strength of 22.40 MPa and an elongation at break above 604.8 % even after four thermal recycling cycles. Furthermore, the addition of conductive carbon black (CB) into this CPU matrix imparts remarkable self-healing properties to the polyurethanes/carbon black composite (CPU-2/CB), activated solely by near-infrared light. This inventive approach effectively enhances the functionality of traditional CCPUs, broadening their application potential.

Dispersion of hydrophobic conductive carbon black (CB) in polytetrafluoroethylene (PTFE) emulsion through liquid bridges and fabrication of PTFE/CB composite film for triboelectric nanogenerators

Polytetrafluoroethylene (PTFE) is a highly electronegative material that is widely used in Triboelectric nanogenerators (TENGs). However, due to the ultralow surface energy of PTFE, it is difficult to achieve a stable and even dispersion of hydrophobic carbon black in the PTFE emulsion. In this study, a novel method was used to achieve a stable and uniform dispersion of hydrophobic carbon black in the PTFE emulsion. An interfacial modifier was added to form liquid bridges between PTFE emulsion particles. The hydrophobic carbon black was then dispersed among these liquid bridges, resulting in its uniform distribution within the aqueous emulsion. The addition of 0.75 wt% CB resulted in a 4.6-fold increase in open-circuit voltage and a 3.5-fold increase in short-circuit current density compared to pure PTFE. Moreover, after 10000 cycles, the open-circuit voltage remained mostly unchanged, indicating that it has great potential for use in wearable devices.

Facile preparation of conductive silicone rubber composite foams with tunable cell morphologies and absorption-dominant characteristics

Flexible silicone rubber (SR) foams with tunable cellular morphologies were fabricated via supercritical CO2 foaming. Conductive carbon black (CB) modified at a low cost and with high complex viscosity was preferentially selected. The effects of the pore size and void fraction on the electrical conductivity and dielectric permittivity of the SR/CB composite foams were carefully investigated. The pore size of the foams affected the specific shielding effectiveness (SSE) and absorption coefficient (A), whereas the variation in the void fraction did not generate evident changes. In comparison with its solid counterpart, a foam with a pore diameter of 59.9 μm showed a 50 % decrease in density, 31.6 % increase in absorptivity, and 95.7 % increase in SSE, demonstrating a considerable electromagnetic interference shielding effectiveness (EMI SE). Decreases in the pore size and void fraction of the foams improved compression modulus and strength. In addition, sample preparation process was simplified, making industrial production easier.

Piezoresistive properties for soft structures using hybrid CCB/CNT-based natural rubber latex composites

This study explores the development of flexible sensors for soft structures. Conductive carbon black (CCB) and carbon nanotubes (CNT) were incorporated into a natural rubber (NR) matrix using glutaraldehyde (GA) as a curing system. The sensor properties of latex-NR composites with 20 phr of CCB, including variations of CNT content (0.5 to 3 phr), were examined. Increasing CNT content beyond 0.5 phr decreased tensile strength and elongation at break, but improved sensitivity and gauge factor (GF). Additionally, applying a voltage over 5 V caused a joule heating of the latex-NR composite strip elements. When integrated onto a soft tendon-based TPU bending actuator, higher CNT content reduced electrical signal drift during cyclic bending, enhancing long-term monitoring. This research highlights the potential of CCB/CNT-based latex-NR composites for soft structure applications, including soft robotics and health monitoring.

Sea urchin-like MnO2@Carbon fiber paper @carbon black modified silicone rubber interface control to improve electromagnetic properties and media factors

With the advent of the information age, the proliferation of intelligent devices has also given rise to the issue of electromagnetic pollution. Flexible materials hold significant applications and development prospects in the realm of electronic device shielding. In this study, MnO2 was synthesized through reduction on the surface of carbon fiber paper (CFP), while conductive carbon black (CB) was incorporated into silicone rubber to fabricate a flexible polymer with both surface relative insulation and internal electromagnetic shielding capabilities. Under 1 wt% CB loading, the modified CFP exhibited an electromagnetic shielding performance reaching 33.22 dB, which is 49.5 % higher than that of its original counterpart. By optimizing the thickness of CB within the silicone rubber matrix filling component, impedance matching properties were enhanced for improved material performance. Adjusting medium factors by thickness optimization, at a thickness of 5 mm, the absorption coefficient A for electromagnetic waves entering into the modified CFP increased by 461.7 % compared to that observed in its original form. Furthermore, a contact angle as high as 110° was achieved on the surface of CFP indicating excellent hydrophobicity; moreover, stable adhesion between conductive fillers and surfaces was confirmed through testing procedures conducted thereafter. Additionally, even after undergoing more than ten freezing experiments, over 99 % electromagnetic shielding performance was retained by our developed material ensuring its viability under harsh low temperature conditions.

Conducting Carbon Black Nano‐Filler Doped Polymer Electrolyte for Electrochemical Application

AbstractThis study provides a development of polymer electrolytes with an emphasis on their use in electrochemical devices. In present study we develop a new conducting carbon black (CB) powder dispersed into polyethylene oxide (PEO) polymer electrolyte using solution cast method. Various characterization techniques such as Impedance spectroscopy technique (EIS), Fourier transform infrared spectroscopy (FTIR), and Window stability (LSV) Linear sweep voltammetry has been studied in detail. The maximum ionic conductivity polymer electrolyte was at 0.05 wt%. of CB with σ value 1.20×10−5 S/cm. Finally the prepared CB dispersed polymer electrolyte using maximum conductivity sample is sandwiched between electrodes to fabricate an Electric double layer capacitor and Dye‐sensitized solar cell which show highest electrical capacity value of 68.5 F/gm at 5 mV/s respectively and 2.97 % efficiency shown by solar cell at 1 sun condition.

Research and simulation of electromagnetic wave absorbing performance for lightweight cement-based materials containing expanded polystyrene with different particle sizes and carbon black

The electromagnetic wave (EMW) absorbing performance of cement-based materials incorporating expanded polystyrene (EPS) with varying particle sizes is comprehensively studied through a combination of experimental and simulation methods. The addition of conductive carbon black (CB) to the cement matrix significantly increases the conductivity and dielectric constant, thereby improving the loss capacity. The frequency shift behavior of single and three-layer absorbing materials adheres to the effective medium theory and interference cancellation principle. The enhancement in overall EM parameters leads to a shift of the reflection loss (RL) peak towards lower frequencies. For three-layer materials, an increase in the thickness of absorbent layer proves beneficial for enhancing absorption performance. Simulations can effectively model cement-based materials by employing uniform material settings, with the size of EPS particles serving as the primary variable. The simulation results reveal that an increase in EPS particle size, in both single-layer and multi-layer materials, causes a shift of the RL peak towards lower frequencies. Additionally, analysis of electric field mode distribution and EM power loss density distribution indicates that scattering at the curved EPS interface alters the propagation direction of EMWs, increasing opportunities for loss inside the cement-based material. Moreover, the three-layer absorbing material, with a density ranging from 850 to 900 kg/m3 and compressive strength exceeding 4 MPa, is suitable for EMW absorption in building envelope structures. In conclusion, an increase in EPS particle size and CB content leads to a low-frequency shift of the RL absorption peak. This discovery not only provides an empirical foundation for the development of absorption materials tailored to specific frequency bands but also offers an efficient approach for repurposing waste EPS of diverse sizes. Furthermore, the grading of EPS with different particle sizes has important practical significance for increasing the content of EPS and preparing lightweight cement-based materials.

A low-fouling electrochemical biosensor based on BSA hydrogel doped with carbon black for the detection of cortisol in human serum

Electrochemical biosensors with high sensitivity can detect low concentrations of biomarkers, but their practical detection applications in complex biological environments such as human serum and sweat are severely limited by the biofouling. Herein, a conductive hydrogel based on bovine serum albumin (BSA) and conductive carbon black (CCB) was prepared for the construction of an antifouling biosensor. The BSA hydrogel (BSAG) was doped with CCB, and the prepared composite hydrogel exhibited good conductivity originated from the CCB and antifouling capability owing to the BSA hydrogel. An antifouling biosensor for the sensitive detection of cortisol was fabricated by drop-coating the conductive hydrogel onto a poly(3,4-ethylenedioxythiophene) (PEDOT) modified electrode and further immobilizing the cortisol aptamer. The constructed biosensor showed a linear range of 100 pg mL−1 - 10 μg mL−1 and a limit of detection of 26.0 pg mL−1 for the detection of cortisol, and it was capable of assaying cortisol accurately in complex human serum. This strategy of preparing antifouling and conductive hydrogels provides an effective way to develop robust electrochemical biosensors for biomarker detection in complex biological media.

Fusedly Deposited Frequency-Selective Composites Fabricated by a Dual-Nozzle 3D Printing as Microwave Filter.

We report a fusedly deposited frequency-selective composite (FD-FSCs), fabricated with a dual-nozzle 3D printer using a conductive carbon black (CB) polylactic acid (PLA) composite filament and a pure PLA polymer filament. The square frequency-selective pattern was constructed by the conductive CB/PLA nanocomposite, and the apertures of the pattern were filled with the pure dielectric PLA material, which allows the FD-FSC to maintain one single plane, even under bending, and also affects the resonating frequency due to the characteristic impedance of PLA (εr' ≈ 2.0). The number of the deposition layer and the printing direction were observed to affect electrical conductivity, complex permittivity, and the frequency selectivity of the FD-FSCs. In addition, the FD-FSCs designed for an X-band showed partial transmission around the resonant frequency and was observed to, quite uniformly, transmit microwaves in the decibel level of -2.17~-2.83 dB in the whole X-band, unlike a metallic frequency selective surface with full transmission at the resonance frequency. FD-FSCs embedded radar absorbing structure (RAS) demonstrates an excellent microwave absorption and a wide effective bandwidth. At a thickness of 4.3 mm, the 10 dB bandwidth covered the entire X-band (8.2~12.4 GHz) range of 4.2 GHz. Therefore, the proposed FD-FSCs fabricated by dual-nozzle 3D printing can be an impedance modifier to expand the design space and the application of radar absorbing materials and structures.

Crystallization induced segregated structure for outstanding conductive property with low percolation threshold

Conductive polymer composites (CPCs) are promising alternatives to metal conductive materials due to their light-weight and low-cost. This work investigates the effect of the crystallization behavior of the matrix on the electrical property of CPCs, where semi-crystalline polypropylene (PP) and amorphous styrene-butadiene-styrene tri-block copolymer (SBS) are selected as a matrix, respectively, and conductive carbon black (CB) particles are introduced into matrixes by melting blending. Based on the electrical properties of CPCs with various CB contents and percolation theory, the percolation threshold of 1.8 vol% in PP matrix composites is obtained, much lower than that of SBS matrix composites (5.4 vol%). The analysis with a polarizing microscope and differential scanning calorimeter confirms that such a significant difference in percolation threshold between two composites is due to the crystallization behavior while the crystallization induced segregated structure is proposed. Finally, the rheology behaviors and mechanical properties are characterized for microstructures and applications, respectively.

Impalement-Resistant, Mechanically Stable, and Anti-Static Superamphiphobic Coatings Enabled by Solvent Regulation and Their Application in Anti-Icing.

Superamphiphobic coatings have good application prospects in many fields but are limited by their low impalement resistance, weak mechanical stability, and easy adhesion of tiny droplets. Here, impalement-resistant, mechanically stable, and antistatic superamphiphobic coatings were fabricated by spraying a mixture of conductive carbon black (CB), silicone-modified polyester adhesive/fluorinated SiO2 microspheres onto Al alloy. The microspheres were obtained by adhesive phase separation and the binding of fluorinated SiO2 to them. The morphology, superamphiphobicity, impalement resistance, and mechanical stability of the coatings could be regulated by using solvents with different boiling points. As a result, the coatings simultaneously exhibited outstanding mechanical stability, impalement resistance, and superamphiphobicity. The addition of conductive CB endowed the coatings with good antistatic and tiny droplet repellent properties. In addition, the coatings exhibited good anti-icing properties due to the steady air layer at the solid-liquid interface and the very small contact area between them. We suppose that the coatings are very promising for practical application in various fields, including anti-icing, due to their outstanding comprehensive properties and simple preparation process.

Construction of a percolation zone for electrostatic discharge in EPDM/CB composites: A comprehensive mechanism to attain the optimum physico‐mechanical properties

AbstractElectrostatic discharge (ESD) is a critical issue in the automobile industry. ESD can occur due to the rubbing of dissimilar materials, potentially damaging sensitive components. Automakers must use ESD protection to safeguard the reliability of the components. In this scenario, the automotive industries demand for suitable materials to address this problem. The present study focuses on the development of EPDM rubber composites with low‐volume resistivity and optimized physico‐mechanical properties, which are the vital parameters to be addressed in electrostatic discharge for automotive applications. EPDM rubber composites were cured by sulfur and peroxide with a special‐grade conductive carbon black (CB). These composites were analyzed by Fourier Transform Infrared Spectroscopy (FTIR), Thermo gravimetric analysis (TGA), and Differential Scanning Calorimetry (DSC). The dispersion of conductive CB in the polymer matrix was examined using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The BET adsorption technique was employed to investigate the specific surface area and porosity of CB. The ESD behavior of the composites was evaluated by measuring the volume resistivity(ASTM D257). The Studies reveal that the developed material has moderate physico‐mechanical properties and consistent thermal stability. Above all, the conductivity offered by the composite is adequate for ESD applications.Highlights Developed sulfur‐cured EPDM rubber composite with low‐volume resistivity. Peroxide cured EPDM rubber has higher thermal stability than sulfur‐cured one. Carbon black (CB) with a high surface area can easily form a conductive network. A good conductive network is formed at the percolation zone. The hardness of the EPDM composite increases with the loading of CB.

A Facile One-Pot Synthetic Approach Towards CB@PCN-222(Fe) Composites for Simultaneous Electrochemical Detection of Dihydroxybenzene Isomers

A novel porphyrin-metal organic frameworks (MOFs) based hybrid composite was created by combining conductive carbon black (CB) and PCN-222(Fe) (PCN = porous coordination network) via a one-pot strategy. The proposed material unquestionably takes advantage of the high specific area from MOFs and the strong conductivity of CB, which contributes to the contact with analytes and detection sensitivity. A series of analyses showed that the proposed modified electrode could be an alternative candidate for electrochemical detection of dihydroxybenzene isomers. A good linear correlation occurred between the differential pulse voltammetry current and the concentration of hydroquinone (HQ), catechol (CC) and resorcinol (RC) under the optimized conditions. With low detection limits (0.122, 0.094 and 0.243 μM) at the ranges (0.5–280, 0.5–280 and 0.5–320 μM) of these isomers mentioned above, the sensor exhibited good cost-effectiveness, repeatability and stability. Our methodology drives us to directly analyze the dihydroxybenzene isomers in actual samples with dependable recovery, further broadening the electrochemical detection field for environmental pollutants based on porphyrin MOFs.

Achieving superior pyroresistive reproducibility at HDPE/PVDF composites with tailored conductive phase size

AbstractCommercial conductive polymer composites (CPCs) with positive temperature coefficient (PTC) behavior usually suffer from inherent poor reproducibility of pyroresistive property. Herein, a conductive carbon black (CB)/high density polyethylene (HDPE)/polyvinylidene fluoride (PVDF) composite with outstanding PTC reproducibility were prepared through introducing cellulose nanocrystals (CNCs) grafted with methyl methacrylate (CNC‐g‐PMMA). Following the minimum interfacial energy mechanism, the CNC‐g‐PMMA tends to locate in PVDF of binary polymer composites. A much finer morphology of conductive CB/HDPE phase is hence obtained owing to the increasement of PVDF/HDPE viscosity ratio by introducing CNC‐g‐PMMA. Undergoing multiple repeated temperature cycles, the room temperature resistance and PTC intensity of as‐prepared material keep almost unchanged, which demonstrates superior PTC reproducibility. The improving mechanism of PTC reproducibility has also been illustrated in detail. This research provides a facile and valid strategy to enhance the PTC reproducibility and will vastly expand the application of PTC composites in the field of intelligent temperature management.Highlights Assembling binary polymer‐based PTC materials with cocontinuous structure Nanocrystals enables conductive HDPE phase with finer morphology. The precise ranges of viscosity ratio ensure the co‐continuous morphology. Small conductive phase size enhances P reproducibility. Narrow spatial domain restricts the self‐aggregation of conductive fillers.

Effects of Modifying Agent and Conductive Hybrid Filler on Butyl Rubber Properties: Mechanical, Thermo-Mechanical, Dynamical and Re-Crosslinking Properties.

Ionic crosslinking of bromobutyl rubber (BIIR) composites was prepared using butylimidazole (IM) and ionic liquid (IL), combined with carbon nanotubes (CNT) and conductive carbon black (CCB) to enhance the intrinsic properties and heal ability of the resulting composites. Variation in the BIIR/CNT-CCB/IM/IL ratios was investigated to determine the appropriate formulation for healing the composites. Results showed that the mechanical properties were increased until the IM:IL:CNT/CCB ratio reached 1:1:1/1.5, corresponding to the optimal concentration of 5:5:5/7.5 phr. Thermo-oxidative degradation, as indicated using temperature scanning stress relaxation (TSSR), demonstrated the decomposition of the composites at higher temperatures, highlighting the superior resistance provided by the proper formulation of BIIR composites. Additionally, the conditions for the healing procedure were examined by applying pressure, temperature, and time. It was observed that the composites exhibited good elasticity at 0 °C and 60 °C, with a high rate of re-crosslinking achieved under appropriate pressure and temperature conditions. This research aims to develop a formulation suitable for the tire tread and inner liner of commercial car tires together with artificial skin products.