β’’-Al2O3 is used commercially as a Na+ conducting ceramic electrolyte for its high ionic conductivity (0.2-0.3 S cm-1 at 300°C) and low materials’ costs. However, for batteries using β'’-Al2O3, about half of the cell resistance arises from the electrolyte itself because traditionally processed electrolyte materials are 1-2 mm thick. One can anticipate dramatic drops in cell resistance at <100 µm. However, traditional high sintering temperatures of 1600 °C/0-4 h cause rapid and excessive Na2O loss driving formation of the β- rather than β'’-Al2O3 phase lowering ionic conductivities limiting final properties. Known methods of β'’-Al2O3 sintering commonly involve covering the sample with the same powder to reduce Na2O loss. The quality (phase, particle size, particle morphology, etc.) of the starting powder has been shown to have a strong effect on β’’-Al2O3 sintering behavior. In line with our latest success of using flame made nanopowders (NPs) to minimize the external energy input for sintering Li7La3Zr2O12, Li+ conducting ceramic electrolyte known for its difficulty in sintering, we show that the same can be achieved for β’’-Al2O3. In this study, β’’-Al2O3, TiO2 and ZrO2 NPs were produced by liquid-feed flame spray pyrolysis (LF-FSP). The NPs were then processed to green films (80 µm) by tape casting such that β'’-Al2O3 with 0, 1, 2, and 3 wt.% of TiO2 addition is produced. TiO2 was selected to aid sintering as Al3+ vacancies generated by Ti4+ doping promote the sintering process. Furthermore, low melting point (1050-1150 °C) Na2O-TiO2 line compounds form inducing liquid phase sintering. As expected, superior densification of β'’-Al2O3 films occurs with increasing TiO2 wt. %. Near full densities are reached at ≥ 1360 °C/2 h with 2 and 3 wt. % added TiO2. However β’’-Al2O3 content reaches only ~65 wt.% and the orientation of the c-axis is perpendicular to the film surface per XRD. The preferred conduction plane is perpendicular to the c-axis reducing net conductivity. Also, the large grain sizes seen in the 2 and 3 wt. % TiO2 samples suggest liquid phase sintering. To perturb grain reorientation during liquid phase sintering, and also pin grain boundaries to reduce grain growth, we introduced 10 wt. % of ZrO2 with 2 and 3 wt.% TiO2. The added ZrO2 may also reduce Na2O loss rate by reducing surface exposure of β’’-Al2O3. Sintering of the aforementioned samples both reduces final grain sizes and degrees of c-axis orientation. Furthermore, nearly full densities could be accessed at 1320 °C/2 h with 85 wt.% β'’-Al2O3. Ionic conductivities obtained equal those reported by others. Our approach is scalable and economical for mass producing β'’-Al2O3 films. Furthermore, the combination of nanopowders with selected additives allows sintering β'’-Al2O3 at 1320 °C, the lowest ever reported. Work supported on NSF subcontract from Na4B to University of Michigan and by a give from Mercedes-Daimler.