Plasma Conditions Research Articles

Particle transport in reduced turbulence neutral beam heated discharges at Wendelstein 7-X

A spontaneous reduction in anomalous particle transport in the plasma core is seen experimentally in reproducible, purely neutral beam heated plasma phases at Wendelstein 7-X (W7-X). Heating and fueling the plasma exclusively with the neutral beam injection system for several seconds leads to continuously peaking plasma density profiles with strong gradients inside mid minor radius. A significant acceleration of the density peaking occurs after a certain onset time and is examined with a detailed particle transport analysis in several discharges. By invoking the particle continuity equation, the total experimental radial electron flux is deduced from the time evolution of the electron density profile and the radially resolved particle sources. Subtracting the modeled neoclassical particle flux contribution gives the anomalous particle flux. Exploiting the evolving plasma conditions, anomalous diffusion and convection coefficients are computed from the flux variation with density and density gradients. In several discharges a significant and consistent change of the anomalous transport coefficients is seen when crossing a specific normalized density gradient length.

Time Profile Study of Type III Solar Radio Bursts Using Parker Solar Probe

Solar type III radio bursts are crucial indicators of energetic electron activity in the solar corona and interplanetary space. Our assessment of 43 interplanetary type III bursts, recorded by the FIELDS instrument on board the Parker Solar Probe during Encounters 05 to 11, has led to significant and complex findings. We have analyzed time profile features across a frequency range of 19–0.5 MHz, revealing dependencies on frequency and providing insights into duration, burst speeds, bandwidths, and drift rates. This novel analysis has unveiled a spectral index of −0.63 ± 0.04 for rise, −0.69 ± 0.03 for decay time, and −0.68 ± 0.03 for the total duration. We have determined the average electron beam velocities for front, middle, and back as 0.15c, 0.13c, and 0.08c, respectively. Our findings show that faster electron beams generate emissions with shorter duration. The average ratio of the front-to-back velocity is 1.87, and the ratio of front-to-middle velocity is 1.23. We have also discovered a strong relationship between burst duration with rise, peak, and decay times, particularly pronounced with decay time (correlation coefficient = 0.95). This indicates that the entire temporal profile, including rise, peak, and decay phases, collectively contributes to event duration and is not solely influenced by external factors like plasma conditions or electron beam dynamics but also by internal burst processes. These complex findings shed light on the physical mechanisms governing burst dynamics, revealing intricate interactions between electron beam characteristics and observed temporal and spectral traits of type III solar radio bursts.

Bound and resonance states of highly charged H‐ and He‐like ions under weakly coupled plasma environment

AbstractThe position of bound () states as well as doubly excited resonance , () states of symmetry has been determined for highly charged He‐like ions (, , , , , and Ar16+) along with their respective one‐electron thresholds (, , and ) under weakly coupled plasma environment. These particular ions and their respective charge states are selected due to their frequent occurrence in astrophysical and laboratory plasmas. Ritz variational method with multi‐exponent explicitly correlated Hylleraas type basis and pure‐exponential basis set are adopted for tackling He‐ and H‐like ions, respectively. The resonance width of a few low‐lying resonance states is determined using the stabilization method under different plasma conditions. Ionization potential depression is noted for both the bound and resonance states of the plasma‐embedded ions. It is evident that the width (or the lifetime) of the considered resonance states originating from different dominant configurations follows different patterns w.r.t. the plasma screening length.

Nitric and nitrous acid formation in plasma-treated water: Decisive role of nitrogen oxides (NOx=1–3)

Nitrogen fixation using low-temperature plasma, particularly in relation to plasma-treated water (PTW) and its chemical and physical properties, has received a renewed research focus. Dissolving highly concentrated nitrogen oxides (NOx = 1–3) generated by air discharge into water results in the formation of two aqueous oxiacids (nitrous and nitric acids; HNOy = 2,3) and their conjugates (nitrate and nitrite ions; NOy-). Nonlinear formation of these species in PTW with respect to plasma conditions has been observed; however, the significance of the time-varying NOx on this nonlinearity has not yet been thoroughly investigated. Here, we demonstrate real-time observations of HNOy/NOy- as well as NOx production in a surface dielectric barrier discharge reactor containing distilled water. Synchronized two optical absorption spectroscopy systems were employed to simultaneously measure gas-phase NOx and liquid-phase HNOy/NOy- in the plasma reactor operated under different oxygen contents of 5, 20, and 50%. Our results showed that reducing the oxygen content in the reactor accelerated the chemical transition from O3 and NO3 to NO1,2, leading to a predominance of nitrite in PTW. Specifically, the NO3-rich period was extended with increasing O2 content, resulting in the production of nitrate-dominant PTW at low pH levels. Our findings highlight the potential for the selective generation of HNOy/NOy- in PTW through the active and passive control of NOx in a plasma reactor. The direct, real-time observation of NOx–HNOy/NOy- conversion presented here has potential for improving the control and optimization of PTW, thereby enhancing its applicability.

Evolution of pre-damaged ITER grade plasma facing components under WEST plasma exposure: smoothing and tungsten sources

The evaluation of the impact of plasma-facing units (PFUs) damage on subsequent plasma operation is an important issue for ITER. This is one of the topic addressed by the operation of dedicated PFUs in WEST. From the start of WEST in 2017, few ITER grade divertor PFUs were tested in the lower divertor for short plasma exposure (experimental campaigns C1–C5). A PFU is an assembly of tungsten blocks on CuCrZr tube via pure copper interlayer. Since 2022, WEST operates with a lower divertor fully equipped with ITER grade PFUs (experimental campaign C6–C7) with long duration plasma exposure capabilities. To test the ageing of the ITER-grade PFUs on an accelerated basis, well controlled damage was implemented on purpose with electron beam loading on the plasma facing surface of two different PFUs (pre-damage#1 and #2 featuring different level of damage). Damage tackled in this study is induced by the loading with numerous transient heat loading events to mimic the ELM impact on the ITER grade PFU. This paper presents the damage before and after WEST plasma exposure and shows the tungsten sources and temperature of the block measured during the operation. On damaged area, surface roughening is heterogeneous. With WEST campaigns (C3, C4 and C7) respectively ended in (2018, 2019 and 2023) a global smoothing of the pre-damaged surfaces, in particular those located in the high loaded erosion area, is observed. No evolution of the crack is observed in the electron beam loaded area, while new cracking are observed on non pre-damaged area on the tungsten top surfaces in highly loaded areas (outer strike point) after significant plasma duration and cumulated energy (first observation in C4 and tends to be confirmed with preliminary observations after the C7 campaign). Smoothing is less pronounced after the 2018 campaign, which may be due to the related short plasma duration. The surface smoothing of blocks also depends on their poloidal position. For PFU which has no shaping, toroidal positioning within a block has no influence on the surface smoothing. After 2019 and 2023 campaigns, equivalent relative smoothing is obtained (between 19 and 32%). For the explored plasma conditions, damage has no influence on the maximum brightness of W.

D4-Chip Reveals Impaired T Cell Function in Sepsis: Insights from Plasma Microenvironment Analysis and Mitochondrial Targeted Therapy.

Sepsis, a systemic inflammation syndrome initiated by infection, poses significant challenges due to its intricate pathophysiology. T cells play a crucial role in combating infections during sepsis. Despite previous observations indicating T cell dysfunction in sepsis, reliable in-vitro detection methods were lacking, and the factors influencing these impairments remained unclear. We developed a novel method using the D4-Chip to assess sepsis T cell migration function. This microfluidic platform enabled precise analysis of migration function under controlled conditions. Additionally, We explored the impact of the plasma microenvironment on T cell behavior, along with the redox environment in sepsis, and assessed the potential efficacy of Mitoquinone mesylate (MitoQ), a mitochondrial-targeted drug. Our findings revealed impaired migration function in sepsis T cells compared to healthy controls. Interestingly, sepsis plasma enhanced the migration of healthy T cells, yet incubation with healthy plasma did not fully restore migration impairments in sepsis T cells. Subsequent investigations uncovered a significant increase in NADH/NAD+ levels in sepsis T cells, with healthy T cells exposed to various sepsis plasma conditions also showing elevated NADH/NAD+ levels. Importantly, MitoQ normalized abnormal intracellular NADH/NAD+ levels and enhanced the migration ability of T cells. Short-term incubation with sepsis plasma does not directly inhibit T cell migration but instead affects T cell function by disrupting the intracellular redox environment. Improving the intracellular redox environment of sepsis patients contributes to restoring impaired migration and proliferation, with MitoQ demonstrating therapeutic potential.

(Invited) Progresses on Plasma Processing of Halide Perovskite Materials for Photovoltaic Applications

Metal halide perovskite (MHPs) solar cells represent a promising newcomer in the front of emerging photovoltaic technologies to address the dramatic energy crisis and climate change that we are facing. The exceptional properties of MHPs derive from their hybrid organic-inorganic nature, which allows also for low-cost and straightforward processing. Solar cells containing MHPs as absorbing layer have already achieved a power conversion efficiency of about 25,7 %, close to the efficiency of silicon-based devices. Nevertheless, a major limitation, still preventing the uptake of the technology, is related to the reduced stability of these materials when exposed to operative conditions, namely temperature, light, and moisture. Herein, an effective defect passivation of MHP surfaces is a key strategy to tackle both the stability and the enhancement of solar cell performances. Although many solution-based approaches 1 have been tested, we propose here an innovative use of plasma, as a solvent-free, scalable, and non-invasive promising strategy to boost MHP solar cells performances 2. As starting point we exposed the surface of Methylammonium Lead Iodide perovskite thin films to different plasma conditions implying the variation of power, gas, and treatment time, both for low-pressure (LP) and atmospheric pressure plasmas (APPs). The impact of Ar, , and LPPs on MAPbI3 optochemical properties and morphology was correlated to the performance of the photovoltaic devices and rationalized by density functional theory calculations3. Herein an interesting improvement in photoluminescence was observed for the Ar and treated films, while an improvement in PCE was observed only for the Ar treated device. This result was ascribed to the efficient removal of the superficial organic component, revealed through X-ray photoelectron spectroscopy (XPS), following suitable surface passivation by the electron transporting layer deposition. Following these results, we tested APP treatments, finding a milder morphological modification than LPP treatments but withstanding good surface passivation, as confirmed through the improved photoluminescence intensity, while the effect in terms of photovoltaic devices is still under investigations. Moving from these encouraging results, we applied plasma surface treatments to tin-based perovskite, finding a very interesting beneficial effect when reductive plasma conditions (forming gas) were used on FaSnI3 thin film.4 The collection of these results already show the great versatility and potential of plasma-based techniques for the intelligent modification of metal halide perovskite for solar energy conversion.

Effect of Discharge Gas Composition on SiC Etching in an HFE-347mmy/O2/Ar Plasma.

This study explores the impact of varying discharge gas compositions on the etching performance of silicon carbide (SiC) in a heptafluoroisopropyl methyl ether (HFE-347mmy)/O2/Ar plasma. SiC is increasingly favored for high-temperature and high-power applications due to its wide bandgap and high dielectric strength, but its chemical stability makes it challenging to etch. This research explores the use of HFE-347mmy as a low-global-warming-potential (GWP) alternative to the conventional high-GWP fluorinated gasses that are typically used in plasma etching. By examining the behavior of SiC etch rates and analyzing the formation of fluorocarbon films and Si-O bonds, this study provides insights into optimizing plasma conditions for effective SiC etching, while addressing environmental concerns associated with high-GWP gasses.

Plasma Dynamics and Electron Transport in a Hall-Thruster-Representative Configuration with Various Propellants: I—Variations with Discharge Voltage and Current Density

The results from a wide-ranging parametric investigation into the behavior of the collisionless partially magnetized plasma discharge of three propellants—xenon, krypton, and argon—are reported in this two-part article. These studies are performed using high-fidelity reduced-order particle-in-cell (PIC) simulations in a 2D configuration that represents an axial–azimuthal cross-section of a Hall thruster. In this part I paper, we discuss the effects of discharge voltage and current density (mass flow rate). Our parametric studies assess the spectra of the resolved instabilities under various plasma conditions. We evaluate the ability of the relevant theories from the literature to explain the variations in the instabilities’ characteristics across the studied plasma parameter space and for various propellants. Moreover, we investigate the changes in the electrons’ cross-magnetic-field transport, as well as the significance of the contribution of different momentum terms to this phenomenon across the analyzed cases. In terms of salient observations, the ion acoustic instability (IAI)-related modes are found to be dominant across the simulation cases, with the ion transit time instability also seen to develop at low current density values. Across the explored parameter space, the instabilities have the main contributions to the electrons’ transport within the plume region. The peak of the electric momentum force term, representing the effect of the instabilities, overall shifts toward the plume as either the current density or the discharge voltage increases. The numerical findings are compared against relevant experimental observations reported in the literature.

A study on neutron emission for proton-induced reactions in 90Zr, 91Zr, and 115In isotopes

Fusion energy heralds the potential of a transformative era, offering a significant solution to global challenges such as climate change, ozone depletion and environmental pollution. Despite its promising prospects, the commercialization of fusion faces several challenges, including high temperature, pressure, plasma stability, fuel supply, costs, etc. It is important to effectively analyze material behavior under plasma conditions, especially in environments where fusion reactions produce high-energy particles such as neutrons. This study investigates the angle-dependent neutron production mechanisms of proton-induced reactions involving the isotopes 90Zr, 91Zr and 115In, which are widely used in fusion reactor materials. Using the Monte Carlo codes PHITS 3.32 and FLUKA, as well as the TALYS 1.96 code, double differential cross-section calculations for neutron emission were performed considering various angles. The research contributes to a broader understanding of fusion processes by providing insights into the behavior of these isotopes under proton-induced reactions.

Study of Plasma Flow Velocity in an Open SMOLA Screw Trap

The physics of confinement of a rotating plasma in a magnetic field with linear helical symmetry is being studied at the Institute of Nuclear Physics SB RAS on the open SMOLA trap. An indicator of the quality of confinement is the plasma flow velocity in the system. The paper describes the applied diagnostics based on the Mach probe under conditions of non-magnetized plasma, which made it possible to determine the longitudinal flow velocity in experiments. The measured longitudinal flow velocity was (0.5–5) · 106 cm/s in various operating modes of the installation. The dependence of the speed on the magnitude of the magnetic field corrugation is discussed. A reverse flow of trapped particles returning to the containment zone has been detected.

Time-of-flight vs time-of-arrival in neutron spectroscopic measurements for high energy density plasmas.

The neutron time-of-flight (nToF) diagnostic technique has a lengthy history in Inertial Confinement Fusion (ICF) and High Energy Density (HED) Science experiments. Its initial utility resulted from the simple relationship between the full width half maximum of the fusion peak signal in a distant detector and the burn averaged conditions of an ideal plasma producing the flux [Lehner and Pohl, Z. Phys. 207, 83-104 (1967)]. More recent precision measurements [Gatu-Johnson etal., Phys. Rev. E 94(8), 021202 (2016)] and theoretical studies [Munro, Nucl. Fusion 56, 035001 (2016)] have shown the spectrum to be more subtle and complicated, driving the desire for an absolute calibration of the spectrum to disambiguate plasma dynamics from the conditions producing thermonuclear reactions. In experiments where the neutron production history is not well measured, but the neutron signal is preceded by a concomitant flux of photons, the spectrum can be in situ calibrated using a set of collinear detectors to obtain a true "time-of-flight" measurement. This article presents the motivation and overview of this technique along with estimates of the experimental precision needed to make useful measurements in existing and future nToF systems such as the pulsed power Z-machine located in Albuquerque, NM, at Sandia National Laboratories.

Development of improved higher-order correction for the NIF opacity spectrometer.

X-ray opacity measurements on the National Ignition Facility (NIF) are in the process of reproducing earlier measurements from the Sandia Z Facility, in particular for oxygen and iron plasmas. These measurements have the potential to revise our understanding of the "solar problem" and of the hot degenerate Q class white dwarf structure by probing plasma conditions near the base of their convection zones. Accurate opacity measurements using soft x-ray Bragg crystal spectrometers require correction for higher-order diffraction effects. Extending prior work in this area [Dutra etal., Review of Scientific Instruments 93, 113527 (2022)], we have developed a new method to remove higher-order spectral components from NIF opacity spectrometer data. By modeling absorption and backlighting continuum spectra and subtracting the second- and third-order components from the measured data, we are able to perform this correction while avoiding imprinting first-order model line features onto the data.

The Orbitron: A crossed-field device for co-confinement of high energy ions and electrons

To explore the confinement of high-energy ions above the space charge limit, we have developed a hybrid magnetic and electrostatic confinement device called an Orbitron. The Orbitron is a crossed-field device combining aspects of magnetic mirrors, magnetrons, and orbital ion traps. Ions are confined in orbits around a high-voltage cathode with co-rotating electrons confined by a relatively weak magnetic field. Experimental and computational investigations focus on reaching ion densities above the space charge limit through the co-confinement of electrons. The experimental apparatus and suite of diagnostics are being developed to measure the critical parameters, such as plasma density, particle energy, and fusion rate for high-energy, non-thermal plasma conditions in the Orbitron. Initial results from experimental and computational efforts have revealed the need for cathode voltages on the order of 100–300 kV, leading to the development of a custom high voltage, ultra-high vacuum bushing rated for 300 kV.

Statistical data analysis of x-ray spectroscopy data enabled by neural network accelerated Bayesian inference.

Bayesian inference applied to x-ray spectroscopy data analysis enables uncertainty quantification necessary to rigorously test theoretical models. However, when comparing to data, detailed atomic physics and radiation transfer calculations of x-ray emission from non-uniform plasma conditions are typically too slow to be performed in line with statistical sampling methods, such as Markov Chain Monte Carlo sampling. Furthermore, differences in transition energies and x-ray opacities often make direct comparisons between simulated and measured spectra unreliable. We present a spectral decomposition method that allows for corrections to line positions and bound-bound opacities to best fit experimental data, with the goal of providing quantitative feedback to improve the underlying theoretical models and guide future experiments. In this work, we use a neural network (NN) surrogate model to replace spectral calculations of isobaric hot-spots created in Kr-doped implosions at the National Ignition Facility. The NN was trained on calculations of x-ray spectra using an isobaric hot-spot model post-processed with Cretin, a multi-species atomic kinetics and radiation code. The speedup provided by the NN model to generate x-ray emission spectra enables statistical analysis of parameterized models with sufficient detail to accurately represent the physical system and extract the plasma parameters of interest.

Issues of ensuring the resistance of high-voltage solar arrays of spacecraft to the effects of secondary arc discharges

We have considered the issues of ensuring the resistance of high-voltage solar battery (SB) of spacecraft to the effects of secondary arc discharges. Research in this area has been going on for more than 50 years, but the answer to all the questions has not yet been found. First of all, this is due to the complexity of the electrophysical processes occurring on the surface of the spacecraft in space and in laboratory conditions. The second reason is the random nature of secondary vacuum arc discharges, which requires the use of special test methods to confirm the effectiveness and reliability of selected design and technological solutions. Tests in conditions close to full-scale conditions do not allow us to solve this problem. We have given a retrospective review of publications on the physical features of secondary arcs arising on SB of spacecraft, the mechanisms of their initiation, experimental research and testing methods. We paid considerable attention to the issues of the occurrence of secondary arc discharges SB of the spacecraft in the conditions of ionospheric plasma and plasma generated by electric propulsion thrusters. We have shown that despite the large amount of accumulated data and knowledge, the transition from low-voltage SB to high-voltage SB remains a difficult scientific and technical problem, which requires additional research to solve. In addition, it is already necessary to start training personnel who possess a wide range of knowledge and are able to work on this topic. To do this, it seems advisable to organize sectoral research, as well as the allocation of targeted funds for the training of highly qualified specialists and their independent research. This approach will make it possible to solve the problem of creating high-voltage SB in the shortest possible time and prepare personnel for the development of this technology.

Harmonic Generation in Molecular Ag2S Plasma.

The molecular laser-induced plasma (LIP) produced during the ablation of silver sulfide (Ag2S) was used as a medium for high-order harmonic generation in the extreme ultraviolet range. The role of LIP formation, the plasma components, and the geometry of plasma in the harmonic conversion efficiency was analyzed. We also analyzed the influence of the driving pulses (chirp, single-color pump, two-color pump, and delay between heating and converting pulses) on the harmonic yield in Ag2S LIP. The application of molecular plasma was compared with the application of atomic plasma, which comprised similar metallic elements (Ag) as well as other metal LIPs. The harmonics from the Ag2S LIP were 4 to 10 times stronger than those from the Ag LIP. The harmonics up to the 59th order were achieved under the optimal conditions for the molecular plasma.

Measurements of atomic hydrogen recombination coefficients and the reduction of Al2O3 using a heat flux sensor

The knowledge of atomic hydrogen recombination coefficient (γ) is essential for plasma simulations to calculate accurate atomic hydrogen fluxes. However, γ is a complex material property, and it is affected by the experimental conditions under which it is measured. Therefore, values of γ can differ even by a few orders of magnitude for the same material. In this paper, we demonstrate measurements of hydrogen recombination coefficients at room temperature using an in-house-built catalytic sensor for two selected materials: aluminum Al-5083 (alimex) and stainless steel 316 l, under the load of low-temperature H2 plasma with an admixture of H2O or N2 gases. The plasma settings were carefully chosen to mimic properties of the so-called extreme ultraviolet-generated plasma.1 The measured γ values agree well with literature data obtained for similar plasma conditions and show a correlation with ion energy. Additionally, we show a novel application of the sensor for indirect measurements of the reduction of oxidized surfaces as a function of ion dose. In these experiments, a correlation between reduction time and background water pressure is observed.

Kinetic simulations of dust grain charging in experimental plasma conditions

This paper presents fully-kinetic numerical investigations of the charging of spherical and irregular dust grains in the OML sheath regime and a stationary experimental plasma environment utilizing the Dusty Parallel Immersed-Finite-Element Particle-in-Cell (PIFE-PIC-D) framework. The simulations account for surface charging of the dust grains immersed in an stationary plasma environment. PIFE-PIC-D explicitly resolves the geometrical and material properties (permittivity) of each individual dust grain. The charge collection over time of each dust grain is investigated with varying size, irregularity, number of grains, spacing between dust grains, and permittivity. The charging behavior of a dust cluster is estimated by calculating its electron Debye length edge-to-edge separation to offer valuable insights into a dust cluster’s general charge dynamics. Lastly, unlike prior studies that focused solely on either fully conducting spheres or perfectly dielectric spheres, this work explores a more comprehensive range of permittivities for irregular dust grain aggregates.

Optimization of separation and MC-ICP-MS methods for determining Eu isotopic ratios in Si- and Ba-rich fractionated igneous rocks and other natural materials

Eu isotope ratio can be precisely measured by MC-ICP-MS using a Sm isotope pair as spike for normalization. The standard chemical reagent NIST3117a exhibits almost no Eu isotope fractionation regardless of the kind of Sm isotope pairs used in normalization. However, Eu isotope fractionation can appear even in high purity Eu chemical reagents due to Gd and Ba impurities, interference with Sm isotope pair or use of different sample introduction methods. The Eu isotope fractionation in highly fractionated igneous rocks or feldspar minerals can arise from Gd and Ba impurities left by incomplete chemical separation. This study describes a modified, optimal method for accurately and precisely determining the degree of Eu isotope fractionation in highly fractionated Si-rich igneous rocks and Ba-rich feldspar. Ba oxide effects on Sm, Eu and Gd isotopes were monitored by MC-ICP-MS using different wet and dry plasma conditions for sample introduction. The Gd impurities exerts more influence than Ba impurities on Eu isotope ratios. The highly fractionated igneous rocks and feldspar materials showed consistent enrichment in the lighter Eu isotope (151Eu) which becomes a negative Eu isotopic value relative to NIST3117a. Results showed that highly purified Eu solutions from reagents containing no detectable Gd and Ba gave consistent Eu isotopic values regardless of Sm isotope pair (e.g., 147Sm149Sm, 147Sm152Sm, 147Sm154Sm, 149Sm154Sm, 150Sm154Sm) used in normalization. In order to obtain the best estimates of Eu isotope fractionation in different kinds of geological materials (including Si- and Ba-rich materials), Ba and Gd matrix must be completely removed and the Eu isotopic values calculated using four or more Sm spike isotope pairs.