Low Temperature Conditions Research Articles

Imaging Nanomechanical Vibrations and Manipulating Parametric Mode Coupling via Scanning Microwave Microscopy.

In this study, we present a novel platform based on scanning microwave microscopy for manipulating and detecting tiny vibrations of nanoelectromechanical resonators using a single metallic tip. The tip is placed on the top of a grounded silicon nitride membrane, acting as a movable top gate of the coupled resonator. We demonstrate its ability to map mechanical modes and investigate mechanical damping effects in a capacitive coupling scheme, based on its spatial resolution. We also manipulate the energy transfer coherently between the mode of the scanning tip and the underlying silicon nitride membrane, via parametric coupling. Typical features of optomechanics, such as anti-damping and electromechanically induced transparency, have been observed. Since the microwave optomechanical technology is fully compatible with quantum electronics and very low temperature conditions, it should provide a powerful tool for studying phonon tunnelling between two spatially separated vibrating elements, which could potentially be applied to quantum sensing.

Fluid-Solid-Thermal Coupled Freezing Modeling Test of Soil under the Low-Temperature Condition of LNG Storage Tank

Due to the extensive utilization of liquid nature gas (abbreviated as LNG) resources and a multitude of considerations, LNG storage tanks are gradually transitioning towards smaller footprints and heightened safety standards. Consequently, underground LNG storage tanks are being designed and constructed. However, underground LNG storage tanks release a considerable quantity of cold into the ground under both accidental and normal conditions. The influence of cold results in the ground freezing, which further compromises the safety of the structure. Existing research has neglected to consider the effects of this. This oversight could potentially lead to serious safety accidents. In this work, a complete set of experiments using a novel LNG underground storage tank fluid-solid-thermal coupled cryogenic leakage scale model were conducted for the first time to simulate the effect of the tank on the soil temperature field, stress field, and displacement field and to analyze the development of the three fields and the results of the effect. This research helps the related personnel to better design, construct, and evaluate the LNG underground storage tanks to avoid the catastrophic engineering risks associated with cryogenic leakage and helps to improve the design process of LNG underground storage tanks.

Cobalt remobilization during tectonic–hydrothermal overprinting: A case from the Tuolugou Co(–Au) deposit in East Kunlun Orogenic Belt, China

Stratiform Cu-Co deposits hosted in (meta-) sedimentary and volcaniclastic rocks contribute two-thirds of the global Co supply. However, the mechanisms driving Co remobilization during tectonic-hydrothermal overprinting events remain poorly understood. As a dominant Co repository, pyrite can provide valuable insights into mineralization history due to its refractory nature. Here, we present the first micro-analytical investigation of pyrite from the Tuolugou Co(–Au) deposit in East Kunlun Orogenic Belt. Ore textures indicate that Co mineralization is attributed to two distinct stages: primary enrichment and subsequent overprinting processes. The former is characterized by pyrite (PyI with up to 3.92 wt% Co) remnants exhibiting oscillatory zones, while the latter is marked by deformation of pyrite (PyII) ores. Three overprinting episodes, namely Da, Db, and Dc, are further distinguished according to varying extents of deformation and mineral assemblages. The Da is characterized by synkinematic PyIIa (up to 4.18 wt% Co) augens, which were most likely formed via pressure–solution mechanism. The Db is represented by polygonal PyIIb (up to 4.75 wt% Co) and siegenite with 120° triple–point junctions. The random orientation and rare intragrain misorientation of cobaltiferous sulfides at Db suggest their formation by recrystallization without plastic strains. The Dc resulted in the formation of Co ± As–rich PyIIc (up to 5.36 wt% Co) along with minor occurrence of cobaltite–gersdorffite, pyrrhotite (up to 1.25 wt% Co), and marcasite (up to 1.28 wt% Co). The PyIIc replacing PyI underscores the role of fluid-coupled dissolution and precipitation during fluid–rock interactions in the formation of these cobaltiferous sulfide assemblages at Dc. The presence of PyIIc infilling within the PyI fissures, in conjunction with the transition from siegenite to cobaltite–gersdorffite, suggests a shift towards low fO2 and low temperature conditions under relatively brittle setting. There is a discernible disparity in sulfur isotope compositions between the two mineralization stages. The PyI exhibits a narrow range of δ34SV–CDT values from –2.14 to 1.35 ‰, indicating a magmatic sulfur origin. In contrast, PyII displays a wide δ34SV–CDT range of –5.22 to 6.16 ‰, suggesting an involvement of strata sulfur during the overprinting stage. Monazite U-Pb dating has effectively constrained two mineralization events. The ca. 453 Ma age implies a potential correlation of the primary Co mineralization with the Late Ordovician to Early Silurian exhalative-syngenetic processes in a Proto–Tethyan-related post–collisional extension setting. Conversely, the ca. 190 Ma age indicates that Co remobilization was instigated by the early Mesozoic ductile–brittle deformation associated with the Paleo-Tethyan orogenesis. Finally, geochemical modeling was performed by simulating the interaction of a Co-rich acidic, reducing fluid with typical quartz-albitite rocks. The simulations demonstrate the appearance of independent Co minerals such as Co-pentlandite during the reaction progression, greatly supporting ore upgrading via tectonic-hydrothermal overprinting.

Metagenomics-based gene exploration and biochemical characterization of novel glucoamylases and α-amylases in Daqu and Pu-erh tea microorganisms

α-Amylases and glucoamylases play a crucial role in starch degradation for various industrial applications. Further exploration of novel α-amylases and glucoamylases with diverse enzymatic characteristics is necessary. In this study, metagenomics analysis revealed a high abundance of these enzymes in the microorganisms of Daqu and Pu-erh tea, identifying 271 glucoamylases and 232 α-amylases with significant sequence identity to known enzymes. Functional studies indicated that these enzymes have broad optimal temperatures (30 °C to 70 °C) and acidic or neutral pH optima. Additionally, two novel low-temperature glucoamylases and one novel low-temperature α-amylases were characterized, demonstrating potential for use in industries operating under low temperature conditions. Further analysis suggested that fewer molecular interactions and more flexible coli regions may contribute to their high activity at low temperatures. In summary, this study not only highlights the feasibility of exploring enzymes through metagenomic approaches, but also presents a library of novel and diverse α-amylases and glucoamylases for potential industrial applications.

A setup for synchrotron infrared microspectroscopy and imaging under magnetic field and low temperature.

Infrared spectroscopy is a powerful spectroscopic technique for investigating the vibrational and electronic states of matter. Temperature and magnetic field provide important methods to manipulate these states by an external field. Recent advancements have underscored the necessity for investigating small samples like two-dimensional materials with high spatial resolution. In this article, we introduce a versatile setup at the synchrotron infrared beamline, which combines synchrotron infrared microspectroscopy and imaging techniques with the application of magnetic fields and low temperature conditions. This setup facilitates infrared microscopic imaging in magnetic fields up to 8T and temperatures as low as 5K, offering a distinctive tool for probing the physical properties of materials under magnetic field and temperature manipulation. This is particularly relevant for studying two-dimensional materials, single cells, and other small samples in geoscience and environmental science, as well as multi-component heterogeneous properties in quantum materials, polymer materials, energy materials, etc.

Enhancement-mode Ga2O3 FETs with an unintentionally doped (001) β-Ga2O3 channel layer grown by metal-organic chemical vapor deposition

High-quality unintentionally doped (UID) (001) β-Ga2O3 homoepitaxial films were grown on native substrates through metalorganic CVD. The surface parallel grooves were repaired under low temperature and pressure conditions, reaching the surface roughness of 2.22 nm and the high electron mobility of 74.6 cm2/Vs. Enhancement-mode MOSFETs were fabricated on the UID β-Ga2O3 film, showing a positive turn-on threshold gate voltage of 4.2 V and a breakdown voltage of 673 V. These results can serve as a reference for (001)-oriented lateral Ga2O3 power transistors and may contribute to the development of Ga2O3 power devices.

Desulfurising Fuels Using Alcohol-Based Deep Eutectic Solvents Using Extractive Catalytic Oxidative Desulfurisation Method

Removal of sulfur compounds from transportation fuels is a requirement in the worldwide effort to reduce emissions from transportation fuels. Refineries use the hydrodesulfurisation (HDS) process to reduce sulfur compounds in fuels. However, the HDS process requires high hydrogen pressure and temperature, making it costly. An alternative to the HDS process is oxidative desulfurisation via solvent extraction, which requires low-temperature operating conditions. In this regard, deep eutectic solvents (DESs) are attractive for researchers to desulfurise transportation fuels via solvent extraction due to their low-cost. In our study, DESs were synthesised using phenylacetic acid (PAA) and salicylic acid (SAA) as hydrogen bond acceptors (HBAs) and tetraethylene glycol (TTEG) as hydrogen bond donor (HBD) in the mole ratio of 1:2. DESs were characterised by using Fourier transform infrared (FTIR) spectroscopy. Physicochemical properties of DESs, such as density, viscosity and refractive index, were also measured. The synthesised DESs were used to extract organosulfur compounds from model fuel and actual diesel. An oxidation study was carried out for model fuel and diesel, followed by solvent extraction using these synthesised DESs. The extraction efficiency for PAA/TTEG(1:2) and SAA/TTEG(1:2) was achieved as 50.16% and 38.89% for model fuel at a temperature of 30°C using a solvent to feed ratio of 1.0 while for diesel, it was 38% and 37%. However, it increased to 77%, 68% and 54%, 73%, respectively, for PAA/TTEG(1:2) and SAA/TTEG(1:2) when the feedstocks were oxidised. These results showed better extraction performance of DES PAA/TTEG(1:2) than that of SAA/TTEG(1:2) at low temperature 30°C using combined extractive catalytic oxidative desulfurisation. Hence, the DES synthesised using SAA and TTEG in the molar ratio of 1:2 works better as an extraction solvent for removing organic sulfur compounds from fuels at low temperatures.

Robotic-based terahertz spectroscopy imaging for non-destructive monitoring of water loss-induced damage in timber materials under low temperature stress

Timber materials are widely used in various industries, from construction to furniture manufacturing. One of the critical factors affecting the structural integrity and longevity of timber is water loss-induced damage, which often occurs under low-temperature stress conditions. Monitoring and assessing this damage traditionally involve invasive and time-consuming methods. This study explores the application of robotic-based terahertz spectroscopy 3D imaging as a non-destructive and efficient system for assessing the impact of water loss on timber materials under low-temperature stress. The detection and localization of damage in a various species of timber-based structures were experimentally investigated by performing pulsed terahertz time-domain spectroscopy and using a six- DOF (degree-of-freedom) robotic arm. The thickness and damage length were monitored by designing the reflection geometry of the terahertz scanner. Additionally, the terahertz source was controlled with a six-DOF robot arm for path planning. The corresponding measured dielectric property reference value for the damage identification was computed using a captured terahertz wave at 12% of moisture content. The reflected signals were analyzed to determine the thickness, defectiveness, and locations of the defects through signal processing in the time and frequency domains. Finally, the validity of the structural health monitoring approach for 3D detection and visualization of water loss-induced defects in timber structures using terahertz waves, was discussed.

A cryogenic forced oscillation apparatus to measure anelasticity of ice.

We have developed a new cryogenic uni-axial forced oscillation apparatus to measure the anelastic behavior of ice by adapting the design of a previous high-precision apparatus for use in low-temperature (<0 °C) conditions. With this new apparatus, Young's modulus and attenuation can be measured over a broad frequency range from 10-4 to 10Hz. We have performed calibration tests with standard materials (steel spring, stainless steel, and acrylic samples) under various conditions to assess the apparatus properties and correct the effects on the obtained raw data. Young's modulus and attenuation for an acrylic sample after all of the data corrections show good agreement with previously published values, demonstrating the validity of the data corrections and reliability of the obtained data. We further obtained a preliminary dataset of Young's modulus and attenuation for an ice polycrystalline sample under small median stress and small stress amplitude. The anelastic response was not strain amplitude-dependent, that is, the response is linear. Moreover, the attenuation data are consistent with the data measured for other polycrystalline materials under similarly small stress conditions in terms of the Maxwell frequency scaling, which is known as a scaling law applicable to linear anelasticity induced by the diffusionally accommodated grain boundary sliding mechanism. Although there is still room for improving the control of testing conditions, we show that the new forced oscillation apparatus is capable of systematic studies on the anelastic properties of ice, the subject of future studies.

Comparative Phenotypic and Transcriptomic Analyses Provide Novel Insights into the Molecular Mechanism of Seed Germination in Response to Low Temperature Stress in Alfalfa.

Low temperature is the most common abiotic factor that usually occurs during the seed germination of alfalfa (Medicago sativa L.). However, the potential regulatory mechanisms involved in alfalfa seed germination under low temperature stress are still ambiguous. Therefore, to determine the relevant key genes and pathways, the phenotypic and transcriptomic analyses of low-temperature sensitive (Instict) and low-temperature tolerant (Sardi10) alfalfa were conducted at 6 and 15 h of seed germination under normal (20 °C) and low (10 °C) temperature conditions. Germination phenotypic results showed that Sardi10 had the strongest germination ability under low temperatures, which was manifested by the higher germination-related indicators. Further transcriptome analysis indicated that differentially expressed genes were mainly enriched in galactose metabolism and carbon metabolism pathways, which were the most commonly enriched in two alfalfa genotypes. Additionally, fatty acid metabolism and glutathione metabolism pathways were preferably enriched in Sardi10 alfalfa. The Weighted Gene Co-Expression Network Analysis (WGCNA) suggested that genes were closely related to galactose metabolism, fatty acid metabolism, and glutathione metabolism in Sardi10 alfalfa at the module with the highest correlation (6 h of germination under low temperature). Finally, qRT-PCR analysis further validated the related genes involved in the above pathways, which might play crucial roles in regulating seed germination of alfalfa under low temperature conditions. These findings provide new insights into the molecular mechanisms of seed germination underlying the low temperature stress in alfalfa.

Weather-related changes in the dehydration of respiratory droplets on surfaces bolster bacterial endurance

HypothesisThe study shows for the first time a fivefold difference in the survivability of the bacterium Pseudomonas Aeruginosa (PA) in a realistic respiratory fluid droplet on fomites undergoing drying at different environmental conditions. For instance, in 2023, the annual average outdoor relative humidity (RH) and temperature in London (UK) is 71 % and 11 °C, whereas in New Delhi (India), it is 45 % and 26 °C, showing that disease spread from fomites could have a demographic dependence. Respiratory fluid droplet ejections containing pathogens on inanimate surfaces are crucial in disease spread, especially in nosocomial settings. However, the interplay between evaporation dynamics, internal fluid flow and precipitation and their collective influence on the distribution and survivability of pathogens at different environmental conditions are less known. ExperimentsShadowgraphy imaging is employed to study evaporation, and optical microscopy imaging is used for precipitation dynamics. Micro-particle image velocimetry (MicroPIV) measurements reveal the internal flow dynamics. Confocal imaging of fluorescently labelled PA elucidates the bacterial distribution within the deposits. FindingsThe study finds that the evaporation rate is drastically impeded during drying at elevated solutal concentrations, particularly at high RH and low temperature conditions. MicroPIV shows reduced internal flow under high RH and low temperature (low evaporation rate) conditions. Evaporation rate influences crystal growth, with delayed efflorescence and extending crystallization times. PA forms denser peripheral arrangements under high evaporation rates and shows a fivefold increase in survivability under low evaporation rates. These findings highlight the critical impact of environmental conditions on pathogen persistence and disease spread from inanimate surfaces.

Chemical characteristics and formation mechanism of secondary inorganic aerosols: The decisive role of aerosol acidity and meteorological conditions

In recent years, there has been a growing concern about air pollution and its impact on the air quality and human health, especially for fine particulate matter (PM2.5) and its associated secondary aerosols in urban areas. This study conducted a year-long field campaign to collect PM2.5 samples day and night in an urban area of central Taiwan. Higher PM2.5 mass concentrations were observed in winter (27.7 ± 9.7 μg/m3), followed by autumn (22.5 ± 8.3 μg/m3), spring (19.2 ± 6.4 μg/m3), and summer (11.0 ± 3.1 μg/m3). The dominant formation mechanism of secondary inorganic aerosols was heterogeneous reactions of NO3− at night and homogeneous reactions of SO42− during the day. Additionally, significant correlations were observed between aerosol liquid water content (ALWC) and NO3− during nighttime, indicating the importance of aqueous-phase NO3− formation. The role of aerosol acidity was explored and a unique alkaline condition was found in spring and summer, which showed lower PM2.5 concentrations than the neutralized condition. Under the neutralized condition, higher PM2.5 concentrations were commonly found when combining the ammonium-rich regime with molar ratios of [NO3−]/[SO42−] exceeding 1.6, suggesting the importance of reducing both NH3 and NOx. Furthermore, the results showed that reducing NH3 should be prioritized under high temperature conditions, while reducing NOx became important under low temperature conditions. Clustering of backward trajectories showed that long-range transport could enhance the formation of secondary aerosols, but local emissions emerged as the main factor driving high PM2.5 concentrations. This study provides insights for policymakers to improve air quality, suggesting that different mitigation strategies should be formulated based on meteorological variables and that using clean energy for vehicles and electricity generation is important to alleviate air pollution.

Stress-induced fluorescence in diamond at ultrahigh pressures and low temperatures

Diamond is widely used as an anvil material in high pressure experiments, such as diamond anvil cell (DAC). The study of the fluorescence emission behaviour of the diamond at high pressure is of great significance for understanding its band structure and optical properties. Here, by combining low-temperature photoluminescence experiments, and fluorescence spectroscopy at controlled pressure (181 GPa–122 GPa) and temperature (296 K–77 K) reveals the relationship between stress-induced diamond fluorescence as a function of temperature and pressure. We also demonstrate that the electron-phonon interaction has an effect on the diamond energy gap, and the temperature and pressure jointly affect the band structure. The electron band gap decreases rapidly under low temperature and high-pressure conditions.

The Capture of Cadmium from Solution during the Replacement of Calcite by Apatite.

The capture of cadmium (Cd) from phosphate-containing solutions during the replacement of CaCO3 by phosphate phases such as hydroxylapatite (HAP) and tricalcium phosphate (TCP) has been studied under high and low temperature and pressure conditions using atomic force microscopy, scanning electron microscopy equipped with an X-ray spectrometer and a backscattered electron detector, Raman spectroscopy, and microprobe analysis. Starting with cubes of Carrara Marble (polycrystalline calcite) and single crystals of calcite, a new solid phosphate phase was observed to incorporate Cd from solution, formed under different pressure and temperature conditions tested. Results showed that Cd precipitated in a new phase on the surface of all samples tested. In Carrara Marble, pseudomorphic replacement of CaCO3 is restricted possibly due to kinetic limitation caused by the adsorption of Cd complexes formed in solution at reactive surface sites and the variation of fluid composition inside the sample. However, on the sample surface, this kinetic limitation is less influential, so the new phase could incorporate higher amounts of Cd faster. Furthermore, this reaction at room temperature was found to have similar and/or better Cd-uptake efficiency as HAP and CaCO3 in pure Cd solution through the precipitation of Cd-containing phosphate crystals on the sample surface. Both reactions were able to capture Cd in the precipitating phase structure and could provide a mechanism for simultaneous Cd and phosphate removal from solutions contaminated with both, in industrial or natural settings.

Sea urchin-like MnO2@Carbon fiber paper @carbon black modified silicone rubber interface control to improve electromagnetic properties and media factors

With the advent of the information age, the proliferation of intelligent devices has also given rise to the issue of electromagnetic pollution. Flexible materials hold significant applications and development prospects in the realm of electronic device shielding. In this study, MnO2 was synthesized through reduction on the surface of carbon fiber paper (CFP), while conductive carbon black (CB) was incorporated into silicone rubber to fabricate a flexible polymer with both surface relative insulation and internal electromagnetic shielding capabilities. Under 1 wt% CB loading, the modified CFP exhibited an electromagnetic shielding performance reaching 33.22 dB, which is 49.5 % higher than that of its original counterpart. By optimizing the thickness of CB within the silicone rubber matrix filling component, impedance matching properties were enhanced for improved material performance. Adjusting medium factors by thickness optimization, at a thickness of 5 mm, the absorption coefficient A for electromagnetic waves entering into the modified CFP increased by 461.7 % compared to that observed in its original form. Furthermore, a contact angle as high as 110° was achieved on the surface of CFP indicating excellent hydrophobicity; moreover, stable adhesion between conductive fillers and surfaces was confirmed through testing procedures conducted thereafter. Additionally, even after undergoing more than ten freezing experiments, over 99 % electromagnetic shielding performance was retained by our developed material ensuring its viability under harsh low temperature conditions.

On the issue of the thermal adaptation of the larvae caucasian brown frog Rаna macrocnemis Boulenger, 1885 (Amphibia, Ranidae) to low-temperature environmental conditions

On the issue of the thermal adaptation of the larvae caucasian brown frog Rаna macrocnemis Boulenger, 1885 (Amphibia, Ranidae) to low-temperature environmental conditions

Bolt-bearing behavior of hybrid CFRP-steel laminates at low temperature

Hybrdization of CFRP with steel sheets enhances bolt-bearing performance. At room temperature, bearing strength is reported to increase while minimum edge and width distances decrease. To assess if this advantage persists under low temperature conditions, bolt-bearing tests following AITM 1-0009 are conducted at 23°C and −55°C. Various monolithic and hybrid configurations with different metal content and joint geometries are examined. Furthermore, ultrasound scanning and optical microscopy of the fracture plane is conducted. Hybridizing composites notably improves bearing capacity. However, the reinforcement effect is less pronounced at low temperatures compared to room temperature. The reduction in minimum edge and width distances with metal hybridization largely depends on the composite ply stacking, challenging general literature recommendations. Regarding damage mechanisms in the joints, fractography indicates that introduction of steel sheets relieves composite plies, isolates damage, and enhances load-bearing capacity through additional bending stiffness and significant plastic deformation of the metal.

Albitization related U and Th mobilization under reducing conditions

Hydrothermally altered quartzofeldspathic gneisses, granites and pegmatites of the West Garo Hills, Shillong Plateau (eastern India) preserve alteration assemblages of monazite, xenotime and zircon comprising thorite and coffinite in the altered domains. Albitization of muscovite and K-feldspars, sericitization of K-feldspar and albite, alteration of biotite to hydrobiotite, and crystallization of tourmaline is suggestive of the involvement of acidic fluids. The microtextural relations and the mineral assemblages indicate prevalence of low-temperature (T < 300 °C) conditions during hydrothermal alteration. The light δ11B values of tourmaline (–15.1 to –13.5 ‰) suggests derivation/interaction of the fluids from/with metapelitic rock and/or S-type granite. Low ‘inferred’ Fe3+/Fe2+ ratio in tourmaline (based on high Al content in Y-site, 0.16–0.56 apfu, avg. 0.36 apfu), estimated excess charge (0.22–0.47, avg. 0.35 apfu) and lack of any Fe–Al relation support a reduced nature of the hydrothermal fluid. Mass balance calculations reveal that Th and U required for the formation of thorite and coffinite, respectively were likely derived from monazite and xenotime, and zircon. Significantly lower Cl─ contents in hydrobiotite (avg. 0.03 wt%) compared to the unaltered biotite (avg. 0.13 wt%) suggests release of Cl─ to the hydrothermal fluid during alteration. Textural evidences of albitization together with Cl─ release from biotite suggest increased Cl─ concentrations in the fluid during hydrothermal alteration. Based on solubility calculations for various U and Th species, we propose that high Cl─ content in the fluid aided mobilization of Th and U as ThCl40 and UCl40/UO2Cl20 complexes from accessory radioactive phases under reducing conditions. These results suggest that significant mobility of U and Th can be achieved in acidic high salinity fluid even under reducing conditions. Thermodynamic calculations for the solubility of Th- and U-chloride complexes and stability of monazite/xenotime in a range of pH and temperature suggest that thorite and coffinite precipitation was the result of an increase in pH.

Electrical Conductivity of Subsurface Ocean Analogue Solutions from Molecular Dynamics Simulations.

Investigating the habitability of ocean worlds is a priority of current and future NASA missions. The Europa Clipper mission will conduct approximately 50 flybys of Jupiter's moon Europa, returning a detailed portrait of its interior from the synthesis of data from its instrument suite. The magnetometer on board has the capability of decoupling Europa's induced magnetic field to high precision, and when these data are inverted, the electrical conductivity profile from the electrically conducting subsurface salty ocean may be constrained. To optimize the interpretation of magnetic induction data near ocean worlds and constrain salinity from electrical conductivity, accurate laboratory electrical conductivity data are needed under the conditions expected in their subsurface oceans. At the high-pressure, low-temperature (HPLT) conditions of icy worlds, comprehensive conductivity data sets are sparse or absent from either laboratory data or simulations. We conducted molecular dynamics simulations of candidate ocean compositions of aqueous NaCl under HPLT conditions at multiple concentrations. Our results predict electrical conductivity as a function of temperature, pressure, and composition, showing a decrease in conductivity as the pressure increases deeper into the interior of an icy moon. These data can guide laboratory experiments at conditions relevant to icy moons and can be used in tandem to forward-model the magnetic induction signals at ocean worlds and compare with future spacecraft data. We discuss implications for the Europa Clipper mission.

Molecular dynamics simulations of wettabilities on shale in three- and four-phase systems

The interfacial properties between three-phase fluid and shale are crucial in carbon dioxide flooding and sequestration. Here, we present an investigation on fluid-solid interfacial properties in the H2O/CO2/decane/shale four-phase system under geological conditions using molecular simulations. The four-phase system exhibits distinct three-phase contacts due to the varying occurrence state of fluids. The method (J. Colloid Interface Sci. 585 (2021) 320-327) for calculating the wettabilities of three-phase systems is not directly applicable to four-phase systems due to the lack of interfaces. The method is extended to four-phase systems by conducting simultaneous simulations of two such systems with different fluid phase positions, ensuring all interfaces are accessible. We found that the relative interfacial free energies at the fluid-solid interfaces and the wettabilities of the H2O/CO2/shale and CO2/decane/shale contacts in the four-phase system are similar to those observed in the corresponding three-phase systems. However, the wettabilities of the H2O/decane/shale contact in the four-phase system significantly differ from those of the H2O/decane/shale three-phase system. The introduction of a CO2 phase not only enhances the wettability but also amplifies this effect, especially under conditions of lower temperatures and higher pressures. For instance, the wettability increases by 35° at 298 K and 6 MPa. This variation in wettabilities is primarily attributed to the substantial influence of CO2 on interfacial energies in the interfaces of decane-solid and H2O-decane. The elevated impact of CO2 at lower temperatures and higher pressures is explained by the enhanced CO2 adsorption in both fluid-solid and fluid-fluid interfaces.