Dispersion Conditions Research Articles

Multifold Topological Point with Quadratic Order in Binary Skutterudite Rhodium Triarsenide.

The exploration of topological nodal point states has recently evolved, moving beyond traditional linear crossings to include higher-order dispersions and multifold degeneracies. This study utilizes first-principles calculations to uncover an ideal multifold nodal point of quadratic order in the binary skutterudite rhodium triarsenide. The band structures around this nodal point show not only simple configuration but also clean distribution. Notably, a type-III dispersion condition has also been identified. When considering the effects of spin-orbit coupling, the nodal point retains both its multiple degeneracy and quadratic characteristics, although the band degeneracy transitions from 3-fold to quadruple. Detailed symmetry argument and model analysis have been provided, and precise band surface distribution has been obtained. Furthermore, the material is characterized by multiple significant arc surface states, as confirmed by the projected topological surface states. The clear separation of these states from the bulk bands facilitates experimental investigation. In summary, the multifold nodal point state identified in this research, along with the corresponding material candidate, presents an exceptional platform for the further study of higher-order topological point states, potentially catalyzing advancements in this emerging field.

Research on a 220-GHz modified staggered double corrugated waveguide backward wave oscillator

The output power of a backward wave oscillator (BWO) is limited by the low interaction impedance of a slow wave structure (SWS) when the frequency is in the THz band. A BWO based on modified staggered double corrugated waveguide (MSDCW) SWS is researched as a high-power source operating at THz band to break through the coupling impedance limitation in this paper. The MSDCW-SWS designed for BWO with wide electronic tunable band is optimized by numerical Eigenmode simulation to obtain higher coupling impedance. The simulation results show that the coupling impedance of MSDCW-SWS at 211.5 GHz is 42% higher than that of the original staggered double corrugated waveguide (SDCW) SWS when the dispersion conditions are the same for both SWSs. The sheet beam MSDCW-BWO with a broadband output structure is designed to operate under voltage between 23 and 49 kV and an electron beam current of 160 mA. The 3-D interaction simulation results reveal that more than 80.6 W of average output power can be produced from 210 to 238 GHz and the highest electron efficiency of 2.5% can be obtained at 211.5 GHz. The MSDCW-BWO can be considered a promising high-power THz source.

Optimizing dissolution and dispersion conditions for metal and metal oxide nanoparticles used as antimicrobial agents

Optimizing dissolution and dispersion conditions for metal and metal oxide nanoparticles used as antimicrobial agents

Efficient CO2 Reduction Reaction on Cu-Decorated Biphenylene.

Developing efficient electrocatalysts for CO2 reduction into value-added products is crucial for a green economy. Inspired by the recent experimental synthesis of biphenylene (BPH) and the excellent catalytic activity of copper dispersed on two-dimensional (2D) materials, we chose to systematically investigate the pristine, defective, and Cu-decorated BPH for the electrocatalytic CO2 reduction to value-added hydrocarbons. It is observed that the CO2 molecules bind weakly to the pristine BPH, indicating their chemical inertness. Carbon single-vacancy defects facilitate CO2 adsorption with a strong binding energy (Eb) of -3.23 eV, detrimental to the CO2 reduction reaction (CRR) mechanism. We have further investigated the binding energy and kinetic stability of Cu-decorated BPH as a single-atom-catalyst (SAC). The molecular dynamics simulations confirm the kinetic stability, revealing that the Cu-atom avoids agglomeration under low metal dispersal conditions. The CO2 molecule gets adsorbed horizontally on the Cu-BPH surface with a ΔEb of -0.52 eV. The CRR mechanism is investigated using two pathways beginning with two different initial states, formate (*OCOH) and carboxylic (*COOH). The formate pathway confirms the conversion of *OCOH to *HCOOH with the rate-limiting potential (UL) of 0.39 eV for the production of HCOOH, while for the carboxylic pathway, the conversion of *COH to *CHOH has a UL of 0.32 eV, eventually producing CH3OH. Our findings highlight the role of Cu-BPH as an efficient SAC for CO2 catalytic activity to C1 products, as compared to the state-of-the-art Cu, and holds promise as an electrocatalyst for CRR.

The Seasonality of PM and NO2 Concentrations in Slovakia and a Comparison with Chemical-Transport Model

The air quality (AQ) of a given location depends mostly on two factors: emissions and meteorological conditions. For most places on Earth, the meteorology of an area changes seasonally. For central Europe, winters are associated with poor dispersion conditions, which, in combination with high emissions from local heating systems, lead to significantly higher concentrations than during summer. In this study, the seasonality of AQ is analysed using hourly measurements from 44 monitoring stations in Slovakia for the years 2007–2023 for NO2, PM10 and PM2.5. Two factors are used to evaluate the seasonality—the difference and ratio of the winter and summer mean concentrations. It was found that the seasonal difference has been gradually decreasing for all pollutants since 2017. In the case of PM2.5, the seasonal ratio drops from a value of around 2.5 in 2018 to approximately 1.7 in 2023. While in the past, the seasonal ratio was the highest for PM2.5, in the last three years it is the highest for NO2 with values larger than 2. Our results imply that summer sources of PM emissions start to play a more important role for the AQ than in the past. The observed seasonality was compared with two full-year chemical-transport model simulations.

Two-group interfacial area concentration model for dispersed gas-liquid flows in large-diameter pipes

Interfacial area concentration (IAC) plays a critical role in heat and mass transfers between gas and liquid phases through the interfaces. As interfacial area increases, mass and heat transfers between phases increase. Hence, a reliable IAC estimation is important for two-phase flow numerical simulations to conduct engineering designs and safety analyses. Gas bubbles show different behavior according to their shapes and sizes. Based on the size, gas bubbles can be classified into two groups that show different characteristics, such as IAC. Hence, two-group modeling helps to achieve a general approach for estimating the IAC in bubbly to beyond-bubbly flow regimes. Available models in the literature use empirical correlations to obtain group one and group two void fractions. These empirical approaches are not reliable for different flow conditions. In addition, these models are usually complex with several empirical constants. This study aims to develop a two-group area-averaged IAC model for upward vertical dispersed flows through large-diameter pipes. In addition, this study proposes using a general approach based on the two-group drift-flux model to calculate two-group void fractions rather than applying empirical correlations. The models are evaluated using 156 two-group measured data points in dispersed flow conditions through large-diameter pipes. The resulting prediction errors for group one and group two IAC models are 24.1 % and 34.2 %, and the errors for group one and group two void fraction predictions are 22.8 % and 25.6 %, respectively.

Electrochemical sensor based on a glassy carbon electrode modified with a 3D carbon nanoporous composite for the detection of paracetamol in pharmaceutical samples

With the continued appearance of new drugs, there is a growing interest in the development of new analytical tools to detect and quantify drugs using a simple and reliable way. In this work, we describe the development of an electrochemical sensor based on glassy carbon electrodes modified with a carbon tubular nanocomposite for the detection of paracetamol in pharmaceutical samples. Paracetamol shows a strong adsorption on the electrode surface, which makes possible its determination by adsorptive differential pulse voltammetry in 0.1 mol/L citrate–phosphate pH 5 buffer solution. Optimal conditions for dispersion of carbonaceous material and best conditions for surface adsorption of paracetamol were obtained from experimental designs based on response surface methodology. The high adsorption capacity of paracetamol on the 3D carbon nanoporous composite and the sensitivity of the electrochemical technique employed showed a synergistic effect that allowed reaching a detection limit of 30 nmol L− 1 (4.5 ppb). In addition, the reproducibility and the repeatability were 7 and 5 %, respectively. The paracetamol determination from pharmaceutical samples was performed without pre-treatment of samples. The values of paracetamol founded for different pharmaceutical samples were in a very good agreement with those values obtained from the same samples using HPLC. Therefore, the developed electrochemical sensor is a promising, inexpensive, and easy-to-use tool for the detection and quantification of paracetamol in pharmaceutical samples.

Nanoparticle transport in partially saturated porous media: Attachment at fluid interfaces

Like the solid-water interface (SWI), air-water and oil-water interfaces (AWI and OWI) also act as collectors for nano-sized particles in porous media. The attachment of hydrophobic nanoparticles, which is often favorable and irreversible, is of particular interest because the transport and retention of such particles is closely linked to the fate of nanoplastics in unsaturated subsurface environments and the success of nanoremediation practices. Here, we show how a pore-network model (PNM) can be used to upscale the kinetics and extent of irreversible nanoparticle attachment at a single fluid-fluid interface under conditions of advection and dispersion in a sphere packing. By focusing on a trapped (immobile) non-wetting phase, we highlight a fundamental difference between the single-collector contact efficiency of AWI/OWI and SWI. Namely, AWI/OWI collectors, which are largely by-passed by the flowing aqueous phase, are exposed to a hydrodynamic environment dominated by diffusion. This difference has profound implications for the modelling of nanoparticle transport in porous media at the continuum (Darcy) scale. This study reveals the potential of pore network modelling as an essential complement to continuum models for upscaling the behavior of nanocolloids in porous media.

Impact of antiaging additives on the conventional properties of bituminous binder

Aging of binders is a complex phenomenon which reduces the longevity of flexible pavements. Aging involves change in physical, chemical, and morphological properties of binder which makes the binder brittle and highly susceptible to fatigue and thermal cracking. Antiaging additives enhance the service life of flexible pavements by reducing the impact of aging on the performance of binders. An iterative approach is essential to identify the optimal dosage of antiaging additive necessary to counteract the aging effects on binder. The present study aims to evaluate the mixing conditions for uniform dispersion of carbon black and hydrated lime within the binder matrix and thereby evaluate the impact of incorporating these antiaging additives on the conventional properties of binder. For this purpose, varying proportions of carbon black and hydrated lime are added to VG 30 binder and is subjected to softening point, ductility, and penetration tests. The optimal dosage of carbon black and hydrated lime is found to be 6 and 12% respectively based on their significant effects on the conventional properties of the binder. An optimal mixing duration of 60 and 75 min ensures uniform dispersion of carbon black and hydrated lime within the binder matrix at a mixing temperature of 120 °C and a speed of 1000 rpm thereby producing a homogenous binder mastic. Incorporation of antiaging additives up to the optimal dosage enhances the softening point whereas decreases the penetration and ductility of binder. The increase in softening point of binder with incorporation of carbon black and hydrated lime signifies enhanced resistance to rutting and permanent deformation of binder, whereas the reduction in ductility and penetration of binder with incorporation of carbon black and hydrated lime signifies the reduced susceptibility of binder to environmental factors such as temperature fluctuations, UV radiation, and oxidation. The surface texture of the additive influences the ability of binder adsorption, which subsequently affects the rheological properties of binder mastics. Significant improvement in conventional properties of binder with incorporation of carbon black and hydrated lime paves a viable and cost-effective solution for engineering application as it has a subsequent effect on the rheological properties of binder.

A Dibenzo[g,p]chrysene‐Based Organic Semiconductor with Small Exciton Binding Energy via Molecular Aggregation

AbstractExciton binding energy (Eb) is understood as the energy required to dissociate an exciton in free‐charge carriers, and is known to be an important parameter in determining the performance of organic opto‐electronic devices. However, the development of a molecular design to achieve a small level of Eb in the solid state continues to lag behind. Here, to investigate the relationship between aggregation and Eb, star‐shaped π‐conjugated compounds DBC‐RD and TPE‐RD were developed using dibenzo[g,p]chrysene (DBC) and tetraphenylethylene (TPE). Theoretical calculations and physical measurements in solution showed no apparent differences between DBC‐RD and TPE‐RD, indicating that these molecules possess similar properties on a single‐molecule level. By contrast, pristine films incorporating these molecules showed significantly different levels of electron affinity, ionization potential, and optical gap. Also, DBC‐RD had a smaller Eb value of 0.24 eV compared with that of TPE‐RD (0.42 eV). However, these molecules showed similar Eb values under dispersed conditions, which suggested that the decreased Eb of DBC‐RD in pristine film is induced by molecular aggregation. By comparison with TPE‐RD, DBC‐RD showed superior performances in single‐component organic solar cells and organic photocatalysts. These results indicate that a molecular design suitable for aggregation is important to decrease the Eb in films.

A Dibenzo[g,p]chrysene-Based Organic Semiconductor with Small Exciton Binding Energy via Molecular Aggregation.

Exciton binding energy (Eb) is understood as the energy required to dissociate an exciton in free-charge carriers, and is known to be an important parameter in determining the performance of organic opto-electronic devices. However, the development of a molecular design to achieve a small level of Eb in the solid state continues to lag behind. Here, to investigate the relationship between aggregation and Eb, star-shaped π-conjugated compounds DBC-RD and TPE-RD were developed using dibenzo[g,p]chrysene (DBC) and tetraphenylethylene (TPE). Theoretical calculations and physical measurements in solution showed no apparent differences between DBC-RD and TPE-RD, indicating that these molecules possess similar properties on a single-molecule level. By contrast, pristine films incorporating these molecules showed significantly different levels of electron affinity, ionization potential, and optical gap. Also, DBC-RD had a smaller Eb value of 0.24 eV compared with that of TPE-RD (0.42 eV). However, these molecules showed similar Eb values under dispersed conditions, which suggested that the decreased Eb of DBC-RD in pristine film is induced by molecular aggregation. By comparison with TPE-RD, DBC-RD showed superior performances in single-component organic solar cells and organic photocatalysts. These results indicate that a molecular design suitable for aggregation is important to decrease the Eb in films.

Standardization of silver nanoparticle synthesis: Photocatalytic application (immobilized with chitosan complex) with textile dyes and antibacterial activity against Staphylococcus aureus using banana pseudo stem

The purpose of the study is to standardize the silver nanoparticle (BP-AgNPs) synthesis and its antibacterial activity and photocatalytic application with the selected dyes using the banana pseudo stem extract. “One-factor analysis (OFTA)” was carried out for the standardization of silver nanoparticle synthesis and nanoparticle-chitosan complex immobilization. The parameters were identified with plant quantity (20 g), silver nitrate concentration (1 mM), the ratio of plant extract and silver nitrate solution (2:8), pH (12), temperature (37 °C), dispersed light conditions, shaking conditions (120 rpm), and time (6 h) were analysed. The photocatalytic decolorization efficiency of the standardized BP-AgNPs (immobilized with chitosan complex) has shown 96.92% for methylene blue (10 ppm) at 3 h and 97.55% for safranin (100 ppm) at 15 h. The antibacterial activity for the synthesised BP-AgNPs was determined. MIC value of the BP-AgNPs was determined to be 15.62 μg. mL−1 for S. aureus. The synthesised BP-AgNPs treated with 0.5×, 1× and 2× MIC concentration (x = 15.62 μg. mL−1) showed decreased viable counts of S. aureus (99.6% at 2× concentration having viable count of 22.6 × 102 CFU. mL−1) at 24 h incubation when compared with the control culture. The structural characteristics of the BP-AgNPs were identified as spherical with SEM and the size was identified as 12.19 ± 1.62 nm with TEM and as 37.23 ± 17.89 nm with XRD. The parameters such as FTIR, Zeta potential, EDS further supports the nanoparticle synthesis with banana pseudostem extract. The current result suggested that, the silver nanoparticles (BP-AgNPs) synthesised using the extract of the banana pseudo stem could be used as an alternative source for dye decolorization and antibacterial activities.

Characteristics of clay dispersion and its influencing factors in saline-sodic soils of Songnen Plain, China

Under the influence of salinity-sodicity stress, soil salinization and sodification tend to be severe and the dispersion of clay particles increases, which threatens agricultural production and food security. To explore the characteristics of clay dispersion in saline-sodic soils and their influencing factors, the quantitative relationship between clay dispersion indices and soil physicochemical parameters in saline-sodic soils of the Songnen Plain in China was investigated, to provide theoretical and data support for clay dispersion control in saline-sodic soils. Forty-two natural soil samples (0–0.2 m) were collected from saline-sodic soils in Songnen Plain, northeast China, and their physicochemical parameters and clay dispersion indices were determined. Correlation analysis, random forest analysis, and multivariate linear regression analysis were used in this study. The results showed that water-dispersible clay (WDC) ranged from 0.60 % to 18.38 % and total clay (TC) ranged from 4.70 % to 20.68 %. The maximum value of the clay dispersion ratio (CDR) is nine times the minimum value. In terms of turbidity, mechanical dispersion turbidity (MDT) ranged from 39.60 to 59,433 NTU, while spontaneous dispersion turbidity (SDT) ranged from 1.11 to 154.67 NTU. In terms of zeta potential, the minimum value of mechanical dispersion ZETA potential (MDZP) was −46.42 mV, and the maximum value was close to 0 mV. There was a significant correlation between soil physicochemical parameters and clay dispersion indices. Exchangeable sodium percentage (ESP) was the most important explanatory variable for CDR, followed by pH, Na+ex, HCO3-, Na+, CEC, CO32-, SAR, CROSS, and SOC, which could help construct the following multiple linear regression model: CDR=0.143+0.015*ESP −0.036*CO32- −0.006*Na+. Exchangeable sodium percentage has the strongest effects on clay dispersion among the soil parameters. Clay dispersion indices vary with soil physicochemical parameters. Compared to MDT, SDT, MDZP, and SDZP, CDR is more suitable for evaluating and predicting the clay dispersion condition in saline-sodic soils.

Temporal characteristics and vertical profiles of atmospheric CH4 at the northern foot of the Qinling Mountains in China

A two-year (March 2021 to February 2023) continuous in-situ atmospheric CH4 measurements and periodic vertical CH4 measurements (<2000 m) in July and November 2021 were conducted at the northern foot of the Qinling Mountains in Xi'an, China, aiming to study the temporal and vertical variations in atmospheric CH4 and the influence of air mass transport. The two-year average CH4 concentration at this site was 2119.6 ± 108.8 ppb. Seasonal CH4 concentrations were the highest in winter (2177.6 ± 121.5 ppb) and lower in summer (2079.1 ± 77.6 ppb) and spring (2073.9 ± 68.4 ppb). Diurnal CH4 peaked at 10:00–11:00. Atmospheric CH4 there was mainly from local source emissions from Xi'an and short distance transport from the southern Qinling Mountains through the valleys. On the July sampling days, vertical CH4 concentrations increased in the morning (08:00) and at mid-night (23:30), while they decreased in the early afternoon (13:00) and late afternoon (18:00) from near the surface (20 m) to 200 m, increased at 200–500 m, and then decreased at 500–1000 m. During the heating period in November, vertical CH4 concentrations increased by 20.0–86.8 ppb at 20–200 m due to horizontal transport and poor atmospheric dispersion conditions, and then decreased up to 2000 m, with the fastest decrease rate (−44.4 ± 51.4 ∼ −17.6 ± 19.3 ppb/100 m) at 500–1000 m. Vertical CH4 concentrations increased at all heights especially below 500 m in serve haze, mainly attributed to horizontal transport from the northwestern and southeastern polluted regions. Vertical observations further confirmed the important influence of transport on CH4 levels at this site.

Contribution to the study of possible transport of PM10 aerosols in the eastern part of the Czech Republic

The article deals with the assessment of air pollution in the eastern regions of the Czech Republic: Moravia and Silesia, where the limits for the protection of human health for PM and benzo[a]pyrene are significantly exceeded, especially in the north-eastern area. The extent to which this heavily polluted part of Moravia and Silesia affects the central, southern and south-eastern parts of Moravia, i.e. south-eastern part of the Czech Republic, has often been discussed but not proven. The assessment demonstrated the influence and extent of pollutant transport by determining the prevailing daily wind direction. The prevailing NE wind direction results in worse dispersion conditions and higher PM10 concentrations throughout the study area. Conversely, the SW wind direction is a carrier of better dispersion conditions with lower PM10 concentrations in the area. The effect of transport of PM10 pollution in the daily type from the NE direction can be observed at those sites located in the NE of the area of interest from the border with Poland to the Prerov site. In the case of more southerly sites, the methodology used does not allow to determine whether and to what extent they are affected by pollution transport from the northeastern part of Moravia or from neighbouring Poland. This methodology is particularly useful when only 24-h pollutant concentrations are available (not at more detailed, e.g. 1-hour intervals). The internal methodology of the Czech Hydrometeorological Institutefor calculating back trajectories of wind from ground stations is particularly applicable for detecting the origin of short-term episodes with high pollutant concentrations.

Distinct biogeographic patterns for bacteria and fungi in association with Bursaphelenchus xylophilus nematodes and infested pinewood.

Our research uncovered specific bacteria and fungi linked to pinewood nematode (PWN) and infested wood in three different vegetation zones in China, as well as samples from the United States. This sheds light on the critical roles of certain microbial groups, such as Pseudomonas, Acinetobacter, and Stenotrophomonas, in influencing PWN fitness. Understanding these patterns provides valuable insights into the dynamics of PWN-associated microbiomes, offering potential strategies for managing pine wilt disease (PWD). We found significant correlations between geographic distance and similarity in bacterial communities in the infested wood, indicating a spatial influence on wood-associated microbial communities due to limited dispersal and localized environmental conditions. Further investigations of these spatial patterns and driving forces are crucial for understanding the ecological processes that shape microbial communities in complex ecosystems and, ultimately, for mitigating the transmission of PWN in forests.

Rancang Bangun Green Portable Cooler Box

Freon is one of the refrigerants used in refrigeration systems. The refrigeration system has a very important role, namely to preserve food ingredients so that food can last longer. The use of freon is not only used in ships but is widely found in home appliances in refrigeration systems used in freezers, air conditioners, refrigerators, and dispensers. If more freon is used, the negative impact that arises is greater, namely the depletion of the ozone layer and global warming which can have a bad influence on health, the life of living things and the environment. The purpose of this researcher is to create a tool to reduce the negative impact of freon use, namely by using peltier as a cooling medium with environmentally friendly thermoelectric modules. This study uses trial and error methods. Where the trial process is carried out by turning on one of the working push buttons and observing the temperature value. Then it is processed by the control system, namely Arduino Mega which will later provide a PWM output signal to the IRF540 mosfet when the output temperature value is in line with the reference value and vice versa. The test of this tool was carried out by comparing measurements between the author's prototype tool and the standard measuring tool, namely the digital thermometer. Based on the test results, this device can produce a minimum temperature of 140C at 30-minute intervals without any media. The trial using 330ml bottled water can reach a temperature of 170C within 30 minutes in the cooler box. This tool is also equipped with an automatic monitoring system using a PWM signal in the form of a change in fan speed, which is 255 RPS maximum speed and when getting a PWM signal it changes to 50 RPS. The percentage of errors resulting from the comparison of standard measuring instruments and sensor values had the highest and lowest percentages of 2.37% and 0.84% in cold dispersion conditions without charge. Then the highest and lowest error percentages were 1.69% and 0.72% in the state of containing a load of 1 330ml mineral bottle. This ptototype uses data recording using Micro-SD as a data logger.

Dispersion, Dynamics, and Mechanics of Polymer Nanocomposites Filled with Rigid-Soft Janus Nanoparticles via Molecular Dynamics Simulation.

The introduction of nanoparticles (NPs) presents boundless possibilities for enhancing the performance of polymer nanocomposites (PNCs). Consequently, the design of novel NPs becomes of paramount significance for PNCs. In our study, we employ the dumbbell two-component model of Janus nanoparticles (JNPs) and design rigid-soft JNPs as fillers. Using coarse-grained molecular dynamics simulations, we systematically investigate the dispersion, dynamics, and mechanical properties of these novel PNCs. First, we determine the optimal dispersion conditions by studying rcutoff and εnp. The simulation indicates that when the interaction between polymer chains and JNPs is a repulsive potential, the JNPs tend to aggregate together, forming a cluster with soft NPs inside and rigid NPs outside. Conversely, under attractive interactions, JNPs show superior dispersion uniformity compared to the repulsive system, and as εnp increases, the dispersion improves. Then, the mean square displacement (MSD) indicates that JNPs effectively impede the mobility of polymer chains, with the degree of hindrance increasing as εnp grows; this effect is more pronounced in attractive systems. Comparing JNPs of different particle sizes, we find that smaller JNP systems exhibit higher temperature sensitivity. Furthermore, there exists a critical particle size (Dnp ≈ 5σ) under a constant filling fraction at which the NPs exert the most pronounced restriction effect on the polymer. Next, upon examining the mechanical behavior, we find that the rigid-soft JNPs demonstrate notable elasticity and variability compared to traditional NPs. This observation is confirmed through measurements of the bond orientation and mean square radius of gyration of the soft segments of JNPs. In summary, this research provides a comprehensive understanding of the intricate interplay among various factors, offering valuable insights for optimizing JNP dispersion and enhancing the mechanical properties of PNCs.

Separation of twin beams generated in a Sagnac fiber loop

We theoretically demonstrate the propagating performance of twin beams generated in a Sagnac fiber loop by developing a practical model of optical parametric loop mirror consisting of an optical coupler with adjustable splitting ratio, a nonlinear fiber, a dispersion element, and two tunable attenuators placed at different positions in the loop. Two situations of frequency degenerate and frequency non-degenerate four-waving mixing are considered and various of factors including dispersion conditions, internal losses in the loop, and splitting ratios of the coupler are investigated in detail. When the splitting ratio of the coupler is 1:1 and no loss is in the loop, both the frequency degenerate and non-degenerate twin beams can propagate from different ports completely by introducing proper dispersion, and switching between phase-sensitive and phase-insensitive amplification can be realized by changing the dispersion within the loop. In general, the propagation of signal and idler beams at the two output ports of the fiber loop are influenced by both the splitting ratio of the coupler and the internal loss within the loop. Adjusting the internal loss can partially compensate for the asymmetry of the splitting ratio of the coupler, facilitating spatial separation of the signal and idler beams. Our research is useful for the generation of twin beams using Sagnac fiber loop and the realization of switchable phase-sensitive amplifiers.

Spatial and temporal changes of air quality in Shandong Province from 2016 to 2022 and model prediction

This study investigates the spatial and temporal dynamics of air quality in Shandong Province from 2016 to 2022. The Air Quality Index (AQI) showed a seasonal pattern, with higher values in winter due to temperature inversions and heating emissions, and lower values in summer aided by favorable dispersion conditions. The AQI improved significantly, decreasing by approximately 39.4 % from 6.44 to 3.90. Coastal cities exhibited better air quality than inland areas, influenced by industrial activities and geographical features. For instance, Zibo's geography restricts pollutant dispersion, resulting in poor air quality. CO levels remained stable, while O3 increased seasonally due to photochemical reactions in summer, with correlation coefficients indicating a strong positive correlation with temperature (r = 0.65). Winter saw elevated NO2 levels linked to heating and vehicular emissions, with an observed increase in correlation with AQI (r = 0.78). PM2.5 and PM10 concentrations were higher in colder months due to heating and atmospheric dust, showing a significant decrease of 45 % and 40 %, respectively, over the study period. Predictive modeling forecasts continued air quality improvements, contingent on sustained policy enforcement and technological advancements. This approach provides a comprehensive framework for future air quality management and improvement.