Particulate emissions from Mt. Etna in the fine-size range below 100 nm were studied in June and September 1989. The aerosol particles were characterized by size, concentration and photoelectric activity. These quantities are sensitive to the physical and chemical properties of the magma. Concentrations varied from 104 to 107 cm-3. The size distributions peak below 20 nm (radius) and are very narrow. The particles are generated mainly by nucleation and condensation of magmatic volatiles in a strong temperature gradient. The photoelectric activity of these particles can indicate high magma levels and increased exsolution of volatiles. It is therefore related to the observed activity of the respective crater and may be helpful as a prediction tool when used in conjunction with other volcano-monitoring techniques.