This paper presents in-depth exploration and verification of the OpenNode nodal diffusion code, a robust tool designed for multigroup neutron diffusion simulations under steady-state conditions. Leveraging the Nodal Expansion Method with a quartic polynomial and moments weighting method, OpenNode demonstrates exceptional accuracy in approximating nodal surface fluxes, further enhanced by the Quadratic Transverse Leakage approximation. The critical concept of commutativity between adjoint and forward solutions is thoroughly investigated, serving as a benchmark for the code’s reliability in predicting system responses, determining single-point reactor kinetics parameters, and facilitating perturbation analyses. The paper meticulously details OpenNode’s methodology for adjoint neutron flux computation, unraveling its rigorous approach through transposition operations and intricate mathematical transformations. Noteworthy features, including support for second and fourth polynomial orders; versatile computation modes; different mesh points; and seamless integration with Python, PyQt5, and Blender, underscore OpenNode’s adaptability. Results from comprehensive analysis of the two-dimensional and three-dimensional International Atomic Energy Agency core benchmark problem showcase OpenNode’s prowess. The code excels in reactor geometry visualizations, benchmark parameters, and neutronic analysis, with a particular emphasis on commutativity verification against various benchmarked codes. The precision of OpenNode is further demonstrated in power distribution analyses, revealing remarkable proximity to reference values and symmetrical power distribution patterns.