Concentrations In Groundwater Research Articles

Assessing Potential Bias in PFAS Concentrations in Groundwater and Surface Water Samples

AbstractPer‐ and polyfluoroalkyl substances (PFAS) encompass a large group of recalcitrant anthropogenic compounds that have been used in a variety of consumer and industrial products and processes over many decades. Drinking water standards were recently finalized for two PFAS at low nanogram per liter concentrations. Due to the widespread use of PFAS and low health‐based thresholds, a literature review and laboratory and field studies were conducted to assess several potential sources of bias in PFAS concentrations. Fluoropolymers are commonly present in equipment, products, and materials used during field sampling, potentially leading to false positive results. Laboratory results confirmed the presence of PFAS in multiple commonly used field materials. However, best practices can be used to limit pathways for cross contamination. Laboratory‐specified hold times and sample storage temperatures are scientifically founded and adequately prevent bias due to PFAS sorption to sampling containers or partial degradation of some PFAS to form others. PFAS are also known to accumulate at the air‐water interface and other interfaces. Results from laboratory and field studies indicate that PFAS enrichment in foam and in the surface microlayer does occur. However, the effect of this phenomenon is within the range of analytical and spatial sampling variability and therefore a change in sampling procedures is not needed. Findings were distilled into science‐based and practical recommendations to minimize bias during PFAS sampling without incurring unnecessary cost and effort.

Unraveling roles of dissolved organic matter in the co-occurrence of arsenic and ammonium in Quaternary alluvial-lacustrine aquifers

Geogenic arsenic (As) and ammonium (NH4+)-contaminated groundwaters are global public concerns, posing threats to human health and ecological security. However, when considering the enrichment of either As or NH4+ in groundwater, the concurrent occurrence of both contaminants warrants further discussion. Herein, we conducted a hydrogeochemical study in the shallow confined aquifer of the central Yangtze River basin to elucidate the key mechanism of coexistence of As and NH4+ through a thorough analysis of groundwater chemistry, inorganic carbon isotope (δ13C-DIC), and dissolved organic matter (DOM). High As and NH4+ groundwater mainly occurs in meanders of the middle reaches of Yangtze River, with maximum concentrations up to 936 μg/L and 45.3 mg/L, respectively. Our findings indicate that the degradation levels and characteristics of DOM play a significant role in the co-occurrence of As and NH4+ with varying concentrations in groundwater. δ13C-DIC signatures show that there was a simultaneous increase in the concentrations of As and NH4+ in groundwater, with the highest concentration of As during fermentative conditions. In contrast, during the progression of OM degradation towards methanogenesis, the NH4+ concentration reached its peak, while the As concentration was lower compared to the fermentation stage. Optical properties of DOM demonstrate that elevated levels of NH4+ result from the mineralization of N-containing organic compounds particularly as the degradation proceeds to methanogenesis stage, while both fermentation and methanogenesis processes significantly contribute to the microbially reductive dissolution of As-bearing iron oxides in groundwater systems. This study presents isotopic and fluorescent evidence to clarify the co-existence of As and NH4+ in Quaternary alluvial-lacustrine aquifers.

Co-occurring characteristics and mechanisms of geogenic ammonium and phosphorus in Quaternary alluvial-lacustrine aquifer systems

High loads of nitrogen (N) and phosphorus (P) in groundwater are a pressing global environmental concern. Geogenic ammonium (NH4+) and P anomalies in groundwater as unique forms of contamination, have been extensively reported. However, despite significant efforts on the enrichment of geogenic NH4+ or P, little is known about their co-occurring characteristics and mechanisms in groundwater. Therefore, focusing on the Dongting Plain (DTP) within the central Yangtze River basin, a typical alluvial-lacustrine plain, this study analyzed hydrogeochemistry, stable carbon isotopes, and dissolved organic matter (DOM) fluorescence. The results revealed a clear correlation between the groundwater DOM humification degree and the redox processes. In different redox processes, four distinct groundwater types emerged sequentially: low-NH4+ & low-P, low-NH4+ & high-P, high-NH4+ & high-P, and high-NH4+ & low-P. In organic matter (OM) degradation process, when dissolved oxygen and nitrate acted as electron acceptors, the low-NH4+ & low-P groundwater dominated. The low-NH4+ & high-P groundwater dominated when Mn(IV) and amorphous Fe(III) (oxyhydr)oxides served as the electron acceptors, where P enrichment was primarily attributed to the reductive dissolution of amorphous Fe(III) (oxyhydr)oxides. The high-NH4+ & high-P groundwater dominated when SO42-, crystalline Fe(III) (oxyhydr)oxides, and CO2 served as the electron acceptors. During this phase, OM mineralization resulted in the enrichment of both NH4+ and P. Furthermore, the reductive dissolution of crystalline Fe(III) (oxyhydr)oxides further increased P concentrations in groundwater. During the strong degradation of OM to the methanogenic stage, two processes occurred simultaneously: anaerobic oxidation of methane and reductive dissolution of Fe(III) (oxyhydr)oxides. These processes led to an increase in the concentration of HCO3– and Fe(II) in groundwater. During this phase, large amounts of HCO3– and Fe(II) combine to form siderite precipitates. These precipitates adsorb P from the groundwater, eventually leading to a decrease in P concentration and the formation of high-NH4+ & low-P groundwater. This study offers novel insights into the simultaneous cycling of N and P in Quaternary alluvial-lacustrine aquifer systems.

BaHys—A Bayesian Modeling Framework for Long‐Term Concentration‐Discharge Hysteresis: A Case Study on Chloride

AbstractImproving river water quality requires a thorough understanding of the relationship between constituent concentration and water discharge during runoff events (i.e., C‐Q hysteresis), which may be strongly non‐linear. Analysis of C‐Q hysteresis on large temporal scales provides unprecedented insights into event dynamics and long‐term concentration trends in surface and groundwater. Despite the increasing availability of time series data on water quality, there are still limited quantitative modeling frameworks that enable this analysis. Here, we combine Bayesian modeling and an existing mass balance to model long‐term C‐Q hysteresis dynamics in multi‐decade constituent concentration and water discharge time series. We focus on the case study of chloride and demonstrate that our model can simultaneously characterize the size and rotation of C‐Q hysteresis, and diffuse and low‐flow inputs to constituent concentration using only time‐series data from the river Rhine. Over 28 years of monitoring, we find that chloride exhibits a dominant clockwise dilution behavior that does not vary considerably under different hydro‐climatic conditions, hinting to similar mobilization mechanisms over time. We also show decreasing chloride concentrations in surface and groundwater, due to the cessation of mining activities in the Rhine. Our approach uses uncertainty estimates to show the range within which model parameter values lie, aiding decision‐makers in a robust assessment of river water quality. We conclude that Bayesian modeling of C‐Q hysteresis provides a powerful framework for investigating long‐term contamination dynamics that can be extended to several constituents to find factors controlling their export, ultimately suggesting mitigation measures for river contamination.

Teasing out the Effects of Natural Stressors at Chemically Contaminated Sites.

Aquatic ecosystems are often impacted by a multitude of stressors, many of which are introduced by a combination of anthropogenic activities such as agricultural development, urbanization, damming, and industrial discharge. Determining the primary stressors responsible for ecological impairments at a site can be complex and challenging; however, it is crucial for making informed management decisions. Improper diagnosis of an impaired system can lead to misguided attempts at remediation, which can be both time consuming and costly. We focused on the development, implementation, and evaluation of methodologies that, in combination, allowed us to identify the primary stressors. These included a four-phase, weight-of-evidence (WOE) assessment including in situ Toxicity Identification and Evaluation (iTIE) testing, physicochemical and macrobenthos characterization, reciprocal sediment transplants, and laboratory and in situ toxicity testing. The contaminants of concern (COCs) at the site were elevated levels of ammonia, chloride, pH, and total dissolved solids in groundwater upwellings into a high-quality waterway. Reciprocal transplants of site sediments and nearby reference sediments and traditional benthic sampling showed impaired benthic indices and multiple stations around a contaminated industrial settling basin. Impaired stations had elevated COCs in groundwaters but exhibited a steep vertical concentration gradient, with concentrations decreasing near the sediment-surface water interface. We describe Phase 4 of the study, which focused on teasing out the role of dissolved oxygen sags in benthic macroinvertebrate responses. Extensive submerged and emergent macrophytes, algae, and cyanobacteria co-occurred at the impaired sites and increased throughout the summer. Laboratory testing suggested that ammonia and pH were possibly toxic at the sites, based on groundwater concentrations. The in situ toxicity testing, however, showed toxicity occurring even at stations with low levels of COCs concurrently with large diurnal fluxes in dissolved oxygen (DO). A final phase using a type of iTIE approach utilized limnocorrals with and without aeration and with in situ toxicity measures using Hyalella azteca. The Phase 4 assessment revealed that low DO levels were primarily responsible for impaired benthic communities, and COC upwellings were diluted at the sediment-water interface to nontoxic levels. These findings will allow for improved management decisions for more efficient and effective restoration activities. Environ Toxicol Chem 2024;43:1524-1536. © 2024 SETAC.

Comprehending hydrochemical fingerprint, spatial patterns, and driving forces of groundwater in a topical coastal plain of Northern China based on hydrochemical and isotopic evaluations

To comprehensively comprehend the hydrochemical features, spatial patterns, and controlling mechanisms of groundwater in the Longkou coastal plain (LCP), a prime coastal plain in northern China, a detailed study utilizing statistical analyses, Piper diagram, Gibbs model diagram, ion ratio methods, and reverse hydrogeochemical simulation was performed on 76 groundwater samples collected in 2021. The findings of this study reveal that the groundwater in the LCP has an average pH value of 7.6, indicating weak alkalinity. The groundwater types are predominantly mixed, followed by Cl–Ca. The NO3− concentration in groundwater is relatively high, with a mean value of 326 mg/L, originating mainly from agricultural production activities. In addition to NO3−, the spatial distribution analysis of the principal chemical constituents in the groundwater demonstrated a subtle north-south gradient. The chemical signatures of groundwater are primarily influenced by the process of rock weathering, resulting from the dissolution of silicates and carbonates minerals as well as gypsum. Indeed, cation exchange represents a pivotal hydrogeochemical reaction within the groundwater system of the region. The intrusion of seawater into groundwater primarily exhibits a mild nature, mostly in the form of mixing intrusion in the initial stage, affecting the western and northern regions of the LCP to a greater extent. The primary source of groundwater recharge is attributed to atmospheric precipitation; however, it is partially affected by evaporation. In addition, LCP groundwater is also being recharged by seawater intrusion, mainly in the western and northern parts of the study area. Overall, the findings of this research hold significant implications for the strategic management of groundwater resources and the implementation of measures to prevent and mitigate seawater intrusion not only in the LCP but also in analogous coastal regions across the globe.

Optimising groundwater recharge to counteract seawater intrusion through an inverse modelling approach and identifying efficient recharge structure locations

In semi-arid coastal urban regions, groundwater faces challenges from seawater intrusion due to reduced recharge and increased extraction. This study employs advanced numerical modeling to comprehensively assess seawater intrusion along the South Chennai coast from 2018 to 2022. The inverse modelling approach utilizes observed data, such as groundwater heads or concentrations, to estimate aquifer properties, like hydraulic conductivity, by minimizing the disparity between model predictions and actual measurements to identify the best-fit parameter values. This inverse method forecasts the necessary recharge rate to address seawater intrusion by increasing groundwater head and decreasing chloride concentrations. The estimation of recharge incorporates variables such as rainfall, soil infiltration capacity, land use, and the vital groundwater draft calculated based on per capita consumption and population. The study uses FEFLOW software to develop a robust conceptual model, simulating groundwater flow and chloride transport. The inverse modeling approach resulted in critical recharge adjustments, enhancing rates by 40%–60% in specific regions. The predictive scenarios, integrating proposed recharge structures, show promising results, notably with a 50% reduction in chloride concentration during the post-monsoon season compared to the pre-monsoon period in wells 8 and 3. A notable decrease in chloride concentration of over 90% was observed during May 2025 in well no: 15 due to its proximity to the Adayar River. These fluctuations are influenced by seasonal variations resulting from climatic changes in South India, with intense rainfall accompanying northeast monsoon winds playing a significant role. Increased recharge rates and strategically placed structures along the Buckingham Canal provide significant relief in the most impacted northern coastal area, acting as effective barriers. These interventions successfully reduce chloride concentration, providing a sustainable and effective solution to mitigate the persistent challenge of seawater intrusion.

Using 222Rn to quantify wetlands interflow volume and quality discharging to headwater streams

Headwater streams are highly dependent on groundwater discharge to maintain low flows during dry periods and to dilute pollutants. Groundwater discharge to streams can have different flow paths, either from groundwater flowing directly to the river through the hyporheic zone or groundwater that emerges at the contact with a riparian wetland and flows mainly on the wetland surface. Differentiating these flows could be useful to assess the contribution of riparian wetlands in protecting stream water quality. The objective of this research was to expand the use of 222Rn as a groundwater tracer for small streams in headwater catchments to distinguish flows received directly from the aquifer and through riparian wetlands. 222Rn activities, phosphate (PO43−) and nitrate (NO3−) concentrations, along with stream flows were used in a mass balance model to establish the proportions of groundwater flow that discharge to a small stream located southwest of the Paris Basin (France). This watershed is typical of headwater catchments in this region because it receives a wastewater treatment plant (WWTP) effluent at its source and its banks are occupied by many small riparian wetlands. To obtain the best accuracy of groundwater flow assessment, the field work was done during low flow conditions, where the stream flow was only 0.079 m3/s at the outlet. The model gives a good estimation of each flow path with 83 % of the stream baseflow originating from riparian wetlands. The large contrast in 222Rn activity between groundwater inflow from the aquifer (mean of 21 200 Bq/m3) and interflows from wetlands (mean of 2310 Bq/m3) renders the mass balance model sensitive to the separation of these two types of groundwater flow paths. At the head of the stream, water is characterized by high concentrations of PO43− and NO3− due to the WWTP effluent into the stream (13 and 21 mg/L respectively). All groundwater flows are PO43− free and contribute to the improvement of stream water quality. The NO3− cycle is more difficult to constrain because of the spatial heterogeneity in groundwater concentrations. Nevertheless, the results of the modeling approach showed that the main part of the evolution of NO3− concentrations along the river can be explained by the dilution of stream flow with interflows. The method developed is considered sufficiently accurate to quantify groundwater inflows for different flow paths in headwater catchments and to estimate the impact of groundwater flow paths on stream water quality.

Mechanism controlling groundwater chemistry in the hyper-arid basin with intermittent river flow: insights from long-term observations (2001–2023) in the lower Heihe River, Northwest China

The geochemical processes of groundwater in arid regions are generally influenced by both natural hydrological processes and human activities. However, impacts of water-rock interactions on groundwater recharge via hydrological processes, controlled by both intermittent river water flow and groundwater withdrawals, is still poorly understood. In this study, 327 groundwater chemistry datasets collected from the upper, middle (including Gobi and riparian zones), and lower regions of the Ejina Delta in Northwest China from 2001 to 2023 were analyzed. Our results revealed that the total dissolved solids (TDS) concentration of groundwater in Ejina Delta ranged from approximately 881.5 ± 331.6 mg/L in the upper regions to 1,953.6 ± 1,208.5 mg/L in the lower regions, with an increasing trend observed. Ecological water conveyance (EWC), recharging aquifer through intermittent river water flow, resulted in a decrease in TDS concentrations from 2001 to 2023 mainly in the upper region. While irrigation notably affected groundwater chemistry in the lower region, resulting in a substantial increase in groundwater salinity. Groundwater chemistry in the Middle Gobi region remained relatively stable over the study period. Generally, the hydrochemical composition shifted from the Na-Mg-SO4-HCO3 and Na-Mg-Ca-SO4-HCO3 types in the upper region to Na-Mg-SO4-HCO3 and Na-Mg-SO4-Cl types in the lower region, with Na-SO4-Cl predominant in the Middle Gobi. These shifts were likely be attributed to the interplay of water-rock interactions, coupled with evaporation-crystallization processes. Inverse modeling using PHREEQC revealed that in the upper-middle region, primary water-rock interactions involved calcite dissolution and the precipitation of dolomite, gypsum, halite, and sylvite salts, as well as cation exchange reactions (2NaX+Ca2+→CaX2+2Na+). In contrast, the hydrogeological system in the middle-lower region exhibited an opposite pattern of water-rock interactions. Overall, ecological water conveyance partially facilitated water-rock interactions during lateral groundwater flow, while irrigation disrupted the natural hydrogeochemical equilibrium, involving halite dissolution and opposite cation exchange reactions compared to other regions.

Exploring dissolved N2O characteristics and unearthing indirect N2O emission factors in the shallow groundwater of paddy and upland fields

Indirect emissions of nitrous oxide (N2O) stemming from nitrogen (N) leaching in agricultural fields constitute a significant contributor to atmospheric N2O. Groundwater nitrate (NO3−-N) pollution is severe in the Ningxia Yellow River Irrigation Area (NYRIA), coupled with high NO3−-N leaching, exacerbates the risk of indirect N2O emissions from groundwater. Over two years of field observations, this study investigated the characteristics and interannual variations of dissolved N2O (dN2O) concentrations and indirect N2O emission factors (EF5g) in shallow groundwater. The research focused on three typical farmlands in the NYRIA, each subjected to six levels of N fertilizer application. The mean dN2O concentrations in the groundwater of paddy, corn and vegetable fields were 5.17, 8.40 and 16.35 μg N·L−1, respectively. Notably, the dN2O concentrations in the shallow groundwater of upland fields exceeded those in paddy fields, with maximum levels in vegetable fields nearly an order of magnitude higher. Elevated N application significantly increased dN2O concentrations across various farmlands, showing statistically significant variation. However, differences in EF5g-A and EF5g-B within the same farmland were negligible. Denitrification was the primary process contributing to N2O production in groundwater, with nitrification also played a crucial role in upland fields. Factors such as NO3−-N, NH4+-N, dissolved oxygen (DO), and pH critically influenced N2O production. EF5g-B, which considers the NO3−-N consumption during denitrification processes in groundwater, was deemed more appropriate than EF5g-A for assessing the indirect N2O emission in the NYRIA. The EF5g of agricultural fields exhibited minimal sensitivity to N input but was significantly affected by other factors, such as the planting pattern. The study revealed the rationality of adopting EF5g-B in assessing indirect N2O emissions, providing valuable insights for N management strategies in regions with high NO3−-N leaching. Minimizing N fertilizer application while ensuring crop yield, especially in upland fields, is beneficial for reducing N2O emissions.

Uranium concentration in groundwater of Charkhi Dadri district of Haryana, India by using LED fluorimeter

Uranium concentration in groundwater of Charkhi Dadri district of Haryana, India by using LED fluorimeter

Noble gas characteristics of microbial gas in the Qaidam Basin, China: Implications for helium enrichment processes

Helium is a critical, strategic and nonrenewable resource with limited reserves and unstable supplies. However, the helium sources and migration processes in petroliferous basins remain unclear. The Qaidam Basin features multiple reservoir layers, multiple genetic types of natural gas, and varying helium concentrations, providing an ideal natural laboratory for understanding the helium enrichment processes. Here, we present the original noble gas isotopic compositions and major gas components of 11 microbial gas samples from three gas layers in the Sebei No.1 gas field, eastern Qaidam Basin, China. The helium isotopic ratios range from 0.007 to 0.057 Ra, reflecting a predominantly crustal source. The Quaternary Sebei microbial gas features much lower helium concentration (0.0003–0.001%), 21Ne/22Ne ratio (0.031–0.034), and 40Ar/36Ar ratio (292–380) than thermogenic natural gases in the Qaidam Basin. The middle gas layer (II) of the Sebei gas field features higher 21Ne/22Ne and 40Ar/36Ar ratios than the top and bottom gas layers, displaying positive correlations with higher 4He groundwater concentrations before degassing, as calculated from 4He/20Ne ratios and 20Ne concentrations in air-saturated water. However, the correlations between the 4He contents in natural gas and the 21Ne/22Ne and 40Ar/36Ar ratios are unclear, suggesting that 4He dissolves into the groundwater system before degassing into a gas reservoir and that the variations in the 4He concentration in the gas phase are caused by the different levels of hydrocarbon dilution. Quantitative calculations of helium production revealed an external helium flux from the crustal basement except for the in-situ production from sedimentary strata even in this broadly-defined self-generating and self-preserving natural gas system. The helium resources in the Qaidam Basin are mainly distributed in tectonically active zones with uplifted pre-Jurassic basement rocks (providing sufficient helium sources), ancient groundwater systems (accumulating more helium) and suitable hydrocarbon production (acting as a carrier gas but diluting helium as slightly as possible).

Co-occurrence of elevated arsenic and fluoride concentrations in Wuliangsu Lake: Implications for the genesis of poor-quality groundwater in the (paleo-)Huanghe (Yellow River) catchment, China

The co-occurrence of high As and F concentrations in saline groundwater in arid and semi-arid regions has attracted considerable attention. However, the factors determining the elevated concentrations of the two elements in surface water in these regions have not been sufficiently studied, and their implications for the poor-quality of local groundwater (high levels of As, F, and salinity) are unknown. A total of 18 water samples were collected from Wuliangsu Lake, irrigation/drainage channels, and the Huanghe (i.e., Yellow River) in the Hetao Basin, China. The pH, concentrations of As and F as well as those of other major elements, and stable isotope (H and O) compositions were analyzed. The water samples had a high pH (7.85–9.01, mean 8.25) and high TDS (402–9778 mg/L, mean 1920 mg/L) values. In six of the 10 lake samples, As concentration was above 10 μg/L (maximum 69.1 μg/L) and, in one of them, F concentration was above 1.5 mg/L. Interestingly, the high As, F, and TDS values simultaneously detected in the lake water were similar to those previously reported in local groundwater, and all water samples showed a significant positive correlation between As and F concentrations (R2 = 0.96, p < 0.01), except for two samples with abnormally high Ca2+ levels. The results of stable isotope analysis and Cl/Br ratios suggested that the lake experienced strong evaporation, which is consistent with the high TDS values. Evaporative concentration is suggested as the main factor contributing to the elevated As and F concentrations in the lake water. In addition, the major ions (e.g., Na+, Cl−, HCO3−, and OH−) and pH in the lake water increased during evaporation, leading to desorption of As and F. Thus, the evaporation process, including evaporative concentration and desorption, was considered primarily responsible for the elevated As and F in the lake water. Based on the results of this study, we presume that the paleolakes in the study area have experienced intense evaporation process. As a result, As, F, and major elements accumulated in sediments (or residual lake water) and were buried in the fluvial basins; then, they were released into the groundwater through multiple (bio)hydrogeochemical processes. By combining the results of this study with those obtained from previous groundwater analyses, we propose a new hypothesis explaining the origin of elevated As and F concentrations in saline groundwater in arid and semi-arid regions.

Hydrochemical characterization and comprehensive water quality assessment of groundwater within the main stream area of Yishu River.

To gain a comprehensive understanding of the hydrochemical characteristics, controlling factors, and water quality of groundwater in the main stream area of Yishu River (MSYR), a study was conducted using water quality data collected during both the dry and wet seasons. Through statistical analysis, hydrochemical methods, fuzzy comprehensive evaluation, and health risk evaluation modeling, the water chemical characteristics of the main stream area of Yishu River were studied, and the water quality of the area was comprehensively evaluated. The findings indicate that HCO3- and Ca2+ are the predominant anions and cations in the MSYR during the dry and wet seasons, respectively. Moreover, anion concentration in groundwater follows HCO3- > SO42- > NO3- > Cl-, while cations are ranked as Ca2+ > Na+ > Mg2+ > K+. Overall, the groundwater manifests as weakly alkaline and is predominantly classified as hard-fresh water. During the wet season, there is greater groundwater leaching and filtration, with rock and soil materials more readily transferred to groundwater, and the concentrations of main chemical components in groundwater are higher than those during the dry season, and the hydrochemical types are primarily characterized as HCO3-Ca·Mg and SO4·Cl-Ca·Mg types. These results also suggest that the chemical composition of the groundwater in the MSYR is influenced mainly by water-rock interaction. The primary ions originate from the dissolution of silicate rock and carbonate rock minerals, while cation exchange plays a critical role in the hydrogeochemical process. Groundwater in the MSYR is classified mostly as class II water, indicating that it is generally of good quality. However, areas with high levels of class IV and V water are present locally, and NO3- concentration is a crucial factor affecting groundwater quality. In the wet season, more groundwater and stronger mobility lead to greater mobility of NO3- and wider diffusion. Therefore, the risk evaluation model shows that nitrate health risk index is higher in the wet season than it is in the dry season, with children being more vulnerable to health risks than adults. To study groundwater in this area, its hydrochemical characteristics, water quality, and health risk assessment are of great practical significance for ensuring water safety for residents and stable development of social economy.

Fluoride concentration in groundwater of the Jalisco Highlands, Mexico

La principal fuente de abastecimiento de agua potable en la mayoría de las regiones administrativas del estado de Jalisco (México) son los acuíferos subterráneos, que en muchos casos son de origen hidrotermal, los cuales se caracterizan por la presencia de compuestos químicos potencialmente nocivos para la salud humana y animal. El área de estudio de este trabajo se ubica en el noreste del estado de Jalisco, comprendiendo 10 municipios en dos regiones administrativas. El presente estudio tiene como objetivo determinar la tendencia de la concentración de flúor en pozos profundos que abastecen de agua potable a los municipios del área de estudio, a partir de dos evaluaciones realizadas durante los años 2021 y 2022. En los resultados se puede observar una tendencia creciente en la concentración de flúor de la mayoría de los pozos analizados en los periodos estudiados, las mayores concentraciones se reportan en las localidades de: Tepatitlán, Arandas, Mexticacán y San Miguel el Alto, así como en los municipios de Valle de Guadalupe y Cañadas de Obregón, representando el uso de estas fuentes como agua potable un mayor riesgo para la salud de la población local, ratificándose así mismo, una tendencia creciente en la concentración de fluoruros en las aguas subterráneas extraídas del área de estudio, una posible causa es la continua disminución en el nivel dinámico de extracción que presentan la mayoría de los pozos evaluados. Es necesario implementar programas y estrategias para garantizar la sostenibilidad de este recurso vital en esta y otras regiones del país.

Localizing and quantifying groundwater‐surface water interactions at different scales: A tracer approach at the River Moselle, Germany

AbstractGroundwater‐surface water interactions (GSI) connect rivers and streams with riparian areas and the adjacent aquifer. Although these interactions exert a substantial control of quantity and quality of both groundwater and surface water, knowledge on GSI along rivers at the regional scale, particularly for inland waterways, is still limited. We investigated GSI along the river Moselle, an important federal inland waterway in Germany, by using radon and tritium to identify gaining (water flux from the aquifer to the surface water) and losing (water flux from the surface water to the aquifer) stream conditions, respectively. Gaining stream conditions were identified by continuously measuring radon along the river during boat surveys with a high spatial resolution (every 2 km) during intermediate (October 2020) and near low flow conditions (August/September 2021). The tritium concentrations in surface water and groundwater and the resulting tritium inventories were used to characterize losing stream conditions Monthly tritium inventories from 2017 to 2022 revealed a mean loss for the whole period of 20.3 % and a mean gain of 21.8%. Both were probably triggered by a combination of losing stream conditions and flood‐induced mass transfer of water from the aquifer back into the river as well as discharge fluctuations. At the investigated site Lehmen there were direct indications of an influence of surface water due to elevated tritium concentrations in the groundwater (up to 13.3 Bq L−1). Using radon mass balance modelling, good agreements of simulated versus measured radon data with respect to two groundwater end‐member scenarios were obtained during intermediate flow (Spearman's ρ: 0.97 and 0.99; MAE: 10.1 and 3.4 Bq L−1) and near low flow (Spearman's ρ: 0.97 and 0.99; MAE: 11 and 6.5 Bq L−1). Considerable groundwater inflow was limited to the meander of Detzem, where cumulated groundwater inflow of about 19 m3 s−1 (9.5% of total discharge) and 4.2 m3 s−1 (3.8% of total discharge) was simulated during intermediate and near low flow, respectively. However, the groundwater inflow was relatively low compared to alpine streams, for example. The study will help to better identify and quantify GSI at the regional scale and provide methodological guidance for future studies focusing on inland waterways.

A slope management method by monitoring soil volumetric water content and its validation through numerical analysis

Landslides induced by heavy rainfall have become increasingly common in recent years. As the groundwater level rises, the safety factor of slopes tends to decrease. However, traditional monitoring methods, such as employing water-level (pressure) gauges in boreholes, require significant effort. Thus, this study proposes a slope management approach based on monitoring the volumetric water content of the ground surface. The monitored slope, approximately 20 m in height and 30 m in length, consists of topsoil mixed with grass roots and sand with a slight silt admixture, as revealed by two borehole investigations. Soil moisture meters were strategically installed at three locations along the slope (upper, middle, and lower sections) to gauge the volumetric water content. Observations indicated a sensitive increase in ground water content following rainfall. Furthermore, a three-dimensional Finite Element Method (FEM) analysis was employed to explore the correlation between rainfall (intensity and duration) and groundwater content. The FEM analysis also examined the impact of rainfall-induced changes in slope water content on the overall slope safety factor, utilizing 3D point cloud data to model the monitored slope. Qualitative agreement was observed between the monitoring and analysis results, highlighting a decrease in slope safety factor as slope water content increased. These findings underscore the potential of conveniently assessing slope safety factors based on the water content of a slope’s ground surface.

Decoding degassing modes of magma chamber of arc volcanoes: Insights from CO2/Cl and Cl/H2O ratios of magmatic fluids in groundwater

The H2O-CO2-Cl composition of the fluids released from the magma chambers for arc volcanoes was calculated based on the solubilities of H2O and CO2 in the silicate melt and the partition coefficient of Cl between the aqueous fluid and melt for the stages defined by a simple evolution model of the magma chamber. The degassing modes consisted of mafic bubbling (MB: first boiling) and felsic bubbling (FB: second boiling) releasing fluids as separate bubbles due to the mafic magma supply and felsic magma formation by differentiation, respectively, and felsic solidification (FS) releasing fluid due to felsic pluton formation. The variations in the CO2/Cl and Cl/H2O ratios of the fluids were examined for each degassing mode at pressures ranging from 150 to 400 MPa and were found to have very large variations at 0.00024–845 for CO2/Cl and 0.00043–0.041 for Cl/H2O. The CO2/Cl is concluded to be a good indicator of magma chamber conditions because each mode has a specific ratio distinguished from that of the other modes; i.e., CO2/Cl > 43 for MB, 0.027–23 for FB, and < 0.62 for FS.The alteration of magmatic composition of fluid during ascent was discussed considering the phase separation of fluid, CO2 bubbling in groundwater, dissolution, and deposition of minerals; furthermore, the limitation of the method when applied to natural groundwater systems were outlined. This method was tested for a natural volcanic system, the Kuju volcano in central Kyusyu, Japan, which is an active volcano complex composed of various magma types from rhyolitic to basaltic, replacing the eruption centers from west to east. Groundwater samples from springs and boreholes were collected and analyzed for chemical and isotopic compositions to determine the magmatic H2O, dissolved inorganic carbon (DIC), and Cl concentrations. The new approach to determine the magmatic CO2 concentration in groundwater using 3He concentration proposed herein cancelled the effect of carbonate deposition/dissolution, addition of DIC from organic matter, and bubbling of CO2. The estimated magmatic CO2/Cl ratios were 0.0009–14, which overlapped consistently with the modeled variation in the CO2/Cl ratio. The spatial variation of magmatic CO2/Cl in groundwater showed that higher-CO2/Cl are found near the central part of the volcanic complex which composed of felsic to mafic volcanoes, and low-CO2/Cl are only found around old felsic volcanoes. The CO2 bubbling springs were found to be associated with younger mafic volcanoes. The condition of the magma chambers, as shown by the spatial variation in CO2/Cl, were consistent with the record of the eruptive activities of the Kuju volcano. The CO2/Cl method proposed in this study using groundwater is useful for estimating magmatic conditions in chambers.

New insights into defluoridation via induced crystallization: Implications of phosphate species regulation for process efficiency and economics

Excess fluoride (F) at low concentrations in groundwater remains a challenge. F removal via fluidized-bed induced crystallization has been receiving increasing attention; however, the precipitant cannot be fully utilized. This results in generation of by-products, inadvertently increases the treatment cost, and impedes the assessment of product purity. In this study, phosphate species regulation was employed to improve the F removal efficiency without decreasing the phosphate utilization efficiency. It shows that F concentration could be reduced from 4.75 to 0.45 mg·L−1, with P concentration in the effluent being only 0.05 mg·L−1 at a P:F molar ratio of 3, involving appropriately mixed phosphate species. Hydroxyapatite (HAP) crystallization, subsequent F adsorption, and directly induced fluorapatite (FAP) crystallization occurred simultaneously in the fluidized bed, which was indirectly confirmed through intermittent operation of the process. The products of the induced crystallization process were FAP and a small amount of HAP, as determined qualitatively using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier-transform infrared spectroscopy (FTIR) tests. Overall, by regulating the phosphate species, the F removal efficiency is maintained, the cost of the precipitant is lowered, and the residual P concentration in the effluent is reduced. The process results in products with FAP as the main component, which can be used as raw material for the phosphoric acid purification process.

Spatial variations in groundwater hydrochemistry, sources, and controls across catchments on Chinese Loess Plateau

Study regionThis study was carried out at the Chinese Loess Plateau (CLP), which is located in the middle reach of the Yellow River in the northern China. Study focusUnderstanding groundwater hydrochemistry and its controlling factors in regions like CLP with thick unsaturated zones is challenging due to limited accessibility. The primary objective of this study was to investigate groundwater hydrochemistry, sources, and controls, and assess groundwater suitability for drinking and irrigation purposes across 14 major catchments in CLP. New hydrological insights for the regionOur results showed that the composition of groundwater dissolved solutes is primarily influenced by weathering rock, particularly silicate rock. However, human activities, especially in agriculture and urban areas, also have a notable impact on groundwater solutes. The presence of elevated nitrate in groundwater in various regions underscores the urgency of addressing long-term nitrogen pollution. Environmental changes such as climate change, erosion rates, and land-use patterns are key factors shaping groundwater quality. As air temperature decreases and erosion intensifies, along with more intensive land use, ion concentrations in groundwater tend to rise. Note that, approximately 91% of groundwater in CLP is suitable for direct drinking, but ensuring proper drainage is crucial to prevent sodium damage during irrigation. These findings enhance our understanding of the factors influencing groundwater solutes and are essential for effectively managing groundwater quality in CLP.