Water Concentration Research Articles

Co-occurrence of elevated arsenic and fluoride concentrations in Wuliangsu Lake: Implications for the genesis of poor-quality groundwater in the (paleo-)Huanghe (Yellow River) catchment, China

The co-occurrence of high As and F concentrations in saline groundwater in arid and semi-arid regions has attracted considerable attention. However, the factors determining the elevated concentrations of the two elements in surface water in these regions have not been sufficiently studied, and their implications for the poor-quality of local groundwater (high levels of As, F, and salinity) are unknown. A total of 18 water samples were collected from Wuliangsu Lake, irrigation/drainage channels, and the Huanghe (i.e., Yellow River) in the Hetao Basin, China. The pH, concentrations of As and F as well as those of other major elements, and stable isotope (H and O) compositions were analyzed. The water samples had a high pH (7.85–9.01, mean 8.25) and high TDS (402–9778 mg/L, mean 1920 mg/L) values. In six of the 10 lake samples, As concentration was above 10 μg/L (maximum 69.1 μg/L) and, in one of them, F concentration was above 1.5 mg/L. Interestingly, the high As, F, and TDS values simultaneously detected in the lake water were similar to those previously reported in local groundwater, and all water samples showed a significant positive correlation between As and F concentrations (R2 = 0.96, p < 0.01), except for two samples with abnormally high Ca2+ levels. The results of stable isotope analysis and Cl/Br ratios suggested that the lake experienced strong evaporation, which is consistent with the high TDS values. Evaporative concentration is suggested as the main factor contributing to the elevated As and F concentrations in the lake water. In addition, the major ions (e.g., Na+, Cl−, HCO3−, and OH−) and pH in the lake water increased during evaporation, leading to desorption of As and F. Thus, the evaporation process, including evaporative concentration and desorption, was considered primarily responsible for the elevated As and F in the lake water. Based on the results of this study, we presume that the paleolakes in the study area have experienced intense evaporation process. As a result, As, F, and major elements accumulated in sediments (or residual lake water) and were buried in the fluvial basins; then, they were released into the groundwater through multiple (bio)hydrogeochemical processes. By combining the results of this study with those obtained from previous groundwater analyses, we propose a new hypothesis explaining the origin of elevated As and F concentrations in saline groundwater in arid and semi-arid regions.

Assessment and accumulation of microplastics in the Indian riverine systems: Risk assessment and implications of translocation across the water-to-fish continuum

Microplastic (MP) pollution has engulfed global aquatic systems, and the concerns about microplastic translocation and bioaccumulation in fish and other aquatic organisms are now an unpleasant truth. In the past few years, MP pollution in freshwater systems, particularly rivers and subsequently in freshwater organisms, especially in fish, has caught the attention of researchers. Rivers provide livelihood to approximately 40 % of the global population through food and potable water. Hence, assessment of emerging contaminants like microplastics in rivers and the associated fauna is crucial. This study assessed microplastics (MPs) in fish, sediment and freshwater samples across the third largest riverine system of peninsular India, the Mahanadi River. The number concentrations of MPs measured in water, sediment and fish ranged from 337.5 ± 54.4–1333.3 ± 557.2 MPs/m3, 14.7 ± 3.7–69.3 ± 10.1 MPs/kg. Dry weight and 0.4–3.2 MPs/Fish, respectively. Surprisingly, MPs were found in every second fish sample, with a higher MP number in the gut than in the gills. Black and blue coloured filaments with <0.5 mm size were the dominant MPs with polypropylene and polyethylene polymers in abundance. The Polymer Hazard Index (PHI) and the Potential Ecological Risk Index (PERI) studies revealed that the majority of the sampling sites fell in Risk category V (dangerous category). An irregular trend in the MP concentration was observed downstream of the river, though relatively elevated MP concentrations in water and fish samples were observed downstream of the river. t-Distributed Stochastic Neighbour Embedding (t-SNE) unveiled distinct patterns in MP distribution with a higher similarity exhibited in the MPs found in fish gill and gut samples, unlike water and sediment, which shared certain characteristics. The findings in the current study contribute to filling the knowledge gap of MP assessment and accumulation in global freshwater systems and highlight the microplastic contamination and accumulation in fish with its potential implications on human health.

AgriTera: Accurate Non-Invasive Fruit Ripeness Sensing via Sub-Terahertz Wireless Signals

The potential to transform the agriculture sector and reduce food waste significantly lies in the ability to assess the quality of fruits and vegetables on a large scale. This article introduces AgriTera, an innovative solution that utilizes sub-terahertz wireless signals for accurate and non-invasive fruit ripeness sensing, without the need for physical contact. The underlying idea is that sugar and water concentrations in fruits, linked to ripening, create distinctive patterns in the wideband spectrum of reflected signals from the fruit body. AgriTera leverages the sub-THz bands due to their wide bandwidth, sensitivity to water, millimeter-scale penetration depth, and non-ionizing features. This enables high-resolution inferences from both the peel and pulp underneath. A chemometric model is developed to translate reflection spectra into well-known ripeness metrics like Dry Matter and Brix. Extensive over-the-air experiments using commercial sub-THz transceivers are conducted and compared with ground truth values from specialized sensors and a vision-based scheme.

CH4 emissions from runoff water of Alaskan mountain glaciers

Recent studies have observed high methane concentrations in runoff water and the ambient air at various glacier sites, including the Greenland Ice Sheet, the glacier forefield in Svalbard, and the ice cap in Iceland. This study extends these findings to smaller mountain glaciers in Alaska. Methane and carbon dioxide concentrations in the ambient air near the meltwater outlet, fluxes of these gases at the surface of runoff water and riverbank sediments, and dissolved methane content in the runoff water were measured at four glaciers. Three of the four glaciers showed conspicuous signals of methane emissions from runoff water, with the Castner Glacier terminus exhibiting a methane concentration three times higher than background levels, along with elevated dissolved methane levels in the runoff water. This study marks the detection of significant methane emissions from small mountain glacier runoff, contributing to the understanding that mountain glaciers also release methane into the atmosphere.

A method for studying the influence of Mn oxyhydroxides on the trace element content of aquatic bryophytes

The main objective of this study was to develop and test a method of separating externally deposited Mn oxyhydroxides and co-precipitated elements from samples of aquatic moss (the moss Fontinalis antipyretica). The method, which uses 0.1 M hydroxylamine to dissolve the oxyhydroxides, was tested with samples collected in rivers with slightly acidic, well‑oxygenated waters, where high rates of Mn precipitation occur. The method was effective (it extracted up to 84 % of the Mn) and selective (Fe oxyhydroxides were not extracted). The elements Ba, Cd, Zn and Ni were associated with the Mn oxyhydroxides, while Al, As, Cr, Cu, Fe, Hg and Pb were not. Deposition of Mn therefore increased the concentration of some elements in the moss samples. However, as Mn precipitation depends on Eh and pH, which are independent of the concentrations of the elements in water, the relationship between water and moss element concentrations is not clear (i.e. the data are noisy). This is a problem in biomonitoring studies, which assume a close relationship between element concentrations in moss and water. The value of the proposed extraction method is that it can be used to correct the effect of Mn deposition. We present an example of this correction applied to the Cd concentrations in the test data. We found that the noise introduced by the Mn, including age-related effects (observed by comparing concentrations in 0–2.5 and 2.2–5.0 cm sections from the shoot apex), can be reduced. Additionally, the correction revealed recent increases in Cd concentrations in one site that were not observed in the uncorrected data. Another finding of interest was the low content of total Mn and different extractability (of most elements) observed in moss samples collected in alkaline waters. Finally, we discuss how future studies designed for different environmental scenarios can benefit from application of the proposed method.

Modeling and FE simulation of coupled water diffusion and viscoelasticity in relaxation tests of polyamide 6

AbstractPolyamides can absorb or desorb water from or to their surrounding environment. The impact of this process is significant as water molecules lead locally to a swelling and a coupling of diffusion and deformation behavior. To model these phenomena, a strongly coupled chemo-mechanical (or diffuso-mechanical) model is required, considering both local water concentration and the viscoelastic material behavior of polyamide. In the present work, we derive and apply such a model to polyamide 6. A diffusion equation describing changes in water concentration is coupled to the balance of linear momentum in polyamide 6. The interaction between deformation and concentration is derived from thermodynamic considerations by introducing a free energy consisting of a mechanical and a chemical part. The mechanical part describes a linear viscoelastic model and includes chemical strains due to the presence of water molecules. The chemical part builds upon the theory of Flory and Huggins, that takes into account changes in enthalpy and entropy of mixing due to the interaction of polymer and water molecules. The coupling of deformation to water concentration arises due to a dependency of the water flux on the hydrostatic stress inside the polyamide. We successfully apply the derived model in Finite-Element simulations to predict the drying of polyamide 6 specimens without any coupling to mechanical loads. In addition, we reproduce experimentally obtained data from relaxation measurements, where the drying of polyamide specimens leads to an increase in relaxation modulus.

Conformations of a highly expressed Z19 α-zein studied with AlphaFold2 and MD simulations.

α-zeins are amphiphilic maize seed storage proteins with material properties suitable for a multitude of applications e.g., in renewable plastics, foods, therapeutics and additive manufacturing (3D-printing). To exploit their full potential, molecular-level insights are essential. The difficulties in experimental atomic-resolution characterization of α-zeins have resulted in a diversity of published molecular models. However, deep-learning α-zein models are largely unexplored. Therefore, this work studies an AlphaFold2 (AF2) model of a highly expressed α-zein using molecular dynamics (MD) simulations. The sequence of the α-zein cZ19C2 gave a loosely packed AF2 model with 7 α-helical segments connected by turns/loops. Compact tertiary structure was limited to a C-terminal bundle of three α-helices, each showing notable agreement with a published consensus sequence. Aiming to chart possible α-zein conformations in practically relevant solvents, rather than the native solid-state, the AF2 model was subjected to MD simulations in water/ethanol mixtures with varying ethanol concentrations. Despite giving structurally diverse endpoints, the simulations showed several patterns: In water and low ethanol concentrations, the model rapidly formed compact globular structures, largely preserving the C-terminal bundle. At ≥ 50 mol% ethanol, extended conformations prevailed, consistent with previous SAXS studies. Tertiary structure was partially stabilized in water and low ethanol concentrations, but was disrupted in ≥ 50 mol% ethanol. Aggregated results indicated minor increases in helicity with ethanol concentration. β-sheet content was consistently low (∼1%) across all conditions. Beyond structural dynamics, the rapid formation of branched α-zein aggregates in aqueous environments was highlighted. Furthermore, aqueous simulations revealed favorable interactions between the protein and the crosslinking agent glycidyl methacrylate (GMA). The proximity of GMA epoxide carbons and side chain hydroxyl oxygens simultaneously suggested accessible reactive sites in compact α-zein conformations and pre-reaction geometries for methacrylation. The findings may assist in expanding the applications of these technologically significant proteins, e.g., by guiding chemical modifications.

Drivers of neritic water intrusions at the subtropical front along a narrow shelf

The near-ubiquitous presence of freshwater over the inner to mid-continental shelf off of the Otago Peninsula in southeast Aotearoa/New Zealand has been previously identified in long-term cross-shelf transects. Occasional influxes of this silicate-rich neritic water past the shelf break and beyond the Subtropical Front have been observed, potentially supporting elevated chlorophyll-a concentrations in SubAntarctic waters. Nearshore salinity variability has been connected to flow rates of the Clutha River, Aotearoa’s largest river by discharge, however, other physical mechanisms influencing the structure of freshwater along this coast have not been explicitly explored. A numerical model of Aotearoa’s southeast continental shelf forced with realistic discharge from the Clutha River is used to assess the drivers of river plume variability and identify conditions associated with the transport of neritic water beyond the shelf break. Event scale, lagged correlation, EOF, and composite analysis of a model passive dye tracer revealed three generalised plume structures that are dependent on river discharge, along-front wind stress, and shelf current velocities. Downfront wind stress suppresses bulge formation at the river mouth and constrains the river plume against the coast, whereas upfront wind stress causes the river plume to move offshore over the shelf and spread across the upper water column. Rarely, upfront wind stress generates a nearshore current reversal over the shelf, causing the plume to deflect straight off-shelf and across the shelf edge before meeting the frontal current and advecting to the northeast. Future observational work is required to validate the mechanisms described and address the biological implications of these findings.

Sources, Fates, and Geochemical Cycling of Mercury in Geothermal Fields: Insights From Mercury Isotopes

AbstractGeothermal fields emit remarkable amounts of mercury (Hg) to the environment. To address the source, fate and geochemical cycling of Hg in geothermal fields, we investigated Hg concentrations and isotopic compositions of hot spring water and fumarole gases from Rehai and Dagejia in SW‐China. Elevated Hg concentrations in fumarole gases (10.0–167 ng m−3) and hot spring water (3.44–84.5 ng L−1) were observed, suggesting that both geothermal fields are of environmental concern. The variation in Δ199Hg (−0.06 to 0.23‰) and Δ200Hg (−0.09 to 0.19‰) in hot spring water supports Hg likely originating from endogenous volcanic degassing and/or rainwater. Negative and nearly zero Δ199Hg in fumarole gases (−0.32 to 0.03‰) supports volcanic degassing and background atmosphere origin. The ranges of δ202Hg in fumarole gases (−0.74 to 0.59‰) and hot spring water (−1.29 to 0.52‰) could reflect limited fluids boiling in geothermal fields. This study, thus, fills an important knowledge gap regarding Hg global cycling.

Selective metasomatism of ultramafic cumulates within Archean supracrustal sequences

The Neoarchean Storø Supracrustal Belt in SW Greenland comprises a sequence of mature quartzite, metapelite, amphibolite, and ultramafic rocks that underwent amphibolite facies metamorphism during the amalgamation of the Mesoarchean Akia Terrane and the Eoarchean Færingehavn Terrane. In this belt, tourmaline is found in a transition zone between ultramafic and metapelitic rocks, but also occurs as orbicules within the ultramafic rocks. These tourmaline orbicules hosted by ultramafic rocks are reported for the first time in the North Atlantic craton, thus indicating a unique formation mechanism. We conducted a comprehensive examination of the petrology, whole-rock and mineral chemistry, and oxygen isotope compositions from borehole samples in the Storø Supracrustal Belt, to elucidate the metasomatic events associated with the formation of the orbicular tourmalines. The Storø ultramafic rocks have high MgO, Cr, and Ni contents, with low abundances of REE and HFSE, and preserve a typical cumulate texture. These features are similar to those of ultramafic cumulates found in other Archean supracrustal belts, suggesting a cumulate origin for the Storø ultramafic rocks. Furthermore, the morphology and composition of the tourmaline orbicules within these cumulates indicate that they originated from melts with high boron and high water concentrations that infiltrated the ultramafic rocks. The main factor influencing the morphology of the tourmaline orbicules is the silicification of the ultramafic rocks, driven by their lower chemical potential of SiO2 compared to the surrounding rocks. This silicification process, in combination with compositional variations of cumulates during fractional crystallization, has contributed to the geochemical diversity observed in Archean ultramafic rocks. Thus, it is crucial to understand the effects of such selective metasomatism on Archean ultramafic rocks, as this will facilitate the extraction of original information preserved in the early rock record.

Hydraulic permeation-induced water concentration gradients in ion exchange membranes

Although substantial literature has detailed transport through swollen membranes, there are still conflicting reports regarding the fundamental physics of hydraulic water transport in such materials, with a long-standing debate centered on the applicability of the pore-flow and solution-diffusion mechanisms. The critical thermodynamic distinction between these models is the presence of a membrane-phase concentration gradient. For pure solvent transport, the pore-flow model presumes that a membrane-phase pressure gradient drives transport in the absence of a concentration gradient. In contrast, the solution-diffusion model proposes that a membrane-phase concentration gradient drives transport and that there is a negligible pressure gradient through the membrane. To address this topic for ion exchange membranes, this study reports measurements of water concentration profiles in pressurized films of Nafion and a commercial membrane based on sulfonated poly (styrene-co-divinylbenzene). Several films were stacked together in a custom-built permeation cell, with the feed side pressurized to between 68.9 and 137.9 bar, and the permeate side held at atmospheric conditions. At steady state, the experiment was stopped, the films were separated, and the water content of each film was measured, revealing a water concentration gradient through the stack thickness that increased with increasing feed pressure. The experimental data were in good agreement with theoretical predictions based on Fick's law and polymer-solvent swelling theories (i.e., Flory-Huggins and Flory-Rehner). These results are consistent with the solution-diffusion model and cannot be explained by a pore-flow mechanism.

Microcystin-LR Induces Estrogenic Effects at Environmentally Relevant Concentration in Black-Spotted Pond Frogs (Pelophylax nigromaculatus): In Situ, In Vivo, In Vitro, and In Silico Investigations.

Harmful cyanobacterial blooms are frequent and intense worldwide, creating hazards for aquatic biodiversity. The potential estrogen-like effect of Microcystin-LR (MC-LR) is a growing concern. In this study, we assessed the estrogenic potency of MC-LR in black-spotted frogs through combined field and laboratory approaches. In 13 bloom areas of Zhejiang province, China, the MC-LR concentrations in water ranged from 0.87 to 8.77 μg/L and were correlated with sex hormone profiles in frogs, suggesting possible estrogenic activity of MC-LR. Tadpoles exposed to 1 μg/L, an environmentally relevant concentration, displayed a female-biased sex ratio relative to controls. Transcriptomic results revealed that MC-LR induces numerous and complex effects on gene expression across multiple endocrine axes. In addition, exposure of male adults significantly increased the estradiol (E2)/testosterone (T) ratio by 3.5-fold relative to controls. Downregulation of genes related to male reproductive endocrine function was also identified. We also showed how MC-LR enhances the expression of specific estrogen receptor (ER) proteins, which induce estrogenic effects by activating the ER pathway and hypothalamic-pituitary-gonadal (HPG) axis. In aggregate, our results reveal multiple lines of evidence demonstrating that, for amphibians, MC-LR is an estrogenic endocrine disruptor at environmentally relevant concentrations. The data presented here support the need for a shift in the MC-LR risk assessment. While hepatoxicity has historically been the focus of MC-LR risk assessments, our data clearly demonstrate that estrogenicity is a major mode of toxicity at environmental levels and that estrogenic effects should be considered for risk assessments on MC-LR going forward.

Identification of microplastics content in milkfish (Chanos chanos), water and sediment in ponds in Muncung Village, Kronjo District

Plastic is a product that is currently popular among people, but over time plastic can be dangerous for the environment. Plastic can degrade into smaller particles known as microplastics. Microplastics in waters can harm aquatic biota such as fish. The size of microplastics is so small that it easily enters the fish's body, settles in the digestive tract and affects the fish's life cycle. Apart from biota, microplastics also pollute water and sediment. The aim of this research is to determine the abundance of microplastics and identify the characteristics of microplastics in milkfish in ponds in Muncung Village. The method used is take fish from ponds at 6 stations along with water and sediment. The fish were dissected and the digestive organs and flesh were removed, while the water and sediment were treated with NaCl. The microplastics found will be tested by FTIR to determine the polymer. The results of the observations showed that there were 3 types of microplastics, namely fragments, fibers and films. The highest abundance in organs was in the intestine, while microplastics were also found in water and sediment. FTIR test results show 6 plastic polymers in milkfish, namely ABS, latex, PVC, PP, EVA and nitrile. Keywords: Microplastics, milkfish, FTIR, Muncung Village

Phosphorus depletion is exacerbated by increasing nitrogen loading in the Bohai sea

Phosphorus (P) is an essential nutrient for algal growth in nearshore ecosystems. In recent years, there has been a shift in nutrient dynamics in nearshore areas, leading to an exacerbation of P limitation, although the underlying mechanisms remain unclear. This study analyzed the P species and budget in the Bohai Sea (BS) from 2011 to 2020, aiming to explore the intrinsic mechanisms of P limitation in the BS. The results show that the main external source of P in the BS was river transport (89%), and the primary fate of P was burial (96%) into the sediment. Due to excessive nitrogen (N) input and biological processes in the BS, the P budget in the BS is unbalanced, resulting in an increase in the N/P ratio, particularly in nearshore areas. Nearshore areas typically have lower concentrations of dissolved inorganic P (DIP) in the water and higher concentrations of reactive P (Reac-P) in the sediments. This pattern is particularly evident in Bohai Bay and the northwest nearshore region, where harmful algal blooms occur frequently. To cope with enhanced P limitation, the biologically driven P regeneration and cycling processes within the BS are accelerated. From 2011 to 2020, the concentration of DIP in the BS during autumn increased, while the content of Reac-P in sediments slightly decreased. Historical data indicate that P depletion in the BS is intensifying and expanding, primarily due to N enrichment and algal production. N enrichment alters the structure and composition of primary production, potentially exacerbating P depletion in the BS. Excessive N may have significant impacts on the P pool, potentially influencing the stability of future coastal ecosystems.

Development of an analytical method to quantify N-acyl-homoserine lactones in bacterial cultures, river water, and treated wastewater.

N-Acyl-homoserine lactones (AHL) play a major role in the communication of Gram-negative bacteria. They influence processes such as biofilm formation, swarming motility, and bioluminescence in the aquatic environment. A comprehensive analytical method was developed to elucidate the "chemical communication" in pure bacterial cultures as well as in the aquatic environment and engineered environments with biofilms. Due to the high diversity of AHLs and their low concentrations in water, a sensitive and selective LC-ESI-MS/MS method combined with solid-phase extraction was developed for 34 AHLs, optimized and validated to quantify AHLs in bacterial conditioned medium, river water, and treated wastewater. Furthermore, the developed method was optimized in terms of enrichment volume, internal standards, limits of detection, and limits of quantification in several matrices. An unanticipated variety of AHLs was detected in the culture media of Pseudomonasaeruginosa (in total 8 AHLs), Phaeobactergallaeciensis (in total 6AHLs), and Methylobacterium mesophilicum (in total 15 AHLs), which to our knowledge have not been described for these bacterial cultures so far. Furthermore, AHLs were detected in river water (in total 5AHLs) and treated wastewater (in total 3 AHLs). Several detected AHLs were quantified (in total 24) using a standard addition method up to 7.3±1.0µg/L3-Oxo-C12-AHL (culture media ofP. aeruginosa).

New long tail gemini surfactant in aqueous solution: Self-assembly, rheological properties and responsiveness to hydrocarbon

Gemini surfactants are promising to replace conventional monomeric surfactants in various applications. In this paper, a new gemini surfactant with long unsaturated oleyl tails and bis(hydroxyethyl) ammonium head groups linked by butyl spacer was synthesized. Its critical micelle concentration in salt-free water (12 µM) is much lower than for its monomeric analog (220 µM). Without any additives this surfactant can form viscoelastic solutions with the viscosity of up to 1 kPa·s and elastic modulus of 15 Pa at the conditions, when the viscosity of the single-chained monomeric analog is close to that of pure water. These are one of the highest values reported so far for C18-tailed gemini surfactants without additives. The structure of the gemini surfactant solutions was studied by cryo-TEM and SAXS. Cryo-TEM revealed the presence of closed-looped micelles coexisting with linear wormlike micelles as well as the regular spacing between the micelles arising from strong electrostatic repulsion between them. The SAXS curves were well-fitted by a form-factor of core–shell cylinder, which yielded the radius of the core and the thickness of the shell equal to 1.4 nm each. Addition of n-decane induced the drop of viscosity by 6 orders of magnitude accompanied by the transformation of wormlike micelles into microemulsion droplets with 4.4 nm radius. Such gemini surfactants providing high viscoelasticity to aqueous solution that is responsive to added hydrocarbon are promising for the application in oil recovery as thickeners of fracturing fluids that can be cleaned up without any breakers at the backflow of oil.

288 Effects of increasing water concentrations of oregano essential oil supplementation for lactating sows

Abstract The use of essential oils as a supplement for sows has gained attention in recent years to potentially improve sow and litter performance. Sows (n = 182; avg. lactation length = 19.8 d) were blocked by parity, genetics, estimated farrowing date, and randomly allotted to one of four treatments when entering the farrowing barn. Treatments included: control, 0 mL, (CON, n = 46), 31 mL (L-OEO, n = 45), 47 mL (M-OEO, n = 46), or 63 mL (H-OEO, n = 45) of oregano oil (OEO; Ecodiar Liquid, Nutrinae, Palo Alto, CA) per liter of dosing water with medicators set at 1:128 dilution. Sows were fed a corn-soybean meal-DDGS based lactation diet that met or exceeded NRC (2012) requirements. Sow body weight (BW) was recorded upon entry, 2 d post-farrowing, and weaning. Sow backfat depth (BF) and loin muscle depth (LD) ultrasound measurements, body condition score (BCS), and Knauer sow caliper measurements were collected upon entry and weaning. Sow average daily feed intake (ADFI) was recorded daily 1-wk post-farrowing, then weekly until weaning. Sow water intake was recorded daily (DWI). Individual piglet BW were recorded d 1, d 7, and weaning. Data were analyzed using Proc Mixed procedure in SAS 9.4 with treatment and rep as fixed effects, parity class (P1, P2/P3, P4+) as a covariate, and individual sow as a random effect. Lactation length and number of piglets weaned were used as covariates for weaning data. Linear, quadratic, and cubic contrasts were analyzed among treatments. Litter scouring and medication rates were analyzed using chi-square analysis in the Proc Freq procedure in SAS 9.4. Differences were considered significant at P ≤ 0.05 and trend at 0.05 &amp;lt; P ≤ 0.10. Week 3 lactation sow ADFI increased for L-OEO and H-OEO treatments but decreased for M-OEO compared with CON sows (CON: 7.29 kg/d, L-OEO: 7.60 kg/d, M-OEO: 7.03 kg/d, H-OEO: 7.55 kg/d; cubic; P = 0.0427). No differences were observed among treatments in overall lactation ADFI, DWI, changes in BF, LD, BCS, and piglet and litter growth performance. Sow BW change tended to decline and then increased as OEO increased in the water (CON: -8.79 kg, L-OEO: -6.36 kg, M-OEO: -8.03 kg, H-OEO: -10.52 kg; quadratic, P = 0.0640). There was a cubic tendency for OEO supplementation to reduce loss of caliper measurement (CON: -1.91, L-OEO: -0.98, M-OEO: -1.68, H-OEO: -1.00; P = 0.0598). Percentage of piglets treated with medications for various health issues decreased in the H-OEO supplemented group compared with the L-OEO and M-OEO supplemented groups, with CON group being intermediate and not different (CON: 7.01%, L-OEO: 9.35%, M-OEO: 9.91%, H-OEO: 4.15%; P = 0.0322). Overall, there were no significant impacts of OEO supplementation on sow and litter performance in this study. Future research is needed to determine the effectiveness of OEO in health-challenged sows and litters and the long-term effects of OEO on piglets post-weaning.

Corrosion and fretting-corrosion behavior of Zr-Nb alloy under aqueous LiOH solution

Zirconium alloys are the key materials for nuclear reactor’s core components due to low neutron cross-section and good mechanical and corrosion properties. During operation in nuclear reactor, some core components (exposed to the corrosive environment of coolant water having LiOH) may undergo corrosion and fretting-corrosion. This work presents a novel experimental approach for investigating the Zr-2.5 Nb alloy's corrosion and in-situ fretting-corrosion response. The corrosion analysis was performed using Electrochemical Impedance Spectroscopy (EIS) and potentiodynamic polarization, to study the effect of LiOH concentration in water and exposure duration. It is observed that the corrosion rate increases with increasing the concentration of LiOH in water and decreases with increasing the exposure duration. The fretting-corrosion tests were performed between SS-410 and Zr-2.5 Nb in aqueous LiOH solution. The results reveal that the contact resistance and coefficient of friction (COF) decrease with increasing concentration of LiOH in the solution. The present work highlights the scientific understanding of corrosion and fretting-corrosion phenomena in zirconium alloy and elucidates key mechanisms and factors governing the degradation behavior which can help in preventing the failure of the components.

A multivariate linear regression model for estimating chlorophyll-a concentration in Quan Son Reservoir (Hanoi, Vietnam) using Sentinel-2B Imagery

Monitoring chlorophyll-a concentration (Chla) in inland waters is vital for environmental assessment. This study develops an empirical multivariate linear regression (MLR) model to directly estimate Chla in Quan Son Reservoir using Sentinel-2B (S2B) Level 2A images. Regression analysis of a 68-point in-situ Chla dataset measured in Quan Son Reservoir between 2021 and 2023, in conjunction with the corresponding S2B reflectance data, reveals a significant correlation between Chla and a combination of the blue (B2), green (B3), and red (B4) bands (coefficient of determination, R² = 0.95). The Chla estimation model is validated using a 30-point in-situ dataset collected on various dates (R² = 0.87; the root-mean-squared error RMSE &lt; 5%). Subsequently, the model is applied to ten S2B images acquired from 2021 to 2023, revealing Chla's spatio-temporal distribution across the reservoir. Two key trends emerge: (1) Chla is lower during winter (November and December) than in summer and early autumn (July and September), and (2) The distribution of Chla undergoes noticeable spatial changes, particularly in July, with elevated levels observed in areas characterized by tourist hotspots. This approach shows promise for monitoring Chla in similar inland waters.

Predicted concentrations of antineoplastic drugs in the aquatic environment: The case of Ría de Vigo (NW, Spain)

The European Medicines Agency (EMA) mandates Environmental Risk Assessments (ERAs) since 2006 to determine potential risks of new marketed medicines. Drugs with a Predicted Environmental Concentration (PEC) in inland surface waters exceeding 0.01 μg L−1 require further environmental risk assessment. PEC may be refined based on prevalence data and/or based on the treatment regimen. In this study, based on EMA regulations, refined PEC of 108 antineoplastic drugs in coastal waters were determined based on the consumption in a coastal health area during 2021, identifying six drugs with potential environmental risk in surface waters (hydroxyurea, capecitabine, abiraterone, ibrutinib, imatinib and 5-fluorouracil) and two in marine ecosystem (hydroxyurea and capecitabine). Comparison of these refined PECs with data from marketing laboratories revealed significant disparities, suggesting the need for regular updates, especially with changes in drug indications or financing. Notably, the identified drugs are not yet on the main reference lists of emerging contaminants.