Toluene Concentration Research Articles

Study of Pt-modified chromium-manganese oxide alloys to improve the performance of toluene abatement

This research is dedicated to solving the environmental problems of volatile organic compounds (VOCs), particularly aromatic chemicals in industrial emissions. The research aims to explore low-temperature, effective catalytic degradation technologies, specifically involving metal oxide and noble metal oxide catalysts, especially the Cr-Mn-Pt series catalysts. The Cr-Mn-Pt catalysts synthesized by the co-precipitation method showed efficient catalytic degradation of VOCs in low-temperature environments. The results of the experiment show that the Cr-Mn-Pt catalysts achieved 90 % toluene conversion at 198 °C, a 1000 ppm toluene concentration, and GHSV=15,000 mL/g·h, which is superior to single MnOx and Cr-Mn catalysts. The catalysts are characterized in depth using X-ray diffraction, specific surface area analysis and Fourier transform infrared spectroscopy. The result shows that the high specific surface area and large volume of pores of the Cr-Mn-Pt catalyst are advantageous for enhancing their catalytic activity and stability. The catalytic mechanism analysis shows that the degradation mechanism of toluene follows the Mars-van Krevelen mechanism with the final conversion of the intermediate product benzoate to CO2 and H2O. In summary, the Cr-Mn-Pt catalyst shows great potential in the technical treatment of VOCs due to their excellent low-temperature catalytic efficiency and stability, and it has enormous practical implications for protecting the environment in the industry.

Assessing VOC emissions from different gas stations: impacts, variations, and modeling fluctuations of air pollutants

Gas stations distributed around densely populated areas are responsible for toxic pollutant emissions such as volatile organic compounds (VOCs). This study aims to measure VOCs emission from three different kinds of gas stations to determine the extent of pollution from the gas stations and the most frequent type of VOC compound emitted. The concentrations of ambient VOCs at three refueling stations with a different type of fuels in Mashhad were monitored. The result of this study showed that CNG fuel stations are less polluting than petrol stations. In all the studied sites, the highest concentrations were related to xylene isomers, irrespective of the fuel type. Total VOCs at the supply of both compressed natural gas (CNG) and gasoline stations was 482.36 ± 563.45 µg m−3. At a CNG station and a gasoline station, total VOC concentrations were 1363.4 ± 1975 µg m−3 and 410.29 ± 483.37 µg m−3, respectively. The differences in concentrations of toluene and m,p-xylene between the fuel stations can be related to the quality and type of fuel, vapor recovery technology, fuel reserves, dripless nozzles, traffic density in these stations, meteorological conditions and the location of sampling sites. The combination of a sine function and a quadratic function could model the fluctuation behavior of air pollutants like m,p-xylene. In all the sites, the highest concentrations were related to xylene isomers, irrespective of the type of fuel. The changing rate of m,p-xylene pollutant in each station was also modeled in this study.

Volatile organic compounds and cancer risk assessment in an intensive care unit.

Changes caused by air-cleaning devices in the amounts of volatile organic compounds in an intensive care unit were monitored in the study. The cancer risk and hazard index were calculated. The measurements were made for one month at isolated room and two different points and times in the intensive care unit. According to the sampling program, the air-cleaning devices were turned off in weeks 1 and 4 and turned on in weeks 2 and 3. Volatile organic compounds were collected by active sampling. Samples were analyzed by a thermal desorber coupled to a gas chromatography-mass spectrometry instrument with selective ion monitoring. The results showed that the concentrations of benzene, toluene, and o-xylene decreased by about 70% after the air-cleaning devices were installed. The cancer risk assessment for naphthalene was recorded at the highest level of cancer risk (Class A). The hazard index value of naphthalene was recorded at the harmful level when air-cleaning devices were not installed. The concentrations of benzene (p = 0.01), toluene (p = 0.02), ethylbenzene (p = 0.02), styrene (p = 0.01), and m, p-xylene (p = 0.04) before the air-cleaning devices were installed were significantly different from those recorded when the air-cleaning devices were turned on.

Association of volatile organic compound levels with chronic obstructive pulmonary diseases in NHANES 2013–2016

Volatile organic compounds (VOCs) represent a significant component of air pollution. However, studies evaluating the impact of VOC exposure on chronic obstructive pulmonary disease (COPD) have predominantly focused on single pollutant models. This study aims to comprehensively assess the relationship between multiple VOC exposures and COPD. A large cross-sectional study was conducted on 4983 participants from the National Health and Nutrition Examination Survey. Four models, including weighted logistic regression, restricted cubic splines (RCS), weighted quantile sum regression (WQS), and the dual-pollution model, were used to explore the association between blood VOC levels and the prevalence of COPD in the U.S. general population. Additionally, six machine learning algorithms were employed to develop a predictive model for COPD risk, with the model’s predictive capacity assessed using the area under the curve (AUC) indices. Elevated blood concentrations of benzene, toluene, ortho-xylene, and para-xylene were significantly associated with the incidence of COPD. RCS analysis further revealed a non-linear and non-monotonic relationship between blood levels of toluene and m-p-xylene with COPD prevalence. WQS regression indicated that different VOCs had varying effects on COPD, with benzene and ortho-xylene having the greatest weights. Among the six models, the Extreme Gradient Boosting (XGBoost) model demonstrated the strongest predictive power, with an AUC value of 0.781. Increased blood concentrations of benzene and toluene are significantly correlated with a higher prevalence of COPD in the U.S. population, demonstrating a non-linear relationship. Exposure to environmental VOCs may represent a new risk factor in the etiology of COPD.

Tailoring oxygen vacancies by synergy of dual metal cations in LaCo0.8M0.2O3 (M = Cu, Ni, Fe, Mn) towards catalytic oxidation of toluene

Enhancing the catalytic performance of transition metal oxide catalysts is prerequisite for the efficient catalytic oxidation of VOCs. Here the B-site partially substituted LaCoO3 (LaCo0.8M0.2O3, M = Cu, Ni, Fe and Mn) catalysts was synthesized for the catalytic oxidation of toluene. Among these catalysts, LaCo0.8Ni0.2O3 catalyst exhibits remarkable catalytic performance for toluene with T50 = 226 °C and T90 = 239 °C at an initial toluene concentration of 1000 ppm, whose T50 (and T90) reduced by 13 °C (and 34 °C) compared with that of LaCoO3. Confirmed by BET, XPS, and EPR characterizations, Ni substitution improves the specific surface area, Co3+/Co2+ ratio, Oads/Olatt ratio, and oxygen vacancies concentration. This improvement indicates the improvement of adsorption and activation of reactant, mobility of oxygen species, thereby contributing to the superior catalytic performance in toluene oxidation. The B-site of LaCoO3 occupied by dual cations caused the lattice distortion and formation of oxygen vacancies due to the ionic radii difference between Co and Ni cations. Moreover, the apparent activation energy of LaCo0.8Ni0.2O3, as the determining factor for the catalytic oxidation rate, was remarkably reduced. Our findings confirmed the synergy effect of Co and Ni cations at B-site on the enhancement of catalytic activity, which provides a promising strategy for oxygen vacancy engineering.

Health risks associated with hazardous airborne chemicals in beauty salons: A pilot study in Kuwaiti salons

The beauty industry has become increasingly popular in recent years, leading to a surge in salon visits for various beauty treatments. However, public concerns were raised about the possible health dangers linked to the widespread use of harmful chemicals in beauty salons. To address these concerns, a pilot study was conducted in Kuwait to evaluate and identify the ten most commonly occurring hazardous airborne chemicals in different beauty salons. Air samples were gathered from inside and outside ten beauty salons situated in diverse regions of Kuwait, covering various periods, including working hours, non-working hours, and a continuous 24-h period. The study used diffusion tubes for sampling and employed the thermo-desorption gas chromatograph/mass spectroscopy technique (TD-GC/MS) to identify the chemical compounds. In addition, the measured concentration of compounds was utilized to assess the potential inhalation health risks associated with both carcinogenic and non-carcinogenic substances, employing the USEPA Cancer Risk Indicator (CRI) and Hazard Quotient Indicator (HQI). The findings indicated that indoor concentrations of hazardous chemicals were significantly higher than those recorded outdoors. A total of 55 hazardous chemicals were detected in the indoor air quality inside beauty salons, and benzene concentrations exceeded ACGIH thresholds, suggesting a potential health concern. Although concentrations of toluene, ethylbenzene, m/p-xylene, and o-xylene remained below NIOSH recommendations, health risk assessments indicated the potential carcinogenicity of three compounds in the indoor air of beauty salons: benzene, ethylbenzene, and 2-ethyl-1-hexanol. Additionally, 15 compounds were identified by non-carcinogenic risk assessments, such as ethyl acetate and 2-ethyl-1-hexanol. These findings emphasize the urgency of implementing measures to address the exposure in Kuwait's beauty salons and conducting further research.

Application of fluorescent carbon quantum dots functional modified carboxymethyl cellulose film in toluene gas specific detection

With the increasing consumption of organic solvents in chemical and pharmaceutical industries, the environment pollution of volatile organic compounds (VOCs) has become an urgent problem. Therefore, the rapid-visual detection method is of great significance in the analysis of VOCs. Based on the fluorescence quenching/enhancement mechanism of carbon quantum dots (CQDs), with the help of carboxymethyl cellulose membrane with porous and large specific surface area structure, a series of green CQDs@carboxymethyl cellulose composite film (CQDs@CMC composite film) was prepared in this study. In the typical-targeted pollutants (toluene) detection application, a fluorescence spectroscopy method was established which could achieve the high sensitivity and strong specificity detection. The mainly conclusions were as follows: The fluorescence spectrometric detection method for toluene: A kind of hydrophobic Lmi/Bet CQDs@CMC composite film was prepared and characterized with imidazole/betaine CQDs and porous carboxymethyl cellulose composite film as raw materials. The toluene detection performance was studied, and the recognition mechanism was explored. The results showed that toluene enhanced the fluorescence of Lmi/Bet CQDs@CMC composite film. The fluorescence intensity of composite films was proportional to toluene concentration when the toluene concentration ranged from 200 to 2200 mg/L. The detection limit of toluene was 1.169 mg/L, which provides a theoretical basis for the detection of toluene by fluorescence spectrometry.

Revisions to Limits for Toluene in Spacecraft Air.

INTRODUCTION: The original Spacecraft Maximal Allowable Concentrations (SMACs) for toluene (set for 1 h, 24 h, 7 d, 30 d, and 180 d) were first established by NASA in 1996 based on a human study in which no irritation or neurotoxicity was reported following 6-h exposure to 40 ppm toluene vapors. While the toluene SMACs were updated in 2008 to account for auditory, visual, and hormonal effects (for 7 d, 30 d, and 180 d) and to include a long-term SMAC (1000 d) in anticipation of longer spaceflight exploration missions, the short-term SMAC limits (1 h and 24 h) remained unchanged. Acute toluene exposure is reported to result in ocular and nasal irritation, although it is not a primary irritant, as well as central nervous system effects including headaches and dizziness. Long-term exposure to toluene can elicit hepatotoxicity, nephrotoxicity, neurotoxicity, and endocrine toxicity.RESULTS AND DISCUSSION: Since publication of the original and revised toluene SMACs, the National Academy of Sciences developed interim Acute Exposure Guideline Limits reviewed by the National Research Council Committee. Based on these data, we have increased the limits for toluene in crewed spacecraft to 40 ppm for 1 h, 24 h, 7 d, and 30 d. SMACs for durations of 180 and 1000 d will remain unchanged.changed.Tapia CM, Langford SD, Ryder VE. Revisions to limits for toluene in spacecraft air. Aerosp Med Hum Perform. 2024; 95(7):399-402.

Simultaneous biofiltration of H2S, NH3, and toluene using compost made of chicken manure and sugarcane bagasse as packing material.

Offensive odors from wastewater treatment plants (WWTP) are caused by volatile inorganic compounds such as hydrogen sulfide and ammonia and volatile organic compounds (VOCs), such as toluene. To treat these pollutants, biofiltration is an effective and economical technology used worldwide due to its low investment and environmental impact. In this work, a laboratory-scale prototype biofilter unit for the simultaneous biofiltration of hydrogen sulfide, ammonia, and toluene was evaluated by simulating the emission concentrations of the El Salitre WWTP Bogotá, Colombia, using a compost of chicken manure and sugarcane bagasse as packing material for the biofilter. The prototype biofilter unit was set to an operation flow rate of 0.089 m3/h, an empty bed residence time (EBRT) of 60 s, and a volume of 0.007 m3 (6.6 L). The maximum removal efficiency were 96.9 ± 1.2%for H2S, at a loading rate of 4.7 g/m3 h and a concentration of 79.1 mg/m3, 68 ± 2% for NH3, at a loading rate of 1.2 g/m3 h and a concentration of 2.0 mg/m3, and 71.5 ± 4.0%for toluene, at a loading rate of 1.32 g/m3h and a concentration of 2.3 mg/m3. The removal efficiency of the three compounds decreased when the toluene concentration was increased above 40 mg/m3. However, a recovery of the system was observed after reducing the toluene concentration and after 7 days of inactivity, indicating an inhibitory effect of toluene. These results demonstrate the potential use of the prototype biofilter unit for odor treatment in a WWTP.

Removal of toluene from Air- scream using semi industrial two-phase bioscrubber with cutting oil: An intervention study

<p>Toluene is a monocyclic aromatic compound that finds widespread use in various industrial processes. Due to its harmful effects on human health and environment, this study aimed to remove toluene from the air stream using a two-phase bioscrubber. The bioscrubber design consisted of an absorption column that separated contaminants from the gaseous phase to the aqueous phase and a bioreactor for the biodegradation of toluene by microorganisms. Organic phases of cutting oil were added at concentrations of 5%, 7.5%, and 10%. The biodegradability test results revealed that 98% of the toluene concentration was further biodegraded after 72 hours compared to the control sample. The results showed that the use of 5% concentration of cutting oil increased the efficiency from 22% to 55%, At a concentration of 7.5%, the lowest efficiency was 38% and the highest was 63%. Also, the minimum and maximum removal capacity are 17 and 269 g/m3.h, respectively. Efficiency at a concentration level of 5% of cutting oil as an organic phase is better than a concentration of 7.5%. These findings indicate that the efficacy of the bioscrubber is better when using a 5% concentration of cutting oil as an organic phase. Moreover, this study is the first to use cutting oil as an organic phase in Iran, which showed that using cutting oil in concentrations less than 10% had no adverse effects on microorganisms' growth.</p>

Water transport across the membrane of a direct toluene electro-hydrogenation electrolyzer: Experiments and modelling

Toluene/methylcyclohexane is a promising liquid organic hydride for hydrogen storage and transport under ambient conditions. Direct toluene electro-hydrogenation electrolyzers, utilizing proton exchange membrane technology, offer benefits in reducing the reversible decomposition voltage and eliminating theoretical heat losses associated with conventional hydrogenation methods. Nevertheless, water transport across the membrane can inhibit the supply of toluene to reaction sites at the cathode. This study investigates water transport across the Nafion™ 117 membrane of an in-house electrolyzer cell, employing sulfuric acid and toluene solutions as the anode and cathode reactant, respectively, and operating at current densities from 0.1 to 0.8 A/cm2. The experiments show that the cathode toluene concentration has a negligible effect on drag water, while water flux increases with electric current and decreases with higher anode sulfuric acid concentrations. The modelling approach assumes electro-osmosis and diffusion mechanisms govern water transport. Simulations predict a linear decrease in the electro-osmotic drag coefficient from 2.3 to 1.6 as the sulfuric acid concentration rises from 0.1 to 1.5 mol/L, while the back diffusion flux increases linearly up to 2 mg/(min·cm2). These findings closely align with experimental data and previous literature, despite the high complexity of water transport in polymer electrolyte membranes.

Effect of toluene on siloxane biodegradation and microbial communities in biofilters

The removal of volatile methyl siloxanes (VMS) from landfill biogas is crucial for clean energy utilization. VMS are usually found together with aromatic compounds in landfill biogas of which toluene is the major representative. In the present study, two biofilters (BFs) packed with either woodchips and compost (WC) or perlite (PER) were used to study the (co–) removal of octamethyltrisiloxane (L3) and octamethylcyclotetrasiloxane (D4) from gas in presence and absence of toluene, used as a representative aromatic compound. The presence of low inlet toluene concentrations (315 ± 19 – 635 ± 80 mg toluene m-3) enhanced the VMS elimination capacity (EC) in both BFs by a factor of 1.8 to 12.6. The highest removal efficiencies for D4 (57.1 ± 1.1 %; EC = 0.12 ± 0.01 gD4 m-3 h-1) and L3 (52.0 ± 0.6 %; EC = 0.23 ± 0.01 gL3 m-3 h-1) were observed in the BF packed with WC. The first section of the BFs (EBRT = 9 min), where toluene was (almost) completely removed, accounted for the majority (87.7 ± 0.6 %) of the total VMS removal. Microbial analysis revealed the impact of VMS and toluene in the activated sludge, showing a clear selection for certain genera in samples influenced by VMS in the presence (X2) or absence (X1) of toluene, such as Pseudomonas (X1 = 0.91 and X2 = 12.0 %), Sphingobium (X1 = 0.09 and X2 = 4.04 %), Rhodococcus (X1 = 0.42 and X2 = 3.91 %), and Bacillus (X1 = 7.15 and X2 = 3.84 %). The significant maximum EC values obtained by the BFs (0.58 gVMS m-3 h-1) hold notable significance in a combined system framework as they could enhance the longevity of traditional physicochemical methods to remove VMS like activated carbon in diverse environmental scenarios.

Fenton-reactive groundwater circulation well for groundwater remediation of a toluene-contaminated site

ABSTRACT In order to improve the remediation efficiency of the groundwater circulation well (GCW) on toluene-contaminated soil, we used a combination of GCW and Fenton reagent for remediation. Taking a toluene-contaminated site in Suzhou City, Jiangsu Province, China, as an example, Fenton reagent with a molar ratio of H2O2/contaminant = 10:1 and H2O2/Fe2+ = 2:1 was added to GCW at an aeration rate of 0.005 m3/s. After 216 h of remediation, the toluene concentrations at the site were reduced to the remediation target values. In this study, the Fenton reagent was rapidly delivered to the influence radius of GCW, which reduced the time required for remediation and provided a new model for the application of GCW.

Experimental Study on the Removal of Toluene from Water by PTFE Hydrophobic Microporous Membrane Using Air Gap Membrane Distillation Process

Toluene is used for various purposes such as a cleansing agent, paint thinner, lacquers, printing, and leather tanning process. However, it has an adverse effect on human bodies, such as skin irritation, leukemia, respiratory issues, mutagenicity, etc, when the chemical gets mixed in drinking and rainwater by the above routes. Therefore, there is a threat to the environment and society because of the presence of toluene in water bodies through industrial effluent. Henceforth, in this study, toluene is separated from water using the air gap membrane distillation (AGMD) process. The hydrophobic microporous poly-tetra- fluoro-ethylene has been employed for this purpose. Primarily, this work focussed on the study of operating parameters such as feed solution temperature and coolant temperature on the AGMD performance namely permeate flux and toluene selectivity. It was observed that the permeate flux increased exponentially from 2.07 kg/m2h to 9.23 kg/m2h, and 0.94 kg/m2h to 3.53 kg/m2h. However, it was found that the permeate flux decreased from 9.48 kg/m2h to 8.12 kg/m2h, and 3.78 kg/m2h to 2.42 kg/m2h on increasing the coolant temperature from 5°C to 25°C at 3 mm and 11 mm air gap, respectively. The membrane selectivity was found to be less than 1, which signifies the efficient toluene-water separation. In order to study the membrane performance in the long run, the permeate flux was estimated continuously till 60 h wherein the estimated flux was found to be almost constant. The membrane morphology before and after the 60 h experimental run was analysed using capture FE-SEM micrographs. The toluene concentration was estimated using a spectrophotometer at a wavelength of 264 nm.

Kaolin-Derived Porous Silico-Aluminate Nanoparticles as Absorbents for Emergency Disposal of Toluene Leakage.

To rapidly eliminate toluene from aqueous environments during leakage accidents, this paper synthesized porous silico-aluminate nanoparticles (SANs) via a hydrothermal method, using cost-effective and non-toxic natural kaolin as the basic raw material. The morphology and structure of the porous SANs were characterized using scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and BET-specific surface area tests. The effects of different conditions, such as the dosage of porous SANs, initial concentration of toluene, temperature, capture time, and pH, on the adsorption performance of porous SANs were analyzed. The as-prepared SANs exhibited a high removal efficiency and rapid adsorption performance toward toluene in aqueous solution. Finally, the kinetics of the adsorption of toluene in aqueous solution by porous SANs were investigated. The mechanism of the adsorption of toluene by porous SANs was further discussed. These findings provide a cost-effective and highly efficient absorbent for the emergency disposal of toluene leakage accidents.

Sensing volatile organic compounds with CVD graphene: insights from quartz crystal microbalance and surface plasmon resonance studies

This study explores the sensing capabilities of chemical vapor deposition (CVD)-grown graphene in detecting volatile organic compounds (VOCs) through quartz crystal microbalance (QCM) and surface plasmon resonance (SPR) techniques. Two distinct sensing devices were developed, each tailored for QCM and SPR transducing mechanisms, utilizing CVD graphene as the sensing element. The sensors demonstrated consistent and reproducible responses when exposed to various concentrations of dichloromethane, chloroform, carbon tetrachloride, benzene, toluene, and m-xylene. Notably, both sensors exhibited unparalleled sensitivity to dichloromethane, with the graphene-coated SPR sensor displaying a sensitivity value of 294 × 10−3 ppm−1 and a limit of detection (LOD) value of 10.62 ppm. Additionally, the SPR sensor showcased remarkably swift response and recovery times, both under 3 sec. Results indicate that the adsorption of VOC molecules on the CVD graphene surface increases with the rising dipole moments and vapor pressure values of the molecules. The utilization of CVD graphene in both sensing approaches demonstrates good reproducibility in detecting ultralow concentrations of VOCs at room temperature.

In situ synthesis of porous metal-organic frameworks NH2-UiO-66 on tea stem biochar and application in odours adsorption

Multiple odour nuisance in livestock farming is a notorious problem that has a significant impact on the living environment of surrounding communities. Adsorbents based on metal-organic framework (MOF) materials show great promise for controlling odour pollution, as they offer a high specific surface area, a controllable structure and an abundance of active sites. However, the MOF formation process is prone to problems such as pore clogging or collapse and reduced porosity, which limits its further application. In this study, a series of odour adsorbents were prepared by in situ growth of NH2-UiO-66 on tea stem biochar (TSBC) using a hydrothermal method and named UiO (Zr)-TSBCx. The physical and chemical properties and composition of UiO (Zr)-TSBCx have been systematically characterized using SEM, TEM, XRD, FT-IR, N2 adsorption-desorption and XPS. The release of odours from the pig farm effluent was monitored using in-situ continuous Proton-Transfer-Reaction Mass Spectrometry (PTR-MS), and the obtained primary compositions were tested for further adsorption. In dynamic adsorption experiments focused on butyric acid, UiO (Zr)-TSBC2 showed a high adsorption capacity of 3.99 × 105 μg/g and exceptional structural stability. UiO (Zr)-TSBC2 showed variable adsorption efficiencies for different odorous gases, with the best performance for the removal of ammonia, toluene and butyric acid. It also demonstrated the ability to rapidly mitigate instantaneous high concentrations of hydrogen sulfide (H2S), methanethiol and toluene resulting from agitation. Additionally, based on the relationship between the adsorption amount and the structural characteristics of the adsorbent as well as the nature of the odours, a possible adsorption mechanism of UiO (Zr)-TSBC2 for a variety of odours released from pig farm effluent was proposed. This work demonstrates a novel approach to promote deodorization applications in livestock and poultry farming environments by the in-situ growth of NH2-UiO-66 on biochar prepared from tea stem.

Biofiltration of toluene in the presence of ethyl acetate or n-hexane: Performance and microbial community.

This study describes the operation of two independent parallel laboratory-scale biotrickling filters (BTFs) to degrade different types of binary volatile organic compound (VOC) mixtures. Comparison experiments were conducted to evaluate the effects of two typical VOCs, i.e., ethyl acetate (a hydrophilic VOC) and n-hexane (a hydrophobic VOC) on the removal performance of toluene (a moderately hydrophobic VOC) in BTFs ''A" and ''B", respectively. Experiments were carried out by stabilizing the toluene concentration at 1.64 g m-3 and varying the concentrations of gas-phase ethyl acetate (0.85-2.8 g m-3) and n-hexane (0.85-2.8 g m-3) at an empty bed residence time (EBRT) of 30 s. In the presence of ethyl acetate (850 ± 55 mg m-3), toluene exhibited the highest removal efficiency (95.4 ± 2.2%) in BTF "A". However, the removal rate of toluene varied from 48.1 ± 6.9% to 70.1 ± 6.8% when 850 ± 123 mg m-3 to 2800 ± 136 mg m-3 of n-hexane was introduced into BTF "B". The high-throughput sequencing data revealed that the genera Pseudomonas and Comamonadaceae_unclassified are the core microorganisms responsible for the degradation of toluene. The intensity of the inhibitory or synergistic effects on toluene removal was influenced by the type and concentration of the introduced VOC, as well as the number and activity of the genera Pseudomonas and Comamonadaceae_unclassified. It provides insights into the interaction between binary VOCs during biofiltration from a microscopic perspective.

Exploring the rate-control step of toluene oxidation over the novel octahedral Pt/Mn3O4 catalyst with stable low-temperature catalytic performance via in situ DRIFTS

The high efficiency and stability of catalysts are crucial for their practical application in toluene oxidation. Herein, a novel octahedral Pt/Mn3O4-110 catalyst with excellent structural stability was synthesized and 100 % toluene conversion can be achieved at low-temperature 160 °C. XRD and Raman results indicated that the structure of Pt/Mn3O4-110 can be well maintained after 120 h on-stream reaction, the resistance to H2O (3 or 5 vol%) and high concentration toluene (3000 ppm)/CO2 (5 vol%) tests. In situ DRIFTS comparative studies between Pt/Mn3O4-110 and Pt/Mn3O4-100 (30 % toluene conversion at 160 °C) samples demonstrated that the rate-control steps of toluene oxidation on Pt/Mn3O4-110 and Pt/Mn3O4-100 were both the further oxidation of benzoate species in the presence of gas-phase oxygen, while the transformation of benzaldehyde to benzoate species was the rate-control step on Pt/Mn3O4-100 in the absence of gas-phase oxygen. The weaker Mn-O bonds, richer oxygen vacancies and higher mobility of oxygen species on Pt/Mn3O4-110 sample than that of Pt/Mn3O4-100 are beneficial for the easier release of lattice oxygen from the surface of catalyst and then participated in toluene oxidation via Mars-van Krevelen mechanism, contributing to easier oxidation of benzaldehyde to benzoate species and formation of formic acid and bicarbonate species.

Enhanced adsorption of toluene on thermally activated ZIF-67: Characterization, performance, and modeling insights

The zeolitic imidazolate framework-67 (ZIF-67) has been explored for the dynamic adsorption of toluene vapor. We synthesized ZIF-67 through a straightforward room-temperature process and characterized it using XRD, FT-IR, DLS, and SEM techniques. The synthesized ZIF-67 possessed a Brunauer–Emmett–Teller (BET) surface area of 1578.7 m2/g and 0.76 μm particle size. Thermal activation under various conditions revealed that ZIF-67, activated in dry air at 250 °C, demonstrated optimal adsorption efficacy. Its adsorption capacity, time of breakthrough, and time of equilibration were 414.5 mg/g, 420 min, and 795 min, respectively. We investigated the impact of diverse operational parameters on adsorption through breakthrough curve analysis. An increase in the toluene concentration from 100 to 1000 ppm enhanced the adsorption capacity from 171 to 414 mg/g, while breakthrough time decreased from 1260 min to 462 min, respectively.Our findings show that increasing relative humidity from 0 to 70 % reduced 53.7 % in adsorption capacity and 46.3 % in breakthrough time. The competitive adsorption of toluene and ethylbenzene revealed that ZIF-67 had a higher selectivity for toluene adsorption. A 98 % adsorbent's regeneration efficiency at the first cycle reveals its reusability. The experimental data were successfully fitted to the Yan, Thomas, and Yoon-Nelson models to describe the adsorption process. The statistical validation of the model parameters confirms their reliability for estimating adsorption parameters, thus facilitating the design of fixed-bed adsorption columns for practical applications.