Brain-inspired neuromorphic sensory devices play a crucial role in addressing the limitations of von Neumann systems in contemporary computing. Currently, synaptic devices rely on memristors and thin-film transistors, requiring the establishment of a read voltage. A built-in electric field exists within the p–n junction, enabling the operation of zero-read-voltage synaptic devices. In this study, we propose an artificial synapse utilizing a ZnO diode. Typical rectification curves characterize the formation of ZnO diodes. ZnO diodes demonstrate distinct synaptic properties, including paired-pulse facilitation, paired-pulse depression, long-term potentiation, and long-term depression modulations, with a read voltage of 0 V. An artificial neural network is constructed to simulate recognition tasks using MNIST and Fashion-MNIST databases, achieving test accuracy values of 92.36% and 76.71%, respectively. This research will pave the way for advancing zero-read-voltage artificial synaptic diodes for neural network computing.