Composite Structures Research Articles

Investigation on the interface properties of Be-Al alloys via first-principles calculation

In this paper, the Be/Al pure interface is constructed using First-principles calculation. Among the six interface structures, the interface adhesion work calculation results show that the Be (001)/Al (100) interface has the largest adhesion work (2.48 J/m2), which proves that the Be (001)/Al (100) interface is the most stable interface structure. Also, the Be (001)/Al (100) composite interface structure doping elements of Ni, Ag, Co and Ge was constructed. The results of segregation heat and interface adhesion work calculation showed that the addition of Ni, Ag and Co was beneficial to the improvement of the Be (001)/Al (100) interface strength. The doping effect of Ag and Co is similar, followed by Ni, and the doping of Ge leads to the degradation of interface properties. The calculation results of the partial density of states (PDOS) and the charge density difference show that in the pure Be (001)/Al (100) interface structure, a metallic bond is formed between Be and Al atoms near the interface. With the introduction of doping elements, the charge between Be and Al atoms is redistributed. A stronger new metal bond of Be-X or Al-X (X=Ni, Ag, Co) is formed, but the doping of Ge elements forms a weaker Be-Ge metal bond, which is not conducive to the performance improvement of Be-Al alloys.

Influence of mandatory waste classification on environmental and economic impacts of residual waste treatment in Xiamen, China.

Mandatory waste classification has been widely considered as an effective solution for reducing the production and treatment amount of municipal solid waste. However, there is limited evidence regarding whether and how waste classification can affect the composition of residual waste (RW) and its environmental economic impacts. Here, an accounting method recommended by the Intergovernmental Panel on Climate Change, field surveys and cost-benefit analysis was utilized to investigate the changes in RW composition, environmental impacts and economic benefits under the waste classification policies implementation in Xiamen, China. This study found that: (1) The implementation of waste classification policies led to a significant increase in recyclable content from 17% to 51% and a decrease in organic content from 56% to 32%. (2) Waste classification effectively reduces greenhouse gas emissions from landfilling and incineration by an additional 0.34 tCO2-eq t-1 RW. (3) The introduction of mechanical recycling achieves a saving of 0.47 tCO2-eq t-1 RW at 40% recycling efficiency, a 4.5-fold increase compared to business as usual (BAU). (4) The operational benefits (900 yuan t-1 RW) from the recyclables sorting system offset the total expenses of investment, operation and waste disposal. The study successfully demonstrated that RW source-classified management can optimize the structure of waste composition, reduce environmental emissions and offer detailed guidance for the development of solid waste management systems in other cities in China.

Energetic properties of core–shell B@PVDF/AP composite micro-units prepared by electrostatic spraying technology

In this study, to improve the ignition and combustion performance of fuel boron (B) powder. The core–shell B@ polyvinylidene fluoride (PVDF)/ ammonium perchlorate (AP) composite micro-unit with the effect of erosion activation is successfully prepared by simple and controllable electrostatic spraying technology. The results of morphology and structural composition show that PVDF and AP are tightly wrapped on the surface of B, forming a uniform shell, which effectively prevents moisture absorption and oxidation of B during storage and transportation. The results of the thermal analysis show that the hydrofluoric acid (HF) gas generated by the decomposition of PVDF at about 100 °C in advance has a pre-ignition reaction (PIR) with the boron oxide (B2O3) film on the surface of B. The PIR generates boron fluoride (BF3) gas and breaks the B2O3 film. This reduces the initial oxidation temperature of B by 12.6 % and enhances the oxidation activity of B powder. In addition, the oxygen (O2) released by AP improves the combustion performance of B and strengthens the effect of erosion activation. It is also found that all samples can be successfully ignited and burned continuously, which improves the ignition and combustion performance of B powder. It is worth noting that the ignition delay time of the composite micro-unit sample with the stoichiometric ratio of B/PVDF/AP of 2: 1: 2 can be shortened to 0.454 s at most, which is 17 % lower than that of the physical mixed sample. Moreover, its combustion intensity and flame temperature also reach the best. These results show that the core–shell B@PVDF/AP composite micro-unit provides a great strategy for application in solid propellant and pyrotechnics.

Coupling interface, electronic and conjugation effects in C-COFs/TiO2 composite structure toward boosting photocatalytic hydrogen evolution

Hydrogen energy, recognized as a pivotal clean energy source, has attracted considerable attention in the realm of photocatalytic hydrogen production. Nevertheless, inorganic materials were difficult to regulate band gaps, resulting in limited photogenerated carrier rates. Additionally, organic materials frequently suffer from insufficient stability and a propensity for electron recombination. Therefore, fully utilizing the interface effect will become an important breakthrough for novel and efficient catalysts. Herein, hydroxylate covalent organic frameworks (H-COFs) were formed by direct synthesis method, in addition, titanium dioxide (TiO2) was used as an inorganic substrate, and TiO2 was transformed titanium acid under weakly acidic conditions, meanwhile, chloride covalent organic frameworks (C-COFs) growth on TiO2 surface by interface effect when H-COFs were formed into C-COFs under titanium acid. The structure characteristics, photoelectric performance, bandgap width and stability of C-COFs/TiO2 were confirmed through characterization analysis. C-COFs/TiO2 exhibit strong stability, conjugation effects, electron deficiency effects, and catalytic efficiency. Hydrogen production rate up to 5598 μmol g−1 h−1 by C-COFs/TiO2 as photocatalyst. C-COFs/TiO2 lead to 161 times improvement in photocatalytic activity for TiO2 and 3.6 times improvement in photocatalytic activity for H-COFs. The catalytic reaction mechanism was obtained by utilizing experimental data and DFT calculation. This synergistic integration of organic inorganic combined catalyst provides a foundational framework for advancing research into novel photocatalysts.

Isogeometric multilayer thin-shell analysis of failure in composite structures with hygrothermal effects

Isogeometric multilayer thin-shell analysis of failure in composite structures with hygrothermal effects

Fatigue and residual strain monitoring for thermoplastic composite using embedded FBG inscribed in highly‑birefringent side-hole elliptical core optical fiber

Monitoring of thermoplastic carbon reinforced composites is critical for the safe operation and optimization of composite structures. Strain measurement during their manufacturing and operation is often achieved with embedded Fiber Bragg Gratings (FBG). However, conventional FBGs can only measure axial strain. To measure multiaxial strain in thermoplastic composites, FBGs inscribed in highly-birefringent side-hole elliptical core optical fiber (SH2 FBG) are proposed. SH2 FBG were used to monitor composite produced by automated tape laying process, first − to measure residual in-plane and out-of-plane strain during the manufacturing stage, second − in plane transverse strain during cyclic loading. It was demonstrated that the sensors can be used to measure multiaxial residual strain, observe changes in material stiffness, and calculate the area of the mechanical hysteresis loop. As a result − it was shown that embedding SH2 FBG can be an effective and robust method for monitoring the carbon fiber reinforced thermoplastic composite.

MXene Composite Electromagnetic Shielding Materials: The Latest Research Status.

MXene emerges as a premier candidate for electromagnetic shielding owing to its unique properties as a novel two-dimensional material. Its exceptional electrical conductivity, chemical reactivity, surface tunability, and facile processing render it highly suitable for diverse electromagnetic shielding applications. The research status of MXene and MXene-based electromagnetic shielding materials is systematically discussed in this paper. First, the research status of MXene as a single-component electromagnetic shielding material is briefly introduced. Subsequently, the research status of composite structures constructed by MXene with polymers, carbon derivatives, and ferrites is introduced in detail. Furthermore, the research progress of MXene-based ternary and quaternary composite electromagnetic shielding materials is further focused. Finally, the application of MXene-based composite electromagnetic shielding materials is prospected. A deeper understanding of MXene's electromagnetic shielding properties is facilitated by this paper, providing the direction for the future development of two-dimensional materials in the design and processing of electromagnetic shielding materials.

Effect of long-term dosage of hydrazine on mainstream anammox process: Biofilm characteristics and microbial community

The impact of the long-term trace hydrazine (N2H4) exogenous supplementation on activity of the anaerobic ammonium oxidation (anammox) biofilm was investigated in a moving bed biofilm reactor (MBBR) for mainstream wastewater treatment. The results of this study demonstrated that the addition of 2–5 mg/L N2H4 enhanced anammox biofilm activity, as evidenced by the augmented nitrogen removal rate (NRR), which increased from 113.4 g/(m3·d) to 126.7 g/(m3·d) with the introduction of 2 mg/L N2H4. However, a higher concentration of N2H4 (10 mg/L) suppressed anammox activity, leading to a reduced NRR of 91.5 g/(m3·d). Bioindicators revealed that the long-term addition of 2 mg/L N2H4 fostered the accumulation of anammox bacteria (AnAOB) biomass, elevating the volatile suspended solids (VSS) content by 12%. Moreover, the structural composition of extracellular polymeric substances (EPS) within the biofilm was altered, resulting in enhanced biofilm strength within the reactor. The protective mechanism of the biofilm was activated, and EPS secretion was stimulated by the continuous N2H4 supplementation. The introduction of an excess dosage of N2H4 led to alterations in the microbial communities, ultimately resulting in a decline in the performance of the reactor. These findings collectively illustrate that N2H4, as an intermediate product, can effectively enhance anammox activity within the MBBR for mainstream wastewater treatment. This study contributes to the understanding of the optimization strategies for anammox processes in wastewater treatment systems.

Fracture modeling of curved composite shell structures using augmented finite element method

This paper presents an augmented finite element method for the fracture modeling of curved composite shell structures considering geometric nonlinear effects. We first derive the composite shell AFEM (CS-AFEM) formulation using a dynamic implicit algorithm, which enhances the numerical convergence when dealing with unstable crack propagations. Besides, the cohesive zone model featuring with shell kinematics is incorporated into the CS-AFEM to describe the quasi-brittle fracture behaviors of composite laminates. Furthermore, a coordinate transformation scheme is proposed to describe both the local material orientation and the crack evolving path in the curved shell structures. Finally, several benchmark examples are numerically investigated, and the capability of the proposed method in modeling the arbitrary evolving cracks in curved composite shell structures has been thoroughly demonstrated.

Bending responses of graphene nanoplatelets reinforced sandwich cylindrical micro panel with piezoelectric layers

Bending responses of a nanocomposite-reinforced cylindrical panel are studied in this article. A cylindrical shell panel is assumed in micro scale and sandwiched by piezoelectric layers. In this article, a micro-size dependent theory named as the modified couple stress theory (MCST) is analytically employed and the kinematic relations are extended through employing shear deformable model in order to investigate the electroelastic bending responses of a three-layered micro-shell bonded between smart layers subjected to an applied voltage, external and internal pressures. The micro-shell is assumed rested on a two parametrically elastic foundation. In order to develop constitutive relations, the mixture’s rule as well as Halpin-Tsai model are utilized to compute governing equations. Electroelastostatic responses are analytically obtained through trigonometric functions. A large extended parametric analysis is presented to explore deflection of the micro-shell with a change in applied voltage, thickness of the piezoelectric layer to radius, length to radius ratio, different characteristics of nanoplatelet reinforcement for the both external and internal pressure. The proposed composite electromechanical structure may be used in the smart structures and systems. A controllable system can be suggested through the usage of graphene nanoplatelets because of flexibility and affecting parameters.

Effects of perlite content and jute fiber reinforcement on flexural behavior of the gypsum/perlite composite core-based sandwich structures

Gypsum wallboards are widely used as a building material, but limitations exist in their weight and brittleness. The incorporation of various fillers in the gypsum makes them lightweight, stiff, and capable of resisting catastrophic failure but with the cost of strength. Sandwiching the filled gypsum using a low-cost material as skin may be an innovative approach to improve the flexural properties. In this work, sandwich structures were fabricated using jute fiber reinforced and unreinforced perlite-filled gypsum as cores and low-cost brown paper as skins. The density, flexural strength, modulus, and toughness of the resulting sandwich structures were investigated. It is found that the increase in perlite content in pure gypsum and jute fiber-reinforced gypsum significantly enhances the flexural strength, modulus, and toughness of the sandwich structures. However, previous research on jute fiber-reinforced and unreinforced gypsum/perlite composite panels (without skin) showed a decrease in flexural strength due to an increase in perlite content. The maximum flexural strengths of unreinforced sandwich (URS) and jute fiber reinforced sandwiches (JRS) at a perlite content of 15 g are found to be 13.29 % and 40.79 % greater than the control sandwich with pure gypsum core. The maximum flexural toughness of the JRS at a perlite content of 20 g and that of the URS at a perlite content of 15 g are respectively 118.31 % and 79.14 % greater than the control sandwich. A significant difference in load-displacement curves between JRSs and URSs is noticed despite the similar failure sequence i.e. core cracking→skin yielding→skin tearing.

Tailoring the structural, optical, hydrophobicity and electrical properties of ZnO thin films by copper doping for self-clean optoelectronic application

Optoelectronic devices such as solar panels, cameras, screens, and sensors frequently suffer reduced performance due to dust accumulation. Incorporating self-cleaning features not only sustains their efficiency but also minimizes maintenance expenses, especially for large or challenging-to-access setups. In this study, copper doped-zinc oxide (CZO) thin films with varying copper (Cu) concentrations were created using the reactive co-sputtering process. These films underwent a comprehensive analysis, including X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy to examine their structure, morphology, and elemental composition. Optical properties were investigated through UV–Vis spectroscopy, while hydrophobicity and electrical characteristics were assessed with contact angle and I–V measurements. Spectroscopic ellipsometry was employed to analyse surface attributes. The results confirmed that as Cu concentrations increased, the crystallite and grain size of ZnO in the films also increased. A red shift in the band gap was observed in UV–Vis spectroscopy, and Cu doping effectively reduced the electrical resistivity of the ZnO thin film. The CZO thin film, with a 60 nm thickness, low roughness (1.49 nm), high optical transmittance (around 80.20 %), a wide band gap (3.22 eV), a substantial contact angle (113°), and low electrical resistivity (5.9 × 105 Ω cm), holds great promise for use in transparent, conductive, and self-cleaning optoelectronic devices.

Controllable morphology, excellent stability and non-equivalent doping-induced optical properties of Mn4+-activated K2NaScF6 red phosphor for high-quality warm WLED

Currently, Mn4+ activated fluoride red phosphor has been widely studied to improve the optical performance of white light-emitting diode (WLED) in the field of high-efficiency lighting and wide color gamut backlight display. In this paper, a series of red-emitting K2NaScF6:Mn4+ phosphors are synthesized by a simple co-precipitation method with a non-equivalent substitution of Mn4+ for Sc3+ at room temperature. The crystal structure, morphology and elemental composition of K2NaScF6:Mn4+ phosphors prepared using different reaction conditions are systematically investigated. Interestingly, the K2NaScF6:Mn4+ phosphors exhibit narrowband red emission with low correlated color temperature (CCT), high color purity and short fluorescence lifetime. Compared to equivalent doping, the mechanism of short fluorescence lifetime caused by non-equivalent doping has also been systematically discussed. The optimal doping concentration is determined by setting a series of Mn4+ doping concentrations and the concentration quenching mechanism is analyzed. The crystal field strength (Dq), Racah parameters (B and C) and nephelauxetic ratio (β1) are calculated in detail to evaluate the crystal field environment of Mn4+ in K2NaScF6. The good water resistance of the as-prepared sample K2NaScF6:Mn4+ is verified by comparing with the commercially available phosphor K2SiF6:Mn4+. Moreover, the thermal stability is also analyzed by calculating the activation energy (Ea), chromaticity shift (ΔE) and chromaticity coordinate variation (CCV). Importantly, the as-packaged warm WLED (InGaN chip + YAG:Ce3+ + K2NaScF6:Mn4+) has excellent optical properties (CCT = 4082 K, color rendering index (CRI, Ra = 91.2) and luminous efficiency (LE) = 78.86 lm/W), and it exhibits good output stability at high drive currents. In summary, our work demonstrates that K2NaScF6:Mn4+ red phosphors possess a great potential application in warm WLED for the indoor lighting.

Zoophilic flies (Diptera) of South Iran–the dominance structure and species composition

ABSTRACT Zoophilic flies play an important role in dairy farms by transmitting diseases to livestock. These flies can cause significant damage to animal husbandry through physical disturbance and the spread of pathogens. This study aims to identify insect species in both traditional and industrial animal husbandry settings, focusing on the dominant species of zoophilic flies. The research involved collecting livestock insects from March to October, between 2017 and 2021, using insect nets, sticky nets, and light traps. A total of 10,942 flies were collected from livestock farms in three counties Marvdasht, Shiraz, and Zarghan. The collected flies belong to 21 species from 6 families. Musca domestica, Fannia canicularis, Musca autumnalis, Stomoxys calcitrans, Muscina stabulans, Calliphora vomitoria, and Lucilia cuprina were identified as the dominant species. Musca domestica, F. canicularis and M. autumnalis accounted for 70.24% of the total number of flies on livestock farms. Among the collected samples, Eristalis tenax (Syrphidae) was found with a frequency of 0.96%. The importance of this species is related to the presence of its larvae that cause myiasis in livestock. Identification of the dominant species of flies put the scientific basis to reduce their populations in dairy farms and the costs caused by the damage made by these pests to livestock farms through safe ways, such as biological control.

Investigating low velocity impact and compression after impact behaviors of carbon fiber/epoxy composites reinforced with helical multiwalled carbon nanotubes

Pre-damage and undetected micro-defects in fiber-reinforced polymer (FRP) composites are significant challenges compromising the integrity and mechanical performance of composite structures in aerospace applications. To address this challenge, this experimental study investigated the low velocity impact (LVI) and compression after impact (CAI) behaviors of carbon fiber/epoxy (CF/E) reinforced with 0.0 (control sample), 0.2, and 0.4 wt% helical multiwalled carbon nanotubes (HMWCNTs). The LVI test results showed that the control samples, with epoxy as the predominant phase, registered the lowest peak force compared to the 0.2 wt and 0.4 wt% HMWCNT/epoxy composite laminates. The CAI test results showed a decrease in strength with increased impact energy and an increase in the weight percent of HMWCNTs. Consequently, the 0.4 wt% HMWCNT ladened composites could withstand higher load without undergoing significant deformations, exhibiting the highest impact resistances due to the presence of CNTs, which function as load-bearing material. The HMWCNT interleaved CF/E composite laminate samples subjected to 25 J of impact energy achieved a higher maximum force of 9870.25 N compared to 8527.26 N for the damaged samples at the same level of impact energies. This fact indicates that the damaged samples could not withstand sufficiently high impact forces due to local instability arising from existing damages. The results strongly suggest a high potential for HMWCNTs CF/epoxy laminate composites in making structural and substructural components in aircraft and automobiles due to their proven superior properties.

Acoustic emission monitoring for damage diagnosis in composite laminates based on deep learning with attention mechanism

During service, advanced composite materials are susceptible to various forms of damage. Developing an efficient real-time Structural Health Monitoring (SHM) method is of profound significance to ensure the normal operational integrity of the advanced composite structures. This study introduces a novel end-to-end SHM approach employing acoustic emission (AE) techniques and a deep learning model with attention mechanisms (AM) to automate the damage diagnosis process and improve prediction accuracy. Low-velocity impact (LVI) experiments were carried out, recording AE signals for subsequent bi-spectrum analysis. Three dedicated AM-based Convolutional Neural Network (CNN) architectures were designed for damage diagnosis, utilizing 2D bi-spectrum contour images as input data. A comparison was made between the proposed CNN model, deep learning and traditional machine learning models in the context of damage diagnostics, revealing that CNN models combined AM exhibit significantly higher accuracy in pattern recognition tasks. The accuracies of the baseline CNN, self-attention-CNN, multi-head attention-CNN and convolutional block attention module-CNN are 98.22%, 98.50%, 98.85%, and 98.87%, respectively. The CNN embedded with AM demonstrated superior predictive performance and fewer instances of misclassification. Considering the specific demands of damage diagnostics in composite materials, the CBAM-CNN is better suited for composite material health monitoring tasks.

Photocatalytic degradation of indigo carmine dye by hydrothermally synthesized graphene nanodots (GNDs): investigation of kinetics and thermodynamics.

Graphene nano dots (GNDs) are an intriguing emerging class of materials at the nano scale with distinctive characteristics and exciting potential applications. Graphene oxide was synthesized in a lab setting using a modified version of Hummers' approach and used as a precursor for synthesis of graphene nano dots. Graphene oxide is then treated through hydrothermal treatment to produce GNDs with exact control over their size and form. Synthesized graphene nano dots were subjected to various instruments to study morphology, crystallinity, size and other properties. UV-visible spectroscopy was used to detect the maximum absorbance of light. For functional group identification, FTIR analysis was conducted. X-ray diffraction analysis explained structural composition and various other parameters i.e., crystal size and diameter, which was further verified by Vesta software. Surface morphology of GNDs was analyzed by scanning electron microscopy. AFM analysis of GNDs demonstrates the topography of the surface. The photo degradation of the indigo carmine dye by the GNDs also demonstrates their superiority as UV-visible light driven photo catalysts. To evaluate the results, the thermodynamics and kinetics of the degradation reactions are examined. The effects of several factors, such as temperature, initial concentration, time, pH and catalyst concentration, are also investigated. The data will be analyzed statistically by regression and correlation analysis using dependent and independent variables, regression coefficient and other statistical techniques.

A novel electrochemical sensor for detection of luteolin in food based on 3D networked electrically interconnected SiO2@GO/MXene composite.

Luteolin (Lu), a compound with various biochemical and pharmacological activities beneficial to human health, has attracted researchers' attention. This study proposes an efficient and scalable method using ultrasound to intercalate graphene oxide (GO)-coated silica spheres (SiO2) into MXenes, resulting in a 3D conductive interconnected structural composite material. Characterization of the composite material was conducted using SEM, TEM, XRD, XPS, and Raman spectroscopy. MXenes exhibit excellent electrical conductivity, and the SiO2@GO surface with abundant hydroxyl and silanol groups provides high-binding active sites that facilitate Lu molecule enrichment. The formation of the 3D conductive interconnected structural composites enhances charge transport, significantly improving sensor sensitivity. Consequently, the sensor demonstrates excellent detection capabilities (detection range 0.03-7000nM, detection limit 12pM). Furthermore, the sensor can be applied toquantitative determinationof Lu in real samples, including chrysanthemums, Jiaduobao, honeysuckle, purple perilla, and peanut shells, achieving recoveries between 98.2 and 104.7%.

Specialized structure and function of the apical extracellular matrix at sense organs

Apical extracellular matrix (aECM), which covers every surface of the body, exhibits tissue-specific structures that carry out specialized functions. This is particularly striking at sense organs, where aECM forms the interface between sensory neurons and the environment, and thus plays critical roles in how sensory stimuli are received. Here, we review the extraordinary adaptations of aECM across sense organs and discuss how differences in protein composition and matrix structure assist in sensing mechanical forces (tactile hairs, campaniform sensilla, and the tectorial membrane of the cochlea); tastes and smells (uniporous gustatory sensilla and multiporous olfactory sensilla in insects, and salivary and olfactory mucus in vertebrates); and light (cuticle-derived lenses in arthropods and mollusks). We summarize the power of using C. elegans, in which defined sense organs associate with distinct aECM, as a model for understanding the tissue-specific structural and functional specializations of aECM. Finally, we synthesize results from recent studies in C. elegans and Drosophila into a conceptual framework for aECM patterning, including mechanisms that involve transient cellular or matrix scaffolds, mechanical pulling or pushing forces, and localized secretion or endocytosis.

Sorption kinetics of salt-in-porous-matrix composites: The effect of expanded natural graphite on cooling power

Sorption heat transformers and thermal energy storage systems are emerging technologies that utilize and store low-grade waste heat for heating and cooling applications. The performance of sorption systems is not only affected by systems’ operating conditions, and overall systems’ design but also by sorption material or composite parameters such as thermal diffusivity, composition, and pore structure, among others. In this study, CaCl2-based salt-in-porous-matrix composites of different compositions and coating thicknesses were synthesized. During synthesis, salt to silica gel and polyvinyl alcohol to silica gel ratios were fixed and the thermal additive (expanded natural graphite) to silica gel ratio was varied with care from 0 to 0.26 (or 0 to 20.5 wt.%, additive to silica gel ratio). The thickness of samples varied from 2.3 to 8.3 ± 0.1 mm. The composites were characterized by a transient plane source (thermal conductivity and thermal diffusivity), nitrogen adsorption porosimetry (specific surface area and total pore volume), and thermogravimetric sorption analysis (water sorption equilibrium) methods. A custom-built gravimetric large pressure jump (G-LPJ) testbed was used to study water sorption kinetics (water uptake vs. time) for selected samples. The thermal conductivity and diffusivity of the studied composite samples have shown significant enhancements, e.g., 240% (0.11 W/(m·K) vs. 0.37 W/(m·K)) and 310% (0.21 mm2/s vs. 0.87 mm2/s), respectively, by adding 12.5 wt.% expanded natural graphite (additive to silica gel ratio is 0.14) as a thermally conductive additive (additive to silica gel ratio) because of thermal percolation effect. This ratio of expanded natural graphite to silica gel was found to be optimal for studied composition. The results indicate that sorption composites with higher thermal diffusivity offer notably higher specific cooling power and improved sorption kinetics, compared to the composites without expanded natural graphite of the same thickness (850 W/kg vs. 480 W/kg at 70% water conversion for samples with thickness of 5.3 mm).