Composition Of Oil Research Articles

Essential oil composition of passiflora foetida L. (passifloraceae) flowers and chemical-biology study of the leaves extracts and isolated compound

Passiflora foetida is a climbing herb employed in ethno-medicine for the treatment of various ailments. The essential oil from flowers of P. foetida was obtained by hydrodistillation. The ethanol extract of the leaves was dissolved in water, then partitioned with n-hexane and n-butanol to obtain the various fractions; the fractions and isolated compound were subjected to in vitro antioxidant activity. Gas chromatography-mass spectrometry afforded the identification of forty-two constituents in the floral oil, dominated by β-caryophyllene (17.2%), cedrol (11.5%), and α-humulene (11.5%). The n-butanol fraction was the most active (70% inhibition and absorbance 0.401; 100 µg/mL) in the 2,2-diphenyl-1-picrylhydrazyl radicals and ferric reducing power assays, respectively. Chromatographic analysis facilitated the isolation of 8-C-β-d-glucosylapigenin (vitexin) from the butanol fraction of P. foetida. Vitexin demonstrated good antioxidant activities (75% inhibition and absorbance 0.424; 100 µg/mL) compared with ascorbic acid. The volatile metabolites of P. foetida flowers are reported for the first time.

Green Packaging: Carrageenan with Clove Oil Nanoencapsulation

The global urgency surrounding plastic waste-induced pollution has ignited significant interest in the biodegradable packaging sector, leading to a dynamic and expanding realm of biodegradable research. Nonetheless, effectively incorporating active agents into packaging materials faces hurdles related to stability and durability. This study takes a momentous leap in this context by shedding light on the transformative potential of integrating clove oil in macro and nanoencapsulation forms into carrageenan-glycerol matrices. A highlight emerges in the remarkable enhancement achieved through nanoencapsulation—a technique that substantially bolsters packaging performance. This improvement is evident in a noteworthy reduction of water vapor transmission, plummeting from an initial 11.011 to merely 6.903 g.mm m-2 d-1. This nearly fifty percent reduction underscores the efficacy of nanoencapsulation in enhancing packaging attributes. Concurrently, the study delves into the nuances of the carrageenan-clove oil composition, unveiling its profound influence on packaging strength, by systematically increasing the carrageenan-clove oil ratio, packaging strength triples, soaring from an initial 0.421 to an impressive 1.434 N/mm. Concerns of heightened brittleness due to increased carrageenan content are firmly dispelled, substantiated by consistent tensile stress values. In summary, this comprehensive investigation advances the core attributes of biodegradable packaging and presents a strategic and adept approach to address the intricate sustainability issues. Through adept manipulation of clove oil integration, the study pioneers the evolution of biodegradable packaging materials, paving the way for a more sustainable and environmentally conscious future.

Low-Salinity Waterflooding for EOR in Field A of Western Offshore Basin: A Pilot Study Analysis with Laboratory and Simulation Studies—Early Observations

Carbonate reservoirs hold vast oil reserves, but their complex properties make traditional enhanced oil recovery (EOR) methods challenging. This study explores the application of low-salinity water flooding (LSWF) as a novel EOR method for India’s largest offshore carbonate oil field. Conventional EOR techniques were deemed unsuitable due to reservoir heterogeneity, pressure decline, high temperature, and the offshore location. Favorable factors for LSWF included successful seawater flooding history, medium-weight crude oil, and existing infrastructure. Following core flooding experiments demonstrating a 6–16% increase in oil recovery, a multi-pronged evaluation process was implemented. Single-well chemical tracer tests (SWCTT) and reservoir simulations confirmed the potential of LSWF. A specific target area was chosen based on reservoir characteristics, production data, and available facilities. Simulations predicted a 1.5% incremental oil recovery using diluted seawater (25% salinity) at 30% pore volume injection. After a positive techno-economic analysis, the first offshore LSWF project in India was completed within 3 years. Initial monitoring results are encouraging. This study highlights the successful journey of LSWF from concept to field deployment in a challenging carbonate reservoir, showcasing its potential for revitalizing such fields. Furthermore, this work provides valuable data relevant to Indian offshore environments, where factors like salinity, mineralogy, and crude oil composition pose unique challenges compared to other LSWF applications. These detailed data fill a critical gap in the existing literature.

Fatty acid and essential oil compositions of seeds of coriander (Coriandrum sativum L.) Cultivated in different regions of Ethiopia

Coriander (Coriandrum sativum L.) seeds are used as spices. In this study, fatty acids extracted from the coriander seeds collected from three places (Sululta, Jimma and Wolaita Sodo) in Ethiopia were determined as their methyl ester using GC-MS. The fatty acid components were assessed using linoleic acid ethyl ester as an external standard. Sululta sample showed five fatty acids, while Wolaita Sodo and Jimma three each with highest amount of petroselinic acid: 68.41%, 72.53%, and 64.4%, respectively, of the total fatty acids. Linoleic acid (omega-6) was found in the range of 18.24-22.37%. The polyunsaturated versus saturated (P/S) index values were found to be 1.69-2.39, which indicated that coriander seeds from the three sites have a good capacity to prevent the development of cardiovascular and some chronic diseases. The number of compounds identified in the essential oils of coriander seeds from Jimma, Sululta, and Wolaita Sodo were 7, 9, and 15 with total percent areas of 99.64, 75.14, and 96.68, respectively. The major component in the essential oils was linalool ranging from 36.72-88.50% of the total amount. In general, the chemical constituents of fatty acids and essential oils of coriander seeds indicates its good nutritional quality and usefulness for human health. KEY WORDS: Coriander seeds, Fatty acids, P/S index, Essential oils, Nutritional quality, Spice Bull. Chem. Soc. Ethiop. 2024, 38(4), 863-876. DOI: https://dx.doi.org/10.4314/bcse.v38i4.4

Image-Based Phenotyping Study of Wheat Growth and Grain Yield Dependence on Environmental Conditions and Nitrogen Usage in a Multi-Year Field Trial

As the global population and resource scarcity simultaneously increase, the pressure on plant breeders and growers to maximise the effectiveness of their operations is immense. In this article, we explore the usefulness of image-based data collection and analysis of field experiments consisting of multiple field sites, plant varieties, and treatments. The goal of this approach is to determine whether the noninvasive acquisition and analysis of image data can be used to find relationships between the canopy traits of field experiments and environmental factors. Our results are based on data from three field trials in 2016, 2017, and 2018 in South Australia. Image data were supplemented by environmental data such as rainfall, temperature, and soil composition in order to explain differences in growth and the development of plants across field trials. We have shown that the combination of high-throughput image-based data and independently recorded environmental data can reveal valuable connections between the variables influencing wheat crop growth; meanwhile, further studies involving more field trials under different conditions are required to test hypotheses and draw statistically significant conclusions. This work highlights some of the more responsive traits and their dependencies.

Impacts of Sustainable Land Management Intervention on the Soil Condition and Landscape Greenness: Evidence from Jimma Arjo District, Southwestern Ethiopia

Soil degradation has been a major environmental and agricultural challenge in Ethiopia in general and in the study area in particular. Recently, several governmental and nongovernmental organizations have made efforts to reduce the problem and improve the productivity of land through sustainable land management (SLM) practices. The main objective of this study was to investigate the impact of sustainable land management practices on soil condition and landscape greenness in the Jimma Arjo District, Southwestern Ethiopia. The impact of SLM practices on soil condition was examined by collecting twenty-eight (28) composite and core (28) soil samples from treated (14) and nontreated (14) lands. Landsat satellite images of 2012 and 2022 were used to detect changes in landscape greenness using the Normalized Difference Vegetation Index (NDVI). ArcGIS® 10.3, ERDAS® 2014, and Microsoft Excel software packages were used for analysis. The significance test was performed using a one-way ANOVA. The result showed a significant difference in soil physiochemical properties (soil texture, soil pH, soil organic carbon, soil organic matter, total nitrogen, and available phosphorous and calcium) between treated and nontreated lands (P<0.01). However, the landscape greenness result shows that the lowest NDVI value in the SLM-treated kebele during 2012 was −0.15 but increased to 0.09 in 2022. Similarly, the highest value was found to be 0.41 in 2012 and the value rose to 0.53 in 2022. It is concluded that sustainable land management practices implemented in the area have resulted in an important positive effect on improving the soil condition and landscape greenness. Hence, strengthening and scaling up SLM practices and continuous maintenance are advisable for better results in land productivity and livelihood improvement.

Potentially Harmful Elements (As, Sb, Cd, Pb) in Soil Polluted by Historical Smelting Operation in the Upper Silesian Area (Southern Poland)

This study aimed at determining the concentration and possibility of migration of potentially harmful elements (PHEs) in soils and mining and metallurgical waste in the Silesian-Cracow region. Our research was carried out in selected locations of Ruda Śląska, Świętochłowice, Bytom, and in the Olkusz region (Bukowno) in southern Poland. The concentrations of metals (e.g., Ag, Ba, Ca, Cd, Cu, Fe, Mg, Mn, Pb, Sr, Zn), metalloids (As, Sb), and sulphur were determined in 33 soil samples (with a depth range of 0.0–0.3 m) and 12 slag samples. These studies show an increased concentration of metals, metalloids, and sulphur, exceeding the level of regional geochemical background. The research results indicate that the degree of the chemical transformation of soils in the analysed regions of Ruda Śląska, Bytom, and Bukowno is advanced. This highlights the high concentrations of most metals, i.e., arsenic, antimony, and sulphur, in the surface layer of soils (topsoil) due to historic Zn-Pb ore mining and Zn and Fe metallurgy. The presence of both primary and secondary metal sulphides, sulphates, carbonates, oxides/hydroxides, silicates, and aluminosilicates was found in the mineral composition of soils and slags.

Chemical composition, antioxidant, antimicrobial and antibiofilm activities of essential oil from the Moroccan endemic Plant, Calendula maroccana (Ball) B. D. Jacks.

Chemical composition, antioxidant, antimicrobial and antibiofilm activities of essential oil from the Moroccan endemic Plant, <i>Calendula maroccana</i> (Ball) B. D. Jacks.

A Study of Lunar Regolith Obtained during the Apollo and Luna Space Programs Based on Principal Component Analysis

In this study, a modern principal component analysis (PCA) of the chemical properties of lunar soils was conducted. American and Soviet results acquired during the Apollo and Luna missions, respectively, were analyzed and compared. The chemical composition of the lunar soil was the focus of our analysis, the main aim of which was to assess any possible differences between the results provided by the missions in question. The results were visualized in two- and three-dimensional spaces. The use of PCA virtual variables enabled the chemical composition of the lunar soil to be fully visualized—something impossible to achieve using traditional techniques—and key similarities and differences among the properties of the lunar soil samples were determined. The sources of any differences were then conceptualized. The work reported in this paper offers new directions for future studies, especially research into the design of new lunar soil simulants for lunar construction and civil engineering programs.

Seasonal bee communities vary in their responses to resources at local and landscape scales: implication for land managers

ContextThere is great interest in land management practices for pollinators; however, a quantitative comparison of landscape and local effects on bee communities is necessary to determine if adding small habitat patches can increase bee abundance or species richness. The value of increasing floral abundance at a site is undoubtedly influenced by the phenology and magnitude of floral resources in the landscape, but due to the complexity of measuring landscape-scale resources, these factors have been understudied.ObjectivesTo address this knowledge gap, we quantified the relative importance of local versus landscape scale resources for bee communities, identified the most important metrics of local and landscape quality, and evaluated how these relationships vary with season.MethodsWe studied season-specific relationships between local and landscape quality and wild-bee communities at 33 sites in the Finger Lakes region of New York, USA. We paired site surveys of wild bees, plants, and soil characteristics with a multi-dimensional assessment of landscape composition, configuration, insecticide toxic load, and a spatio-temporal evaluation of floral resources at local and landscape scales.ResultsWe found that the most relevant spatial scale and landscape factor varied by season. Early-season bee communities responded primarily to landscape resources, including the presence of flowering trees and wetland habitats. In contrast, mid to late-season bee communities were more influenced by local conditions, though bee diversity was negatively impacted when sites were embedded in highly agricultural landscapes. Soil composition had complex impacts on bee communities, and likely reflects effects on plant community flowering.ConclusionsEarly-season bees can be supported by adding flowering trees and wetlands, while mid to late-season bees can be supported by local addition of summer and fall flowering plants. Sites embedded in landscapes with a greater proportion of natural areas will host a greater bee species diversity.

Chemical composition and biological activities of essential oils and extract of Eucalyptus citriodora Hook

In this study, the leaves of Eucalyptus citriodora Hook (Lemon-Scented Eucalyptus) were harvested and collected from Üzümlü neighborhood of Fethiye district of Muğla in 2021. Chemical content analysis of steam distillation and hydrodistillation of essential oils were determined by GC-MS, while phenolic content of methanol extract was determined by HPLC-DAD. Antioxidant activities of essential oils and methanol extracts were determined by DPPH radical removal, ABTS cation removal, β-carotene linoleic acid, and CUPRAC activity methods; Anticholinesterase activity against AChE and BChE enzymes was determined by Ellman method; and tyrosinase inhibition associated with melanin hyperpigmentation, α-amylase inhibition, and α-glucosidase inhibition activities associated with diabetes were determined as an in vitro. The bioactivities and chemical contents of E. citriodora species, a great value of, Türkiye, were determined, bringing new natural products to organic chemistry. As a result of the study, new bioactive extracts would be obtained and thus, they can effectively reveal the potential of new business opportunities. Since methanol extract is effective against incurable diseases such as Alzheimer's and diabetes, it will also be possible to develop therapeutics of such diseases by investigating the advanced chemistry and in vivo activities of the extracts with new projects.

ПРОТИВОКОРРОЗИОННАЯ ЗАЩИТА МЕДИ МАСЛЯНЫМИ КОМПОЗИЦИЯМИ С КОМБИНИРОВАННОЙ ДОБАВКОЙ М-531

The use of anti-corrosion protection is necessary to maintain the performance of agricultural machinery and equipment. The effectiveness of oil compositions with the addition of M-531 in relation to copper was studied. The compositions were obtained on the basis of industrial and motor M10G2k (both fresh and used) oils. Their protective ability was studied using gravimetric and electrochemical methods (polarization and impedance) studies. According to the data obtained from corrosion gravimetric tests in 0.5 M NaCl, it was noted that compositions based on M10G2k oil turned out to be the most effective when 5 wt. % of the additive, the protective effectiveness (Z) was 63%, a further increase in concentration led to a slight increase to Z = 65% at 10 wt. % M-531. The data from electrochemical measurements qualitatively confirm the data from gravimetric tests. Differences in the magnitude of protective effectiveness are associated primarily with different times of exposure to an aggressive environment: the duration of the experiment in the first case was 15 minutes, in the second - 14 days. According to the results of polarization measurements, compositions based on MMO were the most effective, already at a content of 5 wt. % additive value Z = 98%, while compositions containing 5 wt. % M-531 in I20-A and M10G2k had Z = 90%. The results of impedance studies showed that the addition of the M-531 inhibitor to MMO, M10G2K and I20-A oils affects the copper impedance hodographs. The inhibitor concentration had a significant effect on the change in Nyquist diagrams. At 3 wt. % M-531, a moderate change in copper plating impedance was observed, indicating that the inhibitor has some protective ability against corrosion, but its effectiveness may not be sufficient to fully protect copper. When the inhibitor concentration increases to 5 - 7 wt. % noticeable increase in the change in impedance indicated that a higher concentration of the M-531 inhibitor helps to improve the protective properties of the copper coating.

Harmonizing Agriculture: Nurturing Soil through Micronutrients Management and Texture Dynamics

The present review delves into the essential aspect of micronutrient management and soil texture dynamics in agriculture thus emphasizing their pivotal roles in sustaining soil health and optimizing crop productivity. Micronutrients, though required in trace amounts are critical for various physiological and biochemical processes in plants. Micronutrient deficiencies can profoundly impact plant growth and yield, necessitating effective management strategies such as soil amendments, foliar applications, and balanced fertilization practices. Additionally, the paper explores the potential of soil microbes to enhance micronutrient availability. Soil testing emerges as a crucial tool for monitoring nutrient levels and guiding nutrient application decisions. Furthermore, soil texture dynamics significantly influence nutrient availability, highlighting the importance of soil composition and structure. Conservation tillage practices, crop rotation, and the use of micronutrient fertilizers are discussed as means to promote soil health and optimize nutrient profiles. Overall, the paper underscores the importance of integrating micronutrient management and texture dynamics for harmonizing agriculture, ensuring sustainable soil health, and fostering increased crop yields.

Dynamics of Soil Physical and Chemical Properties under Different Current Land Use Types and Elevation Gradients in the Sala Watershed of Ari Zone, South Ethiopia

The dynamics of soil physical and chemical properties have been increasing due to inappropriate land use and unsustainable land management practices in Ethiopia. This study aims to assess the dynamics of selected soil physical and chemical properties under different current land use types and altitudinal gradients in the Sala watershed of Ari Zone in South Ethiopia. In the study area, analyzing and understanding the dynamics of soil physicochemical properties under different land use types play a vital role in sustainable soil productivity. Before collecting a soil sample, land use types and altitudinal variations were surveyed in the study watershed. Three random strata were selected from the watershed, and the major adjacent land use types in each stratum were identified across elevation gradients. A total of 30 composite soil samples were collected from different land uses and elevations using a zigzag sampling technique at 0–20 cm soil depth from upland (12), midland (9), and lowland (9). Laboratory results showed that most soil physical and chemical properties had poor ratings in the watershed area. All soil properties were significantly affected by land use types and elevation factors (P&lt;0.05), except for soil texture, TN, and CEC. Soil texture is highest in the upper and lower elevations of grazing land (61.3%) and shrubland (55.4%), while lowest in cultivated land (11.3%) and barren land (11.6%) at higher altitudes. The highest mean of soil texture was dominated by clay soil (55%) in shrubland followed by sand soil (50.30%) in the barren land and silt soil (20.06%) in cultivated land. Chemical soil properties (pH, SOM, TN, Av. P, Av. K, and CEC) were significantly varied under each land use type across altitudes. The results of this study showed that inappropriate land use and unsustainable agricultural practices had more significantly influenced the soil fertility status. Therefore, appropriate soil and water conservation measures should be implemented in the studied watershed to improve soil fertility and crop productivity.

The migration process and temperature effect of aqueous solutions contaminated by heavy metal ions in unsaturated silty soils

Adsorption-desorption experiments of three heavy metal ions (i.e., lead, copper, cadmium) in silty soil were carried out at different temperatures, and the microscopic characteristics of silty soil loaded with the three heavy metal ions were analyzed. A one-dimensional soil column was used to discuss the influences of heavy metal ion types and concentrations on the soil moisture distribution and the migration level of different heavy metal ions, especially during the dynamic change process from an unsaturated state to a saturated state. Studies show that the adsorption of heavy metal ions onto silty soil is closely related to the mineral composition and functional groups in silty soil. In addition to physical adsorption, the adsorption of heavy metal ions is closely related to the hydrolysis reaction of mineral components such as kaolinite, calcite, dolomite, plagioclase and quartz. Under constant temperature, the types and concentrations of heavy metal ions play an important role in the moisture migration of unsaturated soil. In the presence of heavy metal ions, the penetration of lead ions is the greatest, followed by copper ions and then cadmium ions. The greater the ion concentration is, the stronger the penetration of heavy metal ions in silty soils.

Life on gypsum: the vegetation of gypsum ecosystems in Cyprus

Gypsum ecosystems occur in arid and semi-arid areas, where evaporation is intense and annual precipitation is low and insufficient to leach the gypsum. They host sparse and scattered vegetation, composed of species specialized in this soil type. In Cyprus, gypsophilous vegetation is part of the priority habitat *1520 Iberian gypsum steppes (Gypsophiletalia) characterized by Campanula fastigiata, Gypsophila linearifolia, and Teucrium salaminium. Despite the ecological importance of gypsophilous vegetation, its distribution and ecology in Cyprus is still understudied. This study aimed to provide the first comprehensive account of the gypsum communities, focusing on the distribution of gypsophytes in relation to the substrate and the floristic composition of gypsum soils. Floristic inventory was carried out in 27 sites with gypsum soil. Biophysical information and data about human impact were also recorded. A total of 97 taxa were identified, including three gyspophile species, two gypsoclines, 20 gypsovags, and 72 waifs. A new endemic Rostraria hadjikyriakou was recorded in five locations. The known geographical distribution of gypsophilous vegetation has been updated. For 35% of the sites, gypsophilous vegetation was recorded for the first time while none of the characteristic gypsophilous species was found in the western part of the island.

Soil mycobiome and forest endophytic fungi: Is there a relationship between them?

Fungi are important ecological agents in forests that contribute to increase the resilience of the whole ecosystem against environmental challenges. Mediterranean forests rank among the habitats most threatened by climate change and the spread of pests and diseases, which ultimately lead them into a spiral of decline. As such, changes in the composition of soil and trees’ mycobiota might correlate with health status of the forest and has been scarcely addressed in Mediterranean tree species. In this work, rhizosphere and bark-wood samples from declining Spanish forests of Castanea sativa Mill. (chestnut), Quercus ilex L. (holm oak), Q. suber L. (cork oak) and Q. pyrenaica Willd. (Pyrenean oak) were compared. Fungal communities were characterised by means of ITS metabarcoding. Higher diversity in terms of richness was found in soil, with 674 genera belonging to 15 phyla in soil vs 420 genera and 6 phyla in trees. Fungal genera exclusive to declining forests’ soils and trees didn’t include pathogenic organisms, thus preventing the association of certain genera with forest decline. Alpha diversity didn’t correlate with health status or sample type either, as it only increased in soils of asymptomatic chestnuts and not in any of the other analysed tree species. Some differentially abundant genera found in asymptomatic trees, such as Metarhizium, Aspergillus, Russula, Chaetomium, Mortierella or Cladophialophora, may be related to the biological control of decline-contributing pathogens. Finally, no relationship was found between health status and the primary lifestyles of fungi in soil and bark, which can be interpreted as a sign of resilience against adversities following cross-talk between soil and plant fungal communities.

Construction of biochar-based organohalide-respiring bacterial agent for remediation of 2,4,6-trichlorophenol contaminated soil

Construction of an efficient bio-reductive dechlorination system remains challenging due to the narrow ecological niche and low-growth rate of organohalide-respiring bacteria during field remediation. In this study, a biochar-based organohalide-respiring bacterial agent was obtained, and its performance and effects on indigenous microbial composition, diversity, and inter-relationship in soil were investigated. A well-performing material, Triton X-100 modified biochar (BC600-TX100), was found to have the superior average pore size, specific surface area and hydrophicity, compared to other materials. Interestingly, Pseudomonas aeruginosa CP-1, which is capable of 2,4,6-TCP dechlorination, showed a 348 times higher colonization cell number on BC600-TX100 than that of BC600 after 7 d. Meanwhile, the dechlorination rate in soil showed the highest (0.732 d−1) in the BC600-TX100 bacterial agent than in the other agents. The long-term performance of the BC600-TX100 OHRB agent was also verified, with a stable dechlorination activity over six cycles. Soil microbial community analysis found the addition of the BC600-TX100 OHRB agent significantly increased the relative abundance of genus Pseudomonas from 1.53 % to 11.2 %, and Pseudomonas formed a close interaction relationship with indigenous microorganisms, creating a micro-ecological environment conducive to reductive dechlorination. This study provides a feasible bacterial agent for the in-situ bioremediation of soil contaminated organohalides. Environmental ImplicationHalogenated organic compounds are a type of toxic, refractory, and bio-accumulative persistent compounds widely existed in environment, widely detected in the air, water, and soil. In this study, we provide a feasible bacterial agent for the in-situ bioremediation of soil contaminated halogenated organic compounds. The application of biochar provides new insights for “Turning waste into treasure”, which meets with the concept of green chemistry.

Aviation fuel hydrocarbons from camphorwood and low-density polyethylene: Cascade catalytic approach with CaO and Zn/HBeta

In this study, the co-pyrolysis of camphorwood and low-density polyethylene employing a cascade catalyst system consisting of CaO and Zn-modified HBeta in a fixed-bed reactor was investigated for the production of aviation fuel hydrocarbons (C8–C16). The effect of Zn loading on HBeta, CaO to Zn/HBeta mass ratio, and the feedstock to catalyst mass ratio on both oil yield and composition was investigated. Results revealed that loading Zn onto HBeta led to ZnO cluster and oxygen-bridged Zn dimers ([ZnOZn]2+) formation, which affects HBeta's acid properties and aromatization capacity. The 10 wt%Zn/HBeta catalyst with more ZnO content exhibited weak acid sites, and moderate aromatization capacity, increasing oil yield from 32.06 to 44.25 wt% compared to 3 wt%Zn/HBeta and favoring presence of straight-chain components in oil products. CaO also enhanced straight-chain alkane formation. The highest oil yield, reaching 48.44 wt%, was obtained when CaO and 10 wt%Zn/HBeta cascade by a 1:1 mass ratio was adopted, producing oil with aviation fuel with a maximum yield of 18.45 wt%, and selectivity of 38.09 area%, of which 26.54 area% being aromatics and 11.55 area% being alkanes. Furthermore, the feedstock-to-catalyst ratio influenced the products significantly, with lower feedstock-to-catalyst ratio enhanced aromatization and the ratio of 2:1 recommended. Therefore, this cascade catalytic approach, which combines cost-effective CaO and 10 wt%Zn/HBeta catalysts shows significant potential for enhancing bio-aviation fuel production from solid wastes. Moreover, it provides a viable and promising solution for addressing concerns related to low oil yield and excessive aromatization.

Experience in modeling an asphaltene depositions curve and reducing the intensity of their formation by optimizing oil production technology

Relevance. The need to study the formation of asphaltene deposits in oil production wells. Among the known methods of combating these complications, the greatest interest is in optimizing oil production technology to prevent or reduce the intensity of the formation of these deposits. Aim. To study the possibility of constructing a curve for the formation of asphaltene deposits on the laboratory installation “Wax Flow Loop” and to determine the possibility of optimizing oil production technology to prevent the formation of these deposits. Methods. Laboratory studies on the “Wax Flow Loop“ installation, modeling based on the component composition of oil in the “PVTSim“ software product, calculations in the “Engineering Simulator of Technological Processes“ software product. Results. Based on the results of laboratory studies and numerical calculations, it was possible to construct a curve for the formation of asphaltene deposits. The correctness of the curve was validated against actual data on plugging a production well. The calculation of the influence of installing an electric centrifugal pump and choke-fitting a well showed that the first technology for changing oil production can significantly reduce the intensity of the formation of asphaltene deposits by introducing additional energy. The second technology only slightly shifts the thermobaric conditions of liquid extraction, which does not significantly affect the intensity of the formation of asphaltene deposits. Conclusions. The laboratory installation "Wax Flow Loop" allows correctly forming the curve of asphaltene deposits formation in the production tubing of oil producing wells. Methods for optimizing oil production technology make it possible to prevent the formation of asphaltene deposits with correct modeling and numerical calculations and selection of downhole pumping equipment.