Composition Of Meteoric Water Research Articles

A tipping point in stable isotope composition of Antarctic meteoric waters during Cenozoic glaciation.

Triple oxygen isotopes of Cenozoic intrusive rocks emplaced along the Ross Sea coastline in Antarctica, reveal that meteoric-hydrothermal waters imprinted their stable isotope composition on mineral phases, leaving a clear record of oxygen and hydrogen isotope variations during the establishment of the polar cap. Calculated O- and H-isotope compositions of meteoric waters vary from -9 ± 2‰ and -92 ± 5‰ at 40 ± 0.6 Ma, to -30 and -234 ± 5‰ at 34 ± 1.9 Ma, and intersect the modern Global Meteoric Water Line. These isotopic variations likely depict the combined variations in temperature, humidity, and moisture source regions, resulting from rearrangement of oceanic currents and atmospheric cooling during the onset of continental ice cap. Here, we report a paleo-climatic proxy based on triple oxygen geochemistry of crystalline rocks that reveals changes in the hydrological cycle. We discuss the magnitude of temperature changes at high latitudes during the Eocene-Oligocene climatic transition.

Topographic influence on ecohydrology in volcanic watersheds of the western Pacific monsoon area: evidence from water stable isotope composition of meteoric water, thermal water, and plants

ABSTRACT In Taiwanese volcanic watersheds, we investigated stable water isotopes in meteoric water, plants, and thermal water. Meteoric water exhibited a seasonal cycle, with heavier isotopes in winter and lighter ones in summer, especially in the southern region. The northern monsoon signal lagged the south by two weeks. In the Tatun mountains, young water fractions indicated prevalent old water sources. In the northern watershed, streamwater mainly came from the winter monsoon, while the southern one was influenced by alternating monsoons. Both indices indicated that winter plants depended on summer rainfall. Streamwater and plants had distinct sources in winter, supporting ecohydrological separation. Thermal spring water’s d-excess helped identify water–rock interactions, with low d value signaling such interactions. The topographic wetness index showed a higher summer monsoon contribution to southern streamwater but a lower one to plants. The mean linear channel direction significantly affected the monsoon contribution fraction, with northeast-oriented channels vulnerable to northeastward winter monsoons. Finally, we developed a model illustrating hydrological processes on short and long timescales. Our findings enhance our understanding of hydrological disturbances’ impact on water resources and ecosystems.

ENSO sentinels in the Americas' humid tropics: We need combined hydrometric and isotopic monitoring for improved El Niño and La Niña impact prediction

AbstractThis Scientific Briefing presents results from a nearly 10‐year hydrometric and isotope monitoring network across north‐central Costa Rica, a region known as a headwater‐dependent system. This monitoring system has recorded different El Niño and La Niña events and the direct/indirect effects of several hurricane and tropical storm passages. Our results show that El Niño‐Southern Oscillation (ENSO) exerts a significant but predictable impact on rainfall amount anomalies, groundwater level and spring discharge, as evidenced by second‐order water isotope parameters (e.g., line conditioned‐excess or line‐conditioned (LC)‐excess). Sea surface temperature anomaly (El Niño Region 3) is correlated with a reduction in mean annual and cold front rainfall across the headwaters of north‐central Costa Rica. During El Niño conditions, rainfall is substantially reduced (up to 69.2%) during the critical cold fronts period, limiting groundwater recharge and promoting an early onset of minimum baseflow conditions (up to 5 months). In contrast, La Niña is associated with increased rainfall and groundwater recharge (up to 94.7% during active cold front periods). During La Niña, the long‐term mean spring discharge (39 Ls−1) is exceeded 63–80% of the time, whereas, during El Niño, the exceedance time ranges between 26% and 44%. The regional hydroclimatic variability is also imprinted on the hydrogen and oxygen isotopic compositions of meteoric waters. Drier conditions favoured lower LC‐excess in rainfall (−17.3‰) and spring water (−6.5‰), whereas wetter conditions resulted in greater values (rainfall = +17.5‰; spring water = +10.7‰). The lower and higher LC‐excess values in rainfall corresponded to the very strong 2014–2016 El Niño and 2018 La Niña, respectively. During the recent triple‐dip 2021–23 La Niña, LC‐excess exhibited a significant and consistently increasing trend. These findings highlight the importance of combining hydrometric, synoptic and isotopic monitoring as ENSO sentinels to advance our current understanding of ENSO impacts on hydrological systems across the humid Tropics. Such information is critical to constraining the 21st century projections of future water stress across this fragile region.

Modeling and interpreting triple oxygen isotope variations in vertebrates, with implications for paleoclimate and paleoecology

The 18O/16O ratios of biominerals have been widely used for reconstructing ecophysiology and climatic settings of modern and extinct animals. However, the 18O/16O ratios of body water, which largely determine the 18O/16O ratios of biominerals, are influenced by a host of competing factors. Regional climate and local hydrology are dominant controls on water isotopic composition before water is consumed by an animal. Behavioral and physiological factors, modified by local climate, also have a strong influence on body water compositions. The addition of a third isotope, 17O (expressed as Δ’17O) potentially allows for further resolution of these factors. Here we construct a generalized triple oxygen isotope mass balance model based on the 18O model of (Kohn 1996) (Geochim. Cosmochim. Acta 60, 4811–4829) and examine the influence on vertebrate animal body water Δ’17O of numerous climatic, ecological, and isotopic variables. We evaluate the model against new and previously published triple oxygen isotope data from modern and fossil animals. The model predicts that animals from arid environments will have wider ranges and lower minimum values of body water Δ’17O than animals living in humid environments. Leaf water consumers are more sensitive to variations in relative humidity and have lower Δ’17O than surface water consumers, which more closely track meteoric water compositions. In this model, factors such as body mass and relative proportions of evaporative versus nonevaporative effluxes from the animal have a lesser influence on animal Δ’17O. If δ18O of meteoric water is invariant, body water isotopic compositions will form approximately linear arrays in Δ’17O versus δ18O space with slopes of ∼0.52. Study of Δ’17O becomes most useful when δ18O of meteoric water is variable or unknown (as is generally the case for fossil animals); in this case Δ’17O of body water responds more strongly to changes in relative humidity, evaporated water inputs, and animal water use efficiency. These predictions are generally supported by observations of Δ’17O for modern animals. This agreement suggests that Δ’17O analysis of animal tissues has great potential as a paleo-aridity proxy in continental environments and as a proxy for learning about the ecology of modern and extinct animals.

Environmental controls on the hydrogen isotopic composition of volcanic glass from the Southern Afar rift, eastern Ethiopia

Hydrogen stable isotope values of hydrated volcanic glass as a proxy for the isotopic composition of past meteoric waters provide an opportunity for reconstructing past climates. Here we present new hydrogen stable isotope values from 63 individual tuffs from the Afar region in the lower Awash Valley of eastern Ethiopia. The hydrogen isotopic results from volcanic glass spanning the last 6.4 Ma show a wide distribution with values ranging between −89 and − 32 ‰ (VSMOW). The variability is consistent with the observed paleo-depositional setting (i.e., lower values for fluvial settings while higher values are recorded in lacustrine settings). The reconstructed hydrogen isotopic values of parent waters are considerably lower than those of modern meteoric waters, suggesting a bias toward lower values during the hydration of volcanic glass.Reconstructed hydrogen stable isotope values of water derived from volcanic glass differ from other proxies of regional climate in northeast Africa, pointing to the controls of local meteoric waters on the hydrogen isotopic composition of volcanic glass. There is agreement between the reconstructed isotopic composition of parent waters and the lowest hydrogen isotopic values of modern precipitation in the Awash catchment that correspond to periods of large rainfall. This correspondence probably indicates that volcanic glass is preferentially hydrated during the wettest seasons. To test this idea, we compared the isotopic results from volcanic glass with the reconstructed isotopic composition of surface waters from soil carbonates deposited during the Pliocene and Pleistocene in the lower Awash Valley. The comparison reveals a considerable difference between proxies, with volcanic glass recording lower isotopic values than soil carbonates. Evaporative isotopic enrichment of water in shallow (<1 m) soil profiles probably accounts for the elevated values in soil carbonates. In contrast, the presence of smectite-rich vertisols above volcanic deposits appears to retard infiltration of meteoric waters deep into the subsurface. During rainfall events, vertisols swell and prevent all but the largest rainfall events from penetrating deep (>1 m) into the profiles and promoting the hydration of volcanic glass that display systematically lower isotopic values of meteoric waters than the mean annual rainfall.

Geochemical techniques to identify fluid sources in highly pressured casing-casing annuli (CCA)

The buildup of high pressure in the casing-casing annulus (CCA) threatens well integrity and can cause serious incidents in case of left untreated. Either, trapped water in the cement column or a dynamic water inflow represent potential fluid sources for the elevated CCA pressure. This study presents a sequential methodology to determine the provenance of CCA effluent as trigger for high pressure in newly drilled wells. Single fluid types, multicomponent mixing, and secondary fluid alteration processes were identified through inorganic geochemical techniques; in detail by monitoring the hydrochemical (major, minor, and trace elements) and stable isotopic (δ2H, δ18O) relationship between fluid candidates. As a proof-of-concept, geochemical signatures of CCA effluent from three wells were linked with potential source candidates, i.e., utilized drilling fluids (mud filtrate, supply water) from the prospect well site, groundwater from Lower - Upper Cretaceous aquifers, and Upper Jurassic - Upper Triassic formation waters from adjacent wells and fields. The detection of geochemical affinities of CCA water with groundwater from a Lower Cretaceous aquifer postulates one single lithological unit as source for active groundwater inflow. Nonreactive elements (Na+, Cl−) and environmental isotopes (δ2H, δ18O) were found to be most suited tools for primary fluid identification. The 2H/1H and 18O/16O ratios of supply water and mud filtrate are generally close to global meteoric water and Tertiary groundwater composition, while formation water from Mesozoic units (Cretaceous, Jurassic, and Triassic) can individually be distinguished through increasing ratios in δ18O and δ2H. Compositional anomalies in SO42− and K+, and extreme alkaline conditions for CCA water indicate the occurrence of secondary fluid alteration processes, likely caused by the contact of inflowing groundwater with alkaline minerals in the cement column or by fluid mixing with residuals of potassium chloride (KCl) additives from the drilling process. The geochemical techniques from this study facilitate the detection of high CCA pressure and fluid leakages sources. As a practical benefit, workover engineers are enabled to plan for potential remedial actions prior to moving the rig to affected well sites; thereby significantly reducing operational costs. Appropriate remedial solutions can be induced for safe well abandonment, plus to resume operation at the earliest time.

Isotopic exchange of oxygen, sulfur, hydrogen and copper between aqueous phase and the copper minerals brochantite, libethenite and olivenite

AbstractFractionation factors for the isotopes of O, H, S, or Cu (as appropriate) were determined for the minerals brochantite [Cu4(SO4)(OH)6], libethenite [Cu2(PO4)(OH)] and olivenite [Cu2(AsO4)(OH)] and corresponding aqueous solutions at temperatures between 30 and 70°C. All samples used for this determination were synthetic and the degree of fractionation was expressed as 1000 ln α = (A × 106/T2) + B, where A and B are empirical parameters. A few natural libethenite samples from its type locality Ľubietová-Podlipa were also analysed and compared to the prediction based on the isotopic composition of meteoric water and our fractionation factors. The hydrogen fractionation factors agreed with the prediction well, whereas those for oxygen did not. A possible explanation is the disequilibrium of aqueous phosphate (and also arsenate) species and the solution in our experiments or the interaction of meteoric fluids with the isotopically heavy (in terms of oxygen) country rocks. Because the effects of isotopic disequilibrium in our experiments cannot be ruled out, the oxygen fractionation factors should be used with caution. The determined fractionation factors can be used as an isotope geothermometer, given that it can be proven that the phases of interest precipitated from the same fluid in equilibrium. Libethenite is predicted to have slightly lower δ65Cu values than its parental solution, but brochantite slightly higher δ65Cu values than its parental solution. Simple forward models, simulating neutralisation or reduction of mine drainage, show that precipitation of these minerals and removal of the co-existing fluid, could cause isotopic variations (in δ65Cu) on the order of 1‰ or more.

Prolonged early to middle Holocene drought in the Pacific Northwest inferred from lacustrine carbonate oxygen isotope values and sedimentology

Sediment-based lake-level reconstructions and the oxygen isotopic composition of lacustrine carbonate (δ18OCO3) provide insight on hydroclimate conditions during the early Holocene in western North America and the Pacific Northwest. There are relatively few such records with decadal temporal resolution, and changes in the isotopic composition of meteoric water potentially obscure the hydroclimate signal (precipitation-evaporation) in lacustrine δ18OCO3 data. Here, we present a Holocene-length drought index developed by combining the δ18OCO3 record from Castor Lake, a closed-basin system located in north-central Washington (USA), with the δ18OCO3 record from Lime Lake, which has an open-basin configuration and is located in northeastern Washington. The lake sediment records are dated using primarily a combination of radiocarbon measurements on terrestrial macrofossils, Pb-210, Cs-137, and tephrochronology. The δ18OCO3 drought index, along with changes in Castor Lake sediment facies, suggest periods of prolonged drought in the Pacific Northwest between 11,200 and 6200 cal yr BP, a finding that is supported by other lacustrine proxy records of lake level and temperature change. Early Holocene drought likely resulted from higher than present summer isolation that promoted longer, hotter summers and greater evaporation. Lower than present winter insolation at this time likely altered the location and/or strength of the westerlies, reducing cold season precipitation/snowpack and intensifying the dry conditions. This study highlights the sensitivity of hydroclimate in an already drought- and fire-prone region to the magnitude and duration of summer warmth and precipitation and snowpack levels during the winter.

Climate reconstruction from paired oxygen-isotope analyses of chironomid larval head capsules and endogenic carbonate (Hawes Water, UK) - Potential and problems

Temperature and the oxygen isotopic composition (δ18O) of meteoric water are both important palaeoclimatic variables, but separating their influences on proxies such as the δ18O of lake carbonates is often problematic. The large temperature variations that are known to have occurred in the northern mid-latitudes during the Late Glacial make this interval an excellent test for a novel approach that combines oxygen-isotope analyses of chironomid larval head capsules with co-occurring endogenic carbonate. We apply this approach to a Late Glacial lake sediment sequence from Hawes Water (NW England). Oxygen-isotope values in chironomid head capsules show marked variations during the Late Glacial that are similar to the oxygen isotope record from endogenic carbonate. However, summer temperature reconstructions based on the paired isotope values and fractionation between chironomids and calcite yield values between −20 and −4 °C, which are unrealistic and far lower than reconstructions based on chironomid assemblages at the same site. The composition of a limited number of samples of fossil chironomid larval head capsules determined using Pyrolysis gas-chromatography mass spectrometry indicates the presence of aliphatic geopolymers, suggesting that diagenetic alteration of the head capsules has systematically biased the isotope-derived temperature estimates. However, a similar trend in the isotope records of the two sources suggests that a palaeoclimate signal is still preserved.

Isoscape of Surface Runoff in High Mountain Catchments: An Alternate Model for Meteoric Water Characterization and Its Implications

AbstractWater isotope‐based hydrological and paleoaltimetry studies in high mountain areas are generally done using the isotopic composition of river discharge. However, rivers capture a basin averaged signal of regional precipitation and are less likely to register the meteorological processes intrinsic to distinct hydrological fractions at different altitudes. This has been observed in the Khumbu (Mt. Everest) Himalayan watersheds of Dudh Kosi Basin (DKB), where the δ18O values of snowpack and stream water vary non‐uniformly with altitude while the δ18O values of river water show a uniform relationship. Snow exhibits the highest (+0.9 to −4.4‰/100 m) isotopic lapse rate (ILR), followed by streams (+0.2 to −0.4‰/100 m) and rivers (−0.05‰/100 m). Sublimation, catchment vegetation, diurnal temperature, cloud type, and insolation play a significant role in controlling the isotopic composition of snowpack and stream water. Similarly, the isotopic composition of small streams disproportionately represents the meteoric water composition of an area, as rainfall immediately joins the stream‐runoff while the snow melts gradually around the year. To map the isotopic heterogeneity in DKB surface waters, we have modeled the isoscape for surface runoff using the isotopic composition of snow and stream water, and remotely sensed parameters. Accordingly, we simulate the isoscapes for snow and stream‐runoff via multi‐regression models which extrapolate the observed data as a function of the controlling factors. The amount‐weighted summation of both the isoscapes (relative contribution (%) *δ18O value) constitutes the hydropool. The hydropool model incorporates spatiotemporal variation in ILR computed from the δ18O values of surface runoff.

Regional meteoric water line of the Yucatan Peninsula, Mexico

AbstractThe data set represents the Regional Meteoric Water Line (RMWL) for the Yucatan Peninsula (Mexico), a region with karstic aquifers but little knowledge of the isotopic composition of meteoric water. This data paper comprises the isotopic composition of meteoric water collected from November 2018 to November 2019 as monthly composite samples expressed as weighted monthly mean precipitation from 16 locations across the Yucatan Peninsula. The RMWL was δ2H = 7.803 δ18O + 12.075, with a slope and intercept suggesting precipitation from air that has undergone condensation, air masses with variable moisture or recycled moisture. The average δ18O is −2.57‰ (−12.23 to 1.2‰) and δ2H is −7.94‰ (−83.39 to 18.32‰). This data set was collected by the implementation of an isotopic monitoring network, gathering information useful as a tool for better understanding of the hydrology and hydrogeochemistry of karstic aquifers, and to develop proxies for paleohydrology, ecohydrology, climate change and paleoclimate studies in the Gulf of Mexico and the Great Caribbean Area.

Lake water based isoscape in central-south Chile reflects meteoric water

Warming across the globe is expected to alter the strength and amount of regional precipitation, but there is uncertainty associated with the magnitude of these expected changes, and also how these changes in temperature and the hydrologic cycle will affect humans. For example, the climate in central-south Chile is projected to become significantly warmer and drier over the next several decades in response to anthropogenically driven warming, but these anthropogenic changes are superimposed on natural climate variability. The stable isotope composition of meteoric water provides significant information regarding the moisture source, pathways, and rain-out history of an air mass, but precipitation samples suitable for stable isotope measurements require long-term placement of field equipment making them difficult to obtain. The International Atomic Energy Agency (IAEA) Global Network of Isotopes in Precipitation (GNIP) stations generate isotopic and ancillary data of precipitation from many locations around the world, but remote areas of developing countries like Chile typically have sparse networks of meteorological stations, which inhibit our ability to accurately model regional precipitation. Central-south Chile, in particular, has a sparse network of GNIP stations and, as a result, the isotopic composition of meteoric water is underrepresented in the global database complicating efforts to constrain modern day hydroclimate variability as well as paleohydrologic reconstruction for southern South America. In this study, we measured the stable isotope compositions of hydrogen (δ2H) and oxygen (δ18O) in surface lacustrine waters of central-south Chile to determine what physical and/or climatic features are the dominant controls on lacustrine δ18O and δ2H composition, assess whether or not the isotopic composition of the lakes record time-averaged isotope composition of meteoric water, and determine whether an isoscape map based on lake surface waters could predict the H and O isotope compositions of precipitation at the few GNIP stations in the region.

Triple Oxygen Isotope Paleoaltimetry of Crystalline Rocks

Triple oxygen isotopes of hydrothermally altered minerals from crystalline rocks can be used to determine past elevations of mountain ranges. This method uses all three isotopes of oxygen (16O, 17O, and 18O) to create arrays that can be extrapolated back to the meteoric water line. One advantage of this technique is that it relies only on oxygen isotopes in contrast to previous studies that use oxygen and hydrogen isotopes to determine the isotopic composition of meteoric waters. Our analysis suggests that hydrogen isotopes may exchange with ambient fluids. Triple oxygen isotopes provide an independent check on the reliability of hydrogen isotope studies.

Hydrogeology and origin of waters of the Panyam Volcanic Line springs, Jos Plateau, Nigeria

The PVL springs are used for both domestic and agricultural purposes. The seepage from the springs has resulted in producing a large expanse of wetlands and is therefore intensively use for dry season farming. The aim of this study was to determine the hydrogeological, hydrochemical characteristics, origin and their suitability for domestic and irrigation. The hydrogeology of the springs was determined by field mapping. The physico-chemical parameters were determined in the field and by laboratory methods. For the cation and anion analysis the ICP-MS and the wet methods were employed respectively. The stable isotope composition of oxygen (δ18O) and hydrogen (δ2H) were analyzed by Isotope Ratio Mass Spectrometer. The hydrochemical analysis revealed that the PVL springs waters are generally neutral with an average pH value of 7.3. The average TDS and EC values are 127.8mg/l and 246µs/cm respectively. These values fall within fresh water class. The average Mg2+,Ca2+, Na+ and K+ cation concentration values are 16.3mg/l, 15.8mg/l, 10.8mg/l and 5.58mg/l respectively. The average anions concentration of HCO3-, SO4 and Cl- are 140mg/l, 8.6mg/l and 3.4mg/l respectively. Piper trilinear diagram show that the spring waters is predominantly Mg-Ca-HCO3 water type with potable qualities based on WHO drinking water standards. The sodium Adsorption Ratio (SAR) and Sodium Soluble Percentage (SSP) values range between 0.44 to 0.84 and 26.4 to 54% respectively and falls within irrigation quality standards. Stable isotope compositions of δ18O and δ2H ranges from -3.60/00 to -4.90/00 and -200/00 to -280/00 respectively falls within the meteoric water composition. This is further affirmed by the δ2H versus δ18O plot on the correlation diagram with Standard Meteoric Water Line.

Hydrogeology and origin of waters of the Panyam Volcanic Line springs, Jos Plateau, Nigeria

The PVL springs are used for both domestic and agricultural purposes. The seepage from the springs has resulted in producing a large expanse of wetlands and is therefore intensively use for dry season farming. The aim of this study was to determine the hydrogeological, hydrochemical characteristics, origin and their suitability for domestic and irrigation. The hydrogeology of the springs was determined by field mapping. The physico-chemical parameters were determined in the field and by laboratory methods. For the cation and anion analysis the ICP-MS and the wet methods were employed respectively. The stable isotope composition of oxygen (δ18O) and hydrogen (δ2H) were analyzed by Isotope Ratio Mass Spectrometer. The hydrochemical analysis revealed that the PVL springs waters are generally neutral with an average pH value of 7.3. The average TDS and EC values are 127.8mg/l and 246µs/cm respectively. These values fall within fresh water class. The average Mg2+,Ca2+, Na+ and K+ cation concentration values are 16.3mg/l, 15.8mg/l, 10.8mg/l and 5.58mg/l respectively. The average anions concentration of HCO3-, SO4 and Cl- are 140mg/l, 8.6mg/l and 3.4mg/l respectively. Piper trilinear diagram show that the spring waters is predominantly Mg-Ca-HCO3 water type with potable qualities based on WHO drinking water standards. The sodium Adsorption Ratio (SAR) and Sodium Soluble Percentage (SSP) values range between 0.44 to 0.84 and 26.4 to 54% respectively and falls within irrigation quality standards. Stable isotope compositions of δ18O and δ2H ranges from -3.60/00 to -4.90/00 and -200/00 to -280/00 respectively falls within the meteoric water composition. This is further affirmed by the δ2H versus δ18O plot on the correlation diagram with Standard Meteoric Water Line.

A preliminary evaluation of ecohydrological separation in a semi-arid riparian area

In recent years the ecohydrological separation paradigm has stimulated significant scientific debate, as it challenges the basis of existing hydrological process understanding. Through the use of stable isotope analysis several studies have demonstrated that two isotopically distinct water stores may exist within the subsurface, a matric-bound store which sustains transpiration and a mobile store which contributes to the recharge of groundwater and streams. Despite growing evidence supporting this hypothesis, further testing across a range of climatic regimes and environmental settings has been advocated to develop an improved hydrological understand of this paradigm. In this study, the dual isotopic composition of meteoric and environmental waters was analysed in a semi-arid riparian environment during a significant El Nino induced drought, to ascertain if plants were using water that would have otherwise contributed to stream and/or groundwater recharge. Overall, the results of these investigations showed no clear evidence supporting ecohydrological separation. Environmental waters were found to be significantly different from rainfall, whereas no significant differences were established between xylem, bulk soil water, and streamflow. While, these findings represent a unique scenario with regards to the testing of ecohydrological separation, these results are by no means ubiquitous as sampling was conducted during extreme climatic conditions with limited spatio-temporal representation of the system. Therefore, longer-term sampling and monitoring is recommended to obtain an improved understanding of the system under a range of climatic conditions.

Variaciones geomorfológicas como condicionantes de la química del agua subterránea en el litoral del estuario medio del Río de la Plata

El objetivo del trabajo es determinar los cambios en la química del agua subterránea y los procesos geoquímicos asociados en función de las variaciones geomorfológicas en el ámbito de la planicie costera del Río de la Plata en el sector litoral del estuario medio. Para ello se estableció una red de monitoreo que involucra puntos de muestreo de agua superficial y subterránea donde se determinó el contenido de iones mayoritarios, nitrato e isótopos estables de la molécula de agua. El contenido en isótopos ambientales registra, para el caso del agua subterránea, que el agua de lluvia infiltra sin previa evaporación y recarga al agua subterránea somera. Las muestras de agua superficial presentan porcentajes de evaporación menores al 10%. Estos bajos porcentajes pueden deberse a que el muestreo se realizó en un mes de excesos hídricos. En cuanto al contenido de iones mayoritarios se registran variaciones en función de la geomorfología. Así, la antigua llanura intermareal y la planicie con cordones de conchilla presentan facies que varían según la profundidad del muestreo entre bicarbonatada sódica y clorurada sódica. Estas variaciones estarían controladas por la composición original del agua meteórica y las reacciones químicas producto de la interacción con el sedimento. Particularmente, la química del agua subterránea de la marisma está regulada por los flujos mareales provenientes del Río de la Plata.

Isotope and Geochemistry Characterization of Hot Springs and Cold Springs of Sembalun – Rinjani Area, East Lombok, West Nusa Tenggara – Indonesia

The presence of several hot springs in Sembalun – Rinjani, East Lombok, West Nusa Tenggara is an indicator of geothermal potential in the area. This study aims to determine the characteristics of hot springs and cold springs and also the geothermal potential in Sembalun – Rinjani area using isotopes and geochemistry methods. The result of d18O and d2H stable isotopes analysis shows that most of the hot springs are meteoric water. Except for Kalak hot spring, other hot springs are a mixing product of meteoric water and andesitic water, with meteoric water composition between 64 to 87%. While 14C radioisotope suggests that the age of hot springs in the Sembalun area is about 10,000–12,000 years BP, the surrounding cold springs are mostly Modern except Jorong cold spring. The results of gas analysis (He, Ar, and Ne) also suggest the same origin of geothermal fluid, i.e., meteoric water origin. Based on chemical composition, Kalak hot spring is plotted as sulfate type water, while Sebau hot spring is plotted near mature water composition but not representing reservoir fluid due to its relatively low temperature and high Mg content. Na/K geothermometer calculation from Sembalun area shows that subsurface temperature is varied between 111-161 °C, while from Rinjani hot springs indicates higher subsurface temperature, i.e., 250-260 °C. It is estimated that reservoir fluid has high TDS with chloride content up to 4000 mg/L.

INTERCONECTIVIDADE DE AQUÍFEROS E OS EFEITOS DA DRENAGEM ÁCIDA DE MINA NA QUALIDADE DAS ÁGUAS DA BACIA CARBONÍFERA DE SANTA CATARINA (SC)

A atividade carbonífera no sul de Santa Catarina se desenvolve há mais de um século e a falta de gerenciamento ambiental nos empreendimentos mineiros causou significativas alterações de qualidade nos recursos hídricos da Bacia Hidrográfica do Araranguá. Além da alteração na qualidade das águas, ocorreram fenômenos de colapso e abatimento de minas subterrâneas que ocasionaram fraturamento das camadas sobrejacentes, e permitiram a ampliação dos processos de circulação dos sistemas aquíferos com corpos hídricos superficiais. Com objetivo de melhorar o entendimento destes processos, foram analisadas amostras das águas de 9 poços do Sistema Aquífero Rio Bonito, 4 poços do Sistema Aquífero de Leques Aluviais e 6 amostras de águas superficiais das mesmas microbacias onde estão instalados os poços. As análises hidroquímicas indicam uma predominância de águas bicarbonatadas cálcicas e sódicas, que quando em contato com a drenagem ácida de mina são transformadas em águas sulfatadas. A composição isotópica em termos de isótopos de oxigênio e de hidrogênio das amostras evidencia semelhança com a composição isotópica das águas meteóricas. Este fato contribui com a hipótese da forte interação da água subterrânea com as águas freáticas e superficiais, que ocorre devido à tectônica rúptil que afeta as litologias gonduânicas, e é intensificada pela presença das minas de subsolo.

Active Volcanoes and Thermal Springs of Kunashir Island (Russia)

Since 2002, complex studies of all known thermal springs of Kunashir Island have been carried out. Of the four active volcanoes in the island, three volcanoes have stable hydrothermal systems. In addition to volcanoes, thermal springs in Kunashir are found on the coast and they are associated with tectonic faults. Despite the different morphogenetic types of volcanoes and their activity, the common patterns of zoning of hydrochemical types of thermal waters are typical for volcano-hydrothermal systems. On the periphery of the extrusive domes of the volcanoes, there are solfataric fields with outputs of gases and acid sulfate hydrotherms with temperatures up to 95 °C. Below the slope at a distance from the extrusive domes and solfataric fields an acid chloride-sulfate (sulfate-chloride) sodium hydrotherms with temperatures up to 91 °C are located. At the foot of volcanic edifices, at a considerable distance from the extrusions and outputs of solfataric gases, neutral chloride sodium thermal springs and steams are located. The isotopic composition of oxygen and hydrogen of different hydrochemical types of thermal waters is similar to the isotopic composition of local meteoric waters, which confirms the genesis of hydrotherms due to atmospheric waters with minimal participation of sea and "mantle" waters.