The present study is focused on investigating the effect of the micro-mechanical properties of the natural fiber- (pineapple leaf fiber) reinforced polymeric composites by the addition of pineapple leaf micro-particulates. For the investigation, a two-step approach has been used. In the first step, finite element method-based analysis has been used to characterize the tensile and shear properties of the pineapple leaf fiber-reinforced polymeric composites (FRP) and pineapple paticulate-reinforced polymeric composites (PRC), and the adopted finite element method-based analysis has been validated through the experimental approach. In the second step, the validated finite element method-based analysis has been used to characterize the micro-mechanical properties of the hybrid fiber-reinforced polymeric composites (HFRP) fabricated using the pineapple leaf micro-particle embedded epoxy as a matrix material and the pineapple leaf fiber has been used as reinforcing material. It has been observed through the analysis that the micro-mechanical properties of HFRP were superior to that of FRP. There has been a 10.16% increment in Young’s modulus in the longitudinal direction and a 26.36% increment in Young’s modulus in the transverse direction for HFRP over FRP. Further, a 9.91% increment for in-plane shear modulus and 26.17% increment in outer-plane shear modulus have been observed for HFRP in comparison to FRP. These results suggest that pineapple leaf particulates are good reinforcing materials to enhance the transverse direction and outer plane micro-mechanical properties of the fiber-reinforced composite.