Nanocomposite Materials Research Articles

Microstructure and coupling mechanisms in MnBi–FeSiB nanocomposites obtained by spark plasma sintering

Fabrication and extensive characterization of hard-soft nanocomposites composed of hard magnetic low-temperature phase LTP-MnBi and amorphous Fe70Si10B20 soft magnetic phase for bulk magnets are reported. Samples with compositions Mn55Bi45 + x⋅(Fe70Si10B20) (x = 0, 3, 5, 10, 20 wt.%) were prepared by spark plasma sintering of powder mixtures. Characterization has been performed by X-ray diffraction, scanning and transmission electron microscopy, magnetometry and 57Fe Mӧssbauer spectroscopy. It was shown that samples contain crystallized and nanometric LTP-MnBi phases with various elemental compositions depending on the degree of Bi clustering. Complex correlations between starting compositions, processes during fabrication, and functional magnetic characteristics were observed. Unexpected special situations of the relation between microstructure and magnetic coupling mechanisms are discovered. Exchange spring effects of different strengths occur, being very sensitive to morpho-structural and compositional features, which in turn are controlled by processing conditions. An in-depth analysis of related microscopic characteristics is provided. Results of this work suggest that fabrication by powder metallurgy routes, such as spark plasma sintering of hard and soft magnetic powder mixtures, of MnBi-based composites with exchange spring phenomena have a high potential in designing and optimization of suitable materials with tunable magnetic properties towards rare-earth–free permanent magnet applications.

Preparation of 3D Composite Nanomaterials Based on Opal Matrices by Reduction of Palladium and Platinum Compounds

Preparation of 3D Composite Nanomaterials Based on Opal Matrices by Reduction of Palladium and Platinum Compounds

Investigating the bending and buckling behaviors of composite porous beams reinforced with carbon nanotubes and graphene platelets using a TRPIM path following mesh-free approach

The aim of the present work consists in investigating the nonlinear behavior of porous beams reinforced with graphene platelets (GPL) and supported carbon nanotubes (CNT), termed functionally graded graphene platelets reinforced composite beam (FG-GPLRC) and functionally graded nanotube carbon reinforced composite beam (FG-CNTRC), respectively. Notably, the distribution of GPL/CNT is explored in both uniform and non-uniform patterns across the beam's thickness. What sets this research apart is its utilization of a refined beam model as enhanced FSDT incorporating nonlinear shear terms which is a crucial advancement in accurately capturing the post-buckling response in certain boundary conditions, a feature lacking in the existing FSDT literature. Innovatively, the post-buckling load-deflection relationship is derived through the solution of governing equations incorporating cubic nonlinearity. This is achieved by employing Galerkin's method alongside a non-iterative high-order continuation technique based on the asymptotic numerical method coupled with the Tchebychev-radial point interpolation method (TRPIM), using a path-following where the solutions are obtained branch-by-branch by eliminating the need for iterative processes. In essence, this research underscores the pivotal role of porosity and GPL/CNT reinforcement in shaping the post-buckling configuration of both perfect and imperfect nanocomposite beams, thereby advancing our understanding of structural behavior in porous nanocomposite materials. The findings of this study illuminate the significant influence of parameters such as porosity coefficient, porosity distribution, GPL/CNT distribution, and GPL-weight/CNT-volume fraction on the nonlinear buckling behavior of porous beams.

Investigation of the Replication Quality of Microstructures on Injection Moulded Specimens Made from Recycled Polypropylene Composites Reinforced with Carbon Nanotubes

During the research, functional microstructures were created on the cavity surface of the injection moulding tool using femtosecond laser technology. Automotive-grade polypropylene (PP), as well as its recycled and carbon nanotube-reinforced composites, were used as the raw materials. The replicated structures were examined using confocal microscopy. It is expected that by optimizing the process parameters, the filling of the structured cavity surface with nanocomposite materials can reach a quality level comparable to plastic specimens made from non-reinforced raw materials. The aim is to provide results of scientific and industrial value to demonstrate the influence of the modified mould surface on the flow of the polymer melt and thus on the filling of the injection moulded products.

In-Situ Hydrothermal Fabrication of ZnO-Loaded GAC Nanocomposite for Efficient Rhodamine B Dye Removal via Synergistic Photocatalytic and Adsorptive Performance.

In this work, zinc oxide (ZnO)/granular activated carbon (GAC) composites at different ZnO concentrations (0.25M-ZnO@GAC, 0.5M-ZnO@GAC, and 0.75M-ZnO@GAC) were prepared by an in-situ hydrothermal method and demonstrated synergistic photocatalytic degradation and adsorption of rhodamine B (RhB). The thermal stability, morphological structure, elemental composition, crystallographic structure, and textural properties of developed catalysts were characterized by thermal gravimetric analysis (TGA/DTG), scanning electron microscopy equipped with energy dispersive-x-ray (SEM-EDS), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) analysis. The successful loading of ZnO onto GAC was confirmed by SEM-EDS and XRD analysis. The BET surface areas of GAC, 0.25M-ZnO@GAC, 0.5M-ZnO@GAC, and 0.75M-ZnO@GAC were 474 m2/g, 450 m2/g, 453 m2/g, and 421 m2/g, respectively. The decrease in GAC could be attributed to the successful loading of ZnO on the GAC surface. Notably, 0.5M-ZnO@GAC exhibited the best photocatalytic degradation efficiency of 82% and 97% under UV-A and UV-C light over 120 min, attributed to improved crystallinity and visible light absorption. The photocatalytic degradation parameters revealed that lowering the RhB concentration and raising the catalyst dosage and pH beyond the point of zero charge (PZC) would favor the RhB degradation. Photocatalytic reusability was demonstrated over five cycles. Scavenger tests revealed that the hydroxyl radicals (•OH), superoxide radicals (O2-•), and photoinduced hole (h+) radicals play a major role during the RhB degradation process. Based on the TOC results, the RhB mineralization efficiency of 79.1% was achieved by 0.5M-ZnO@GAC. Additionally, GAC exhibited a strong adsorptive performance towards RhB, with adsorption capacity and the RhB removal of 487.1 mg/g and 99.5% achieved within 90 min of equilibrium time. The adsorption characteristics were best described by pseudo-second-order kinetics, suggesting chemical adsorption. This research offers a new strategy for the development of effective photocatalyst materials with potential for wider wastewater treatment applications.

Synthesis of GN/ MnO2 nanocomposite materials for photo-assisted supercapacitor with enhanced capacities

Supercapacitors with the advantages of high power density and rapid discharging rate have widespread applications in energy storage. Nevertheless, their development is hindered by the limitation of low specific capacity. Traditional approaches to enhance specific capacity primarily involve incorporating foreign atoms and blending with additional reactive substances. Herein, a photo-assisted supercapacitor electrode material (GN/MnO2 nanocomposite) with excellent capacity is developed. As a photoactive material, graphene generates electrons and holes with photoirradiation. As the photogenerated carriers increase, electrons are separated from the holes and stored as charges. Photoirradiation is the driving force that promotes the energy storage and conversion of supercapacitors. Although there are many reports on GN/MnO2 composites, there are still few reports on the photo-assisted energy storage of this composite material. The specific capacity of this photo-assisted GN/MnO2 electrode materials could reach 210 F/g with photoirradiation. It was higher than that without photoirradiation (170 F/g). The development of this study provides important theoretical guidance and practical significance for the research of photo-assisted energy storage materials, and plays a significant role in advancing the progress of energy storage devices with high specific capacity.

Frequency analysis of open/closed polygonal channel aerostructures made of hybrid nanocomposite materials and supported by piecewise elastic foundation using GDQE technique

This research delves into the theoretical exploration of the generalized differential quadrature element (GDQE) method for analyzing the dynamic response and natural frequency of aerospace structures, specifically polygonal channels found in aircraft, satellites, and space vehicle components. These structures are critical in aerospace engineering, serving in various capacities such as airframe components and fluid conveyance systems. Emphasizing the practical significance of these structures, the study incorporates the influence of ground or support conditions, employing a two-parameter piecewise elastic foundation model. The investigated open or closed channels are characterized as laminated functionally graded hybrid nanocomposites, specifically denoted as FG-HNC, reinforced with Carbon nanotubes (CNTs) and Clay nanoparticles (CNP). Each composite layer is reinforced with randomly oriented and uniformly distributed tubes and particles. The homogenization of the hybrid composite domain is performed using the hierarchy Halpin-Tsai micromechanical rule. Utilizing the GDQE technique, the channels are discretized into plate elements, and motion equations for each plate element are calculated based on first-order shear deformation theory and Hamilton's principle. The resulting equations are then solved using the standard GDQ method, with subsequent application of appropriate continuity conditions at shared element boundaries. In this comprehensive study, the research scrutinizes the effects of structure dimensions, channel sides crank angles, composite characteristics, and boundary conditions on the free vibration behavior of the polygonal channels. By offering detailed insights into the vibrational characteristics of FG-HNC structures, this study contributes to the advancement of aerospace engineering design and analysis.

Nanocarbons decorated TiO2 as advanced nanocomposite fabric for photocatalytic degradation of methylene blue dye and ciprofloxacin

In this research, C [graphene (Gr), multi-walled carbon nanotubes (MWCNTs), and single-walled carbon nanotubes (SWCNTs)] decorated TiO2 nanostructures were developed and further utilized to modify textile to achieve high-performance photocatalytic degradation of mixed water pollutants including methylene blue (MB) dye and pharmaceutical active compound, Ciprofloxacin (CPF) on solar radiation exposure (∼105 Lumens). The crystallite sizes of TiO2, TiO2-MWCNT, TiO2-SWCNT, and TiO2-Gr nanocomposites were observed in the 7.2–10.4 nm range. The bandgap, Eg of nanostructured C-TiO2, was observed in the 3.09–3.14 eV range. The photocatalytic performance of C-TiO2 showed almost complete removal of MB under the irradiation of the solar spectrum in just 120 min. Among C-based TiO2 nanocomposites, nanostructured TiO2-SWCNT showed the highest degradation efficiency of ∼98.86 % for MB dye. Further, the textile membrane showed a good degradation efficiency of 99.49 % for MB dye and 95.7 % for CPF within 120 min. An impressive removal efficiency of ∼93 % was observed for the mixture of MB and CPF solution due to a combination of several properties like surface groups (OH− & O2−), low charge recombination rate due to CNTs, and small crystal size. This proof-of-the-concept study can be the potential platform to manage water quality according to sustainability goals.

Advances in the Application of Nanozymes in Joint Disease Therapy

Nanozymes are nanoscale materials with enzyme-mimicking catalytic properties. Nanozymes can mimic the mechanism of natural enzyme molecules. By means of advanced chemical synthesis technology, the size, shape, and surface characteristics of nanozymes can be accurately regulated, and their catalytic properties can be customized according to the specific need. Nanozymes can mimic the function of natural enzymes, including catalase (CAT), superoxide dismutase (SOD), and glutathione peroxidase (GPx), to scavenge reactive oxygen species (ROS). Reported findings have shown that nanozymes have the advantages of excellent stability, low cost, and adjustable catalytic activity, thereby showing great potential and broad prospects in the application of disease treatment. Herein, we reviewed the advances in the application of nanozymes in the treatment of joint diseases. The common clinical manifestations of joint diseases include joint pain, swelling, stiffness, and limited mobility. In severe cases, joint diseases may lead to joint destruction, deformity, and functional damage, entailing crippling socioeconomic burdens. ROS is a product of oxidative stress. Increased ROS in the joints can induce macrophage M1 type polarization, which in turn induces and aggravates arthritis. Therefore, the key to the treatment of joint diseases lies in ROS scavenging and increasing oxygen (O2) content. Nanozymes have demonstrated promising application potential in the treatment of joint diseases, including rheumatoid arthritis, osteoarthritis, and gouty arthritis. However, how to ensure their biosafety, reduce the toxicity, and increase enzyme activity remains the main challenge in current research. Precise control of the chemical composition, size, shape, and surface modification of nanomaterials is the main development direction for the future.

Modular and Photoreversible Polymer-Nanoparticle Hydrogels via Host-Guest Interactions.

Polymer-nanoparticle (PNP) hydrogels are a class of nanocomposite materials showing potential as injectable platforms for biomedical applications. Their design is limited by incomplete knowledge of how the binding motif impacts the viscoelastic properties of the material and is generally constrained to non-responsive supramolecular interactions. Expanding the scope of available interactions and advancing the understanding of how defined interactions influence network formation would accelerate PNP hydrogel design. To address this gap in the design of PNP hydrogels, the study designs and investigates a tunable platform based on beta-cyclodextrin (βCD) host-guest cross-links between functionalized polymers and nanoparticles. A host-functionalized polymer (βCD hyaluronic acid) and guest harboring block co-polymer (poly(ethylene glycol)-b-poly(lactic acid)) NPs are synthesized. The presence and accessibility for binding of the host and guest moieties are characterized via isothermal titration calorimetry. PNP hydrogels with varying concentrations of functionalized polymer and NPs reveal a limited window of concentrations for gelation. It is hypothesized that network formation is governed by the capacity of polymer chains to effectively bridge NPs, which is related to the host-guest ratios present in the system. Further, photo-responsive guests are incorporated to engineer photoreversible gelation of PNP hydrogels via exposure to specific wavelengths of light.

Pd nanoparticles supported on silver, zinc, and reduced graphene oxide as a highly active electrocatalyst for ethanol oxidation

In this manuscript, we present a facile approach to synthesize a highly active catalyst for the electro-oxidation of ethanol using Pd nanoparticles supported on a Ag–Zn alloy on reduced graphene oxide. This nanocomposite material was fabricated via a two-step process of incineration followed by sol-gel synthesis. The physical properties of the catalyst were evaluated using X-ray diffraction, X-ray photoelectron spectroscopy, and scanning and transmission electron microscopies. To understand the catalyst's activity for ethanol oxidation, we performed a series of cyclic voltammetry and electrochemical impedance spectroscopy experiments in alkaline medium. The catalyst exhibited good catalytic activity with a current density of 13.01 mA cm−2, a value seven times higher than the commercial standard Pd/C catalyst and higher than any other previously reported Pd-based catalyst. The results were attributed synergistic effects between the Pd and alloy support along with the large electrochemically active surface area of the material. Taken together, these results suggest that ethanol electrocatalysts based on nanocomposites of Pd, Ag, and Zn is promising candidates for future ethanol fuel cells.

PEDOT-Doped Mesoporous Nanocarbon Electrodes for High Capacitive Aqueous Symmetric Supercapacitors.

Poly(3,4-ethylenedioxythiophene) (PEDOT) and PEDOT-functionalized carbon nanoparticles (f-CNPs) were synthesized by in situ chemical oxidative polymerization and pyrolysis methods. f-CNP-PEDOT nanocomposites were prepared by varying the concentration of PEDOT from 1 to 20% by weight (i.e., 1, 2.5, 5, 10, and 20 wt%). Several characterization techniques, such as field-emission scanning electron microscopy (FESEM), attenuated total reflectance-Fourier transform infrared (ATR-FTIR), X-ray diffraction (XRD), N2 Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) analyses, as well as cyclic voltammetry (CV), galvanostatic charge discharge (GCD), and electrochemical impedance spectroscopy (EIS), were applied to investigate the morphology, the crystalline structure, the N2 adsorption/desorption capability, as well as the electrochemical properties of these new synthesized nanocomposite materials. FESEM analysis showed that these nanocomposites have defined porous structures, and BET surface area analysis showed that the standalone f-CNP exhibited the largest surface area of 801.6 m2/g, whereas the f-CNP-PEDOT with 20 wt% exhibited the smallest surface area of 116 m2/g. The BJH method showed that the nanocomposites were predominantly mesoporous. CV, GCD, and EIS measurements showed that f-CNP functionalized with 5 wt% PEDOT had a higher capacitive performance compared to the individual f-CNPs and PEDOT constituents, exhibiting an extraordinary specific capacitance of 258.7 F/g, at a current density of 0.25 A/g, due to the combined advantage of enhanced electrochemical activity induced by PEDOT doping, and highly developed porosity of f-CNPs. Symmetric aqueous supercapacitor devices were fabricated using the optimized f-CNP-PEDOT doped with 5 wt% of PEDOT as active material, exhibiting a high capacitance of 96.7 F/g at 1.4 V, holding practically their full charge, after 10,000 charge-discharge cycles at 2 A/g, thus providing the highest electrical electrodes performance. Hereafter, this work paves the way for the potential use of f-CNP-PEDOT nanocomposites in the development of high-energy-density supercapacitors.

The Impact of Synthesis Techniques on Polyetheretherketone/Hydroxyapatite Hybrid Carbonaceous Nanocomposites for Orthopaedic Applications

Nanocomposites containing polymers, hydroxyapatite, and carbon nanotubes have shown great potential for orthopedic applications. However, the synthesis process selected significantly impacts the properties and performance of these nanocomposites. Our study described here investigated the effects of various synthesis methods on the mechanical and structural characteristics of functionalized Multi-Walled Carbon Nanotubes/Polyetheretherketone/Hydroxyapatite (f-MWCNT/PEEK/HAp) hybrid nanocomposites. Our primary objective was to comprehensively understand the many synthesis strategies that could be employed to customize these materials for orthopedic purposes. Several synthesis methods were explored by the authors to produce homogeneous nanocomposites with uniform dispersion and good interfacial bonding. Chemical solution blending, selective chemical solution blending, and three-dimensional mechanical mixing are all examples of such techniques. The produced nanocomposites were tested for crystallinity, tribological properties and molecular compositions using X-ray diffraction (XRD), tribological testing and Fourier transform infrared (FTIR) spectroscopy methods. This study demonstrated different synthesis methods for an orthopedic-targeted hybrid nanocomposite material. The hybrid nanocomposite’s formulation was changed to enhance the material’s properties. The composite was composed of polyetheretherketone (PEEK), hydroxyapatite (HAp) and functionalized multi-walled carbon nanotubes (f-MWCNT). The outstanding tribological performance of the generated nanocomposite was ensured by including the f-MWCNT and HAp in the PEEK.

Phosphorous recovery from sewage effluent by vanadium-substituted composite synthesized via reverse coprecipitation route

MgFe2O4/MgO (S-sample) and a novel V-modified MgFe2O4/MgO (V-sample) nanocomposites were successfully synthesized using the reverse coprecipitation method and were carefully characterized by X-ray diffractometry, Infrared and 57Fe Mössbauer spectroscopies, magnetization, electron microscopy (both transmission and scanning) and surface area analysis to comprehend their structural, morphological, hyperfine and magnetic properties before and after P adsorptions. MgFe2O4 and V-modified MgFe2O4 phases (with 30 nm average in “diameter”) govern the nanocomposite magnetic properties and these phases are chemically stable in phosphate-rich effluents. 50 nm in size MgO phase is responsible for P adsorption, but it showed chemical corrosion, as suggested by surface analysis. Adsorption kinetic revealed that there are two controlling steps: film and intraparticle diffusion. The nanocomposite materials fitted better to the Freundlich isotherm model, indicating that the adsorption site distribution for P is heterogeneous, and a multilayer adsorption mechanism is favored. Multicycle reuse experiments with secondary sewage effluent were performed, and the adsorption capability of the V-sample over 3 consecutive adsorption cycles was 11 mg g−1, a value 30 % higher than that found for the S-sample. The desorption efficiency of the V-sample was about 97 %, while the S-sample reached 76 %. The V-substituted composite is a promising nanoadsorbent for water remediation process in phosphate-rich effluents and should be also tested in remediation of other contaminants.

Neutron Reflectivity Study on the Adsorption Layer of Polyethylene Grown on Si Substrate.

To investigate the structure of the interface between polyethylene films and substrates, the neutron reflectivity (NR) of deuterated polyethylene (dPE) thin films deposited on Si substrates was measured, demonstrating water accumulation at the interface, even under ambient conditions. After leaching the thermally annealed dPE films in hot p-xylene, NR measurements were conducted on the layers remaining on the substrate, clearly revealing that the adsorption layer of dPE grew during annealing and consisted of two layers, an inner adsorption layer and an outer adsorption layer, as previously proposed for amorphous polymers. The inner adsorption layer was approximately 3.7 nm thick with a density comparable to that of the bulk. The outer adsorption layer was several nanometers thick and appeared to grow insufficiently on top of the inner adsorption layer under the annealing conditions examined in this study. This study clarifying the growth of the adsorption layer of polyethylene at the interface with an inorganic substrate is useful for improving the performance of polymer/inorganic filler nanocomposites due to the wide utility of crystalline polyolefins as polymer matrix materials in nanocomposites.

Mechanical properties of additively manufactured ultrafine grain stainless steel-titanium boride (SS–TiB2) nanocomposites

Stainless-steel, particularly the 316L alloy, is extensively utilized across diverse industrial sectors. Nonetheless, its inherent limitation of low yield strength poses a significant challenge. In this study, we propose a novel method to address this limitation by incorporating trace quantities of TiB2 nanoparticles into the 316L matrix. The methodology involves a combination of low-energy ball milling for the preparation of the powder feedstock, followed by selective laser melting (SLM) for the fabrication of nanocomposites. The resulting stainless-steel nanocomposite exhibits a nearly-full dense structure characterized by the uniform dispersion of TiB2 nanoparticles (30–40 nm in diameter) within the matrix grain interiors and at grain boundaries. This leads to a substantial refinement in the matrix grain and a remarkable enhancement in mechanical properties. Specifically, the incorporation of 3 vol% TiB2 nanoparticles results in substantial enhancements in tensile yield strength (90.5 %), microhardness (81.4 %), ultimate strength (78.03 %) and bulk modulus (75.2 %) at room temperature compared to plain SLMed stainless-steel. This notable enhancement arises from the uniform dispersion of TiB2 nanoparticles and grain refinement, achieved without discernible processing defects such as agglomeration or interface microcracks. These findings offer a promising avenue for enhancing the mechanical characteristics of stainless-steel-based nanocomposites, thereby expanding their applicability in demanding engineering environments.

Utilizing a novel green ternary polymeric nanocomposite material to remove tetracycline antibiotic effectively from aqueous solutions

Utilizing a novel green ternary polymeric nanocomposite material to remove tetracycline antibiotic effectively from aqueous solutions

Ultrafast laser-induced topochemistry on metallic glass surfaces

Manufacturing multifunctional nanocomposite materials and engineered surface nanopatterns involves a strategic blend of topography, crystal structures, and chemistry. Here, we report the controllable formation of crystalline nanoparticles and intermetallic compounds on thin films of metallic glasses (Zr50Cu50, Ti50Cu50, and Zr67Ag33) irradiated by ultrafast laser beams. Mapping the structural modification of the photoexcited and subsequently heated alloys reveals previously neglected chemical reactions with air, offering a direct solution for incorporating nanoparticles into an amorphous oxide matrix and broadening the range of laser-induced surface self-organization features. Our findings are attributed to the occurrence and enrichment of oxygen surface contamination that reacts with selected elements of the metallic glasses. Additionally, the growth of the crystalline phase from undercooled liquid may originate from the dissolution of oxides. Finally, our results establish that the combination of crystalline nanoparticles on amorphous periodic patterns can be universally obtained in a wide range of binary systems of irradiated metallic glasses.

Electrical conductivity of polyvinyl alcohol/carboxymethyl cellulose doped by zinc oxide and hematite nanoparticles for optoelectronics devices

This research explores polymer nanodielectrics, a category of materials where nanoceramic fillers are incorporated into polymers. These hybrid materials are gaining significant interest because of their tunable optical and electrical characterization, making them potentially well-suited for applications in flexible optoelectronic and organic electronic devices. Polyvinyl alcohol (PVA), Carboxymethyl cellulose (CMC), zinc oxide (ZnO), and hematite (Fe2O3) nanoparticles were utilized to fabricate PVA/CMC-ZnO/Fe2O3 films XRD analysis indicated a reduction in the crystalline character of the PVA/CMC blend following the doping of ZnO/Fe2O3 nanoparticles (NPs). FTIR data approved the complexation between the PVA/CMC blend and the ZnO/Fe2O3, leading to a decrease in intermolecular interactions within the polymeric matrix and coordination with the ZnO/Fe2O3. Electrical analysis obtained an enhancement in σac values with the increase of ZnO/Fe2O3 NPs concentration up to 30 min of laser ablation times The findings from this study suggest the promise of these materials for applications in high-performance batteries, supercapacitors, or other next-generation energy storage and conversion devices.

Organo-Mediated Ring-Opening Polymerization of Ethylene Brassylate from Cellulose Nanofibrils in Reactive Extrusion.

Ethylene brassylate is a renewable macrolactone from castor oil that can be polymerized via ring-opening polymerization (ROP) to obtain a fully biosourced biodegradable polyester. ROP mediated by organometallic catalysts leads to high molar mass poly(ethylene brassylate) (PEB). However, the use of metal-free organocatalysis has several advantages, such as the reduction of toxic and expensive metals. In this work, a novel cellulose nanofibril (CNF)/PEB nanocomposite fabrication process by organocatalysis and reactive extrusion (REx) is disclosed. Here, ROP was carried out via solvent-free REx in the presence of CNFs using organic 1,5,7-triazabicyclo[4.4.0]dec-5-ene as a catalyst. Neat or lactate-esterified CNFs (LACNF) were used as initiators to investigate the effect of surface topochemistry on the in situ polymerization and the properties of the nanocomposites. A molar mass of 9 kDa was achieved in the presence of both unmodified and LACNFs with high monomer conversion (>98%) after 30 min reaction in a microcompounder at 130 °C. Tensile analysis showed that both nanofibril types reinforce the matrix and increase its elasticity due to the efficient dispersion obtained through the grafting from polymerization achieved during the REx. Mechanical recycling of the neat polymer and the nanocomposites was proven as a circular solution for the materials' end-of-life and showed that lactate moieties induced some degradation.