Cementitious Composites Research Articles

Development and characterisation of myristic acid-paraffin wax, silica fume and zinc oxide cementitious composites for thermal control in buildings

This study focuses on the development of a cement-based phase change material (CBPCM) to improve thermal performance in construction applications. The CBPCM was synthesised by blending 90 wt% of myristic acid with 10 wt% of paraffin wax, absorbed into 10 wt% of silica fume to prevent leakage. Additionally, 5 wt% of zinc oxide was added to improve thermal conductivity. A leakage test conducted with 10 wt% of SF exhibited no signs of leakage during thermal cycling. Scanning electron microscopy (SEM) established the uniform dispersion of the nano-enhanced phase change material (NEPCM) within the cement. Fourier transform infrared spectroscopy (FTIR) analysis revealed no chemical structure changes after 100 thermal cycles. Thermogravimetric analysis (TGA) confirmed thermal stability in the temperature range of 74.8–236.64 °C with a mass loss of 6.3 wt%. The material demonstrated minimal variation in phase change temperatures and latent heats after 100 cycles. The latent heat of the CBPCM was 1.09 J/g during melting and 1.887 J/g during solidification. Incorporating NEPCM into the cement increased the thermal conductivity of the cement matrix to 0.559 W/m K. These findings underline the potential of the CBPCM for energy-efficient construction, offering enhanced thermal storage, stability, and conductivity.

Performance Assessment of a Novel Green Concrete Using Coffee Grounds Biochar Waste

An actual scientific problem in current concrete science is poor knowledge of the problem of modifying concrete with plant waste. At the same time, plant waste benefits from other types of waste because it is a recycled raw material. A promising technological approach to modifying concrete with plant waste is the introduction of components based on the processing of coffee production waste into concrete. This study aims to investigate the use of biochar additives from spent coffee grounds (biochar spent coffee grounds—BSCG) in the technology of cement composites and to identify rational formulations. A biochar-modifying additive was produced from waste coffee grounds by heat treatment of these wastes and additional mechanical grinding after pyrolysis. The phase composition of the manufactured BSCG additive was determined, which is characterized by the presence of phases such as quartz, cristobalite, and amorphous carbon. The results showed that the use of BSCG increases the water demand for cement pastes and reduces the cone slump of concrete mixtures. Rational dosages of BSCG have been determined to improve the properties of cement pastes and concrete. As a result of the tests, it was determined that the ideal situation is for the BSCG ratio to be at a maximum of 8% in the concrete and not to exceed this rate. For cement pastes, the most effective BSCG content was 3% for concrete (3%–4%). The compressive and flexural strengths of the cement pastes were 6.06% and 6.32%, respectively. Concrete’s compressive strength increased by 5.85%, and water absorption decreased by 6.58%. The obtained results prove the feasibility of using BSCG in cement composite technology to reduce cement consumption and solve the environmental problem of recycling plant waste.

Investigating the interfacial vertical shear behavior of BFPMPC mortar and cement concrete with pothole repair

Magnesium phosphate cement (MPC) has both traditional cement properties and ceramic properties with fast setting and hardening characteristics. To rapidly reopen traffic and extend its service life, MPC has been widely used in the rapid repair of highway and airport cement concrete pavement. This study utilizes basalt fiber-reinforced polymer-modified magnesium phosphate cement (BFPMPC) developed in previous research to rapid repair the typical potholes on cement concrete pavement, aims to reveal the interface properties between BFPMPC mortar and cement concrete and further investigate the underlying mechanisms for such properties. Firstly, the optimal mixture ratio was determined by orthogonal test design. Then, the shear strength of the repair interface was measured by composite BFPMPC mortar and cement concrete specimens. The mechanical characteristics of the repair interface and the microscopic mechanism were characterized by nano-indentation technology and SEM/EDS. Finally, the interface constitutive model was established by DIGIMAT and finite element model was developed to simulate the interface failure. Results showed that the no new hydration products were produced by the addition of polymer in BFPMPC. BFPMPC matrix became denser with the increase of age, resulting in the better bonding between fiber and paste. The interface vertical shear strength at 6 h and 3 d were 3.1 MPa and 3.9 MPa, respectively. SEM/EDS results showed that polymer has a certain self-healing ability to decrease the crack width with increase of curing age, and a variety of inclusions in the repair interface were observed. The elastic modulus of each inclusion phase can be effectively analyzed by nanoindentation. The simulation results showed that the pressure on upper surface of BFPMPC mortar transfers to the bottom through the repair interface. As the tensile stress on the bottom over the maximum interface tensile stress, the cracks were extend from the bottom to upper, then the structure was failed. Interface vertical shear strength of numerical simulation was, respectively, 3.149 MPa and 3.957 MPa. It is close to the plain shear strength experimental value, validating the proposed interface constitutive relationship.

Efficient sealing of cemented sheath: An oil-responsive self-healing latex with toughness enhancement for cement composites

The integrity of the cemented sheath is important to the safe exploration of oil and gas resources. Sealing failure of cement sheath will result in formation fluid channeling and pressure carryover in the annulus. The both toughening and oil-responsive self-healing latex (TOS) was prepared to achieve efficient sealing of cemented sheath, and prolong its service life. The structure and oil swelling behavior of TOS, its toughening and self-healing effects on hardened cement paste (HCP) were analyzed by comprehensive characterizations. Results demonstrated that TOS possessed excellent stability and an oil swelling rate of 1235 %. Cement specimens by curing 28d containing 8 % TOS exhibited a 27.8 % increase in flexural strength, a 48.7 % reduction in elasticity modulus and a 33.8 % reduction in brittleness coefficient. The addition of TOS can effectively improve the toughness of cement. The average pore size of specimens containing 8 % TOS admixture decreased to 9.17 nm. This indicates that TOS enhanced the structural density of cement materials. The crack about 103μm in the cracking specimens with 8 % TOS was almost healed, and the corresponding permeability was reduced 99.1 % after curing in oil. Adsorption and film formation of TOS can resist the cracking of cement sheath, and the oil swelling expansion of film in cement matrix can repair the cracked structure.

Passivation behavior of reinforcement in simulated pore solutions of composite cement incorporating ultrafine steel slag and blast furnace slag

The steel slag and ground granulated blast furnace slag with high fineness exhibit synergistic effects on hydration progress and can be introduced into concrete in high volume. In this paper, the simulated pore solution (SPS) of ternary cement incorporating ultrafine steel slag (US) and ultrafine ground granulated blast furnace slag (UG) was prepared to examine the passivation behavior of the HRB400 reinforcing steel under SPS. It is found that the rapid growth of passive films occurs primarily within the initial 2–3 days after immersion in the SPS, while the compaction of passive films takes place mainly at the later stages. The open circuit potential and charge transfer resistance of the passive films initially increase and then decrease with the continuous rise in the US content. The Fe2O3 constitutes a significant portion of the passive films above the steels treated with the SPS irrespective of US dosages, whereas the content of FeO is highly influenced by US dosages. The UG-US-C pore solution could enhance the passivation behavior because of lower Ca2+ and higher Na+. In case of UG/US ratio at 2:3, the passive film exhibits the greatest thickness at 7.5 nm and meanwhile with the highest compaction and the least roughness.

Cyclic loading effects on the heat-generation performance of carbon nanotube-embedded cement composites

Abstract This study investigates the heat-generation stability of carbon nanotube (CNT)/cement composites after exposing to cyclic loading conditions. The specimens were fabricated with varying CNT contents and levels of fly ash replacement. Results showed that increasing CNT content reduced electrical resistivity, while the impact on the electrical characteristics was found to be insubstantial, even though a considerable portion of fly ash was replaced. In addition, the electrical resistivity of the specimens after exposed to cyclic loading increased. Electrical heating tests revealed both negative and positive temperature coefficient effects depending on the applied voltages. Higher CNT contents improved the heat-generation capability, but the heating capability decreased after exposed to the cyclic loadings which is deduced from the damage of CNT networks during cyclic loadings. In this regard, the authors concluded that the heat-generation stability can be significantly affected by the applied loadings. Thus, the future research will be conducted to improve the heat-generation stability of the cement-based electrical heating systems as exposed to artificial deteriorations.

Mesoscale Modeling of Microcapsule-Based Self-Healing Cementitious Composites under Dynamic Splitting Tension

Microcapsule-based self-healing cementitious composite (MSCC) offers autonomous damage repair, extending the service life of structures. However, most of the existing studies focus on static behavior and healing effectiveness but rarely explore dynamic responses. This study developed the mesoscale modeling approach to investigate MSCC behavior under dynamic split tensile loading. At the mesoscale, MSCC can be treated as a four-phase composite consisting of coarse aggregates, interfacial transition zones, cement mortar, and microcapsules. Alternatively, it can be simplified as a two-phase composite comprising a homogeneous mortar matrix and microcapsules. Four-phase and two-phase mesoscale MSCC models were developed for 2D simulations, while a two-phase 3D model was also developed for comparison. Mesoscale numerical simulations were conducted based on Split-Hopkinson Pressure Bar Brazilian disk-splitting tests, considering various strain rates. Simulation results of different mesoscale models were compared with experimental results. All of the models accurately predicted the tensile strength of MSCC, with the 2D four-phase model providing the best representation of failure modes and crack propagation. Both experimental and numerical data exhibited obvious strain rate effects, indicating that MSCC’s mechanical properties were sensitive to the loading rate. Dynamic increase factors were obtained, quantifying rate sensitivity. The obtained dynamic mechanical properties of MSCC provide insights for designing MSCC components and structures that can better withstand collisions or explosions.

Shear performance of perfobond leiste (PBL) connectors in engineered cementitious composites (ECC)

Substituting normal concrete with ductile Engineered Cementitious Composites (ECC) is a promising way to address the safety and durability issues caused by cracking in steel-concrete composite structures. To realize a synergistic deformation behavior between steel and ECC, Perfobond Leiste (PBL) shear connectors are preferred to be used owing to their superior shear resistance, shear stiffness, and excellent fatigue performance. This research comprehensively investigated the shear performance of PBL connectors in ECC through experimental, numerical, and analytical approaches. Firstly, the shear load-slip relationships of PBL connectors in ECC and concrete were studied through push-out tests of 36 H-shaped specimens. It indicated that the fracture of penetrating bars dominated the final failure of PBL connectors in ECC, whereas premature concrete spalling happened in concrete specimens. By establishing a refined finite element model, the parametric study was then conducted to clarify the influence of the compressive strength of ECC, hole diameter, penetrating bar diameter, and penetrated plate thickness on the shear characteristics of PBL connectors in ECC. Finally, an analytical model for predicting the shear carrying capacity of PBL connectors embedded in ECC was derived, matching well with the test results.

Alkali-Silica Reaction and Residual Mechanical Properties of High-Strength Mortar Containing Waste Glass Fine Aggregate and Supplementary Cementitious Materials

This paper presents the influence of supplementary cementitious materials (SCMs), such as fly ash (FA), silica fume (SF), ground granulated blast furnace slag (GGBS), and waste glass fine aggregate (GA), on the alkali-silica reaction (ASR) in high-strength and normal-strength mortar using an accelerated mortar bar test (AMBT). Residual mechanical properties and scanning electron micrographs were used to assess the changes in the matrix. GA reduced the mechanical properties of both normal-strength (NGA_OPC) and high-strength mortars (HGA_OPC), contributing to a decline in overall performance. This phenomenon was a result of the slipping of the GA from the matrix owing to its smooth surface. However, the inclusion of reactive SF and GGBS in the HGA improved the slip phenomenon of the GA, leading to a significant enhancement in its mechanical properties. Following the ASR expansion measurement, HGA_OPC demonstrated an ASR expansion rate approximately three times higher than that of NGA_OPC. This was attributed to the dense structure of HGA_OPC, which resulted in greater expansion than that of NGA_OPC. However, with the incorporation of SCMs into both HGA and NGA, a significant reduction in ASR expansion was observed. This was attributed to the delayed ASR of GA due to alkali activation or the pozzolanic reaction of the SCMs. Continuous exposure to the AMBT environment can lead to the destruction of GA. This was caused by the inner ASR that originated from the surface crack of the GA, which resulted in a reduction in the flexural strength of the mortar. The HGA with SF exhibited the highest resistance to ASR expansion and residual mechanical properties’ degradation. Therefore, various durability and long-term performance-monitoring studies on ultra-high-performance concrete or high-strength cementitious composites with very high SF contents and GA can be conducted.

Performance of normal-weight and lightweight 3D printed cementitious composites with recycled glass: Sorption and microstructural perspective

The development of sustainable mixtures has been a widely researched topic in the last decade, as the cement and concrete industries are among the most polluting sectors. Recycled materials can eliminate the need for extraction of natural materials through re-utilization of waste, reducing the environmental impact. To date, few studies have analyzed the effects of incorporating recycled glass aggregates on the water transport properties and microstructure of 3D printable mixtures.This study assesses the feasibility of incorporating recycled glass as a replacement for natural aggregate in 3D printable mixtures. For this purpose, three normal-weight and three lightweight mixtures containing 0, 50, and 100 vol.% of recycled glass aggregate as basalt aggregate replacement were evaluated in cast and printed samples. Expanded thermoplastic microspheres (ETM) were included to create the lightweight mixture composition. This experimental work evaluated the effects of incorporating recycled glass, ETM, and the impact of the printing process on the microstructure, sorption, and capillary water porosity (CWP).The printing process has proven to be an influential factor affecting the shape, size, and quantity of porosity. In addition, the printing process was demonstrated to be more influential on porosity formation than the inclusion of recycled glass or ETM. Incorporating recycled glass results in a slight decrease in the PHg porosity, more spherical pores, and lower anisotropic tendency. Furthermore, adding ETM has a filling effect, leading to a more compact microstructure.

Synergistic enhancement of g-C3N4/CoAl-LDH nanoflower and mineral admixtures on the properties of nano-engineered cementitious composites

The nano-engineered cementitious composites (NCC) were prepared using g-C3N4/CoAl-LDH nanoflower (nano-CN/L), in combination with mineral admixtures including fly ash (FA), metakaolin (MK), and ground granulated blast furnace slag (GGBFS). The synergistic effects and mechanisms of nano-CN/L and mineral admixtures on the mechanical, chloride penetration resistance and air purification properties of NCC were investigated. The results show that nano-CN/L promotes the early hydration of cementitious materials and improves the composition and morphology of C-S-H gel. Furthermore, the filling effect of nano-CN/L significantly optimizes the pore structure and interfacial crack width of NCC, thereby eliminating the adverse impact of FA, MK, and GGBFS on its early mechanical strengths. Additionally, nano-CN/L enhances the chloride penetration resistance and NOx removal properties of NCC through its strong ion adsorption and photocatalytic activity, respectively. Incorporating 0.9 % nano-CN/L by mass of cementitious materials reduces the chloride diffusion coefficient of NCC at curing age of 56d by 26.9 % and increases the NOx removal ratio by 11 times. The 7d’s compressive and flexural strengths of NCC increase by 13.6 % and 4.6 %, respectively, compared to the one without nano-CN/L. As a novel multifunctional nanomaterial, nano-CN/L not only provides a new pathway for extending the service life of cementitious composites, but also injects new momentum into their environmental-friendly development.

High-volume recycled glass cementitious and geopolymer composites incorporating graphene oxide

This study presents the development of high-volume recycled glass construction materials using recycled glass aggregate (RGA) as a 100 % sand replacement, recycled glass powder (RGP) as 40 wt% of the binder, and 0.1 wt% graphene oxide (GO) as nano-reinforcement. The research investigates the individual and their combined effects on the engineering performance, reaction kinetics (using calorimetry, X-ray diffraction-XRD, Fourier Transform Infrared-FTIR and Thermogravimetric analysis-TGA), and microstructure (Scanning Electron Microscopy/ Energy Dispersive X-ray Spectroscopy-SEM/EDS) for both cementitious and geopolymer systems. The results indicate that while RGA reduces strength and exacerbates alkali-silica reaction (ASR), the presence of 40 wt% RGP significantly mitigates ASR despite a lower strength gain in both systems. Geopolymers exhibit significantly lower ASR expansion compared to cementitious matrices owing to their superior alkali-binding capacity and denser microstructure, which restricts water and alkali ion mobility. 0.1 wt% GO was found to accelerate geopolymerisation, enhancing the strength of geopolymer mixes, but it decreased compressive strength in cement-based mixes due to self-desiccation-induced micro-cracking under ambient curing condition. The study also highlights that cement and metasilicate, as well as slag, are the main contributors to cost and CO2 emissions in cementitious and geopolymer systems, respectively. Overall, geopolymers exhibit a significantly lower global warming potential (< 180 kg CO2-eq/m3) compared to cement-based mixes (> 365 kg CO2-eq/m3) with a comparable cost (190–230 AUD/m3). The results indicate the potential for sustainable construction applications using high volumes of recycled glass, incorporating over 70 % of the mixture by weight.

Development of engineered polymeric reinforced cementitious composite (EPRC) using nature-inspired hollow architectures: Flexural experimental and numerical evaluations

This study explores the integration of nature-inspired architectural designs into Mechanics of Materials (MoM)-based reinforcement layouts for reinforced cementitious composites (RCs). While traditional MoM layouts focus on longitudinal rebars for tensile strength, this study aims to enhance the flexural properties of RCs by incorporating nature-inspired elements like hollow tubes found in plant stems. The research utilizes both experimental and numerical methods to evaluate the flexural performance of engineered polymeric reinforced cementitious composites (EPRCs) with integrated nature-inspired motifs. A numerical model, based on the material properties of reinforcing elements and the cementitious matrix, was developed to simulate the flexural performance of EPRCs reinforced with both solid and hollow bars, including MoM-based solid and hollow rebars. The model's predictions were validated through experimental testing of 3D-printed MoM-based solid and hollow rebars under three-point bending conditions. The results demonstrated that EPRCs reinforced with hollow rebars exhibited significantly improved flexural properties compared to those with solid rebars. Specifically, the hollow-reinforced samples achieved an average modulus of rupture of 8.68 MPa, toughness of 11.76 N m, and mid-point deflection of 1.99 mm, representing increases of 34 %, 55 %, and 93 %, respectively, over their solid counterparts. These enhancements are attributed to improved shear reinforcement and bond strength despite the reduced moment of inertia of the hollow rebars. The study provides valuable insights for optimizing the mechanical properties of RCs in civil engineering applications through the incorporation of nature-inspired architectural designs.

Mechanical properties and durability of lightweight cenosphere cementitious composites under coupling effect of dry-wet cycles and salt erosion

Cenospheres are suitable as supplementary cementitious materials to partially replace cement in the production of environmentally friendly lightweight cenosphere cementitious composites (LCCC). In this study, the correlation between the content and particle size of the cenosphere, the early curing system and the performance of LCCC was analyzed. The macroscopic properties and microstructural changes of LCCC under the conditions of dry-wet cycles and salt erosion were studied with different early curing conditions. The durability changes of LCCC mortar under the coupling effect of salt erosion and dry-wet cycles were studied by examining the mass loss rate, relative dynamic modulus of elasticity and salt corrosion resistance coefficient of LCCC mortar. Finally, a comparative analysis of the impact of existing cracks on the performance of LCCC under the coupling effect of dry-wet and salt erosion was conducted. The main innovation of the study includes the mechanical properties and durability of LCCC under dry-wet-salt erosion conditions, as well as the clarification of the impact of prefabricated cracks on the mechanical properties and durability of LCCC. It is found that the flexural strength and the compressive strength of specimens cured at high temperature is generally lower than that of the specimens cured under normal temperature conditions. The wet-dry salt corrosion can exacerbate the erosion the outer shell and inner wall of cenospheres and disrupt the stability of the internal interface transition zone (ITZ) in LCCC. LCCC with CsS exhibits better macroscopic performance and microstructural properties. Pre-existing cracks accelerates the erosion in the cenosphere shell and inner wall under salt solution.

Experimental and simulation study on seismic performance of seawater sea-sand PVA cementitious composite columns with GFRP bars

The seismic properties of seven seawater sea-sand (SWSS) PVA cementitious composite columns with Glass Fiber Reinforced Polymer (GFRP) bars were studied. The effects of four parameters, namely polyvinyl alcohol (PVA) fiber content, axial compression ratio, cementitious composite strength and stirrup spacing, on the seismic performance of composite columns were analyzed. The failure of the specimen was observed, and the hysteresis curve, skeleton curve, stiffness degradation, energy dissipation capacity, ductility and strain of the specimen were analyzed. The test results show that the large chip-based spalling will occur when the specimen without fiber incorporation is damaged, and the incorporation of PVA fiber, the reduction of stirrup spacing and the reduction of axial compression ratio will delay the rate of crack formation and development. In addition, through cross-section analysis and considering the reinforcement effect of PVA fibers, a proposed formula for calculating the horizontal bearing capacity of composite columns is proposed. Finally, the finite element model of SWSS PVA cementitious composite columns with GFRP bars is established, and it is found that increasing the strength grade of cementitious materials can greatly improve the seismic performance of composite columns. The conclusions could be references for the engineering application. In the context of the global emphasis on green development and environmental protection, seawater and sea-sand cementitious composites and components with fiber reinforcement will have a wide range of application prospects in the construction of coastal areas.

A novel conceptual design for self-healing of cracked cementitious composites incorporating two bacteria-based capsules

Expanded polystyrene (EPS) is a low-density material prone to float during composite mixing and vibration. Inspired by this, a two-bacteria-capsule system was reported in this study to enhance the self-healing capacity of cracked mortar. Specifically, the BC-A capsule, containing aerobic bacteria, EPS, and superabsorbent polymer (SAP), and the BC-N capsule, containing anaerobic bacteria and SAP, are prepared through granulation using polyethylene glycol. Sulphoaluminate cement and epoxy resin are used to encapsulate the core materials. The BC-A capsules automatically float in the composite preparation process, while the BC-N capsules are distributed in the middle and bottom regions due to extrusion effect. Upon capsule rupture, the two types of bacteria are released in regions favorable for biomineralization, corresponding to the principle that oxygen concentration reduces along the crack depth. The self-healing behaviour was evaluated as well as the healing products were characterized. The results showed that the capsules cracked simultaneously with the composite and the coating effectively avoided premature release of the self-healing materials. Cementitious composites containing double capsules achieved 90 % closure of cracks with initial widths of 50–600 μm. The three-dimensional healing capacity was significantly enhanced, particularly in terms of impermeability and strength recovery ratio. The main healing products in the cracks were calcite and swollen SAP. The swollen SAP provided nucleation sites and enough water for biomineralization in the healing process.

Bio-inspired 3D printing of strain-hardening cementitious composites reticulated shell roofs

Inspired by the diving bell structure of the water spider, this study presents an innovative 3D printed strain-hardening cementitious composite (3DP-SHCC) reticulated shell roof. The compressive behavior of the 3DP-SHCC reticulated shell roof is evaluated using a combination of experimental tests and numerical simulation approaches. The 3DP-SHCC reticulated shell roof features excellent mechanical properties and an aesthetically pleasing appearance. The specific energy absorption and ductility index of this structure are 0.065 J/g and 0.078, respectively. The feasibility of this concept is validated by constructing a complete building structure within just 16 min. This printing process has the potential to create complex designs with minimal labor, making it suitable for rapid construction in extreme environments.

Cerium as a crystalline phase stabilizer of α-TCP and its hydration and photothermal properties

Bone cement with photothermal properties can treat bone defects caused by bone tumors while killing residual tumor cells or preventing recurrence. In this study, trace amounts of cerium ions were introduced to enhance the crystal stability of α-TCP, thereby improving the hydration properties of α-TCP and obtaining excellent photothermal properties. The experimental results showed that the content of α-TCP in CON-TCP was 96.05 %, and the content of α-TCP in 1% Ce-TCP was 99.77 %, with an increase of 3.87 %; the compressive strength of 0.5% Ce-CPC hydrated for 5d increased from 16.6 MPa±2.18 MPa to 32.16 MPa±2.77 MPa, with an increase of 93.73 %. The temperature of 0.5% Ce-CPC can be raised to 50.9°C in two minutes under the irradiation of 808 nm laser, which is an increase of 31.5% compared with that of 38.7°C in the blank group. Therefore, trace cerium-doped calcium phosphate bone cement has excellent physicochemical and photothermal properties, and it is a promising composite bone cement material, and the results of the present study are expected to be used to treat bone defects in bone tumors.

High-modulus engineered cementitious composites: Design mechanism and performance characterization

Engineered cementitious composites features with high tensile performance while relatively weak compressive stiffness. This study endeavors to address the inherent trade-off between tensile properties and elastic modulus in conventional Engineered Cementitious Composites (ECC). Utilizing the distinctive characteristics of iron ore aggregates, known for their relatively stiff nature, smooth surface and rounded shape, an Iron Sand-based ECC (IS-ECC) emphasizing both high elastic modulus and ductility is formulated. Guided by micromechanical design theory and multiscale homogenization model, this study systematically explores the impacts of aggregate types, water-to-binder (w/b) ratios, sand-to-binder (s/b) ratios, and sand particle sizes on ECC properties. Compared with Quartz Sand-based ECC (QS-ECC), IS-ECC exhibits notably enhanced matrix fluidity and elastic modulus, reduced matrix toughness, and more robust strain-hardening behavior. The proposed three-level multiscale homogenization model accurately predicts the elastic modulus of ECC and provides insights into the underlying mechanism contributing to the enhanced elastic modulus of IS-ECC. With a resulting high elastic modulus of 33.3–48.6 GPa and superior tensile properties, IS-ECC holds promise for widespread applications in structural engineering.

Nature-inspired approach for enhancing the fracture performance of 3D printed strain-hardening cementitious composites (3DP-SHCC)

3D printing technology enhances design flexibility, enables the creation of complex geometrical structures, facilitates rapid prototyping, and allows the fabrication of micro- and macroscopic structures. This study investigates the use of 3D concrete printing to create Bouligand structures inspired by mantis shrimp. Bouligand-printed strain-hardening cementitious composites (SHCC) with different pitch angles (15°, 30°, 45°, 60°, 75°, and 90°) are fabricated and compared with traditional parallel-printed and mold-cast SHCC. The fracture behavior of these specimens is investigated through three-point bending tests on notched beams. The results reveal that Bouligand-printed specimens exhibit enhanced flexural strength, fracture energy, and fracture toughness, ranging from 0.97 to 1.29 times, 0.99 to 1.63 times and 0.87 to 1.47 times that of the mold-cast specimens, respectively. Bouligand-printed specimens with a pitch angle of 30° exhibits the highest flexural strength, fracture energy, and fracture toughness. The Bouligand-printed SHCC enhance toughness through the synergistic effects of crack twisting and bridging. A finite element model integrating cohesive elements with the concrete plastic damage model is developed to numerically replicate the experimental process. This study highlights the potential of 3D concrete printing for the fabrication of biomimetic concrete structures with superior fracture performance.