Intrusive Complex Research Articles

Type intrusive series of the Far East belt of lithium-fluoric granites and its ore content

The evolution and ore content of granitoid magmatism in the Far East belt of lithium-fluoric granites lying in the Russian sector of the Pacific ore belt have been studied. Correlation of intrusive series in the Novosibirsk-Chukotka, Yana-Kolyma and Sikhote-Alin granitoid provinces of the studied region allowed to establish the unity of composition, evolution, and ore content of the Late Mesozoic granitoid magmatism. On this basis, a model of the type potentially ore-bearing intrusive series of the Far East belt of lithium-fluoric granites has been developed: complexes of diorite-granodiorite and granite formations → complexes of monzonite-syenite and granite-granosyenite formations → complexes of leucogranite and alaskite formations → complexes of rare-metal lithium-fluoric granite formation. The main petrological trend in granitoid evolution is increasing silicic acidity, alkalinity, and rare-metal-tin specialization along with decreasing size and number of intrusions. At the end of the intrusive series, small complexes of rare-metal lithium-fluoric granites form. The main metallogenic trend in granitoid evolution is an increasing ore-generating potential of intrusive complexes with their growing differentiation. Ore-bearing rare-metal-granite magmatism of the Russian Far East developed in the Late Cretaceous and determined the formation of large tungsten-tin deposits with associated rare metals: Ta, Nb, Li, Cs, Rb, In in areas with completed intrusive series. Incompleteness of granitoid series of the Pacific ore belt should be considered as a potential sign of blind rare-metal-tin mineralization. The Far East belt of lithium-fluoric granites extends to the Chinese and Alaskan sectors of the Pacific belt, which allows the model of the type ore-bearing intrusive series to be used in the territories adjacent to Russia.

Geoscience Poster G15: Seismic, petrophysical and petrological constraints on the alteration of igneous rocks in the Northern Carnarvon Basin, Western Australia: implications for petroleum exploration and drilling operations

Poster G15 The Northern Carnarvon Basin (NCB) hosts an extensive record of Jurassic–Cretaceous rift-related igneous activity, manifested by a >45 000 km2 intrusive complex and series of volcanic centres constrained by seismic mapping. However, there are relatively few well penetrations of these igneous rocks (<1% of ~1500 exploration wells) in comparison to other basins that witness extensive magmatism, and thus, their lithological and petrophysical characteristics are poorly understood. Here, we describe the properties of igneous rocks encountered in nine petroleum exploration wells and scientific boreholes in the NCB and evaluate their impacts on exploration and development issues. Igneous rocks in the NCB are characterised by pervasive alteration, with ramifications for seismic imaging and drilling. For example, low acoustic velocities in mafic lavas altered to clays in Toro-1 were mistaken for overpressure, whilst intrusive rocks in Palta-1 were initially unrecorded and only recognised due to subsequent post-drilling thermal history analysis. The alteration of mafic igneous rocks to clays reduces acoustic impedance contrasts relative to sedimentary host rocks, making their identification prior to drilling more challenging. Whilst the preferential emplacement of intrusive rocks in Triassic strata deeper than reservoir targets is primarily responsible for the paucity of well penetrations, our findings of extensive alteration of igneous rocks in the NCB suggests that additional wells may intersect as yet unrecognised intrusive or extrusive sequences. To access the poster click the link on the right. To read the full paper click here

Geochemistry of granitoids from the Austroalpine Seckau Complex: a key for revealing the pre-Alpine evolution of the Eastern Alps

Recent studies revealed that the calc-alkaline metagranitoids of the Seckau Complex comprise both (1) a Late Cambrian to Early Ordovician and (2) a Late Devonian to Early Carboniferous (early Variscan) intrusive complex. The older rocks of the Hochreichart Plutonic Suite reflect I to S-type affinity and are peraluminous and characterized by a general decrease in TiO2, Al2O3, MgO, CaO, P2O5, FeOt and MnO with increasing SiO2. Chondrite-normalized rare earth element (REE) plots display a slight enrichment in light rare earth elements (LREE) relative to heavy rare earth elements (HREE) as well as negative Eu anomalies ((Eu/Eu*)N = 0.15- 0.77). The whole-rock initial 87Sr/86Sr ratios calculated back to the time of emplacement (~ 496 Ma) vary between 0.7056 to 0.7061. The early Variscan rocks of the Hintertal Plutonic Suite can be subdivided into (a) the meta- to peraluminous granodioritic suite of the Pletzen Pluton and (b) the peraluminous granitic suite of the Griessstein Pluton. The Pletzen Pluton shows typical magmatic fractionation trends for most of the major oxides and trace elements plotted against SiO2. On a chondrite-normalized diagram, metagranitoids are strongly enriched in LREE and show no significant negative Eu anomaly. Metagranitoids of the Griessstein Pluton have a more peraluminous character and similar major and trace element fractionation trends compared to the Pletzen Pluton. However, the contents in SiO2, major and trace elements clearly point towards a more evolved melt with generally lower TiO2, Al2O3, MgO and CaO values and higher K2O content. Metagranitoids of the Griessstein Pluton are additionally characterized by a slight negative Eu anomaly of about 0.81 on a chondrite-normalized REE plot. Initial 87Sr/86Sr values calculated back to the time of emplacement (~ 353 Ma) of the Pletzen Pluton and the Griessstein Pluton vary between 0.7051—0.7061 and 0.7054—0.7063, respectively, and suggest the same magmatic source for both units. Application of rhyolite-MELTS modelling to the Hintertal Plutonic Suite revealed that the Griessstein Pluton formed by fractional crystallization (~ 30%) from the more primitive Pletzen Pluton. Our geochemical data from the Hochreichart Suite granitoids suggest the existence of a Late Cambrian to Early Ordovician active margin with its remnants now exposed in the Seckau Complex. The early Variscan grainitoids of the Seckau Complex are inferred as part of a magmatic arc along the southern Bohemian active continental margin that was related to the subduction of differently termed oceanic domains (Galicia-Moldanubian Ocean or Paleotethys), prior to the final collision of Gondwana and Laurussia. The general paleogeographic position of the Seckau Complex during the Variscan orogeny is considered to be south to southeast of the Bohemian Massif, adjacent to the eastern Hohe Tauern, the Schladming Tauern, and the Western Carpathians.

Late Cretaceous volcanic arc magmatism in southeast Anatolian Orogenic Belt: Constraints from whole‐rock, mineral chemistry, Sr–Nd isotopes and U–Pb zircon ages of the Baskil Intrusive Complex (Malatya, Turkey)

The voluminous intrusive and extrusive magmatism was formed in the Elazığ‐Malatya region of the Southeast Anatolian Orogenic Belt (SAOB) as a consequence of the continental collision and/or convergent orogeny. The SAOB holds a great number of stratigraphic, metamorphic and tectonomagmatic units in the Elazığ‐Malatya region that are crucial for recognition of the geodynamic setting of southeast Anatolia during the Upper Cretaceous. The Baskil Intrusive Complex (BIC) is composed of mainly tonalitic/granodioritic and dioritic/gabbroic plutonic rocks, while its sub‐volcanic phase is represented by granophyre, aplite and microgabbro, which were intruded into the Upper Cretaceous supra‐subduction zone (SSZ)‐type İspendere ophiolites (SE Turkey). New U–Pb laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) zircon data provided crystallization ages ranging from 84.3 to 81.5 Ma for the BIC. Mafic and felsic rocks of the BIC have a low‐ to medium‐K calc‐alkaline, I‐type, metaluminous character, whereas extremely evolved felsic rocks of this complex show a peraluminous composition. The aluminium‐in‐hornblende barometery (~196 to 299 MPa) of magnesio‐hornblendes in the Baskil intrusive rocks indicates their emplacement in the shallow‐ to moderate crustal plutonic levels at a minimum of 7.3 km to a maximum of 11.1 km depth. The Baskil intrusive rocks present depletion in Ti, Nb, Ta, light REE with respect to primitive mantle, and relative enrichment in large‐ion lithophile element (Rb, Ba, Pb, Sr, Th), thus infer a pronounced subduction signature. Both mafic and felsic intrusives show low initial 87Sr/86Sr ratios (0.70357–0.70561) together with a high initial 143Nd/144Nd ratios (0.51279–0.51289), and high ƐNd(T) values (5.0–7.0) and relatively young Nd crustal residence model ages (TDM = 0.31–0.48 Ga). Based on our field, mineralogical and geochemical findings, we suggest that the BIC was originated from an amphibolitic source that interacted with subducted crust within SSZ and was changed by fluids during the early stages of the short‐lived volcanic arc magmatism that evolved at the fringe of the Tauride Platform.

Seismic, petrophysical and petrological constraints on the alteration of igneous rocks in the Northern Carnarvon Basin, Western Australia: implications for petroleum exploration and drilling operations

The Northern Carnarvon Basin (NCB) hosts an extensive record of Jurassic–Cretaceous rift-related igneous activity, manifested by a >45 000 km2 intrusive complex and series of volcanic centres constrained by seismic mapping. However, there are relatively few well penetrations of these igneous rocks (<1% of ~1500 exploration wells) in comparison to other basins that witness extensive magmatism, and thus, their lithological and petrophysical characteristics are poorly understood. Here, we describe the properties of igneous rocks encountered in nine petroleum exploration wells and scientific boreholes in the NCB and evaluate their impacts on exploration and development issues. Igneous rocks in the NCB are characterised by pervasive alteration, with ramifications for seismic imaging and drilling. For example, low acoustic velocities in mafic lavas altered to clays in Toro-1 were mistaken for overpressure, whilst intrusive rocks in Palta-1 were initially unrecorded and only recognised due to subsequent post-drilling thermal history analysis. The alteration of mafic igneous rocks to clays reduces acoustic impedance contrasts relative to sedimentary host rocks, making their identification prior to drilling more challenging. Whilst the preferential emplacement of intrusive rocks in Triassic strata deeper than reservoir targets is primarily responsible for the paucity of well penetrations, our findings of extensive alteration of igneous rocks in the NCB suggests that additional wells may intersect as yet unrecognised intrusive or extrusive sequences.

Petrogenesis of the quartz diorite from the Lietinggang-Leqingla Pb-Zn-Fe-Cu-(Mo) deposit in southern Tibet: Implications for the genesis of a skarn-type polymetallic deposit in the Tibetan-Himalayan collisional orogen

The Lietinggang-Leqingla deposit is a representative skarn-type polymetallic deposit in the eastern of the central Lhasa subterrane. It comprises Pb-Zn and Fe-Cu-(Mo) mineralization that are part of the same metallogenic system. Garnet-skarn hosting Fe-Cu-(Mo) mineralization distributed in the contact zone between the Jubuzhari complex intrusions and carbonate strata of the Mengla Formation. The Pb-Zn mineralization is hosted in distal garnet-pyroxene and pyroxene-actinolite skarns, which formed in the strata of Mengla Formation. Here, we investigate quartz diorites (61.06 ± 0.93 Ma) that are related to Fe-Cu mineralization in the northern part of the mining area. The quartz diorites are characterized by low SiO2 (61.57–65.88 wt%), low K2O (2.53–3.07 wt%), and high total alkali (Na2O + K2O) contents (5.69–6.35 wt%). They are enriched in large-ion lithophile elements and light rare earth elements, but depleted in high field strength elements and heavy rare earth elements. The quartz diorites yield variably low (La/Yb)N ratios (4.29–7.07, the average value is 6.36) with moderately negative Eu anomalies (Eu/Eu* = 0.49–0.72). Furthermore, they exhibit a narrow range in (87Sr/86Sr)i ratios (0.706355–0.706807) and weakly negative εNd (t) (−2.08 to −1.57), and positive εHf (t) (+0.14 to +3.46) values. Based on the geochemical characteristics presented in this study and previously published data, we propose that the ore-forming rocks related to Fe-Cu and Pb-Zn mineralization were formed at the same time. The intermediate intrusions associated with Fe-Cu mineralization were derived from partial melting of lithospheric mantle mixed with the rejuvenated lower crustal melts, after which the mixed magma underwent minor fractional crystallization during upwelling. The felsic intrusions associated with Pb-Zn mineralization were formed by melting of mantle-derived basaltic magmas with old lower crust component contributions and which underwent extensive fractional crystallization.

Permeability heterogeneity of sandstone intrusion fluid‐escape systems, Panoche Hills, California: Implications for sedimentary basins globally

AbstractNatural surface gas seeps provide a significant input of greenhouse gas emissions into the Earth’s atmosphere and hydrosphere. The gas flux is controlled by the properties of underlying fluid‐escape conduits, which are present within sedimentary basins globally. These conduits permit pressure‐driven fluid flow, hydraulically connecting deeper strata with the Earth’s surface; however they can only be fully resolved at sub‐seismic scale. Here, a novel ‘minus cement and matrix permeability’ method using three‐dimensional X‐ray micro‐computed tomography imaging enables the improved petrophysical linkage of outcrop and sub‐surface data. The methodology is applied to the largest known outcrop of an inactive fluid‐escape system, the Panoche Giant Intrusion Complex in Central California, where samples were collected along transects of the 600 to 800 m stratigraphic depth range to constrain porosity and permeability spatial heterogeneity. The presence of silica cement and clay matrix within the intergranular pores of sand intrusions are the primary control of porosity (17 to 27%) and permeability (≤1 to ca 500 mD) spatial heterogeneity within the outcrop analogue system. Following the digital removal of clay matrix and silica (opal‐CT and quartz) cement derived from the mudstone host strata, the sand intrusions have porosity−permeability ranges of ca 30 to 40% and 103 to 104 mD. These calculations are closely comparable to active sub‐surface systems in sedimentary basins. Field observations revealed that, at decreasing depth, the connected sand intrusion network reduces in thickness and becomes carbonate cemented, terminating at carbonate mounds formed from methane escape at the seafloor. A new conceptual model integrates the pore‐scale calculations and field‐scale observations to highlight the key processes that control sand intrusion permeability, spatially and temporally. The study demonstrates the control of matrix and cement addition on the physical properties of fluid‐escape conduits, which has significance for hydrocarbon reservoir characterization and modelling, as well as subsurface CO2 and energy storage containment assessment.

Diversity of Net-Textured Sulfides in Magmatic Sulfide Deposits: Insights from the Eagle’s Nest Ni-Cu-(Platinum Group Element) Deposit, McFaulds Lake Greenstone Belt, Superior Province, Canada

Abstract The Eagle’s Nest Ni-Cu-(platinum group element; PGE) deposit occurs within the 2.73 Ga Esker intrusive complex of the Ring of Fire intrusive suite in the McFaulds Lake greenstone belt of northern Ontario. Mineralization occurs along the northern margin of a formerly ~500-m-high, ~85-m-thick, >1,500-m-long subvertical structurally rotated blade-shaped dike composed of harzburgite, lherzolite, and wehrlite. Three sulfide textural facies are present (percentage as proportion of total mineralization): (1) disseminated (~5%), (2) net texture (~80%), and (3) semimassive to massive (~15%). Five subfacies of net texture have been identified: (1) bimodal olivine-bearing leopard net texture (~50%), (2) inclusion net texture (~5%), (3) orthopyroxene-bearing pinto net texture (<1%), (4) localized zones of disrupted net texture (~30%) containing 3- to 5-cm-thick zones of barren amoeboid crosscutting pyroxenite, and (5) fine-grained patchy net texture (~15%). All textural facies are characterized by typical magmatic pyrrhotite-pentlandite-chalcopyrite-(platinum group mineral) assemblages. Massive sulfides are localized in two embayments along the basal contact separated by a topographic high, grading upward to rare semimassive, laterally more continuous net-textured, and disseminated sulfides, with gradational contacts between all textures except massive. Similar mean ore tenors of different sulfide textural facies (Ni100 ~7.5, Cu100 ~4.8), suggest that the majority of the mineralization formed from similar magma compositions at similar magma/sulfide ratios, but the presence of different inclusion populations (peridotite, gabbro, chromitite) and the presence of disrupted net texture indicates that the olivine, inclusions, and sulfide melts accumulated from multiple pulses in a dynamic system. The smaller, blade-shaped, sulfide-rich, chromite-poor Eagle’s Nest body does not appear to be the feeder to the overlying larger, oblate, sulfide-poor, chromite-rich Double Eagle body. This highlights the need to understand the fluid dynamics of entire plumbing systems when exploring for these deposit types and the significance of smaller, more dynamic magmatic conduits as environments favorable for Ni-Cu-(PGE) mineralization.

Seismic Constraints on the Trompsburg Layered Igneous Intrusion Complex in South Africa Using Two Deep Reflection Seismic Profiles

The discovery and characterization of layered intrusions around the globe have been predicated to a large degree on the imaging capabilities of the reflection seismic method. The ability of this tool to detect mineralization zones and structural controls such as faults and folds has been critical in unlocking the economic potential of igneous complexes, most notably the Bushveld Complex in South Africa. In this study, we present novel seismic constraints on the lesser-known Trompsburg Complex in South Africa. Two yet-unpublished seismic profiles were conducted end-to-end in the early 1990s, with a southwest-to-northeast trend through the centre of the ∼2,400 km2 Trompsberg potential field anomaly in South Africa, attributed to a 1915 ± 6 Ma buried layered intrusion complex. The complex was first detected by magnetic and gravity measurements near the town of Trompsburg in 1939 and was subsequently confirmed as a layered intrusion by borehole cores drilled thereafter. The combined length of the two profiles is 108 km. Both profiles have been reprocessed and interpreted to further constrain the subsurface expanse of the Trompsberg Complex along the seismic traverse. Processing and interpretation of the seismic profiles were aided by a handful of studies found in the literature: stratigraphy and physical property measurements of borehole cores that were drilled into the complex in the 1940s; pre-Karoo (∼317 Ma) lithological maps that were constructed based on boreholes in and around the investigation area; and potential field maps of the intrusion area near the town of Trompsburg. Most of the seismic reflection energy is concentrated within the top 1 km in both profiles, where localized reflectors with strong amplitudes are observed, due likely to the dolerite sills that permeate the Karoo cover. These sills obstruct seismic illumination of underlying structures due to their high acoustic impedance contrast with the surrounding soft rock sediments, rendering underlying reflections challenging to identify and enhance. The base of the Karoo is confidently identified to be at an average depth of 1.5 km and several reflection packages have been identified thereunder. These are linked to Proterozoic supracrustals associated with the Witwatersrand, Ventersdorp, Transvaal/Griqualand West, and Kheis Supergroups, as well as the Trompsburg Complex that intruded into them. The geometry of the Trompsburg Complex along the seismic traverse has been constrained with a moderate degree of confidence. It comprises a series of 30° northeasterly dipping reflectors near its southwestern boundary, flat reflectors near its centre at the town of Trompsburg, and 45° southwesterly dipping reflectors near its northeastern boundary. The lateral sub-Karoo extent of the complex is 60 km and its total thickness is difficult to constrain due to lack of deep reflections, but is likely between 6.6 and 7.5 km. The complex subcrops against the Karoo cover except near the southwestern region, where it is overlaid by Waterberg Group sediments.

3D modeling of the Esker intrusive complex, Ring of Fire intrusive suite, McFaulds Lake greenstone belt, Superior Province: Implications for mineral exploration

A 3D geological model of the Archean Esker ultramafic–mafic intrusive complex of the Ring of Fire intrusive suite of northwestern Ontario (Canada) is presented, providing insight into the nature of its magmatic plumbing system and allowing for speculation on the formation of its valuable Ni-Cu-(PGE) and chromitite deposits. The 3D model was constrained by exploration drillholes and high-resolution aeromagnetic data, which allowed the interpretation of the broad internal structure of the intrusive complex and two shear zones, which define for a major part of their strike extent the contacts between ultramafic and overlying mafic intrusive rocks. Restoring the post-emplacement component of strike-slip displacement and subsequently rotating the intrusive complex back from its tilted to sub-horizontal orientation of emplacement, provides a three-dimensional rendition of a 14 km-long dominantly tabular-shaped intrusive complex. The complex is defined by intact basal intrusive contacts with localized keel-shaped ultramafic promontories parallel to a nearby blade-shaped magmatic conduit. The keels extend in a subparallel orientation to depths of up to 1 km into the underlying tonalitic rocks and coincide with significant offsets of the basal intrusive contact, leading to speculation that their intrusion may have been guided by pre-existing normal faults. Two of these magmatic conduits host Ni-Cu-(PGE) deposits/prospects that formed from gravitational segregation of sulfides. The chromitite deposits, hosted in ultramafic rocks at higher stratigraphic levels, were modeled based on drill hole assay data. Zones of dominantly massive to semi-massive chromitite were defined by the ≥ 35% Cr2O3 threshold, while intercalated sequences of chromitite in dunite/peridotite were defined by the ≥ 15% to ≤ 35% Cr2O3 percentage range. The 3D modeled surfaces fitted to these constraints exhibit ore zones with lateral extents from several hundreds of meters for massive bodies up to a maximum of 2 km for intercalated chromitite ore that are dominantly conformable to the layering of the ultramafic host rocks. The lack of lateral continuity of chromitite ore zones beyond this scale, suggests that the chromitite layers are not continuous along the entire strike extent of the Esker intrusive complex, which is consistent with bifurcations of the 3D modeled ore shells signifying pinch-outs of both the massive chromitite layers and the dunitic interlayers. This discontinuous distribution of chromitite ore resembles that in the stratiform deposits of the Stillwater Complex and may support recent models of mechanical segregation of chromitite from cotectic chromite-olivine slurries. Based on our 3D model, we propose that the Esker intrusive complex evolved as a series of individual intrusions that were emplaced during multiple magmatic pulses that eventually coalesced to form a composite ultramafic–mafic complex prior to being dissected and partly dismembered by post-ore shear zone deformation.

The roles of emplacement depth, magma volume and local geologic conditions in the formation of the giant Yulong copper deposit, Eastern Tibet

The relative importance of the oxidation state, water content, and copper and sulfur content of the causative magma in the formation of porphyry Cu deposits is hotly debated. The giant Yulong Cu deposit in Eastern Tibet, with proven reserves of 6.5 Mt Cu at 0.62%, is an example of an economically important porphyry deposit. We investigate the relative roles of factors and different processes controlling the formation of the ores. Zircon U-Pb age data and whole rock, amphibole and apatite major and trace element geochemistry are reported together with previously published data. The results indicate a focused sub-alkaline magma event at 41 Ma in the North Yulong district and contemporaneous mineralization between 41.0 and 40.9 Ma at Yulong. Among the Yulong intrusive complex, the causative K-feldspar granite porphyry with high K2O (up to 7 wt%) and SiO2 (∼70 wt%) contents and elevated Sr/Y ratios (70–90), is interpreted to be a product of fractional crystallization of the evolved sub-alkaline magma. When the Yulong deposit is compared with the global porphyry Cu deposits with similar metal endowment and coeval sub-economic intrusions and barren igneous rocks in the belt, we find that high oxidation states (ΔFMQ + 1.0∼+2.5) and water contents (∼4–6 wt%) coupled with elevated background Cu contents (∼40–120 ppm) in the causative magma are essential in the formation of porphyry Cu deposits. However, the porphyry Cu deposits have magmatic S concentrations (∼10–100 ppm; estimated from apatite SO3 contents) comparable to that of the barren igneous rocks, independent of the relative timing of apatite crystallization to fluid exsolution. Overall, these conditions are necessary but not sufficient alone to form a porphyry deposit. The economic porphyries commonly have shallower emplacement depths (∼4–5 km) which favor extensive fluid exsolution and larger magma volume (∼50–250 km3 at Yulong) which provide enough storage of ore elements than the barren igneous rocks. In the North Yulong district, extensive fluid exsolution is absent from the two sub-economic intrusions indicated by their relatively high and fixed oxygen fugacity and H2O and Cl contents in the magma evolution. In contrast, at Yulong, a local anticlinal structure provided a trap in which exsolved fluid from the magma was concentrated, and carbonate wall rocks triggered the efficient precipitation of metals during intense fluid-rock interactions and skarn alteration. Both are also critical processes in the formation of the giant Yulong Cu deposit.

Geodynamic Formation Conditions and Age of Granitoids from Small Intrusions in the West of the Yana–Kolyma Gold Belt (Northeast Asia)

Abstract We report results of geological, mineralogical-petrographic, geochemical, isotope-geochemical (Sm–Nd, Rb–Sr), and geochronological (U–Pb, 40Ar/39Ar) studies of acid and intermediate intrusive rocks (granodiorites, leucocratic granites, subalkaline granites, and subalkaline leucocratic granites, diorites, and quartz diorites) of the Bukeschen and Samyr small plutons in the western part of the Yana–Kolyma gold belt (northeast Asia). These rocks are combined with Late Jurassic (151–145 Ma) dikes of basic, intermediate, and acid compositions into a single complex of small intrusions. They intrude the Upper Triassic–Middle Jurassic terrigenous deposits of continental margin blocks in the eastern part of the Verkhoyansk–Kolyma folded area. Our new U–Pb data for zircon (SHRIMP-II) indicate that the Bukeschen and Samyr pluton granitoids formed in the Berriasian, at 144.5 and 143 Ma, respectively. The small-intrusion granitoids have geochemical and isotope (Sm–Nd and Rb–Sr) characteristics similar to those of Late Jurassic dikes of varying composition. Therefore, they can be united into a single complex of small intrusions generated from a mixed source with the participation of mantle (OIB- and E-MORB type), lower crust, and subduction components and with Paleoproterozoic–Mesoproterozoic Sm–Nd model age estimates for the magma sources. Late Jurassic–Early Cretaceous magmatic and postmagmatic events and cooling of the intrusions played an important role in the processes of gold localization in the western part of the Yana–Kolyma gold belt. This is reflected in two tectonothermal stages (accounting for closing temperatures of the U–Pb, 40Ar/39Ar, and Re–Os isotope systems for different minerals) estimated at 151–141 and 138–137 Ma. These results for the small-intrusion complex agree with the tectonic model of the evolution of an active continental margin (northeastern Siberia) in the Mesozoic era, whose final development stage in the Berriasian age saw the formation of mostly small granitoid plutons.

Experimental constraints on truly conjugate alkaline silicate – carbonatite melt pairs

Physical separation of immiscible carbonatites from CO2-bearing alkaline silicate melts is frequently invoked to explain the common presence of carbonatites in alkaline rock suites. We present new isobaric 1.0 GPa crystallization and liquid immiscibility experiments between 1250 and 925°C on chemically complex CO2-bearing subvolcanic basanitic, nephelinitic and nepheline-syenitic compositions from the intrusive complex on Brava Island, Cape Verdes. In the experiments, carbonatites exsolve from silicate melt along the basanite–nephelinite melt fractionation pathway throughout an unmixing temperature window from 1100 to 950°C. Liquid immiscibility is suppressed by 950°C by the onset of alkali-feldspathoid crystallization, which deflects the residual silicate melt away from the two-liquid field. While evolving along the two-liquid field boundary, silicate melt increases in SiO2 from 46 to 51 wt% and decreases in CaO / (Na2O + K2O) (by weight) from 0.83 to 0.12, reproducing the observed compositional array of alkaline silicate subvolcanic rocks from Brava. The conjugate carbonatite melts are moderately alkaline Ca-carbonatites with 5 to 9 wt% SiO2 and CaO / (Na2O + K2O) that decreases from 5.64 at 1100°C to 1.60 at 950°C. These coexisting silicate and carbonatite melt compositions show that previous high-pressure experimental studies have not yielded truly conjugate melt pairs, mainly due to the use of modified starting materials resulting in melt compositions too enriched in alkalis to match the natural alkaline silicate rock record.

A Study on Apatite from Mesozoic Alkaline Intrusive Complexes, Central High Atlas, Morocco

There are abundant phosphate mines in the High Atlas Mountains of Morocco. Gem-quality apatite is produced at the Anemzi deposit, but its associated gem mineralogy is relatively poorly studied. In this study, apatite from the Anemzi mine in Morocco was analysed using standard gemmological characterisation methods, including basic tests (hardness, relative density, microscopy, etc.), spectroscopic tests (infrared, Raman, and ultraviolet–visible spectroscopy), and chemical analyses (electron probe and laser ablation inductively coupled plasma mass spectrometry). This paper explores the gemmological characteristics of Moroccan apatites and the information on diagenesis recorded for apatites by comparing them with apatites from other sources. Apatite from the Anemzi deposit is an igneous fluorapatite. The relatively high Cl content of the apatite suggests that the magma in the area has a high Cl content, whereas the high Cl/F ratio may indicate that the deposit formed in a slab subduction environment. The characteristics of the major and trace elements indicate high oxygen and sulphur escapes in the apatite-forming magma.

New clues for magma-mixing processes using petrological and geochronological evidence from the Castelo Intrusive Complex, Araçuaí Orogen (SE Brazil)

Bimodal magmatism was recorded during the post-collisional stage that occurred during the Brasiliano/Pan-African cycle in the Araçuaí Orogen (southeastern Brazil) at ∼500 Ma. The Castelo Intrusive Complex (CIC) is a zoned post-collisional pluton in the orogen and is composed of monzogranites, granodiorites, quartz monzodiorites and diorites. CIC (∼100 km2) was emplaced along a regional lineament during the post-collisional stage of the orogeny and cut pre-collisional granitoids and metasedimentary sequences. In this work, a detailed petrographic study associated with data on U–Pb ages and Hf isotopic compositions of zircons from monzogranites, quartz monzodiorites and leucocratic dikes is presented to detail the geochronology, composition and context of CIC emplacement. Macroscale and microscale records show that several CIC lithotypes demonstrate the direct interaction of contemporaneous felsic and mafic magmas. U–Pb age dating of zircons (by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS)) reveal crystallization ages of 486 ± 6 Ma for quartz monzodiorites and 524 ± 5 Ma to 499 ± 4 Ma for monzogranites. The analyzed leucocratic dike at 426 ± 15 Ma represents a late magmatic pulse. Hafnium isotopic data show variable ƐHf(t) values (from −24.05 to +12.7) and depleted mantle model ages (TDM) of 2.71–0.64 Ga, indicating the involvement of distinctly different mantle and crustal sources. At least two crustal sources with different Hf isotope signatures were distinguished (TDM of 2.6–2.4 Ga and ƐHf(t) of −26 to −22; and TDM of 2.2–1.7 Ga and ƐHf(t) of −17 to −8). These results suggest that the rocks in this study were partially derived from Archean and Paleoproterozoic crust. The isotopic data also show TDM model ages ranging from 1.28 to 0.64 Ga, with highly positive ƐHf(t) values (from +1.6 to +12.7). These data suggest the existence of a mantle reservoir source for magma generation and for heat that induced crustal melting during the post-collisional stage of the Araçuaí Orogen.

Hydrothermal Vent Complexes Control Seepage and Hydrocarbon Release on the Overriding Plate of the Tyrrhenian-Ionian Subduction System (Paola Basin)

Active fluid seeps have been described in a wide range of geological environments and geodynamic contexts, which include continental shelves of non-volcanic passive margins and accretionary wedges. Fluids seeping in hybrid volcanic-sedimentary basins, characterized by the presence of magmatic intrusive complexes, have always received less attention. We detected and imaged dozens of distinct gas flares, as high as 700 m, on the continental slope of the Paola Basin in the southeastern Tyrrhenian Sea, at 550–850 m water depth. The sedimentary basin is surrounded by Pleistocene active and inactive volcanoes and volcanic-intrusive complexes, which formed in the back-arc basin of the Calabrian subduction zone, in response to subduction-induced mantle flow. Gas flares develop above pockmarks, craters and mud flows that form over and along the scarps of mound structures and correspond to seismic zones of free gas accumulation in the sub-seafloor. Here, methane-derived siderite shows enrichment in δ13C and δ18O isotopes likely related to methanogenesis and intermittent venting of deep-sourced CO2. Multichannel seismic reflection data showed that the gas flares develop in correspondence of doming and diapirism apparently originating from the top of the Messinian evaporites and nearby magmatic sills, that are present in the lower part of the Plio-Quaternary succession. These diapiric structures can be related to seafloor hydrothermal vent complexes fed by the igneous intrusions. Our data suggest that the vent complexes acted as fluid migration pathways and gas conduits, which at times are bounded by deep-rooted normal faults, leading to post-explosive near-surface microbial activity and seep carbonate formation. Fluids being mobilised by magmatism in the study area include: hydrocarbons and hydrothermal fluids generated at depth, interstitial water expelled during formation of polygonal faults. The close spatial correlation between seafloor seep manifestations, fluid migration pathways in the sub-surface involving part of the Messinian units and igneous features indicates that magmatic activity has been the main driver of fluid flow and can have a long-term effect in the southern Tyrrhenian Sea.

Long‐Distance Lateral Magma Propagation and Pamir Plateau Uplift

AbstractLong‐distance lateral magma propagation may reflect the complex interaction between regional tectonics and crustal uplift. Here, we report observations on the Taxkorgan intrusive complex (TIC) of the Central Pamir. TIC is a 70 km long, 10–18 km wide, north‐northwest–elongated body intruded into mid‐upper crust in parallel with, and close to, the Kongur Shan Extensional System. New zircon U‐Pb dating shows that syenite samples exhibit a clear younging pattern from south to north along the pluton axis within an interval between 11.5 and 10.3 Ma, which is interpreted as lateral magma propagation from a single feeder zone at its northwestern margin. The lateral magma propagation was caused by a combination of crustal rigidity differences, and a topography‐induced pressure gradient that is nearly orthogonal to the least compressive stress. We propose that long‐distance lateral magma propagation plays an important role in plateau expansion, restraining the thickness and elevation of the Pamir Plateau.

Petrogenesis and tectonic setting of the Pan-African Deng-Deng intrusive complex in the Lom series, Eastern Cameroon

The Deng-Deng intrusive complex belongs to the Central African Fold Belt (CAFB) in eastern Cameroon and includes granodiorite and diorite. Both rocks are classified as metaluminous to slightly peraluminous, high-K calc-alkaline, and I-type granitoids (A/CNK <1.1). Primitive mantle-normalized trace-element patterns display large-ion lithophile elements (LILE) enrichment, such as Rb, Cs, Ba and K, and depletion in high-field-strength elements (HFSEs), such as Nb, Ti, Ta and P. The studied rocks are enriched in LREEs relative to HREEs and exhibit weak negative Eu anomalies (Eu/Eu* = 0.61–0.92 and 0.59–0.67 for the granodiorite and diorite, respectively), suggesting active continental margin arc affinity. The emplacement temperatures of these granitoids are estimated between 775 and 806 °C. Combined with their diagnostic ratios (e.g., Th/Ta, Rb/Sr, Nb/La, and La/Sm), we propose that the Deng-Deng granitoids were sourced by mixing between mafic magma derived from the lithospheric mantle and felsic magma derived from partial melting of a lower crust in a convergent margin setting.

Isla San Pedro Nolasco as a Late Miocene intrusive record at the eastern margin of the Gulf of California: Insights from geological, geochemical and geochronological studies

Isla San Pedro Nolasco (ISPN) is a structural high bounded by inactive dextral oblique-slip faults in the east-central part of the Gulf of California rift zone and is composed of intrusive rocks not exposed on other Gulf of California islands. Here we present the reconnaissance results from geological mapping, as well as first geochemical and geochronological data for the ISPN intrusive complex. The intrusive rocks compose a sheet-like body of intermediate and felsic composition intruded by an intermediate and acidic dike swarm. All intrusive rocks (host and dikes) range in age from ca. 9 Ma to 10 Ma (40Ar/39Ar) and show a hydrous ferromagnesian mineral association (amphibole and biotite) with a calc-alkalic and transitional affinity. This hydrated mineralogical association has not been recognized in the coeval rocks along the onshore western margin of the North American plate (coastal Sonora). However, such hydrous mineralogical association is found in the coeval rift transitional volcanic rocks from the Baja California Microplate at Santa Rosalía and Bahía de Los Ángeles – Bahía de Las Ánimas. The ISPN continental block, at least 40 km long, has been pulled apart by transtensional faulting of the late Miocene Gulf of California shear zone before the westward migration of the North America-Pacific plate boundary at ca. 3–2 Ma. Eventually, ISPN became isolated as an island during the late Miocene flooding of the Gulf of California seaway.

Hysteresis parameters and magnetic anisotropy of silicate-hosted magnetite exsolutions

SUMMARYAnisotropy of remanent magnetization and magnetic susceptibility are highly sensitive and important indicators of geological processes which are largely controlled by mineralogical parameters of the ferrimagnetic fraction in rocks. To provide new physical insight into the complex interaction between magnetization structure, shape, and crystallographic relations, we here analyse ‘slice-and-view’ focused-ion-beam (FIB) nano-tomography data with micromagnetic modelling and single crystal hysteresis measurements. The data sets consist of 68 magnetite inclusions in orthopyroxene (Mg60) and 234 magnetite inclusions in plagioclase (An63) were obtained on mineral separates from the Rustenburg Layered Suite of the Bushveld Intrusive Complex, South Africa. Electron backscatter diffraction was used to determine the orientation of the magnetite inclusions relative to the crystallographic directions of their silicate hosts. Hysteresis loops were calculated using the finite-element micromagnetics code MERRILL for each particle in 20 equidistributed field directions and compared with corresponding hysteresis loops measured using a vibrating sample magnetometer (VSM) on silicate mineral separates from the same samples. In plagioclase the ratio of remanent magnetization to saturation magnetization (Mrs/Ms) for both model and measurement agree within 1.0 per cent, whereas the coercivity (Hc) of the average modelled curve is 20 mT lower than the measured value of 60 mT indicating the presence of additional sources of high coercivity in the bulk sample. The VSM hysteresis measurements of the orthopyroxene were dominated by multidomain (MD) magnetite, whereas the FIB location was chosen to avoid MD particles and thus contains only particles with diameters &amp;lt;500 nm that are considered to be the most important carriers of palaeomagnetic remanence. To correct for this sampling bias, measured MD hysteresis loops from synthetic and natural magnetites were combined with the average hysteresis loop from the MERRILL models of the FIB region. The result shows that while the modelled small-particle fraction only explains 6 per cent of the best fit to the measured VSM hysteresis loop, it contributes 28 per cent of the remanent magnetization. The modelled direction of maximal Mrs/Ms in plagioclase is subparallel to [001]plag, whereas Hc does not show a strong orientation dependence. The easy axis of magnetic remanence is in the direction of the magnetite population normal to (150)plag and the maximum calculated susceptibility (χ*) is parallel to [010]plag. For orthopyroxene, the maximum Mrs/Ms, maximum χ* and the easy axis of remanence is strongly correlated to the elongation axes of magnetite in the [001]opx direction. The maximum Hc is oriented along [100]opx and parallel to the minimum χ*, which reflects larger vortex nucleation fields when the applied field direction approaches the short axis. The maximum Hc is therefore orthogonal to the maximum Mrs/Ms, controlled by axis-aligned metastable single-domain states at zero field. The results emphasize that the nature of anisotropy in natural magnetite does not just depend on the particle orientations, but on the presence of different stable and metastable domain states, and the mechanism of magnetic switching between them. Magnetic modelling of natural magnetic particles is therefore a vital method to extract and process anisotropic hysteresis parameters directly from the primary remanence carriers.