ABSTRACT Black hole (BH) accretion discs formed in compact-object mergers or collapsars may be major sites of the rapid-neutron-capture (r-)process, but the conditions determining the electron fraction (Ye) remain uncertain given the complexity of neutrino transfer and angular-momentum transport. After discussing relevant weak-interaction regimes, we study the role of neutrino absorption for shaping Ye using an extensive set of simulations performed with two-moment neutrino transport and again without neutrino absorption. We vary the torus mass, BH mass and spin, and examine the impact of rest-mass and weak-magnetism corrections in the neutrino rates. We also test the dependence on the angular-momentum transport treatment by comparing axisymmetric models using the standard α-viscosity with viscous models assuming constant viscous length-scales (lt) and 3D magnetohydrodynamic (MHD) simulations. Finally, we discuss the nucleosynthesis yields and basic kilonova properties. We find that absorption pushes Ye towards ∼0.5 outside the torus, while inside increasing the equilibrium value $Y_\mathrm{ e}^{\mathrm{eq}}$ by ∼0.05–0.2. Correspondingly, a substantial ejecta fraction is pushed above Ye = 0.25, leading to a reduced lanthanide fraction and a brighter, earlier, and bluer kilonova than without absorption. More compact tori with higher neutrino optical depth, τ, tend to have lower $Y_\mathrm{ e}^{\mathrm{eq}}$ up to τ ∼ 1–10, above which absorption becomes strong enough to reverse this trend. Disc ejecta are less (more) neutron rich when employing an lt = const. viscosity (MHD treatment). The solar-like abundance pattern found for our MHD model marginally supports collapsar discs as major r-process sites, although a strong r-process may be limited to phases of high mass-infall rates, $\dot{M}\, \, \raise0.14em\rm{\gt }\lower0.28em\rm{\sim }\, \, 2\times 10^{-2}$ M⊙ s−1.
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