In this paper, we introduce the left multiplication operators on the Riordan group, and carry out a systematic study on them. By using these operators, we obtain a family H of infinite Riordan subgroups. This family includes not only some well-known subgroups, but also the subgroup families introduced recently in literature. Fundamental properties of the left multiplication operators and the subgroup family H are presented. The Riordan involutions and pseudo-involutions, the stabilizer subgroups in family H, and the n-th commutator subgroup of any subgroup in family H are studied. Some further applications of the left multiplication operators are also provided. In particular, we study a class of left multiplication operators which are closely related to the diagonal translation operator and the [m]-complementary operator, and enrich the theory of complementary Riordan arrays. Moreover, we introduce and study the higher-level lifts of Riordan arrays as well as the vertical and horizontal 1/m Riordan arrays. As a result, it can be found that the left multiplication operators provide a unified approach to numerous subgroups, operators and transformations of the Riordan group.
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