Commercial Refrigeration Research Articles

Methodology of Multiple-Criteria Decision Making for Selecting a Refrigerant to Be Used in Commercial Refrigeration Equipment

This paper presents the application of the multiple-criteria decision-making (SAW) method for selecting the optimum refrigerant for the refrigeration systems of commercial cooling equipment used in gastronomy furniture, which is paramount in storing food under optimal conditions. The analysis focused on comparing different refrigerants, including natural refrigerants such as R744 (carbon dioxide) and R290 (propane) and synthetic refrigerants such as R455A, R449A, and R452A. As a result of the analysis using the SAW method, the refrigerant R455A was found to be the best solution. This choice resulted from the consideration of various decision criteria, such as energy efficiency, environmental impact, operating costs, and technology availability. R455A stands out as a synthetic refrigerant that provides high energy efficiency with minimal environmental impact. Its use supports sustainability goals by reducing greenhouse gas emissions and electricity consumption, which is crucial given the modern regulatory requirements and environmental standards. This study offers a practical decision-making tool for commercial refrigeration equipment designers and manufacturers, supporting them while selecting the optimal technological solutions. The choice of refrigerant R455A addresses the need to integrate energy efficiency, environmental protection, and cost-effectiveness in the process of designing modern refrigeration systems for catering furniture.

Large cryogenic magnetocaloric effect in Na5Gd4F(SiO4)4

The adiabatic demagnetization refrigeration based on the magnetocaloric effect of magnetic materials has been regarded as an effective technology to attain sub-Kelvin temperature. In this article, the magnetic properties and MCE of Na5Gd4F(SiO4)4 compound are investigated. Due to the high Gd3+ ion/anion ligand ratio and weak magnetic interaction, Na5Gd4F(SiO4)4 exhibits a large magnetic entropy change of 49.6 J·kg−1·K−1 under magnetic field change of 0–7 T at 2.6 K, which surpasses the commercial magnetic refrigerant Gd3Ga5O12 under the same conditions. Besides, its refrigeration capacity and the relative cooling power under magnetic field change of 0–7 T reaches up to 308.9 J·kg−1 and 406.7 J·kg−1, respectively. These properties indicate that Na5Gd4F(SiO4)4 compound is a promising magnetic refrigeration material.

Exploring the potential of biomass-derived carbons for the separation of fluorinated gases with high global warming potential

The development of advanced and innovative biomaterials with porous structural characteristics for the capture of fluorinated gases (F-gases) is important to contribute to the reduction of emissions of these gases with very high global warming potential. In this work, four biocarbons (CC-1:3H3PO4, CC-1:1H3PO4, CC-K2CO3 and CC-CO2) were produced by chemical and physical activation of corn cob biomass (CC). The adsorption equilibria of difluoromethane (R-32), pentafluoroethane (R-125), 1,1,1-tetrafluoroethane (R-125), 1,1,2-tetrafluoroethane (R-134a), sulphur hexafluoride (SF6), and nitrogen (N2) on these biocarbons were determined at 303.15 K. The highest adsorption capacities were obtained for CC-K2CO3 and CC-CO2 and a full characterization was also performed for these biomaterials at 283.15 and 323.15 K. On the other hand, the selectivities of SF6/N2 and the commercial refrigerants R-410A, R-407C, and R-407F were estimated using the Ideal Adsorption Solution theory (IAST). The results obtained for SF6/N2 show that the biocarbon CC-K2CO3 stands out from the other materials. In addition, the CC-CO2 shows a preference for R-32 over R-125 for the separation of the R-410A. Finally, CC-K2CO3 has a greater preference for R-134a over R-32 and R-125 in the R-407C and R-407F blends. Overall, these novel biocarbons improve the separation and purification of the F-gases under study, facilitating their application on a pilot scale.

Enhancing circular economy of waste refrigerants management using deep eutectic solvents

The use of fluorinated gases (F-Gases) in the refrigeration industry is subjected to increasingly restricted laws, such as the F-Gas regulation 517/2014 in Europe, due to their high global warming potential (GWP). Currently, there is a lack of standardized recovery technologies, so most of the F-gases used to be incinerated at the end of their life cycle. This is contrary to the principles of circular economy and development of sustainable processes, which should consider the recycling of these gases. The difficult separation of F-Gases blends might have a solution on the use of Deep Eutectic Solvents (DES) as green absorbents. In this work, the performance of a DES was assessed for the recovery of pentafluoroethane (R-125) and difluoromethane (R-32) from the commercial refrigerant R-410A combining a dual approach based on the experimental measurement of the F-Gases absorption in the DES and on process simulation using Aspen Plus. The environmental impacts of the designed recovery process (circular economy scenario) were examined using a life cycle assessment (LCA) approach and it was compared to the environmental impacts of the industrial manufacture of R-125 (lineal economy scenario). In comparison to the conventional R-125 production, the results of the proposed recovery process revealed a significant reduction in the environmental impacts between 92 and 99% with a recovery of R-125 of 76.7%, acceptable for its further reuse (purity of 98% w/w). The results of this work could pave the way for developing innovative F-Gases recovery technologies using DES, which can contribute to reduce the environmental impacts of these compounds via circular economy strategies.

Scaling up gaseous chlorine dioxide (ClO2) treatment in the cold storage of fresh apples

Novel interventions are needed to mitigate microbial risks, like Listeria monocytogenes, before shipping fresh apples to retail markets. Batch gaseous chlorine dioxide (ClO2) in-storage treatments were conducted to assess the inactivation of Listeria innocua, reduction of spoilage microorganisms, and changes in quality. Gaseous ClO2 was generated using equal amounts of dry precursors inside the modified commercial refrigerator with 82 kg and 330 kg apples for pilot and semi-industrial scale experiments, respectively. A cocktail of L. innocua was spot inoculated on the calyx of fresh Fuji apples and treated with an initial ClO2 input of 1.2 g of each precursor/kg of produce at a pilot scale for 30 d and semi-industrial scale for 90 d. Headspace ClO2 concentrations, temperature, and relative humidity were measured during the batch treatments. Reductions of 1.4±0.2 and 1.2 log CFU/mL of Listeria innocua were achieved by pilot-scale and semi-industrial scale trials, respectively. The presence of spoilage microorganisms was not significantly (P>0.05) impacted, and apples displayed no signs of deterioration. This study confirms that ClO2 can significantly inhibit foodborne pathogens, such as Listeria, during prolonged cold storage and reduce the risk of contamination for apple growers.

Analysis of refrigerants used in supermarket commercial equipment and the potential for increasing energy efficiency and reducing environmental impact

Refrigerants used in the commercial equipment of supermarkets are the object of the research. The Montreal Protocol calls for a complete phase-out of hydrochlorofluorocarbons (HCFCs) by 2030, and the Kigali Amendment regulates the use of hydrofluorocarbons (HFCs) from 2019. Developed countries began phasing out HFC use in 2019, while developing countries plan to freeze HFC consumption from 2024. These global efforts are aimed at reducing the depletion of the ozone layer and combating climate change. The number of supermarkets in the world varies greatly: in Europe they number from 110 thousand to 115 thousand, and in China – from 65 thousand to 70 thousand, which reflects various needs in refrigeration equipment. Stringent environmental regulations are forcing the commercial refrigeration sector to remain globally competitive. Modernization of supermarkets using natural refrigerants is important for solving emerging challenges. The results of the study show significant improvements in energy efficiency ratio (EER) and coefficient of performance (COP) when using a mixture of hydrocarbons (R290: 85 %, R600a: 15 %) compared to traditional refrigerants R404a, R449a and R502. Specifically, at the evaporation temperature of Tevap=–10 °C, EER increased by 38–44 % and COP by 26–31 % compared to R404a and R449a, respectively. At Tevap=–25 °C, EER increased by 17–34 % and COP by 2–22 % compared to R404a and R449a. Additionally, compared to R502, the hydrocarbon blend showed a 38–44 % increase in EER and 28–31 % COP at Tevap=–10 °C, and a 17–34 % increase in EER and 5–22 % COP at Tevap=–25 °C. These results highlight the advantages of the hydrocarbon mixture at different evaporation temperatures, indicating its potential to improve energy efficiency in refrigeration applications. The obtained data suggest the possibility of a wider application of the mixture of hydrocarbons in commercial refrigeration plants, offering both improved performance and compliance with safety regulations.

Shifting to low GWP alternatives in commercial refrigeration

Shifting to low GWP alternatives in commercial refrigeration

Polymer‐based supporting materials and polymer‐encapsulated phase change materials for thermal energy storage: A review on the recent advances of materials, synthesis, and characterization techniques

AbstractPhase change materials (PCMs) can be classified as smart materials having its applications in varied fields like domestic and commercial refrigerators, solar absorption chillers, air conditioning, free and radiative cooling, solar air heaters, solar stills, solar absorption cooling, electric and electronic devices for cooling purposes and in textiles. Here, in this review, the various polymer‐based and encapsulated PCMs used for fulfilling the above applications are discussed along with their varied synthesis/fabrication methods. Furthermore, chemical characterization is discussed by FTIR for understanding the chemical structure along with functional groups present in the materials. The thermogravimetric analysis (TGA) is also critically discussed for understanding the thermal stability of the Polymer PCM or the phase change composites and the latent heat of PCM melting was also explored by differential scanning calorimetry (DSC) for various PCM which gives insight into the thermal energy storage capability and property. The inbuilt surface structure of the polymer PCM was also tried to be investigated by scanning electron microscopy (SEM) which when understood gives a clear picture about the structure–property relationship.Highlights Polymeric supporting materials and polymer encapsulation on PCM were reviewed. The materials used and the synthesis of polymeric PCM were studied in depth. Chemical characterization was reviewed for chemical structure. Thermal stability checks by TGA and latent heat prediction was done by DSC. Morphology was reviewed using SEM for the structure–property relationship.

Structure, magnetism and magnetocaloric properties in performance GdClWO4 compound

Rare earth elements possessing a diverse range of optical, electrical, and magnetic properties has attracted more attention. In the present work, GdClWO4 compound with monoclinic structure was prepared, the structure, magnetism and magnetocaloric effect (MCE) were investigated. The magnetic phase transition temperature (TN), magnetic ground state and maximum magnetic entropy change (−ΔSMmax) were derived from magnetization measurements. Both first principles calculation and experimental results suggest that the compound displays antiferromagnetic (AFM) interactions, with a magnetic transition occurring at 0.6 K, shifting from a paramagnetic (PM) state to an AFM state. The −ΔSMmax is up to 35.2 J kg−1 K−1 (205.9 mJ cm−3 K−1) for GdClWO4 at T = 1.3 K under a magnetic field change of 0–50 kOe. In particular, the volumetric magnetic entropy change still remains 83.1 mJ cm−3 K−1 at 0.5 K and μ0ΔH = 20 kOe, which is almost twice as much as that of commercial refrigerant Gd3Ga5O12 (GGG) under μ0ΔH = 20 kOe, establishing GdClWO4 compound as a potential candidate for cryogenic refrigeration applications.

A cryogenic magnetic refrigerant: Magnetocaloric study of EuB2O4 compound

Adiabatic demagnetization refrigeration (ADR) technology has the advantage of not relying on helium-3 resources and gravity compared to traditional ultra-low temperature refrigeration technology. The key to the development of ADR technology is finding magnetic refrigeration materials with brilliant magnetocaloric properties. In this study, polycrystalline EuB2O4 was successfully prepared by solid-phase reaction method. The analysis of magnetic susceptibility curves and first-principles calculations reveals a magnetic phase transition from antiferromagnetic (AFM) to paramagnetic (PM) of EuB2O4, with TN = 0.72 K. The magnetic entropy change (-ΔSM) is evaluated up to 5 T, with the maximum value of 19.4 J·kg−1K−1 (88.7 mJ·cm−3K−1), 35.0 J·kg−1K−1 (160.0 mJ·cm−3K−1) and 50.8 J·kg−1K−1 (232.2 mJ·cm−3K−1) at around T = 1.3 K and under μ0ΔH = 1 T, 2 T and 5 T, respectively, which were significantly higher than those of the commercial magnetic refrigerant Gd3Ga5O12. The large -ΔSM suggest that EuB2O4 is a potentially great magnetic refrigerant for obtaining ultra-low temperature.

A Modeling-Based Flammable Risk Treatment of Refrigerant Leakage from a Commercial R-290 Refrigeration Machine

Because of serious concerns about global warming, manufacturers have started phasing out high global warming potential (GWP) refrigerants in commercial refrigeration equipment (e.g., R-134a). As a potential replacement, propane (R-290) is an environmentally friendly refrigerant for commercial refrigeration equipment because its GWP is only three. However, propane is flammable and is therefore classified as a Class A3 refrigerant per ASHRAE Standards, so safety is a very important consideration when propane-based equipment is designed and deployed in buildings. In the event of a refrigerant leak, flammability of the refrigerant depends on the refrigerant’s local concentration, which is highly affected by the indoor air environment, including temperature and air flow. In this study, a ventilation system attached to a commercial R-290 refrigeration device was designed to eliminate the flammability risk. Moreover, a computational fluid dynamics (CFD) model was developed to investigate the refrigerant leak, thereby evaluating effects of the ventilation system. The CFD model can visualize the flammable zones owing to the leak.

Cooling and heating innovations: exploring the diverse applications of heat pumps

Heat pumps are versatile and energy efficient devices that play a crucial role in modern heating, cooling, and refrigeration applications. This paper provides a concise overview of the diverse applications and benefits of heat pumps across residential, commercial, industrial, and transportation sectors. The paper discusses the principles of heat pump operation, emphasizing their capability to transfer heat from one location to another using thermodynamic processes. The work highlights key applications such as residential heating, ventilation, and air conditioning systems, commercial refrigeration, hot water heating, process cooling, and renewable energy integration. The energy efficiency and environmental benefits of heat pumps are also emphasized, showcasing their potential to reduce carbon emissions and contribute to sustainable energy practices. By understanding the broad scope of heat pump applications outlined in this work, researchers, engineers, policymakers, and industry stakeholders can gain insights into the significance of heat pump technology in advancing energy efficiency and addressing climate change challenges.

Metallic local-moment magnetocalorics as a route to cryogenic refrigeration

Commercial adiabatic demagnetisation refrigerators still employ the same hydrated salts that were first introduced over 85 years ago. The inherent limitations of these insulating magnetocalorics – poor thermal conductivity at sub-Kelvin temperatures, low entropy density, corrosiveness – can be overcome by a new generation of rare-earth based metallic magnetocalorics. Here, we present the metallic magnetocaloric YbNi1.6Sn as an attractive alternative to conventional refrigerants. YbNi1.6Sn retains high entropy into the 100 mK regime and avoids the noble metal constituents of alternative refrigerants. Demagnetisation tests demonstrate that YbNi1.6Sn enables economical and durable alternatives to traditional cooling devices for temperatures reaching below 120 mK. We find that the magnetocaloric properties of this material are facilitated by unusually small Kondo and RKKY interactions, which position YbNi1.6Sn in the extreme local moment limit on the generalised Kondo lattice phase diagram.

Dynamic acoustic optimization of pulse tube refrigerators for rapid cooldown

Pulse tube refrigerators are a critical enabling technology for many disciplines that require low temperatures. These refrigerators dominate the total power consumption of most modern cryostats, including those that reach millikelvin temperatures using additional cooling stages. In state-of-the-art commercial pulse tube refrigerators, the acoustic coupling between the driving compressor and the refrigerator is fixed and optimized for operation at base temperature. We show that this optimization is incorrect during the cooldown process, which results in wasted power consumption by the compressor and slow cooldown speed. After developing analytic expressions that demonstrate the need for acoustic tuning as a function of temperature, we dynamically optimize the acoustics of a commercial pulse tube refrigerator and show that the cooldown speed can be increased to 1.7 to 3.5 times the original value. Acoustic power measurements show that loss mechanism(s)—and not the capacity of the compressor—limit the maximum cooling available at high temperatures, suggesting that even faster cooldown speeds can be achieved in the future. This work has implications for the accessibility of cryogenic temperatures and the cadence of research in many disciplines such as quantum computing.

Assessment of booster refrigeration system with eco-friendly working fluid CO2/halogenated alkene (HA) mixture for supermarket application around the world: Energy conservation, cost saving, and emissions reduction potential

For the scope of commercial supermarkets, the demand for energy efficiency improvement and environmentally-friendly working fluid of the refrigeration system is necessary. In this study, supermarket booster refrigeration system by using eco-friendly working fluid CO2/halogenated alkene (HA) mixture is proposed, and the mixture used in systems with two evaporation temperatures and operating modes affected by ambient temperature are studied. The energy efficiency, economic performance and emission reduction potential of the whole life cycle are conducted to compare with the pure CO2 booster refrigeration system. Furthermore, the influence of climate condition is discussed when used in 40 typical cities around the world. The results show the coefficient of performance (COP) of booster refrigeration system can be significantly improved by using CO2/HA mixtures. As the ambient temperature is 33 °C, the CO2/R1234yf (93/7) operates with the maximum COP of 1.367, which is 11.59 % higher than that of pure CO2. Using CO2/HA mixtures in the booster refrigeration system can significantly improve the exergy efficiency of system. Moreover, the system using CO2/HA mixtures has higher annual performance factor and lower life cycle cost (LCC) than pure CO2. LCC of the system using CO2/R1234yf (94/6) is the lowest, and the reduction rate is 3.06–5.59 %. Meanwhile, the life cycle carbon emissions of systems in different climatic regions using CO2/R1234yf can be reduced by 2.39–5.21 %. The booster refrigeration system adopting CO2/HA mixtures is a promising alternative solution for commercial supermarket refrigeration and energy-saving.

Investigation of environmentally friendly new generation refrigerant R471A instead of R404A in low and medium temperature commercial refrigeration system

Hydrofluorocarbon (HFC) refrigerants (such as R134a and R404A), which are widely used in commercial refrigeration systems, contribute greatly to global warming. Because the global warming potential (GWP) values of HFC refrigerants are high. With increasing concerns about the environment (global warming, climate change, etc.) various legal regulations have been made to limit or phase out the use of refrigerants with high GWP values. To use the R471A refrigerant developed by Honeywell in 2022 as an environmentally friendly new-generation refrigerant in the commercial refrigeration system, the performance of the R471A refrigerant should be comprehensively evaluated. In this study, energy, exergy, and environmental analyses of using R471A refrigerant instead of R404A in low and medium-temperature commercial refrigeration systems were carried out and presented. Evaporator temperatures of − 30 °C, − 25 °C, − 20 °C, − 15 °C and − 10 °C and condenser temperatures of 30 °C, 40 °C, and 50 °C were selected to represent low and medium cooling temperatures and hot and cold country seasons. It was seen that R471A presents a lower mass flow rate (between 67 and 71%) and cooling capacity (between 61 and 68%) than R404A however has higher COP (between 6% and 14%) and R404A has exergy efficiency value of 6–14% lower than R471A. Also, from an environmental point of view, R471A has better environmental results than R404A.

Assessing the environmental performance of optimized commercial refrigerators with alternative refrigerants and remote monitoring system: A cradle-to-grave life cycle assessment

Refrigerators, as other cooling systems, are responsible for a significant parcel of anthropogenic emissions since they are essential and heavy appliances that use energy during its lifespan and are loaded with refrigerant gases. Three types of commercial refrigerators and their new versions, with incorporated CO2 as refrigerant gas and an wireless system for maintenance monitoring (WSMM) were investigated to evaluate how optimization could impact on the environmental performance during their entire life cycle. This study conducted a comprehensive Life Cycle Assessment (LCA) of the refrigerators, from the production to their end-of-life. The findings revealed that the use phase and the raw materials were responsible for most of the environmental impact throughout the refrigerators' life cycle. Key impact categories such as Fossil Resource Scarcity, Freshwater Eutrophication, and Global Warming were particularly affected, largely due to the electricity mix in the use phase. Additionally, the extraction and production of raw materials, specifically steel and copper, made significant contributions to Terrestrial Ecotoxicity and Human Carcinogenic Toxicity categories. The optimization measures impacted mainly in the energy consumption during the use phase, resulting in a notable reduction of approximately 57 % for models that underwent refrigerant change and 60 % for the model that underwent both refrigerant change and electronic system installation. As a result of decreased energy consumption, there was a significant decrease of 13 %–16 % across all impact categories, underscoring the positive environmental implications of these optimization strategies.

Theoretical Investigation of Low Global Warming Potential Blends Replacing R404A: The Simple Refrigeration Cycle and Its Modifications

Abstract R404A refrigerant is one of the most widely used hydrofluorocarbons in the commercial refrigeration industry for low and medium temperatures. However, this refrigerant contributes negatively to the environment due to its high global warming potential (GWP = 3943), and for several years, it has been labeled as one of the refrigerants that should be phased out. The present study theoretically evaluates low-GWP refrigerants as a replacement alternative to R404A, including R407H, R442A, R449A, R454A, R454C, R455A, R459B, and R465A. The analysis focuses on the comparison between relative differences in the volumetric flow in the compressor suction and the coefficient of performance for four configurations of the vapor compression cycle, such as the basic cycle, the cycle with an internal heat exchanger, the cycle with direct injection, and the cycle with a sub-cooler. According to the proposed operating conditions of evaporation temperature (−10 °C and −40 °C) and condensation temperature (40 °C and 55 °C), R454A could be the best long-term replacement option for its low GWP, energy performance, and direct fit for any configuration. R459B could also be considered a viable option, but with certain design modifications. On the contrary, the refrigerants R465A, R455A, and R454C would be discarded because they present a greater non-adaptation to the compressor in each configuration analyzed.

Colossal Barocaloric Effect of Binary Fatty Acid Methyl Esters under Low Pressures near Room Temperature.

Refrigeration technology based on the caloric effect is one of the more environmentally friendly alternatives to gas compression refrigeration. The barocaloric effect utilizes pressure to induce phase transition and results in a large entropy change. In this work, a colossal barocaloric effect in the liquid-solid transition (L-S-T) of binary fatty acid methyl esters (BFAMEs) was discovered. At 295 K, an isothermal entropy change as high as 591 J kg-1 K-1 and a reversible entropy change of 356 J kg-1 K-1 at a hydrostatic pressure of 80 MPa were obtained by mixing methyl palmitate and methyl stearate with a specific ratio to synthesize a BFAME. The value of the isothermal entropy change of the BFAME is comparable to that of a commercial gas compression refrigerant, R134a. This work will provide a new L-S-T candidate material to replace commercial refrigerants for the potential application of caloric effect refrigeration technology.

Functional properties of cream and butter oil from milk of Holstein cows abomasally infused with increasing amounts of high-oleic sunflower fatty acids.

This research paper addresses the hypothesis that there is an optimal amount of intestinally available oleic acid (provided via abomasal infusion) to produce higher-oleic acid milk fat with satisfactory functional characteristics of cream and butter oil. A control and four increasing doses of free fatty acids from high oleic sunflower oil (HOSFA) were infused into the abomasum of four lactating dairy cows in a crossover experimental design with 7-d periods. Treatments were: (1) control (no HOSFA infused), (2) HOSFA (250 g/d), (3) HOSFA (500 g/d), (4) HOSFA (750 g/d), and (5) HOSFA (1000 g/d). All treatments included meat solubles and Tween 80 as emulsifiers. Viscosity, overrun and whipping time as well as foam firmness and stability were evaluated in whipping creams (33% fat). Solid fat content (from 0 to 40°C), melting point and firmness were determined in butter oil. Whipping time of cream increased linearly and viscosity decreased linearly as infusion of HOSFA increased. Overrun displayed a quadratic response, decreasing when 500 g/d or more was infused. Foam firmness and stability were not affected significantly by HOSFA. For butter oil, melting point, firmness, and solid fat content decreased as HOSFA infusion increased. Changes in 21 TG fractions were statistically correlated to functional properties, with 6-10 fractions showing the highest correlations consistently. Decisions on the optimal amount of HOSFA were dependent on the dairy product to which milk fat is applied. For products handled at commercial refrigeration temperatures, such as whipping cream and butter oil, the 250 g/d level was the limit to maintain satisfactory functional qualities. Palmitic acid needed to be present in at least 20% in milk fat to keep the functional properties for the products.